Power and Energy Commons^™

Electrochemical Activities Of Oxygen-Doped Carbon Surface For V(Iv)/V(V) Redox Couple, Huan Zhang, Lin-Lin Qin, Yi-Ning Shi, Ming-Sen Zheng, Quan-Feng Dong, Zhao-Wu Tian

Journal of Electrochemistry

Graphite plate electrodes were treated with oxygen plasma and doped with oxygen as well as oxygen functional groups. With the treatment, the activities of graphite plate electrodes toward VO²⁺/VO₂⁺ redox reactions were improved. FT-IR and EDS analysis results indicated that oxygen functional groups were introduced to the surface of graphite plates after oxygen plasma treatment. In this paper, the graphite plate treated for 20 min showed the highest activity. The average charge efficiency reached 91%, suggesting an increase of 19%, compared with that of the untreated graphite plate under a current density of 8 mA·cm^{-2 …}

Solar Cell Design Using Metamaterials, Yang Liu, Yitung Chen, Jichun Li

College of Engineering: Graduate Celebration Programs

Natural structure with simultaneous negative permittivity and permeability has not been discovered yet. However, using specially-designed metal embedded in dielectric bodies can achieve a kind of artificial negative index. This periodic structure which is smaller than the guided wavelength is known as a metamaterial. However, recent designs of metamaterials have some disadvantages when they are used in the application of solar cell. The perfect absorption is only within a narrow band, and for most of the solar spectrum, the absorption is no more than 10%. Here, a new kind of absorber for the solar spectrum has been designed and analyzed, …

A Computation Model For Nanoantenna-Based Solar Cell With High Conversion Efficiency, Yiyan Li, Ke-Xun Sun, Yingtao Jiang

College of Engineering: Graduate Celebration Programs

• Build a model of spiral nanoantenna and an antenna
  array based solar cell collector.
• Using Rao-Wilton-Glisson (RWG) basis functions to
  simulate the spiral nanoantennas.
• We calculate the frequency response of the radiation
  gain as the indicator of receiving bandwidth which is a
  key factor in conversion efficiency.

Novel Control Of Pv Solar And Wind Farm Inverters As Statcom For Increasing Connectivity Of Distributed Generators, Mahendra Ac

Electronic Thesis and Dissertation Repository

The integration of distributed generators (DGs) such as wind farms and PV solar farms in distribution networks is getting severely constrained due to problems of steady state voltage rise and temporary overvoltages (TOV). This thesis presents a first time application of a patent-pending PV solar farm control as a dynamic reactive power compensator (STATCOM), termed PV-STATCOM, for mitigating the voltage rise and TOV issues, and significantly enhancing the connectivity of a neighbouring wind farm both during night and day in a realistic distribution feeder in Ontario. The effectiveness of PV-STATCOM is demonstrated even if the solar farm is located 30 …

Aeroelastic Energy Harvesting Using A Nonlinear Electromagnetic Oscillator, Katherine Bender, Ndungu Muturi, Alex Spies, Christopher Lee

Christopher Lee

Results are presented from the design, fabrication and testing of an electromagnetic-inductor device to convert aeroelastic-induced oscillations of an airfoil into electricity. The energy harvester consists of three magnets configured such that the force-displacement relationship can be described by a fifth-degree polynomial. the integration of the harvester into a two-degree-of-freedom, pitch/plunge airfoil system introduces nonlinear stiffness into the plunge direction. This nonlinearity gives rise to limit cycle oscillations which, in turn, are converted to electric power by the harvester. Experimental measurements from wind tunnel tests are compared to predictions of limit cycle response and resulting power generation using a two-degree-of-freedom …

Optimization Of Wireless Power Transfer Via Magnetic Resonance In Different Media, Olutola Jonah

FIU Electronic Theses and Dissertations

A wide range of non-destructive testing (NDT) methods for the monitoring the health of concrete structure has been studied for several years. The recent rapid evolution of wireless sensor network (WSN) technologies has resulted in the development of sensing elements that can be embedded in concrete, to monitor the health of infrastructure, collect and report valuable related data. The monitoring system can potentially decrease the high installation time and reduce maintenance cost associated with wired monitoring systems. The monitoring sensors need to operate for a long period of time, but sensors batteries have a finite life span. Hence, novel wireless …

Hybrid Power System Intelligent Operation And Protection Involving Distributed Architectures And Pulsed Loads, Ahmed A. Mohamed

FIU Electronic Theses and Dissertations

Efficient and reliable techniques for power delivery and utilization are needed to account for the increased penetration of renewable energy sources in electric power systems. Such methods are also required for current and future demands of plug-in electric vehicles and high-power electronic loads. Distributed control and optimal power network architectures will lead to viable solutions to the energy management issue with high level of reliability and security. This dissertation is aimed at developing and verifying new techniques for distributed control by deploying DC microgrids, involving distributed renewable generation and energy storage, through the operating AC power system.

To achieve the …

Wireless Electrical Power System Network: A Imagine, Engineer Radhey Shyam Meena

Radhey Shyam Meena

Today large number of new technologies depends on electrical supply system, so complexity of wires is very high. In this project, as requirement of wireless electrical power system, project team present an analysis the concept of cable less transmission i.e. Power without the usage of any kind of the electrical conductor or wires. Transmission or distribution of 50 or 60 Hz electrical energy from the generation point to the consumers end without any physical wire has yet to mature as a familiar and viable technology.

Battery Energy Storage System In Solar Power Generation, Radhey Shyam Meena Er., Deepa Sharma

Radhey Shyam Meena

Grid-connected solar PV dramatically changes the load profile of an electric utility customer. The expected widespread adoption of solar generation by customers on the distribution system poses significant challenges to system operators both in transient and steady state operation, from issues including voltage swings, sudden weather-induced changes in generation, and legacy protective devices designed with one-way power flow in mind

Direct Power Control Of Wind-Turbine-Driven Dfig During Transient Grid Voltage Unbalance, Emad Gameil Shehata E. G. Shehata

Emad Gameil Shehata E. G. Shehata

In this paper, a direct power control (DPC) of a wind-turbine-driven doubly fed induction generators (DFIGs) under unbalanced network voltage conditions is studied. Variations of the stator output active, reactive and electromagnetic powers are fully deduced in the presence of negative sequence supply voltage. The rotor side converter is controlled on the basis of DPC to eliminate the electromagnetic torque oscillations at double supply frequency under unbalanced stator supply. The rotor voltage references estimation requires only simple calculations without any integral operation. The proposed control scheme removes rotor current regulators and the decomposition processing of positive and negative sequence rotor …

End-To-End Modeling For Variability And Reliability Analysis Of Thin Film Pv, Sourabh Dongaonkar, Muhammad Alam

Sourabh Dongaonkar

We present an end-to-end modeling framework, spanning the device, module and also system levels, for analyzing thin film photovoltaics (PV). This approach is based on embedding a detailed, statistically relevant, physics based equivalent circuit into module and array level simulations. This approach enables us to analyze key variability and reliability issues in thin film PV, and allows us to interpret their effect on process yield and intrinsic module lifetimes. Our results suggest that the time-zero gap between cell and module efficiencies, a key variability concern for thin-film PV, can be attributed to processrelated shunts with log-normal PDF distributed randomly across …

Reverse Stress Metastability Of Shunt Current In Cigs Solar Cells, Sourabh Dongaonkar, Erik Sheets, Rakesh Agrawal, Muhammad Alam

Sourabh Dongaonkar

Partial shading in thin film solar panels can result in reverse bias stress across shaded cells. Therefore, it is important to understand the effect of such reverse stress in commercially competitive PV technologies such as CIGS. In this paper, we systematically investigate the effect of moderate reverse bias on solution-processed CIGS solar cells. We subject the solar cells to varying degrees of reverse biases and continuously monitor the impact of the stress on dark current. We also explore the relaxation behavior of dark current following passive storage and the long term effect of the shadow stress on power output of …

Dc House Distribution Panel, Khanh Ho

Electrical Engineering

This paper details the process in designing the distribution panel, or circuit breaker box for a DC house. The main purpose of the project is to design a distribution panel that will provide electrical power to the DC house while also providing an electrical system protection through the use of circuit breakers, or fuses. An actual hardware design for the distribution panel was built and tested. The results demonstrate the functionality of the breaker box to supply power to the DC House ensuring safe operation of the DC House.

Microgrid Power Quality Analysis, Nikolai Kempcatala, Daniel Pleau, Scott Clemons

Electrical Engineering

The microgrid power quality analysis senior project addresses power quality assessment. Our senior project uses the PowerSight 3000 power measurement tool to record and analyze various electrical measurements including voltage, current, power, power factor, harmonics and AC frequency.

Our project will analyze power quality issues that result from switching from the utility grid to a smart grid run on primarily photovoltaic distributed generation. In the event of a utility failure, the smart grid can serve as an isolated grid for the system, this is called islanded mode. Our project assesses the reliability of operation in islanded mode. Our analysis should …

An In Situ Ftir Spectroelectrochemical Study On Methanol Oxidation At Pt-Mo2c/Gc Catalyst, Hai-Ping Huang, Xi-Yu Yao, Pei-Kang Shen

Journal of Electrochemistry

A 40% Pt on Mo2C/GC catalyst has been prepared by ion exchange method. The mechanism of methanol electrooxidation on Pt-Mo2C/GC and commercial Pt/C catalysts in acidic media was studied by cyclic voltammetry, XRD measurements and in-situ Fourier transform infrared spectroelectrochemistry. The results revealed that the Pt nanoparticles were uniformly dispersed on Mo2C/GC with an average particle size of 3 nm. The cyclic voltammetric and chronopotentiometric experiments indicated that Pt-Mo2C/GC catalyst exhibited a better performance for methanol oxidation than that of Pt/C in acid solution. A negative shift over 90 mV of the onset potential for methanol oxidation was found on …

Electrochemical Performance Of Fe3o4/C Composites As Negative Material For Lithium-Ion Batteries, Jun-Jie Cai, Shu Yao, Ze-Sheng Li, Hui Meng, Pei-Kang Shen

Journal of Electrochemistry

The Fe3O4/Carbon composites have been synthesized through coprecipitation pathway and by insitu aniline polymerization as a carbon source. Structural characterization and morphological study of the composites were investigated by using XRD, SEM and TEM techniques. The results showed that the nanosized Fe3O4 particles (40 ~ 80 nm) were encapsulated in the amorphous carbon. During the electrochemical tests, the Fe3O4/C composites exhibited high capaticity and excellent cycle ability, the retention of capaticity was about 1000 mAh?g-1 after 30 cycles of charge/discharge tests at 50 mA?g-1.

A Dft Calculation Screening Of Pt-Based Bimetallic Catalysts For Oxygen Reduction, Li-Hui Ou, Sheng-Li Chen

Journal of Electrochemistry

Developing Pt-lean catalysts for oxygen reduction reaction (ORR) is the key for large-scale application of proton exchange membrane fuel cell (PEMFC). In this paper, we have proposed a multiple-descriptor strategy for screening efficient and durable ORR alloy catalysts of low Pt content. We argue that an ideal Pt-based bimetallic alloy catalyst for ORR should possess simultaneously negative alloy formation energy, negative surface segregation energy of Pt and a lower oxygen binding ability than pure Pt. By performing detailed DFT calculations on the thermodynamics, surface chemistry and electronic properties of various Pt-M alloys (M refers to non-precious transition metals in the …

Sodium Carbonate Catalyzed Photoelectrochemical Water Splitting Over Tio2 Nanotubes Photoanode, De-Sheng Kong, Jing Wang, Xue-Di Zhang, Xi Zhao, Chao Wang, Yuan-Yuan Feng, Wen-Juan Li

Journal of Electrochemistry

Surface recombination of the photogenerated electron-hole pairs at semiconductor/electrolyte interface is one of the most essential reasons responsible for lowering photoconversion efficiency (Φ) of light to chemical energy for photoelectrochemical (PEC) water splitting reaction. In this paper，the catalytic effect of sodium carbonate on the oxygen evolution reaction (OER) over TiO₂ nanotubes photoanode during PEC water splitting was investigated by performing photocurrent and ac impedance measurements. It was demonstrated that the addiction of 1 mmol•L^-1 Na₂CO₃ in 0.5 mol•L^-1 NaClO₄ electrolyte can effectively improve the charge transfer properties for the photogenerated holes …

Effect Of Ti/Pbo2 Electrodes Doped With Different Elements On Electrocatalytic Oxidation Characteristics Of Phenol, Xiao-Lei Liu, Yuan-Yuan Dan, Hai-Yan Lu, Hai-Bo Lin, Ming-Li Ouyang, Chuan-Jun Yun

Journal of Electrochemistry

Three types of electrodes, namely, Ti/PbO₂, F-doped PbO₂ (Ti/PbO₂-F) and nano-Co₃O₄-doped PbO₂ (Ti/PbO₂+Nano-Co₃O₄) electrodes, were prepared by electro-deposition method on the Ti substrate with the interlayer of SnO₂-Sb₂O₅. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to study the compositions, structures and film morphologies of the electrodes. Electrocatalytic oxidation characteristics to phenol on the prepared electrodes were investigated by electrochemical method. The experimental results showed that compared with the Ti/PbO₂ electrode, the potentials of oxygen …

Oxygen Reduction Reaction On Glycin Modified Pt(111) Electrode, Ming-Fang Li, Jing Kang, Ling-Wen Liao, Yan-Xia Chen, Shen Ye

Journal of Electrochemistry

Oxygen reduction reaction (ORR) on glycin (NH2CH2COOH) modified Pt(111) electrode has been investigated using hanging meniscus rotating disk electrode system (HMRD) in 0.05 mol•L^-1 H₂SO₄ and 0.1 mol•L^-1 HClO₄ solutions, respectively. Cyclic voltammograms of the glycin modified Pt (111) electrode measured in 0.05 mol•L^-1 H₂SO₄ solution similar to that of CN^- modified Pt(111) electrodes, demonstrating that sulfate adsorption is strongly inhibited at the glycin modified Pt(111). From the polarization curve of ORR recorded in 0.05 mol•L^-1 H₂SO₄ solution, it is found that the ORR activity …