Thermodynamics Commons^™

Brrbox, Shawn J. Myers, Lane Cline, Michael Davis, Christian Secrest

Williams Honors College, Honors Research Projects

This report details the project known as “The BRRBOX”, a reusable, insulated thermoelectric cooler developed to keep internal temperatures at refrigeration levels or cooler for at least 48 hours. The cooler will track its internal temperature during this period and be able to give the data at the end of its delivery cycle to keep up with food and pharmaceutical standards during delivery. The BRRBOX uses Peltier-based cooling alongside vacuum insulation panels and fans to achieve efficient thermal control. An onboard microcontroller will monitor temperature, record the data, and adjust the cooling output to minimize power consumption. The box will …

Effect Of Inter Electrode Distance On Electrochemical Mineralization Of Calcium Carbonate In Mildly Acidic Environments, Irene Walker, Ivy Wu, Steven Decaluwe, Robert Bell, Kerry Rippy

Reviews, Analyses, and Instructional Studies in Electrochemistry (RAISE)

The effect of inter electrode distance (IED) on electrochemical mineralization in a parallel plate cell with a stainless-steel working electrode is presented. Three IEDs were tested, 6.5 mm, 15.5 mm, and 22.0 mm, for their water reduction effectiveness to create a region of local alkalinity that stimulates calcium carbonate precipitation in mildly acidic conditions. Chronoamperometry at -1.6 V for 30 minutes with ex-situ optical microscopy and scanning electron microscopy (SEM) were used. At the smallest IEDs, crystal clusters formed in growth-favored regimes as compared to the largest IED, where nucleation dominated, leading to encasement of the SS mesh. Rapid precipitation …

Temperature And Speciation Measurements Of Aluminum-Laden Detonation Flows Via A Three-Color Wavelength Modulation Spectroscopic Sensor, Marc B. Etienne

Graduate Studies Theses and Dissertations 2026

Tunable diode lasers are widely used and are known to be great options for continuous wave lasing applications. Because of their stability and spectral selectivity, they have become an important diagnostic tool for modern combustion research. Previous combustion research, particularly those focused on solid and hybrid rocket systems, have shown that the interaction of aluminum with a reacting flow can greatly affect the dynamics and the thermochemical properties of the surrounding gas, therefore understanding the effects of aluminum-laden flows is critical for the advancement of these propulsion systems. However, due to the high degree of optical interference, high temperatures, and …

Flow Field Characterization Of The Hyperreact Vitiated Hypersonic Wind Tunnel, Erik R. Fernandez

Graduate Studies Theses and Dissertations 2026

Reliable interpretation of hypersonic ground-test data requires knowledge of the thermochemical state delivered to the test section, especially in combustion-heated facilities where the gas is chemically altered before nozzle expansion. This thesis investigates the HyperReact vitiated hypersonic wind tunnel using the effective specific-heat ratio, γeff, as an experimentally inferred indicator of the coupled chemical and gas-dynamic behavior of hydrogen-air vitiated flow. HyperReact produces high stagnation temperatures through hydrogen-air combustion before expanding the mixture through interchangeable converging-diverging nozzles. During this expansion, temperature-dependent specific heats, molecular-weight changes, finite-rate chemistry, and internal energy relaxation can modify the relationship between Mach number, pressure ratio, …

The Development Of An Experimental Chemical Reactor Network Facility For Power Generation And Aviation Gas Turbines, Kesly Lubin

Graduate Studies Theses and Dissertations 2026

Gas turbines are the backbone of power generation globally; however, they are also one of the largest contributors to greenhouse gases and harmful emissions. Advanced combustion strategies, when applied to energy generation, can offer increased optimization of the combustion process with more complete and efficient combustion. With global efforts to reduce NOx formation in energy generation, combustion staging strategies like Rich Quench Lean (RQL), Lean-Premixed (LPM), and Exhaust Gas Recirculation (EGR) have gained more attention in research. The major challenge that exists in the research sector is the ability to evaluate and further develop these techniques at a fundamental level. …

Numerical And Experimental Evaluation Of A Simple, Low-Energy Lunar Volatile Separation Technology, Eleanor L. Zimmermann

Dissertations, Master's Theses and Master's Reports

In-situ resource utilization (ISRU) is the practice of finding, extracting, and using the local resources found on extraterrestrial bodies, such as the Moon and Mars. ISRU enables in-situ production of mission consumables—such as rocket fuel and potable water—which will be critical for establishing a sustainable human presence on the Moon, a goal NASA intends to accomplish by 2028 with the Artemis missions. The separation and liquefaction of locally extracted volatiles—such as water, CO₂, and Methane—is an essential component in lunar surface sustainability, but there are very few technologies being developed for this purpose. This report introduces the Radiative …

Advancing Sustainable Co2 Mitigation: Experimental And Computational Analysis Of Thermal Carbon Chitosan Sorbent For Automotive Exhaust Capture, Dalia A. Ali Dr., Amir Ahmed Elgamal Eng., Rania Rushdy Moussa Dr.

Chemical Engineering

This study investigated the efficiency of thermal carbon chitosan (TCCS) sorbent for CO2 capture from vehicle exhaust emissions within a designed adsorption system. TCCS was synthesized and meticulously characterized using a series of analytical techniques, including Brunauer-Emmett-Teller (BET) surface area analysis, Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), Ther- mogravimetric Analysis (TGA), Energy Dispersive X-ray Spectroscopy (EDX), and Differential Scanning Calo- rimetry (DSC). The TCCS adsorbent showed high thermal stability and a heating value (HHV) of 23.5 MJ/kg. Adsorption isotherm study demonstrated that the maximum capacity of CO2 adsorption is 0.084 kg.CO2/kg. TCCS, as well …

Predicting Simulation Times For Multiphase Thermal-Hydraulic Models, Andrew Yule, Andrew Taylor

SMU Data Science Review

Addressing the challenge of computationally intensive OLGA

simulations in the oil and gas industry, a machine learning framework is

developed for accurate runtime prediction. A specialized feature extraction

pipeline identifies key parameters—such as simulation time, time step,

number of branches, and section count—from OLGA input files that serve as

high-impact predictors. Multiple predictive models, including regression,

tree-based ensembles, and neural networks, are implemented to validate

accuracy and robustness. Results reveal that prioritizing simulations based on

predicted runtimes optimizes licensing resources and reduces operational

costs, making real-time scheduling more efficient. This research demonstrates

the effectiveness of data-driven runtime prediction in enhancing …

Non-Reciprocal Coupling Of Minimal Active Colloids Under Confinement: Rotating Ferromagnetic Janus Particles Near Boundaries, Amrutha Raghu

LSU Doctoral Dissertations

Active colloids are microscopic particles that convert energy at the single-particle level into sustained motion and dynamically evolving assemblies. Their ability to transform continuous energy input into controlled motion opens new frontiers in microrobotics, adaptive materials, and targeted transport. Yet, achieving efficient propulsion at the microscale remains fundamentally challenging because viscous forces dominate while inertia becomes negligible. Unlike macroscopic systems that sustain propulsion through momentum, active colloids must harness non-reciprocal interactions with the surrounding fluid to generate persistent, time-irreversible motion. Studying minimal active systems—the simplest realizations that still capture the essential physics—provides a powerful route to uncover the non-equilibrium principles …

Equilibration And Transport Of Binary Mixtures On Planar And Porous Nanomaterials, Andrew Torres

Electronic Theses and Dissertations

We present results of a Kinetic Monte Carlo investigation of the adsorption dynamics of binary gas mixtures on planar and porous sorbents, with a focus on identifying and characterizing kinetic processes involved in uptake evolution and how they influence equilibrium conditions. We also investigate varying thermodynamic simulation parameters such as interactions, alkane lengths, partial pressures and pore configurations to determine how they impact these kinetic processes as well as equilibrium properties. This study matters both for better understanding how kinetics and equilibrium are connected and for improving practical techniques in separation applications. For planar surfaces, weak species overshoot kinetic processes …

Theoretical And Experimental Investigation Of Liquid-Liquid Phase Separation: Characterizing Elastin-Like-Polypeptides, Adam D. Quintana

Chemical and Biological Engineering ETDs

This dissertation develops and validates a semi-empirical Flory–Huggins-based interaction model, combined with Cahn–Hilliard simulations, for predicting multi-component liquid–liquid phase separation (LLPS) in elastin-like polypeptide (ELP) systems. Equilibrium droplet compositions, measured using a PDMS-based microfluidic device, enabled direct parameterization of interaction coefficients. The model was applied to generate phase diagrams and assess composition dependence in ternary mixtures. Cahn–Hilliard simulations were conducted to explore potential phase morphologies under different interfacial conditions. Multi-component Lattice Boltzmann simulations were implemented to model droplet morphology evolution under varying interfacial and diffusive parameters, reproducing experimentally relevant morphologies. A three-phase wetting study revealed conditions for selective wetting and …

Experimentally Driven Numerical Model Of Carbon/Polyaniline-Based Glucose Monitoring Sensors: An Evaluation Using A New Figure Of Merit, Ziad Khalifa, Kyrillos Selim, Amira Ali, Sameh Abdellatif

Chemical Engineering

This study presents an experimentally driven numerical model for evaluating carbon/polyaniline (PANI)- based glucose monitoring sensors (GMSs), focusing on innovative configurations using graphene-PANI and carbon nanotube (CNT)-PANI composites. We performed a thorough analysis of the morphological, electrophysical, and electrical properties of these materials, ultimately leading to the extraction of key electrical parameters for integration into a finite element model (FEM). This model simulates the entire sensor, enabling the estimation of critical performance metrics such as sensitivity, limit of detection (LOD), linearity, and power consumption. Our findings demonstrate that the CNT-PANI configuration significantly outperforms the laser-induced graphene (LIG)-PANI electrode, achieving a …

Comprehensive Review Of Sensible Thermal Storage Systems For Cooking Applications, Anna K. Shariishoy

Tanzania Journal of Engineering and Technology (TJET)

This paper reviewed the sensible thermal storage systems specifically designed for cooking applications. The review focuses on the characteristics of storage materials, their practical applications, and the overall performance of the systems. The review consolidated an array of experimental and numerical research published across various sources such as journals, conferences, books, online resources, and professional reports. A systematic review is used to reach the conclusion of this paper. Significant findings from this study include the wide range of storage capacities attained from small-scale systems that can store ~1–5 MJ of energy for a single meal to bigger systems that can …

Evaluation Of Thermal And Emission Performances Of Briquettes Produced From Carbonized Corn Cob And Corn Husk, Karina S. Motani

Tanzania Journal of Engineering and Technology (TJET)

The Mozambican agro-industrial sector relies heavily on various crops, with maize being the most significant. During processing, substantial waste is generated, which is often discarded as organic matter or burned, contributing to environmental pollution and the loss of potential energy resources. This study evaluated the thermal and emission performance of briquettes made from carbonized corn cob (CCC) and carbonized corn husk (CCH), using cashew nut skin as a binder for clean cooking applications. The briquettes were assessed against firewood and charcoal as control fuels, focusing on several energy performance parameters: water boiling time (WBT), combustion index (CI), thermal efficiency (TE), …

Predicting The Influence Of Aggregate Size And Distribution On Cementitious Concrete Properties: A Review, Innocent J. Macha

Tanzania Journal of Engineering and Technology (TJET)

Cement concrete has been in use for centuries as one of the primary construction materials. Its demand in the construction industry is expected to continue for several centuries before the full development of alternative products. However, one of the main areas of research interest is understanding how its constituents can be tailored to make its properties predictable to reduce risks associated with structural failures, reconstruction and reduced durability. These hindrances associated with cementitious concrete result from several attributes, including constituent material characteristics, mixing ratios and workmanship. Understanding the predictability of cement concrete properties requires computer modelling tools to provide reliable …

Root Cause Analysis Of Performance Degradation For An Xyz Thermal Power Plant In Tanzania, Simon I. Marandu

Tanzania Journal of Engineering and Technology (TJET)

Thermal power plants in Tanzania have been experiencing performance degradation, typically arising from component and subsystem failures, which contribute to power system instability and unreliability. This paper presents a case study of the root causes of performance degradation of an XYZ thermal power plant. The study was conducted by reviewing plant documentations, including maintenance and operational data logbooks, and by standardising the approach through the adoption of ISO 14224:2016 for maintenance and reliability data exchange. Data evaluation was carried out using principal component analysis and scree plot analytical techniques to enhance the depth and accuracy of root cause identification. Additionally, …

Zn–Assisted Synthesis Of M (Mn/Fe/Co/Ni)-N-C Catalysts For Multifunctional Electrochemical Activity, Kemila A. Chaudhary

Electronic Theses & Dissertations

The design and development of atomically dispersed M-N-C catalysts (metal (M) supported on an nitrogen-carbon (NC) matrix with high multifunctional electrocatalytic performance is desirable but proved to be very challenging. Herein, we synthesized M-N-C catalysts (M = Fe, Co, Mn, and Ni) using Zn-assisted high temperature treatment and characterized using various techniques. The prepared catalysts were tested for their electrocatalytic performance towards oxygen and hydrogen evolution reaction (OER and HER) as well as oxygen reduction reaction (ORR) in alkaline media. The results indicated that Mn-N-C catalyst showed higher performance towards both the ORR (E_1/2 = 0.90 V) and …

Ultrafast Laser Surface Structuring For Wettability Control On Copper, Akshay Arvind Nagvenkar

All Theses

Wettability is a crucial surface property influencing various phenomena, including heat transfer, cell adhesion, and corrosion. Engineering devices can achieve superior performance by precisely manipulating surface wettability. As a result, extensive research has focused on developing surfaces that exhibit either extreme water attraction (superhydrophilic) or strong water repellency (superhydrophobic). Tailoring surface wettability paves the way for numerous applications, such as drag reduction in marine vessels, controlled drug delivery, efficient water collection, advanced liquid transport systems, oil-water separation, anti-corrosion coatings, friction reduction, and self-cleaning materials. Ultrafast laser surface structuring is a promising approach for engineering multifunctional surfaces, effectively modifying material properties …

Using Gaussian Process Regression To Learn Thermodynamic Equations Of State With Uncertainty Quantification, Austen T. Lee

Chemical Engineering Undergraduate Honors Theses

This study investigates the use of derivative-informed Gaussian Process (GP) models to estimate thermodynamic behavior across temperature and density by building a Helmholtz-based equation of state. Argon, a stable monatomic gas, was chosen as a case study within the vapor region. The GP model was trained using values of experimentally measurable properties found by taking first and second derivatives of the original potential function. Results show that while the GP model offered uncertainty quantification and informed thermodynamic behavior, it predicted values that deviated from the ground truth depending on the property. The model exhibited high confidence in regions with substantial …

Cellulose Recovery From Waste Denim Fabrics Through Indigo Vat Dye Reduction And Spandex Dissolution, Tito N. Venance

Tanzania Journal of Engineering and Technology (TJET)

This study addresses environmental conservation by tackling end-of-life management for post-consumer denim garments through the recycling of cotton fibres from waste denim. The purification process involved dithionite reduction of vat dyes in the presence of an alkali followed by selective dissolution of spandex using N,N-dimethylformamide (DMF). Optimal conditions for dye removal were determined at 90°C for 120 minutes with sodium hydroxide at 25 g/L, sodium dithionite at 6 g/L and PVP at 4.5 g/L, while spandex extraction was achieved using a 5% DMF solution at 70°C for 4 hours. Ultraviolet (UV)-vis spectrophotometric analysis indicated a significant increase in whiteness (DL*). …