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Review For Applications Of "Lead Carbon" Batteries In Energy Storage System, Yong-quan MA, Ke KE, Da-ming GU 2015 Harbin Institute of Technology, Harbin 150001, Heilongjiang, China; Chilwee Power Co., Ltd., Changxing 313100, Zhejiang, China;

Review For Applications Of "Lead Carbon" Batteries In Energy Storage System, Yong-Quan Ma, Ke Ke, Da-Ming Gu

Journal of Electrochemistry

Three types of “lead carbon” batteries are introduced by comparing their advantages and disadvantages. Then their applications in energy storage system (ESS), especially in the field of renewable energy power generation, are discussed. The prospects and potential applications of “lead carbon” batteries in EES for electric power supply system are analyzed by combining the state-of-the-art techniques in this field.


Characterization Of The Separator With Thermal-Shutdown Layer For Use In Lithium Batteries, Li BAI, Yong-jian HUAI, Xin-ping AI, Hai JIA 2015 China Aviation Lithium Battery Co., Ltd., Luoyang 471003, Henan, China;

Characterization Of The Separator With Thermal-Shutdown Layer For Use In Lithium Batteries, Li Bai, Yong-Jian Huai, Xin-Ping Ai, Hai Jia

Journal of Electrochemistry

In this paper, the lithium ion battery coated with the thermal-shutdown functional layer has been introduced. The shutdown temperature of the separator could be decreased by using the melting point of thermal-shutdown functional layer. When the internal battery environment reached a critical temperature, the functional layer melted and coated the anode/separator with a non-conductive barrier, halting Li-ion transport and shutting down the cell permanently. The results showed that the functional layer did not affect the resistance, rate performance and cycle life. It was found the functional layer can significantly improve the safety of the battery when misused.


Impact Of Water Content On The Performance Of Lifepo4 Based Lithium-Ion Battery, Jun-ting NIU, Lin SUN, Shu-wen KANG, Zhen-wei ZHAO, Zi-feng MA 2015 Shanghai Electrochemical Energy Devices Research Center, Department of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China;

Impact Of Water Content On The Performance Of Lifepo4 Based Lithium-Ion Battery, Jun-Ting Niu, Lin Sun, Shu-Wen Kang, Zhen-Wei Zhao, Zi-Feng Ma

Journal of Electrochemistry

Through different dry conditions and measuring by moisture test instrument, cathode pole pieces with different water contents of 0.3‰ ~ 0.7‰ were obtained to prepare lithium-ion batteries. Cycling performance and high rate performance at 1C ~ 5C discharge rates were tested. Moreover, ASR performances of LiFePO4 base lithium-ion batteries after 200 cycles with different water contents were investigated by EIS. The results showed that the cycle performance and rate performance were closely related to the water content of the electrode. When the water content went up to 0.6‰ the cycle stability and rate performance fell. Meanwhile, the internal resistance and …


Effects Of Microstructures Of Active Material On Performance Of Vrla Battery, Lei JIANG, Shou-zhong YI 2015 Shenzhen Center Power Tech. Co., LTD, Shenzhen 518120, Guangdong, China;

Effects Of Microstructures Of Active Material On Performance Of Vrla Battery, Lei Jiang, Shou-Zhong Yi

Journal of Electrochemistry

The structure, morphology and content of the as-prepared and the processed samples were characterized by the means of SEM and XRD. The discharge capacities and cycle life performances of the as-prepared and the processed samples were tested by electrochemical measurements with different rates. The results indicated that the 4BS technology which can affect the plate design, deep cycle capability and cycle life is a basic technology for the VRLA batteries. It was also confirmed that the contents and structures of α-PbO2 and β-PbO2 formed with different processing conditions can affect the performance of the VRLA batteries, suggesting that …


Preparation And Performance Of Lithium-Rich Manganese Layered Materialsâ 0.6li[Li1/3Mn2/3]O2·0.4liniXMnYCo1-X-YO2(X < 0.6, Y > 0), Hai-Lan FENG, Ya-Fei LIU, Yan-Bin CHEN 2015 Beijing General Research Institute of Mining and Metallurgy, Beijing 100160, China;Beijing Easpring Material Technology Co. Ltd., Beijing 100160, China;

Preparation And Performance Of Lithium-Rich Manganese Layered Materialsâ 0.6li[Li1/3Mn2/3]O2·0.4liniXMnYCo1-X-YO2(X < 0.6, Y > 0), Hai-Lan Feng, Ya-Fei Liu, Yan-Bin Chen

Journal of Electrochemistry

Lithium-rich manganese based cathode materials 0.6Li[Li1/3Mn2/3]O2⋅0.4LiNixMnyCo1-x-yO2 (x < 0.6, y > 0) were synthesized by carbonate co-precipitation and high temperature solid-state reaction. The structures and morphologies of the as-prepared materials were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM). The results of high temperature in-situ XRD test show that the lattice parameters change significantly with increasing temperature and Ni content. The cation mixing gets serious and the spinel phase appears in the high Ni content samples when the temperature is up to 800 oC. Under voltages ranging from 2.0 to …


Performance Limiting Factors Of Cu2znsn(Sxse1-X)4 Solar Cells Prepared By Thermal Evaporation, Sandip Das, Raghu N. Bhattacharya, Krishna C. Mandal 2015 Kennesaw State University

Performance Limiting Factors Of Cu2znsn(Sxse1-X)4 Solar Cells Prepared By Thermal Evaporation, Sandip Das, Raghu N. Bhattacharya, Krishna C. Mandal

Faculty Articles

Cu2ZnSn(SxSe1−x)4 (CZTSSe) thin film solar cells have been prepared by vacuum-based thermal evaporation of metal and binary sulfide precursors followed by annealing in a mixed chalcogen vapor at 550 °C for one hour. The Zn/Sn ratio in the precursor was varied from 0.75 to 1.50 keeping the Cu/(Zn+Sn) ratio constant at 0.7. The best performing solar cell was obtained with a final film composition of Cu/(Zn+Sn)=0.77 and Zn/Sn=1.13 corresponding to a Zn/Sn ratio of 0.9 in the precursor. The champion cell exhibited an open-circuit voltage (VOC) of 506 mV, short-circuit current density (J …


Bidirectional Ac-Dc Converter For Vehicle-To-Grid (V2g) Applications, Arjun Raj Prabu Andhra Sridhar 2015 Marquette University

Bidirectional Ac-Dc Converter For Vehicle-To-Grid (V2g) Applications, Arjun Raj Prabu Andhra Sridhar

Master's Theses (2009 -)

Electric vehicles are growing at a rapid pace in the internal combustion engine dominated transportation sector, and bring environmental and economic benefits to society. Electric vehicles produce nearly zero carbon emission, provided that they are charged through renewable energy sources. Electric vehicles reduce our dependency on foreign oil and also offer additional benefits like Vehicle-to-grid (V2G). V2G is a technology that allows electric energy stored in the electric vehicle batteries to be returned to the grid during peak demand. V2G can also provide voltage regulation, voltage shaving, reactive power compensation and distributed generation. This necessitates that an electric vehicle battery …


Improving Operator Situational Awareness With Wide Area Geographic Data View Displays Of The Electric Power Grid, Esa M. Rantanen, Limor Hochberg, Diego Klabjan, Mingyang Di 2015 Rochester Institute of Technology

Improving Operator Situational Awareness With Wide Area Geographic Data View Displays Of The Electric Power Grid, Esa M. Rantanen, Limor Hochberg, Diego Klabjan, Mingyang Di

Articles

To reduce clutter on wide-area geographic data view displays of electric power systems, substations in geographically compact areas should be spread out and line overlaps and intersections minimized. Such pat- terns optimized with respect to given constraints can be modeled as a multicommodity flow problem. Due to the size of the developed model, we developed two clustering-based iterative algorithms to decompose the global network into smaller regions and then iteratively solve the subproblem in each region by readjusting some values. Three solutions were selected for experimental evaluation. The experimental results were somewhat inconclusive, due to naïve participants, simple task, and …


Accelerated Aging Test On Multiple Xlpe Mv Cables Simultaneously To Induce Water Trees, Shane Conlan, Jane Courtney, Tom Looby 2015 Technological University Dublin

Accelerated Aging Test On Multiple Xlpe Mv Cables Simultaneously To Induce Water Trees, Shane Conlan, Jane Courtney, Tom Looby

Conference papers

The objective of this paper is to develop an accelerated ageing test to induce water tree growth which is capable of testing up to ten 10 kV cable samples simultaneously. An existing accelerated ageing method was used as a basis for this project. This method uses a high frequency power supply (3 kHz) to achieve a test duration of 14 days. Modifications were made to this method to allow for multiple samples to be tested simultaneously. A specially designed variable inductor was utilised in a parallel RLC resonance circuit. This resonance circuit limits the current draw from a high frequency …


Modeling And Test Of The Efficiency Of Electronic Speed Controllers For Brushless Dc Motors, Clayton R. Green 2015 California Polytechnic State University, San Luis Obispo

Modeling And Test Of The Efficiency Of Electronic Speed Controllers For Brushless Dc Motors, Clayton R. Green

Master's Theses

Small electric uninhabited aerial vehicles (UAV) represent a rapidly expanding market requiring optimization in both efficiency and weight; efficiency is critical during cruise or loiter where the vehicle operates at part power for up to 99% of the mission time. Of the four components (battery, motor, propeller, and electronic speed controller (ESC)) of the electric propulsion system used in small UAVs, the ESC has no accepted performance model and almost no published performance data. To collect performance data, instrumentation was developed to measure electrical power in and out of the ESC using the two wattmeter method and current sense resistors; …


Fast Sequence Component Analysis For Attack Detection In Synchrophasor Networks, Jordan Landford, Rich Meier, Richard Barella, Xinghui Zhao, Robert B. Bass, Scott Wallace 2015 Portland State University

Fast Sequence Component Analysis For Attack Detection In Synchrophasor Networks, Jordan Landford, Rich Meier, Richard Barella, Xinghui Zhao, Robert B. Bass, Scott Wallace

Electrical and Computer Engineering Faculty Publications and Presentations

Modern power systems have begun integrating synchrophasor technologies into part of daily operations. Given the amount of solutions offered and the maturity rate of application development it is not a matter of "if" but a matter of "when" in regards to these technologies becoming ubiquitous in control centers around the world. While the benefits are numerous, the functionality of operator-level applications can easily be nullified by injection of deceptive data signals disguised as genuine measurements. Such deceptive action is a common precursor to nefarious, often malicious activity. A correlation coefficient characterization and machine learning methodology are proposed to detect and …


Synthesis, Structure And Electrochemical Performance Of Na2Mnsio4/C Cathode Material For Na-Ion Batteries, Shou-ding LI, Jiang-huai GUO, Yong XIE, Jin-xiao MI, Yong YANG 2015 State Key Lab of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China;

Synthesis, Structure And Electrochemical Performance Of Na2Mnsio4/C Cathode Material For Na-Ion Batteries, Shou-Ding Li, Jiang-Huai Guo, Yong Xie, Jin-Xiao Mi, Yong Yang

Journal of Electrochemistry

As a promising cathode material for sodium ion batteries, pure phase Na2MnSiO4/C nanocomposite was successfully synthesized by a sol-gel method with a citric acid as a complex agent. The as prepared material was characterized by XRD, FTIR, SEM and TEM techniques. XRD and Rietveld refinement results indicated that the sample was indexed as monoclinic structure with space group of Pn. It was observed by SEM and TEM that the obtained product consisted of micro-scaled secondary particles, which were composed of NaMnSiO4 nanocrystallites and amorphous carbon network. More importantly, the uniform carbon network in the …


Preparation And Characterization Of Carbon Supported Pd-Sb Composite Nanocatalysts For Formic Acid Electrooxidation, Long-long WANG, Xiao-lu CAO, Ya-jun WANG, Jin-hao PING, Qiao-xia LI 2015 Key Laboratory of Shanghai Colleges and Universities for Corrosion Control in Electric Power System and Applied Electrochemistry, Shanghai University of Electric Power, Shanghai 200090, China;

Preparation And Characterization Of Carbon Supported Pd-Sb Composite Nanocatalysts For Formic Acid Electrooxidation, Long-Long Wang, Xiao-Lu Cao, Ya-Jun Wang, Jin-Hao Ping, Qiao-Xia Li

Journal of Electrochemistry

Palladium is considered as an efficient anode catalyst with high catalytic activity for electrooxidation of formic acid. To further improve the catalytic activity and stability, alloying or surface modification with Sb is an effective way. In this work, the well dispersed carbon supported Pd-Sb composite nanocatalysts (Pd-Sb/C) were synthesized by traditional impregnation reduction method with trisodium citrate as the complexing agent, sodium borohydride as the reducing agent. The morphologies of Pd-Sb/C and the effects of molar ratio of Pd to Sb on the electrocatalytic properties of Pd-Sb/C for HCOOH electrooxidation were studied. The XRD and XPS analyses on the as-prepared …


Essentials For On-Campus Photovoltaic Charging Station(Pv-Cs): Grangegorman, Ayda Esfandyari, Brian Norton, Michael Conlon, Sarah McCormack 2015 Technological University Dublin

Essentials For On-Campus Photovoltaic Charging Station(Pv-Cs): Grangegorman, Ayda Esfandyari, Brian Norton, Michael Conlon, Sarah Mccormack

Conference Papers

As Light weight Electric Vehicles (LEVs) are gaining interest, Technological University Dublin (DIT) realises the value and application of these vehicles for short distance commutes around its newly built campus of “Grangegorman” located in inner Dublin city. Introduction of the campus Photovoltaic Charging Station (PV-CS) that generates clean electricity from the sun and charges the LEV’s batteries can help achieving Ireland’s 2020 targets on both national and international levels. This paper highlights the design essentials of on-campus PV-CS, via assessments of: LEV load consumption, vehicle tracking and sizing of the storage unit. The pattern for LEVs charging and load consumption …


Preparation And Enhanced Rate Capability Of Spinel Limn1.9Al0.1O3.95F0.05, Jun-yan HU, Meng-meng WANG, Hong-tao LIU 2015 College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China;

Preparation And Enhanced Rate Capability Of Spinel Limn1.9Al0.1O3.95F0.05, Jun-Yan Hu, Meng-Meng Wang, Hong-Tao Liu

Journal of Electrochemistry

Spinel LiMn1.9Al0.1O3.95F0.05 cathode materials with good crystallinity were synthesized by a sol-gel process followed with a high-temperature solid reaction. The effects of partial substitution of Al for Mn, and F for O on the structure and the electrochemical performance were investigated. The results showed that LiMn1.9Al0.1O3.95F0.05 exhibited the same crystalline state as LiMn2O4, but much better electrochemical stability at higher rate cycling. As a result, LiMn1.9Al0.1O3.95F0.05 could maintain stable electrochemical lithium storage even suffering from …


An Investigation On Electrochemical Performance Of Supercapacitor Electrode Materials Prepared By Mno2 With Four Different Crystal Forms, Zhen-Kun WEI, Xiao-Zhen HUA, Ke XIAO, Xian-Liang ZHOU, Zhi-Guo YE 2015 School of Material Seience and Engineering, Nanchang Hangkong Universityv, Nanchang 330063, China

An Investigation On Electrochemical Performance Of Supercapacitor Electrode Materials Prepared By Mno2 With Four Different Crystal Forms, Zhen-Kun Wei, Xiao-Zhen Hua, Ke Xiao, Xian-Liang Zhou, Zhi-Guo Ye

Journal of Electrochemistry

Four types of α-MnO2, β-MnO2, γ-MnO2 and δ-MnO2 powders were synthesized by relatively simple methods. The differences in crystal structures and surface morphologies for these forms of MnO2 were investigated by using X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), thermogravimetric analysis (TGA) and specific surface area analysis (BET). The electrochemical performances were characterized by cyclic voltammetry (CV) and stability analysis. Based on the experimental results, four kinds of MnO2 electrodes showed good capacity properties, and the α-MnO2 electrode had the largest specific capacity due to the highest specific surface …


Effect Of Adsorption Potential On Co Oxidation At Au@Pt Nanoparticles Electrodes, A Surface Enhanced Raman Spectroscopic Study, Pu ZHANG, Yi WEI, Yong-li ZHENG, Yan-xia CHEN, Zhong-qun TIAN 2015 Hefei National Laboratory for Physical Science at Microscale and Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, China;

Effect Of Adsorption Potential On Co Oxidation At Au@Pt Nanoparticles Electrodes, A Surface Enhanced Raman Spectroscopic Study, Pu Zhang, Yi Wei, Yong-Li Zheng, Yan-Xia Chen, Zhong-Qun Tian

Journal of Electrochemistry

The adsorption/oxidation of CO on the 55 nm [email protected] nm Pt nanoparticles electrode in both potentiodynamic and potentiostatic modes were investigated by surface enhanced Raman spectroscopy in a thin layer electrochemical flow cell under controlled mass transport, with the aim of clarifying the origin CO oxidation at lower electrode potentials (in current pre-wave region of corresponding cyclic voltammograms). Our results demonstrated that the CO oxidation kinetics differed significantly from the three kinds of different CO adsorption history, with almost no CO oxidation current in the pre-peak potential region after 0.35 VRHE CO adsorption with or without subsequent holding the …


Synthesis And Electrochemical Performance Of Mn3O4/Graphene Composites, Shan-shan YANG, Qian ZHANG, Xiong-gui LIN, Ming-sen ZHENG, Quan-feng DONG 2015 State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China;

Synthesis And Electrochemical Performance Of Mn3O4/Graphene Composites, Shan-Shan Yang, Qian Zhang, Xiong-Gui Lin, Ming-Sen Zheng, Quan-Feng Dong

Journal of Electrochemistry

The Mn3O4/Graphene composites were synthesized by hydrothermal method with the in-situ redox reaction of graphene oxide (GO) and manganese acetate (Mn(Ac)2). The phase structures and morphologies of the materials were characterized by XRD, SEM and TEM. The XPS and IR techniques were used for studying the residual function groups of reduced graphene oxide (RGO). The electrochemical performances of the hybrids were tested in a coin cell. Results showed that the composites prepared with the addition of ammonia water (RM-A) have better performance. The graphenes in RM-A were better-reduced and the Mn3O4 …


Tungsten Carbide/Carbon Electrode Material Synthesized By Block Copolymer Template Method, Xiao-ling LANG, Ye-kun JIANG, Mei-qin SHI, Ling-zhi KANG, Chun-an MA 2015 State Key Laboratory Breeding Base for Green Chemistry Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310032, China;College of Chemical and Materials Science, Longyan University, Longyan 364000, Fujian, China;

Tungsten Carbide/Carbon Electrode Material Synthesized By Block Copolymer Template Method, Xiao-Ling Lang, Ye-Kun Jiang, Mei-Qin Shi, Ling-Zhi Kang, Chun-An Ma

Journal of Electrochemistry

At present, one of the major hurdles for commercialization of system with direct methanol fuel cell (DMFC) is still the requirement of a significant amount of platinum (Pt) catalyst to achieve an acceptable power density. Pt and Pt-based metals are expensive due to limited supplies. In order to find the catalyst alternative to the Pt metal, we selected tungsten carbide (WC) and its composites as the study object. We synthesized WC with carbon materials as the suitable support to modify the electronic structure and to increase the specific surface area of WC. In this study, tungsten carbide/carbon (WC/C) was prepared …


Mechanism Study On The Electrocatalytic Oxidation Of Acetylene To Oxalic Acid, Xiu-li SONG, Rui-long JIA, Wen-yan DONG, Zhen-hai LIANG 2015 College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China; Department of Chemistry, Taiyuan Normal University, Taiyuan 030031, China;

Mechanism Study On The Electrocatalytic Oxidation Of Acetylene To Oxalic Acid, Xiu-Li Song, Rui-Long Jia, Wen-Yan Dong, Zhen-Hai Liang

Journal of Electrochemistry

A new method of electrocatalytic synthesis oxalic acid from acetylene was explored and the synthesized oxalic acid was characterized by Ultraviolet-visible spectrophotometry (Uv-vis) and Infrared spectroscopy (IR). First-principles calculations were carried out to examine the adsorption of acetylene over the Pt(111) surface. The electrocatalytic oxidation behavior of acetylene has been investigated on a Pt electrode by cyclic voltammetry (CV) and steady-state polarization in Na2SO4 solution. The formation mechanism of oxalic acid in the Na2SO4 solution was proposed and the transfer coefficients of the reaction were calculated. The results show that acetylene molecule tends to …


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