Power and Energy Commons^™

Performance Of Sulfur-Super Conductive Carbon Black Composite In Electrolyte Mixed With Room Temperature Ionic Liquid, Bo Zhang, Si-Ting Chen, Xue-Ping Gao

Journal of Electrochemistry

The sulfur-super conductive carbon black composite was prepared as cathode material of lithium/sulfur battery.The composite was characterized by scanning electron microscopy(SEM),X-ray diffraction(XRD),and electrochemical impedance spectroscopy(EIS).The sulfur composite shows a high discharge capacity and a good cycle performance in electrolyte mixed with 50% of room temperature ionic liquid.In particular,the discharge capacity of the composite was stabilized at 483.6 mAh/g after 50 cycles.

Electrochemical Properties Of Ni(Oh)2 Doped By Nio, Fei-Biao Chen, Bo-Rong Wu, Wei-Feng An, Zhao-Jun Yang, Feng Wu, Shi Chen

Journal of Electrochemistry

The Ni(OH)₂ cathode material of MH/Ni was doped by NiO,which behaves as a capacitor and can improve the charge-discharge rate capacity of Ni(OH)₂.The electrochemical properties of Ni(OH)₂ was characterized by charge-discharge curves and cyclic voltammetry.The results showed that the material had the best discharge property when doped by 5% NiO,and the discharge specific capacity could reach 310.1 mAh/g at 0.2 C rate and remianed 79.5% at 3 C rate.The difference oxidation and reduction potentials between the of the battery was 164 mV when the Ni(OH)₂ was doped by 5% NiO,which showed a good cyclic property.

Investigation Of Ceo2 As Cathode Electrocatalyst For Direct Borohydride Fuel Cell, Xue-Min Ni, Ya-Dong Wang, Mu Pan

Journal of Electrochemistry

The performance of CeO₂ as oxygen reduction electrocatalyst in direct borohydride fuel cell was investigated.The experimental results indicate that CeO₂ shows significant electrocatalytic performance for oxygen reduction and exhibits no observed promotion effect on hydrolysis or electro-oxidation of BH₄^-.The power density of experimental one-compartment fuel cell with CeO₂ as cathode electrocatalyst can reach a 67.8 mW·cm^-2 at room temperature.

Preparation And Electrochemical Behavior Of Li4Ti5O12 Nanosheets As Anode Material For Lithium Ion Battery, Yi-Fei Wang, Yu-Feng Tang, Zheng Qiu, Li Yang

Journal of Electrochemistry

Spinel lithium titanate(Li₄Ti₅O₁₂) nanosheets with a size range of 200 ～400 nm were synthesized by hydrothermal process from the amorphous hydrous titanium oxide precursors.The as-prepared products were characterized by X-ray powder diffraction(XRD),scanning electron microscopy(SEM) and transmission electron microscopy(TEM).The electrochemical behaviors of Li₄Ti₅O₁₂ electrode in conventional organic electrolyte and ionic liquid electrolyte were investigated by using cyclic voltammetry,galvanostatic charge-discharge and AC impedance techniques.The experimental results indicate that the as-prepared nanostructured Li₄Ti₅O₁₂,evaluated as anode material,exhibited good reversibility and cycle performance.It is expected to be a …

Synthesis Of High-Performance Lini1/3Co1/3Mn1/3O2 Cathode Materials Via Azeotropic Distillation Method, Sheng-An Xia, Li-Xia Yuan, Ze Yang, Zhao-Hui Wang, Yun-Hui Huang, Shuang Li, Wu-Xing Zhang, Ya-Bin Meng, Wei-Gong Zheng

Journal of Electrochemistry

Layered LiNi_1/3Co_1/3Mn_1/3O₂ is one of the most promising alternative materials for LiCoO₂ in lithium ion batteries due to its low cost,large capacity and excellent cyclability.In this paper,LiNi_1/3Co_1/3Mn_1/3O₂ was synthesized via azeotropic distillation method with isobutyl alcohol as an azeotropic agent.The structure and surface morphology were characterized by X-ray diffraction(XRD) and scanning electron microscope(SEM),respectively.The as-prepared LiNi_1/3Co_1/3Mn_1/3O₂ shows a layered α-NaFeO₂ structure;the particles are small and uniformly distributed.As compared with the sample prepared by traditional method,the present cathode material …

Electrochemical Behavior Of Co-Ru Composite In Alkaline Solution, Su-Mei Yao, Guo-Chun Li, Xue-Ping Gao

Journal of Electrochemistry

The electrochemical properties of Ru doped cobalt hydroxides synthesized via homogeneous chemical co-precipitation were investigated in 6 mol·L^-1 KOH solution by galvanostatic charge-discharge process and cyclic voltammetry(CV).It is demonstrated that Ru doped cobalt hydroxides exhibited good capacitive characteristic and high specific capacitance.The sample with a Co/Ru molar ratio of 8 /1 shows the optimized electrochemical performance,including capacitive property and discharge capacity.The microstructure and morphology of the obtained Ru doped hydroxides were characterized by X-ray diffraction(XRD) and scanning electron microscope(SEM).The amorphous structure of ruthenium dioxide nanoparticles and single-crystal structure of Co(OH)₂ platelets were confirmed.Based on a structure analysis and …

Electrosynthesis Of P-Aminobenzenearsenic Acid, Chun-An Ma, Qin-An Zheng, Qiang Zhou, Ying-Hua Xu

Journal of Electrochemistry

The electrochemical reduction of p-nitrophenyl arsonit acid to p-aminobenzenearsenic acid was studied using controlled-current electrolysis.The results showed that the yield of p-aminobenzenearsenic acid was determinated by the following factors:the concentrations of sulphuric acid,the amount of additive,temperature and the concentrations of p-nitrophenyl arsenic acid.The optimum electrolytic conditions were obtained to be is 10% H₂SO₄,1% NaCl,80 ℃,25 g/350 mL p-nitrophenyl arsenic acid and 10 A·dm^-2.The yield of arsanilic acid could be reached 64.7% under the optimum electrolytic conditions.

Electrocatalytic Reduction Of L-Cystine At Pb/Nanotio2 Film Electrode, Dao-Bao Chu, Feng Wang, Ying Xiao, Xue-Jiao Zhang

Journal of Electrochemistry

The nanoporous Ti-based TiO₂ films electrodes modified with Pb particles(Pb/nanoTiO₂) were prepared by using anodization and potentiostatic electro-deposition.The optimum deposition conditions were determined by comparing with various deposition potentials and time.The SEM analyses indicated that the TiO₂ films were homogeneous nanoporous structure,and the Pb particles well dispersed on the TiO₂ films.The L-cystine electrocatalytic activity reduction on the Pb/nanoTiO₂ film electrodes was investigated by cyclic voltammetry and Chronoamperometric curves.The results showed that this type of the electrode posseses high acticity and stability.

Cobalt-Doped Todorokite Prepared By Refluxing At Atmospheric Pressure As Lithium-Ion Battery Cathode, Rui-Qi Li, Chun-Hua Song, Chao Xu, Li-Xing Tu, Guo-Hong Qiu, Fan Liu

Journal of Electrochemistry

Cobalt-doped todorokites were prepared by refluxing at atmospheric pressure,and then charactered by X-ray diffraction(XRD),thermogravimetry(TG) and the analysis of chemical compositions.These measurements showed that all of the refluxing products were single phase of todorokites and the structure formulas were Mg_xCo_yMnO_z·nH₂O,where 0.18 ≤ x ≤ 0.22,0 ≤ y ≤ 0.24,2.10 ≤ z ≤ 2.53,and 0.35 ≤ n ≤0.73.The electrochemical characteristics of cobalt-doped todorokites were examined as lithium insertion hosts for cathodes in rechargeable lithium batteries.The first discharge capacity of undoped todorokite electrode was 211 mAh/g and the discharge capacity became 37 mAh/g after 30 …

Fabrication And Characterization Of The Ni-Scsz Composite Anodes With A Lscm-Ceo2 Catalyst Layer In Thin Film Sofc, Yun-Yun Wang, Bo Huang, Xin-Jian Zhu, Wan-Qi Hu, Qing-Chun Yu

Journal of Electrochemistry

Solid oxide full cell(SOFC) running directly on hydrocarbon fuels has attracted much attention in recent years. In this paper, a dual-layer structure anode was fabricated by tape casting and screen printing method. The addition of a LSCM-CeO₂ catalyst layer to the supported anode surface yielded better performance in ethanol fuel. The maximum power density reached 710 and 669 mW/cm² at 850 ℃ running on hydrogen gas steam and ethanol steam,respectively. No significant degradation in performance has been observed after 216 h of cell testing when the Ni-ScSZ13 anode was exposed to the ethanol steam at 700 ℃. Very …

2010 Spring Engr333 Project Assignment, Matthew K. Heun

ENGR 333

The Spring 2010 ENGR333 project assessed options for the design of a redundant data center for the Calvin campus.

I asked the students “What would it take to build a redundant data center at Calvin that is 30% more energy efficient than the existing data center?”

Note: Because I was on sabbatical in Fall 2009, ENGR333 was moved to Spring 2010.

Customer

The customer for this project was Calvin’s VP for finance Henry DeVries.

The Value Of Concentrating Solar Power And Thermal Energy Storage, Ramteen Sioshansi, Paul Denholm

Publications (E)

This paper examines the value of concentrating solar power (CSP) and thermal energy storage (TES) in four regions in the southwestern United States. Our analysis shows that TES can increase the value of CSP by allowing more thermal energy from a CSP plant’s solar field to be used, by allowing a CSP plant to accommodate a larger solar field, and by allowing CSP generation to be shifted to hours with higher energy prices. We analyze the sensitivity of CSP value to a number of factors, including the optimization period, price and solar forecasting, ancillary service sales, capacity value and dry …

Doe Request For Information (Rfi) De-Foa-0000153 Pv Manufacturing Initiative: Summary Report, National Renewable Energy Laboratory

Publications (E)

Clean Cities hosts a collection of tools on the exploring concepts for a “PV Manufacturing Initiative” to facilitate the development of a strong photovoltaic (PV) manufacturing industry in the United States. As an integral part this effort, and to inform the creation of a new funding opportunity in this area, DOE sought feedback from the PV industry.

This document summarizes the results of the PV Manufacturing Request for Information (RFI), DE-FOA-0000153. (See Attachment 1.) The RFI was posted on http://www.grants.gov on 4 September 2009 and the NREL Web site on 9 September 2009. Respondents were asked to submit RFI inputs …

Ab Initio Simulations Of Hydrogen And Lithium Adsorption On Silicene, Tim H. Osborn

Browse all Theses and Dissertations

The energies and temperature-dependent dynamics of hydrogen and lithium chemisorption on a silicon nanosheet, called silicene, were studied using density functional theory and molecular-dynamics (MD) simulations. Silicene has a buckled honeycomb structure, and has been fabricated as suspended monolayer sheets and nanoribbons in recent experiments. We calculated the adsorption energies of hydrogen and lithium on silicene for different adsorption ratios between 3.1% and 100%. The studies will clarify the characteristics of these novel and promising nanomaterials, and pave the way for their applications.

For Hydrogen, the adsorption energy had a maximum of 3.01 eV/H for complete hydrogenation, and decreased by …

Estimating The Yield Of Micro Wind Turbines In An Urban Environment: A Methodology, Keith Sunderland, Michael Conlon

Conference papers

Micro wind turbines currently have the majority share of micro (electricity) generation installations in Ireland. These technologies are being installed predominantly in rural environments, and current applications to the Distribution Services Operator (DSO) for connection of all types of micro generator stand at less than 500. Poor market dissemination of information and research findings compounded with poor options for spill payment - as well as onerous planning restrictions do not –it appears - create a platform conducive to encouraging development in this market.

This paper outlines the complexities associated with evaluating the wind resource within an urban environment and investigates …

Simulation Procedure For The Co-Optimization Of Photovoltaic Water Pumping Systems., Brian Norton

Articles

Abstract: Photovoltaic (PV)-powered centrifugal water pumping systems have been modelled based on field experience and analysis of long-term measured performance of several installed PV-powered water pumping systems. This paper presents detailed modelling of a PV array, an inverter, a three-phase induction motor, a centrifugal pump, a well, a storage tank, an overflow controller, and an integrated reverse osmosis desalination unit. The component models were validated using both laboratory measurements and long-term monitored data. All system components have been modelled separately, and the system was modelled in TRNSYS. The models are capable of simulating grid-connected, diesel-powered, and PV-powered water pumping systems, …

Design Of An Integrated Starter-Alternator For A Series Hybrid Electric Vehicle: A Case Study In Axial Flux Permanent Magnet Machine Design, Jessica L. Colton

Department of Electrical and Computer Engineering: Dissertations, Theses, and Student Research

This thesis details the design of an electric machine to perform as both a starter and alternator in a series hybrid electric vehicle. The focus of the work is on practical design aspects specific to single-sided axial flux permanent magnet machines with non-overlapped windings. First, a characterization of the rotor losses in these machine types is presented through experimental validation of finite element analysis estimates. The approaches taken to model the axial flux geometry, especially in two-dimensions, are detailed, and the difficult issue of validating the finite element analysis estimates with experimental data is addressed with a prototype 24-slot, 20-pole …

Near Infrared Photovoltaic Micro-Cell For Optical Fibre Based Power Harvesting, Gary Allwood

Theses : Honours

A photonic power system using a silicon or germanium based device as a photonic power converter was proposed. The properties of each device were investigated to determine the optimum structure, design, configuration and efficiency for power conversion. These included, but were not limited to, device geometry, doping concentration and the wavelength of the incident beam. Relevant inferences were made from the results obtained and compared to previous work. Currently, research into photovoltaic power converters is focused on the efficiencies of complex heterostuctures made from gallium-arsenide compounds. Here, the properties of a silicon device were investigated in detail as the predicted …

Fabrication Of Zinc Oxide Thin Films For Renewable Energy And Sensor Applications, Theresa Y. Hill

Browse all Theses and Dissertations

Progress in commercializing renewable energy technologies is being advanced by developments in Zinc Oxide material science. The photovoltaic cell, for example, generates electricity by receiving solar energy into the cell, generating electrons, and simultaneously transporting electrical charge out of the cell. Metals are capable of removing electrical charge but block transmission of sunshine. Glass and plastics are capable of transmitting sunshine but block the removal of electrical charge. Therefore an exterior layer that is both optically transparent and electrically conductive is desirable. Transparent conductive oxides (TCOs) are the ideal material for such applications since they are capable of both functions. …

Sulfur-Tolerant Catalyst For The Solid Oxide Fuel Cell, Bozeman Joe Frank Iii

Browse all Theses and Dissertations

JP-8 fuel is easily accessible, transportable, and has hydrogen content essential to solid oxide fuel cell (SOFC) operation. However, this syngas has sulfur content which results in a poisonous hydrogen sulfide that degrades electrochemical activity and causes complete SOFC failure in some cases. The goal is to synthesize and verify a cost-effective, catalyst supported on cerium oxide that either stabilizes ionic conductivity in the presence of hydrogen sulfide and/or is highly sulfur-resistant. After thorough computational analysis, it was concluded that the platinum-copper skin catalyst was the most cost-effective, sulfur-resistant catalyst. Experimental synthesis of copper, platinum, and platinum-copper skin catalysts supported …