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Oxone® Mediated Tempo-Oxidized Cellulose Nanomaterials: Material Characterization, Ultrafiltration Membrane Separations, And Thin Film Composite Gas Transport Analysis, John Phillips Moore 2021 University of Arkansas, Fayetteville

Oxone® Mediated Tempo-Oxidized Cellulose Nanomaterials: Material Characterization, Ultrafiltration Membrane Separations, And Thin Film Composite Gas Transport Analysis, John Phillips Moore

Graduate Theses and Dissertations

Cellulose nanomaterials (CNMs) are derived from plant matter and are comprised of nanoscopic cellulose crystals and fibers. They have a diverse set of applications, from cosmetics to oil recovery. This study focuses on the properties of Oxone® mediated TEMPO-oxidized cellulose nanomaterials (OTO-CNMs) and their use in controlling the transport properties of polymeric substrates. Synthesis and characterization of cellulosic nanoparticles have resulted in the creation of OTO-CNMs with properties that increase hydrophilicity. With added hydrophilicity, OTO-CNMs possess lower fouling propensity, making them ideal membrane additive for transport limited separations such as hemodialysis.

To utilize the material and unique properties thereof, this …


Optoelectronic Valley-Spin Qubits With Ambipolar Quantum Dots, Jeremy Tull 2021 University of Arkansas, Fayetteville

Optoelectronic Valley-Spin Qubits With Ambipolar Quantum Dots, Jeremy Tull

Electrical Engineering Undergraduate Honors Theses

The current limitations of qubit-based processors are caused by imperfections in quantum gates, leading to a lack of gate fidelity. Gate fidelity can be refined by extending the coherence of qubits and reducing logic operation speed. A potential solution is to develop a hybrid qubit that has the coherence of electrically-controlled quantum dots and the gate speed of their optically-controlled counterparts. Quantum bits that utilize ultrafast optical gating to perform gate operations require precise control of the gating pulse duration. Optical dispersion can cause adverse effects pulse duration, such as pulse broadening, so dispersion-compensation techniques must be employed; by properly …


Design And Fabrication Of A Microstrip Bandpass Filter In Ltcc, Allison Rucker 2021 University of Arkansas, Fayetteville

Design And Fabrication Of A Microstrip Bandpass Filter In Ltcc, Allison Rucker

Electrical Engineering Undergraduate Honors Theses

The goal of the project was to design and fabricate a bandpass filter with a center frequency of 25GHz with a 2GHz bandwidth. The first step was to do the calculation to design a bandpass filter to meet these specifications along with the properties of the DupontTM GreenTapeTM 9K7. HFSS was then used to verify the results from the initial calculations. There was a significant error between the two results, so more tweaking was done to the calculations to get a better center frequency. After a final design was decided, the fabrication process started. Low-Temperature Co-Fired Ceramics (LLTC) …


Fabrication And Simulation Of Perovskite Solar Cells, Maniell Workman 2021 University of Kentucky

Fabrication And Simulation Of Perovskite Solar Cells, Maniell Workman

Theses and Dissertations--Electrical and Computer Engineering

Since the dawning of the industrial revolution, the world has had a need for mass energy production. In the 1950s silicon solar panels were invented. Silicon solar panels have been the main source of solar energy production. They have set the standard for power conversion efficiency for subsequent generations of photovoltaic technology. Solar panels utilize light’s ability to generate an electron hole pair. By creating a PN Junction in the photovoltaic semiconductor, the electron and hole are directed in opposing layers of the solar panel generating the electric current. Second generation solar panels utilized different thin film materials to fabricate …


Perovskite Thin Films Annealed In Supercritical Fluids For Efficient Solar Cells, Gilbert Annohene 2021 Virginia Commonwealth University

Perovskite Thin Films Annealed In Supercritical Fluids For Efficient Solar Cells, Gilbert Annohene

Theses and Dissertations

In the field of photovoltaics, scientists and researchers are working fervently to produce a combination of efficient, stable, low cost and scalable devices. Methylammonium lead trihalide perovskite has attracted intense interest due to its high photovoltaic performance, low cost, and ease of manufacture. Their high absorption coefficient, tunable bandgap, low-temperature processing, and abundant elemental constituent provide innumerable advantages over other thin film absorber materials. Since the perovskite film is the most important in the device, morphology, crystallization, compositional and interface engineering have been explored to boost its performance and stability. High temperatures necessary for crystallization of organic-inorganic hybrid perovskite films …


Inventions Of Scientists, Engineers And Specialists From Different Countries In The Area Of Nanotechnologies. Part V, Leonid A. Ivanov, Li D. Xu, Konstantin E. Razumeev, Valentina M. Feoktistova, Petr S. Prokopiev 2021 Old Dominion University

Inventions Of Scientists, Engineers And Specialists From Different Countries In The Area Of Nanotechnologies. Part V, Leonid A. Ivanov, Li D. Xu, Konstantin E. Razumeev, Valentina M. Feoktistova, Petr S. Prokopiev

Information Technology & Decision Sciences Faculty Publications

Introduction. Advanced technologies impress people's imagination demonstrating the latest achievements (materials, methods, systems, technologies, devices etc.) that dramatically change the world. This, first of all, concerns nanotechnological inventions designed by scientists, engineers and specialists from different countries. Main part. The article provides an abstract overview of inventions of scientists, engineers and specialists from different countries: Russia, USA, China, Belarus, Italy. The results of the creative activity of scientists, engineers and specialists, including inventions in the field of nanotechnology and nanomaterials allow, when introduced to industry, achieving a significant effect in construction, housing and communal services, and related sectors of the …


Superresolution Enhancement With Active Convolved Illumination, Anindya Ghoshroy 2021 Michigan Technological University

Superresolution Enhancement With Active Convolved Illumination, Anindya Ghoshroy

Dissertations, Master's Theses and Master's Reports

The first two decades of the 21st century witnessed the emergence of “metamaterials”. The prospect of unrestricted control over light-matter interactions was a major contributing factor leading to the realization of new technologies and advancement of existing ones. While the field certainly does not lack innovative applications, widespread commercial deployment may still be several decades away. Fabrication of sophisticated 3d micro and nano structures, specially for telecommunications and optical frequencies will require a significant advancement of current technologies. More importantly, the effects of absorption and scattering losses will require a robust solution since this renders any conceivable application of metamaterials …


Development Of Light Actuated Chemical Delivery Platform On A 2-D Array Of Micropore Structure, Hojjat Rostami Azmand, Hojjat Rostami Azmand 2021 CUNY City College

Development Of Light Actuated Chemical Delivery Platform On A 2-D Array Of Micropore Structure, Hojjat Rostami Azmand, Hojjat Rostami Azmand

Dissertations and Theses

Localized chemical delivery plays an essential role in the fundamental information transfers within biological systems. Thus, the ability to mimic the natural chemical signal modulation would provide significant contributions to understand the functional signaling pathway of biological cells and develop new prosthetic devices for neurological disorders. In this paper, we demonstrate a light-controlled hydrogel platform that can be used for localized chemical delivery in a high spatial resolution. By utilizing the photothermal behavior of graphene-hydrogel composites confined within micron-sized fluidic channels, patterned light illumination creates the parallel and independent actuation of chemical release in a group of fluidic ports. The …


Optical Metasurfaces, Fatih Balli 2021 University of Kentucky

Optical Metasurfaces, Fatih Balli

Theses and Dissertations--Physics and Astronomy

Traditional optical elements, such as refractive lenses, mirrors, phase plates and polarizers have been used for various purposes such as imaging systems, lithographic printing, astronomical observations and display technology. Despite their long-term achievements, they can be bulky and not suitable for miniaturization. On the other hand, recent nanotechnology advances allowed us to manufacture micro and nanoscale devices with ultra-compact sizes. Metasurfaces, 2D engineered artificial interfaces, have emerged as candidates to replace traditional refractive lenses with ultra-thin miniaturized optical elements. They possess sub-wavelength unit cell structures with a specific geometry and material selection. Each unit cell can uniquely tailor the phase, …


Treated Hfo2 Based Rram Devices With Ru, Tan, Tin As Top Electrode For In-Memory Computing Hardware, Yuvraj Dineshkumar Patel 2020 New Jersey Institute of Technology

Treated Hfo2 Based Rram Devices With Ru, Tan, Tin As Top Electrode For In-Memory Computing Hardware, Yuvraj Dineshkumar Patel

Theses

The scalability and power efficiency of the conventional CMOS technology is steadily coming to a halt due to increasing problems and challenges in fabrication technology. Many non-volatile memory devices have emerged recently to meet the scaling challenges. Memory devices such as RRAMs or ReRAM (Resistive Random-Access Memory) have proved to be a promising candidate for analog in memory computing applications related to inference and learning in artificial intelligence. A RRAM cell has a MIM (Metal insulator metal) structure that exhibits reversible resistive switching on application of positive or negative voltage. But detailed studies on the power consumption, repeatability and retention …


Technique Design Of Filter On Surface-Acoustic Waves, Dilmurod Abdujalilovich Davronbekov, Zafar Tulyaganovich Khakimov 2020 Tashkent University of Information Technologies named after Muhammad al-Khwarizmi

Technique Design Of Filter On Surface-Acoustic Waves, Dilmurod Abdujalilovich Davronbekov, Zafar Tulyaganovich Khakimov

Acta of Turin Polytechnic University in Tashkent

The article describes the design of filters on surface acoustic waves (SAWs), which are selective elements and are widely used in blocks, devices and signal processing systems in telecommunications, including wireless communication systems such as cellular, trunking and others. Designs of filters for surfactants are considered, which are divided into two large groups - by functional purpose and by a systematic approach to the synthesis of performance characteristics of filters for surfactants. Optimization algorithms and methods for synthesizing surfactant filters have been developed and improved. An improved technique for the synthesis of a filter based on surface acoustic waves is …


Approaches To Studying Bacterial Biofilms In The Bioeconomy With Nanofabrication Techniques And Engineered Platforms., Michelle Caroline Halsted 2020 University of Tennessee, Knoxville

Approaches To Studying Bacterial Biofilms In The Bioeconomy With Nanofabrication Techniques And Engineered Platforms., Michelle Caroline Halsted

Doctoral Dissertations

Studies that estimate more than 90% of bacteria subsist in a biofilm state to survive environmental stressors. These biofilms persist on man-made and natural surfaces, and examples of the rich biofilm diversity extends from the roots of bioenergy crops to electroactive biofilms in bioelectrochemical reactors. Efforts to optimize microbial systems in the bioeconomy will benefit from an improved fundamental understanding of bacterial biofilms. An understanding of these microbial systems shows promise to increase crop yields with precision agriculture (e.g. biosynthetic fertilizer, microbial pesticides, and soil remediation) and increase commodity production yields in bioreactors. Yet conventional laboratory methods investigate these micron-scale …


3-D Fabry–Pérot Cavities Sculpted On Fiber Tips Using A Multiphoton Polymerization Process, Jonathan W. Smith, Jeremiah C. Williams, Joseph S. Suelzer, Nicholas G. Usechak, Hengky Chandrahalim 2020 Air Force Institute of Technology

3-D Fabry–Pérot Cavities Sculpted On Fiber Tips Using A Multiphoton Polymerization Process, Jonathan W. Smith, Jeremiah C. Williams, Joseph S. Suelzer, Nicholas G. Usechak, Hengky Chandrahalim

Faculty Publications

This paper presents 3-D Fabry–Pérot (FP) cavities fabricated directly onto cleaved ends of low-loss optical fibers by a two-photon polymerization (2PP) process. This fabrication technique is quick, simple, and inexpensive compared to planar microfabrication processes, which enables rapid prototyping and the ability to adapt to new requirements. These devices also utilize true 3-D design freedom, facilitating the realization of microscale optical elements with challenging geometries. Three different device types were fabricated and evaluated: an unreleased single-cavity device, a released dual-cavity device, and a released hemispherical mirror dual-cavity device. Each iteration improved the quality of the FP cavity's reflection spectrum. The …


Engineering Electromagnetic Systems For Next-Generation Brain-Machine Interface, Brayan Ricardo Navarrete 2020 Florida International University

Engineering Electromagnetic Systems For Next-Generation Brain-Machine Interface, Brayan Ricardo Navarrete

FIU Electronic Theses and Dissertations

MagnetoElectric Nanoparticles (MENPs) are known to be a powerful tool for a broad range of applications spanning from medicine to energy-efficient electronics. MENPs allow to couple intrinsic electric fields in the nervous system with externally controlled magnetic fields. This thesis exploited MENPs to achieve contactless brain-machine interface (BMIs). Special electromagnetic devices were engineered for controlling the MENPs’ magnetoelectric effect to enable stimulation and recording. The most important engineering breakthroughs of the study are summarized below.

(I) Metastable Physics to Localize Nanoparticles: One of the main challenges is to localize the nanoparticles at any selected site(s) in the brain. The fundamental …


Fabrication And Application Of Flexible Sensors, Tallis Huther da Costa 2020 Louisiana State University and Agricultural and Mechanical College

Fabrication And Application Of Flexible Sensors, Tallis Huther Da Costa

LSU Doctoral Dissertations

A transfer printing method was developed to transfer carbon nanotubes (CNTs) from polyethylene terephthalate (PET) film to poly(dimethyl siloxane) (PDMS) polymer. Carbon nanotubes are composed of carbon atoms arranged in a honeycomb lattice structure, which are electrically conducting. When embedded in a nonconducting polymer, carbon nanotubes impart electrical conductivity to the nanocomposite, thus forming a nanocomposite that has potential applications in highly sensitive strain and pressure sensors. Several printing methods have been studied to deposit carbon nanotubes onto PDMS, including inkjet printing. Inkjet printing is a desirable deposition method since it is low-cost, simple, and allows the processing of aqueous-based …


Thermal Transport Modeling Of Semiconductor Materials From First Principles, Aliya Qureshi 2020 University of Massachusetts Amherst

Thermal Transport Modeling Of Semiconductor Materials From First Principles, Aliya Qureshi

Masters Theses

Over the past few years, the size of semiconductor devices has been shrinking whereas the density of transistors has exponentially increased. Thus, thermal management has become a serious concern as device performance and reliability is greatly affected by heat. An understanding of thermal transport properties at device level along with predictive modelling can lead us to design of new systems and materials tailored according to the thermal conductivity. In our work we first review different models used to calculate thermal conductivity and examine their accuracy using the experimentally measured thermal conductivity for Si. Our results suggest that empirically calculated rates …


Nonlinear Nanophotonic Devices In The Ultraviolet To Visible Wavelength Range, Jinghan He, Hong Chen, Jin Hu, Jingan Zhou, Yingmu Zhang, Andre Kovach, Constantine Sideris, Mark C. Harrison, Yuji Zhao, Andrea M. Armani 2020 University of Southern California

Nonlinear Nanophotonic Devices In The Ultraviolet To Visible Wavelength Range, Jinghan He, Hong Chen, Jin Hu, Jingan Zhou, Yingmu Zhang, Andre Kovach, Constantine Sideris, Mark C. Harrison, Yuji Zhao, Andrea M. Armani

Engineering Faculty Articles and Research

Although the first lasers invented operated in the visible, the first on-chip devices were optimized for near-infrared (IR) performance driven by demand in telecommunications. However, as the applications of integrated photonics has broadened, the wavelength demand has as well, and we are now returning to the visible (Vis) and pushing into the ultraviolet (UV). This shift has required innovations in device design and in materials as well as leveraging nonlinear behavior to reach these wavelengths. This review discusses the key nonlinear phenomena that can be used as well as presents several emerging material systems and devices that have reached the …


Flexible Capacitive Pressure Sensors And Triboelectric Energy Harvesters Using Laser-Assisted Patterning Process For Flexible Hybrid Electronic Applications, Valliammai Palaniappan 2020 Western Michigan University

Flexible Capacitive Pressure Sensors And Triboelectric Energy Harvesters Using Laser-Assisted Patterning Process For Flexible Hybrid Electronic Applications, Valliammai Palaniappan

Masters Theses

This work focuses on the design, fabrication and characterization of novel flexible capacitive pressure sensors and triboelectric energy harvesters using laser-assisted patterning process for flexible hybrid electronic applications. Initially, the capacitive pressure sensor was developed by fabricating a set of polydimethylsiloxanes (PDMS) dielectric films with pyramid shaped micro-structures using a laser-assisted patterning process. The pressure sensor consists of two electrodes (top and bottom) that were fabricated by depositing silver (Ag) on flexible polyethylene terephthalate (PET) using additive screen-printing process. Finally, the pressure sensor was assembled by attaching the top and bottom Ag electrodes to the smooth side of pyramid shaped …


Nanoelectronic Applications Of Magnetoelectric Nanostructures, Ping Wang 2020 Florida International University

Nanoelectronic Applications Of Magnetoelectric Nanostructures, Ping Wang

FIU Electronic Theses and Dissertations

The greatly increased interest in magnetoelectric materials over the last decade is due to their potential to enable next-generation multifunctional nanostructures required for revolutionizing applications spanning from energy-efficient information processing to medicine. Magnetoelectric nanomaterials offer a unique way to use a voltage to control the electron spin and, reciprocally, to use remotely controlled magnetic fields to access local intrinsic electric fields. The magnetoelectric coefficient is the most critical indicator for the magnetoelectric coupling in these nanostructures. To realize the immense potential of these materials, it is necessary to maximize the coefficient. Therefore, the goal of this PhD thesis study was …


Development And Test Of High Temperature Surface Acoustic Wave Gas Sensors, Armando E. Ayes Moncada 2020 University of Maine

Development And Test Of High Temperature Surface Acoustic Wave Gas Sensors, Armando E. Ayes Moncada

Electronic Theses and Dissertations

The demand for sensors in hostile environments, such as power plant environments, exhaust systems and high-temperature metallurgy environments, has risen over the past decades in a continuous attempt to increase process control, improve energy and process efficiency in production, reduce operational and maintenance costs, increase safety, and perform condition-based maintenance in equipment and structures operating in high-temperature, harsh-environment conditions. The increased reliability, improved performance, and development of new sensors and networks with a multitude of components, especially wireless networks, are the target for operation in harsh environments. Gas sensors, in particular hydrogen gas sensors, operating above 200°C are required in …


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