Synthesis, Structure And Electrochemical Performance Of Na2Mnsio4/C Cathode Material For Na-Ion Batteries,
2015
State Key Lab of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China;
Synthesis, Structure And Electrochemical Performance Of Na2Mnsio4/C Cathode Material For Na-Ion Batteries, Shou-Ding Li, Jiang-Huai Guo, Yong Xie, Jin-Xiao Mi, Yong Yang
Journal of Electrochemistry
As a promising cathode material for sodium ion batteries, pure phase Na2MnSiO4/C nanocomposite was successfully synthesized by a sol-gel method with a citric acid as a complex agent. The as prepared material was characterized by XRD, FTIR, SEM and TEM techniques. XRD and Rietveld refinement results indicated that the sample was indexed as monoclinic structure with space group of Pn. It was observed by SEM and TEM that the obtained product consisted of micro-scaled secondary particles, which were composed of NaMnSiO4 nanocrystallites and amorphous carbon network. More importantly, the uniform carbon network in the …
Essentials For On-Campus Photovoltaic Charging Station(Pv-Cs): Grangegorman,
2015
Technological University Dublin
Essentials For On-Campus Photovoltaic Charging Station(Pv-Cs): Grangegorman, Ayda Esfandyari, Brian Norton, Michael Conlon, Sarah Mccormack
Conference Papers
As Light weight Electric Vehicles (LEVs) are gaining interest, Technological University Dublin (DIT) realises the value and application of these vehicles for short distance commutes around its newly built campus of “Grangegorman” located in inner Dublin city. Introduction of the campus Photovoltaic Charging Station (PV-CS) that generates clean electricity from the sun and charges the LEV’s batteries can help achieving Ireland’s 2020 targets on both national and international levels. This paper highlights the design essentials of on-campus PV-CS, via assessments of: LEV load consumption, vehicle tracking and sizing of the storage unit. The pattern for LEVs charging and load consumption …
Synthesis And Electrochemical Performance Of Mn3O4/Graphene Composites,
2015
State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China;
Synthesis And Electrochemical Performance Of Mn3O4/Graphene Composites, Shan-Shan Yang, Qian Zhang, Xiong-Gui Lin, Ming-Sen Zheng, Quan-Feng Dong
Journal of Electrochemistry
The Mn3O4/Graphene composites were synthesized by hydrothermal method with the in-situ redox reaction of graphene oxide (GO) and manganese acetate (Mn(Ac)2). The phase structures and morphologies of the materials were characterized by XRD, SEM and TEM. The XPS and IR techniques were used for studying the residual function groups of reduced graphene oxide (RGO). The electrochemical performances of the hybrids were tested in a coin cell. Results showed that the composites prepared with the addition of ammonia water (RM-A) have better performance. The graphenes in RM-A were better-reduced and the Mn3O4 …
Tungsten Carbide/Carbon Electrode Material Synthesized By Block Copolymer Template Method,
2015
State Key Laboratory Breeding Base for Green Chemistry Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310032, China;College of Chemical and Materials Science, Longyan University, Longyan 364000, Fujian, China;
Tungsten Carbide/Carbon Electrode Material Synthesized By Block Copolymer Template Method, Xiao-Ling Lang, Ye-Kun Jiang, Mei-Qin Shi, Ling-Zhi Kang, Chun-An Ma
Journal of Electrochemistry
At present, one of the major hurdles for commercialization of system with direct methanol fuel cell (DMFC) is still the requirement of a significant amount of platinum (Pt) catalyst to achieve an acceptable power density. Pt and Pt-based metals are expensive due to limited supplies. In order to find the catalyst alternative to the Pt metal, we selected tungsten carbide (WC) and its composites as the study object. We synthesized WC with carbon materials as the suitable support to modify the electronic structure and to increase the specific surface area of WC. In this study, tungsten carbide/carbon (WC/C) was prepared …
Mechanism Study On The Electrocatalytic Oxidation Of Acetylene To Oxalic Acid,
2015
College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China; Department of Chemistry, Taiyuan Normal University, Taiyuan 030031, China;
Mechanism Study On The Electrocatalytic Oxidation Of Acetylene To Oxalic Acid, Xiu-Li Song, Rui-Long Jia, Wen-Yan Dong, Zhen-Hai Liang
Journal of Electrochemistry
A new method of electrocatalytic synthesis oxalic acid from acetylene was explored and the synthesized oxalic acid was characterized by Ultraviolet-visible spectrophotometry (Uv-vis) and Infrared spectroscopy (IR). First-principles calculations were carried out to examine the adsorption of acetylene over the Pt(111) surface. The electrocatalytic oxidation behavior of acetylene has been investigated on a Pt electrode by cyclic voltammetry (CV) and steady-state polarization in Na2SO4 solution. The formation mechanism of oxalic acid in the Na2SO4 solution was proposed and the transfer coefficients of the reaction were calculated. The results show that acetylene molecule tends to …
Preparation And Enhanced Rate Capability Of Spinel Limn1.9Al0.1O3.95F0.05,
2015
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China;
Preparation And Enhanced Rate Capability Of Spinel Limn1.9Al0.1O3.95F0.05, Jun-Yan Hu, Meng-Meng Wang, Hong-Tao Liu
Journal of Electrochemistry
Spinel LiMn1.9Al0.1O3.95F0.05 cathode materials with good crystallinity were synthesized by a sol-gel process followed with a high-temperature solid reaction. The effects of partial substitution of Al for Mn, and F for O on the structure and the electrochemical performance were investigated. The results showed that LiMn1.9Al0.1O3.95F0.05 exhibited the same crystalline state as LiMn2O4, but much better electrochemical stability at higher rate cycling. As a result, LiMn1.9Al0.1O3.95F0.05 could maintain stable electrochemical lithium storage even suffering from …
Reaction Mechanisms Study Of Pb Electrodes In Sulfuric Acid And Sodium Sulfate Solutions By Eqcm,
2015
School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China;
Reaction Mechanisms Study Of Pb Electrodes In Sulfuric Acid And Sodium Sulfate Solutions By Eqcm, Xian-Ping Zou, Zong-Xuan Kang, Yu-Lan Huang, Dong Shu, Ya-Yun Zhong, Jun-Nan Hao, Yu-Qing Liao
Journal of Electrochemistry
Surface reaction processes of Pb electrodes were investigated in H2SO4 and Na2SO4 solutions by LSV, CV and EQCM. The results in the voltammogram and the mass change curve of the Pb electrode indicated that the oxide products of lead included PbSO4 and PbO·PbSO4 in sulfuric acid solution with a positive-going potential scan from -1.0 V to -0.4 V and then PbO·PbSO4 transformed into PbSO4. However, the oxide product of lead was only PbSO4 in sodium sulfate solution. The experimental results revealed that the acid solution is necessary for the …
An Investigation On Electrochemical Performance Of Supercapacitor Electrode Materials Prepared By Mno2 With Four Different Crystal Forms,
2015
School of Material Seience and Engineering, Nanchang Hangkong Universityv, Nanchang 330063, China
An Investigation On Electrochemical Performance Of Supercapacitor Electrode Materials Prepared By Mno2 With Four Different Crystal Forms, Zhen-Kun Wei, Xiao-Zhen Hua, Ke Xiao, Xian-Liang Zhou, Zhi-Guo Ye
Journal of Electrochemistry
Four types of α-MnO2, β-MnO2, γ-MnO2 and δ-MnO2 powders were synthesized by relatively simple methods. The differences in crystal structures and surface morphologies for these forms of MnO2 were investigated by using X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), thermogravimetric analysis (TGA) and specific surface area analysis (BET). The electrochemical performances were characterized by cyclic voltammetry (CV) and stability analysis. Based on the experimental results, four kinds of MnO2 electrodes showed good capacity properties, and the α-MnO2 electrode had the largest specific capacity due to the highest specific surface …
Effect Of Adsorption Potential On Co Oxidation At Au@Pt Nanoparticles Electrodes, A Surface Enhanced Raman Spectroscopic Study,
2015
Hefei National Laboratory for Physical Science at Microscale and Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, China;
Effect Of Adsorption Potential On Co Oxidation At Au@Pt Nanoparticles Electrodes, A Surface Enhanced Raman Spectroscopic Study, Pu Zhang, Yi Wei, Yong-Li Zheng, Yan-Xia Chen, Zhong-Qun Tian
Journal of Electrochemistry
The adsorption/oxidation of CO on the 55 nm [email protected] nm Pt nanoparticles electrode in both potentiodynamic and potentiostatic modes were investigated by surface enhanced Raman spectroscopy in a thin layer electrochemical flow cell under controlled mass transport, with the aim of clarifying the origin CO oxidation at lower electrode potentials (in current pre-wave region of corresponding cyclic voltammograms). Our results demonstrated that the CO oxidation kinetics differed significantly from the three kinds of different CO adsorption history, with almost no CO oxidation current in the pre-peak potential region after 0.35 VRHE CO adsorption with or without subsequent holding the …
Preparation And Characterization Of Carbon Supported Pd-Sb Composite Nanocatalysts For Formic Acid Electrooxidation,
2015
Key Laboratory of Shanghai Colleges and Universities for Corrosion Control in Electric Power System and Applied Electrochemistry, Shanghai University of Electric Power, Shanghai 200090, China;
Preparation And Characterization Of Carbon Supported Pd-Sb Composite Nanocatalysts For Formic Acid Electrooxidation, Long-Long Wang, Xiao-Lu Cao, Ya-Jun Wang, Jin-Hao Ping, Qiao-Xia Li
Journal of Electrochemistry
Palladium is considered as an efficient anode catalyst with high catalytic activity for electrooxidation of formic acid. To further improve the catalytic activity and stability, alloying or surface modification with Sb is an effective way. In this work, the well dispersed carbon supported Pd-Sb composite nanocatalysts (Pd-Sb/C) were synthesized by traditional impregnation reduction method with trisodium citrate as the complexing agent, sodium borohydride as the reducing agent. The morphologies of Pd-Sb/C and the effects of molar ratio of Pd to Sb on the electrocatalytic properties of Pd-Sb/C for HCOOH electrooxidation were studied. The XRD and XPS analyses on the as-prepared …
Effect Of Carbon Nanotubes On Anodic Properties Of Ti/Ru-Ir-Sn Oxides,
2015
Qingdao University of Science and Technology, Qingdao 266061, Shandong, China;State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute, Qingdao 266101, Shandong, China;
Effect Of Carbon Nanotubes On Anodic Properties Of Ti/Ru-Ir-Sn Oxides, Feng Lian, Yong-Lei Xin, Bo-Jiang Ma, Li-Kun Xu
Journal of Electrochemistry
The Ru-Ir-Sn metal oxide anodes coated on titanium (Ti/Ru-Ir-Sn) were prepared by thermal decomposition. The effects of amounts of carbon naotubes (CNTs) on anodic properties were studied by TGA, SEM, EDS, cyclic voltammetry, EIS, polarization measurements and accelerated life test. The thermogravimetric analysis and EDS spectrum data showed that the high temperature oxidation decomposition of CNTs did not take place under the condition of the sintering temperature of 470 ℃, and the CNTS still existed in the anode coating in an element form. Compared with the contrast samples, the surface crack of the coating increased, but remained typical morphology. Adding …
Research On The Application Of Solar Photovoltaic System On Large Ocean-Going Ships,
2015
World Maritime University
Research On The Application Of Solar Photovoltaic System On Large Ocean-Going Ships, Wanhe Huang
Maritime Safety & Environment Management Dissertations (Dalian)
No abstract provided.
Adaptive Online Transient Stability Assessment Of Power Systems For Operational Purposes,
2015
University of New Orleans
Adaptive Online Transient Stability Assessment Of Power Systems For Operational Purposes, Hussain Hassan Al Marhoon
LSU New Orleans Theses and Dissertations
Online stability assessment is an important problem that has not been solved completely yet. The purpose of this research is to tackle online transient stability assessment. Currently, most utility companies use step-by-step integration in order to set protective equipment so that they effectively work for critical contingencies. However, there are times an unforeseen contingency may occur which may cause the system to transit and the protective equipment to misoperate and does not isolate the disturbed part of the system. This research introduces a method that automatically determines a group of generators that participate in system separation and hence transient instability. …
Wireless Power Transfer To A Small, Remote Control Boat,
2015
Purdue University
Wireless Power Transfer To A Small, Remote Control Boat, Mark M. Oscai, Michael D. Sinanis, Abbas Semnani, Dimitrios Peroulis
The Summer Undergraduate Research Fellowship (SURF) Symposium
Over the past few decades, researchers have explored and implemented methods of wireless power transmission to operate devices that traditionally have been powered using plug-in power supplies and batteries. It is with this objective in mind that we built a boat, which is powered wirelessly from a field of harvestable energy. This project sought to develop a wirelessly powered remote control boat to be a proof of concept for the idea of wireless power transfer. Our criteria for success is that the boat should receive sufficient power to run anywhere in a 2.5 meter squared area. Having defined the field …
Simulation Design For Photovoltaics Using Finite Difference Time Domain And Quadratic Complex Rational Function Methods,
2015
Purdue University
Simulation Design For Photovoltaics Using Finite Difference Time Domain And Quadratic Complex Rational Function Methods, Jacob R. Duritsch, Haejun Chung, Peter Bermel
The Summer Undergraduate Research Fellowship (SURF) Symposium
Photovoltaics (PV) can in principle supply enough renewable energy to offset a great deal of fossil fuel usage. To achieve this transition, it is critical to develop improved PV cells with decreased material costs and improved efficiencies. This goal can be greatly facilitated by a tool simulating the absorption and efficiency of experimentally relevant 3-D PV designs made of realistic materials, including those that have not yet been discovered. By incorporating the quadratic complex rational function algorithm (QCRF) with the finite difference time domain methods (FDTD), simulations can include frequency response and optical properties, while allowing full customization of tandem …
Temperature Dependence Of Electrical Performance Of Tritium Sourced Betavoltaic Cells,
2015
Purdue University
Temperature Dependence Of Electrical Performance Of Tritium Sourced Betavoltaic Cells, Darrell S. Cheu, Tom Adams, Shripad Revankar
The Summer Undergraduate Research Fellowship (SURF) Symposium
There is an increasing need for devices that can be powered for extended periods of time where it is impossible for maintenance or replacement, such as pacemakers, long term space flight or undisturbed sensors for military use. Since 1971, most devices run off a Lithium-Iodide battery, which gives a high amount of power but could only last approximately 2 to 5 years, requiring frequent replacement. However, replacement is unnecessary for betavoltaic cells as they can last at least 20 years. Commercially available tritium betavoltaic cells provided by City Labs Inc. were tested at a temperature range of -50°C to 150°C …
Renewable Energy In Industrial Applications,
2015
Kennesaw State University
Renewable Energy In Industrial Applications, Seshi Reddy Kasu
Dissertations, Theses and Capstone Projects (Full IR Collection)
Manufacturing industry accounts for about one third of total energy use worldwide. Roughly three quarters of industrial energy use is related to the production of energy-intensive commodities such as ferrous and non-ferrous metals, chemicals and petrochemicals, non-metallic mineral materials, and pulp and paper. In these sectors, energy costs constitute a large proportion of total production costs, so managers pay particular attention to driving them down. As a result, the scope to improve energy efficiency tends to be less in these most energy intensive sectors than in those sectors where energy costs form a smaller proportion of total costs, such as …
The Future Of Rural Communities,
2015
Boise State University
The Future Of Rural Communities, Alondra B. Perez, Yanliang Zhang (Mentor)
Idaho Conference on Undergraduate Research
There is a problem in how modern energy is being distributed throughout the world; less than a quarter of the population have access to energy. Limited energy access is seen in rural areas because of the costs that comes from transporting material and making modern energy resources (solar panels, wind turbines, etc..). Through research on thermoelectric devices, there have been many theories tested in order to improve energy efficiency focusing on easy maneuverable resources. At Boise State’s Advanced Energy Lab, thermoelectric generators are being created and modified which can be used to help communities from rural areas power utilities needed …
Broadband High Efficiency Fractal-Like And Diverse Geometry Silicon Nanowire Arrays For Photovoltaic Applications,
2015
University of Arkansas, Fayetteville
Broadband High Efficiency Fractal-Like And Diverse Geometry Silicon Nanowire Arrays For Photovoltaic Applications, Omar Hassan Al-Zoubi
Graduate Theses and Dissertations
Solar energy has many advantages over conventional sources of energy. It is abundant, clean and sustainable. One way to convert solar energy directly into electrical energy is by using the photovoltaic solar cells (PVSC). Despite PVSC are becoming economically competitive, they still have high cost and low light to electricity conversion efficiency. Therefore, increasing the efficiency and reducing the cost are key elements for producing economically more competitive PVSC that would have significant impact on energy market and saving environment. A significant percentage of the PVSC cost is due to the materials cost. For that, thin films PVSC have been …
Current Status And Prospect Of Cathode Materials For Lithium Sulfur Batteries,
2015
Department of Chemistry, Institute of New Energy, Fudan University, Shanghai 200438, China;
Current Status And Prospect Of Cathode Materials For Lithium Sulfur Batteries, Lan Zhou, Ai-Shui Yu
Journal of Electrochemistry
Elemental sulfur has been extensively investigated as a promising candidate of cathode material for next generation lithium secondary batteries. However, some troublesome issues, such as the low electric conductivity of sulfur (5×10-30 S·cm-1) and the high solubility of lithium polysulfide intermediates in organic electrolytes, resulting in a low utilization of active material and a redox shuttling of dissolved polysulfide ions between the sulfur cathode and the lithium anode, which eventually leads to a deposition of insoluble and insulating Li2S2/Li2S on the electrode surface and a fast reduction in the specific capacity. …
