Utilization Of Caputo Fractional Derivative In Mhd Nanofluid Flow With Soret And Thermal Radiation Effects, 2024 Ganpat University
Utilization Of Caputo Fractional Derivative In Mhd Nanofluid Flow With Soret And Thermal Radiation Effects, Harshad Patel, Gopal Nanda
Applications and Applied Mathematics: An International Journal (AAM)
In existence of heat diffusion and thermal radiation, an analytical equation is found for unsteady MHD flow past an exponentially accelerating vertical plate in optically thick water based nanofluid. The governing equations are made dimensionless by similarity transformation. A definition of Caputo fractional derivative is applied to generalize governing system of partial differential equations. Laplace transform techniques are applied and obtained the analytical solutions of proposed problems. For a physical point of view, numerical results are obtained using MATLAB software and presented via graphs. From the results, it is concluded that magnetic fields tend to reduce velocity. It is also …
Thermal, Electrical, And Spin Transport: Encompassing Low-Damping Ferromagnets And Antiferromagnetic/Ferromagnetic Heterostructures, 2024 University of Denver
Thermal, Electrical, And Spin Transport: Encompassing Low-Damping Ferromagnets And Antiferromagnetic/Ferromagnetic Heterostructures, Matthew Ryan Natale
Electronic Theses and Dissertations
Continuing technological advancements bring forth escalating challenges in global energy consumption and subsequent power dissipation, posing significant economic and environmental concerns. In response to these difficulties, the fields of thermoelectrics, spintronics, and spincaloritronics emerge as contemporary solutions, each presenting unique advantages. Thermoelectric devices, based on the Seebeck effect, other a passive, carbon-free energy generating solution from waste heat. Although current thermoelectric technology encounters hurdles in achieving optimal efficiencies without intricate designs or complex materials engineering, recently research into low-damping metallic ferromagnetic thin films have provided a new method to enhance spin wave lifetimes, thus contributing to thermoelectric voltage improvements. As …
Carbon Dioxide Gasification Of Biochar: A Study On Utilizing Captured Co2 To Mitigate Greenhouse Gas Emission And Improving Carbon Conversion Efficiency, Nnamdi Ofuani
Electronic Theses and Dissertations
With rapidly growing global economies and world population, fossil fuel continues to play a major role in meeting current energy demands. Carbon capture and storage (CCS) technologies have, hence, been implemented to reduce CO2 emissions in the atmosphere. With the implementation of CCS technologies comes the need to utilize the captured CO2. This research, therefore, proposes CO2 gasification of biochar as a viable carbon utilization pathway. With captured CO2 coming at various concentrations, there is a need to understand how CO2 concentration affects biochar conversion to useful products. This study, therefore, evaluates the effects …
Microplate-Like Metal Pyrophosphate Engineered On Ni-Foam Towards Multifunctional Electrode Material For Energy Conversion And Storage, 2023 Pittsburg State University
Microplate-Like Metal Pyrophosphate Engineered On Ni-Foam Towards Multifunctional Electrode Material For Energy Conversion And Storage, Rishabh Srivastava
Electronic Theses & Dissertations
High clean energy demand, dire need for sustainable development, and low carbon footprints are the few intuitive challenges, leading researchers to aim for research and development for high-performance energy devices. The development of materials used in energy devices is currently focused on enhancing the performance, electronic properties, and durability of devices. Tunning the attributes of transition metals using pyrophosphate (P2O7) ligand moieties can be a promising approach to meet the requirements of energy devices such as water electrolyzers and supercapacitors, although such a material’s configuration is rarely exposed for this purpose of study.
Herein, we grow …
Computationally-Driven Insights Into The Ligand Environments Of Materials For Catalysis And Separations, 2023 Clemson University
Computationally-Driven Insights Into The Ligand Environments Of Materials For Catalysis And Separations, Stephen Vicchio
All Dissertations
Designing new catalytic and sorption materials is necessary to limit global temperature rise below 1.5 ◦C by 2050, while also meeting global energy demands. Climate change and energy production are not mutually exclusive; global population growth has direct impacts on global energy demands and climate. In both catalysis and adsorption applications, new technologies are needed to address these challenges. Catalysis can provide alternate, low-energy routes for converting low-value gases into higher-value chemical commodities, thus altering our current energy production. Likewise, new sorption materials can capture previously emitted CO2 from decades of energy production from fossil fuels, thus helping to …
Assessing The Thermodynamic Potential Of Deep Eutectic Solvents In The Absorption Of Greenhouse Gases Through Computational Methods, 2023 Florida Institute of Technology
Assessing The Thermodynamic Potential Of Deep Eutectic Solvents In The Absorption Of Greenhouse Gases Through Computational Methods, Thomas Michael Quaid
Theses and Dissertations
Greenhouse gas (GHG) capture is a fundamental technology in the fight against climate change. Some species of devastating GHGs like fluorinated compounds are released directly to the air from industrial processes. Some GHGs are co-produced in sustainably derived biofuels which require absorptive upgrading. The development of more efficient, cost effective, and environmentally friendly methods of capturing GHG’s from pollutant sources and industrial streams is of utmost importance in the fight against climate change. Deep eutectic solvents have entered the separations stage as potential disruptors to conventional solvent choices for a variety of applications. Deep eutectic solvents (DES) are compounds of …
Use Of Photo Isomers To Enhance The Removal Of Lignin From Woody Biomass Hydrolysate, 2023 University of Maine
Use Of Photo Isomers To Enhance The Removal Of Lignin From Woody Biomass Hydrolysate, Dipesh J. Karki
Electronic Theses and Dissertations
In this investigation we propose a novel method to enable precipitation of desired solutes using photo-isomers in the extraction solvent. This photo-switchable solvent would enable dissolution or precipitation of desired components using alternating UV or visible light to modify the solubility of the compounds of interest. Three photo-isomers namely native azobenzene, diethoxy azobenzene and diethylamino azobenzene were studied in three different organic solvents: medium chain length alcohol, ethanol and acetone. It was found that among the different combinations of solvent and photo-isomer, acetone and the 4,4’-diethoxy azobenzene solution was most efficient at precipitating dissolved lignin in response to UV light …
Measuring Of Thermal Conductivity And Heat Capacity Of Different Papers And Heat-Sealing Process Of Papers With A Polymer Layer, 2023 University of Maine
Measuring Of Thermal Conductivity And Heat Capacity Of Different Papers And Heat-Sealing Process Of Papers With A Polymer Layer, Amenah Khalaf
Electronic Theses and Dissertations
Packaging is an important and safe way to protect our food and other things through transportation, but the use of plastic based packaging is causing issues with plastic pollution. To replace plastic packaging with a paper-based option that has a barrier coating, good heat sealing will be needed to be a drop-in replacement. While much as been studied on the heat sealing of polymer layers, little has been reported around the heat sealing of paper that has a polymeric barrier coating.
Experiments were conducted to characterize the thermal conductivity and heat capacity of paper as a function of press pressure …
Efficient Sintering Of Lunar Soil Using Concentrated Sunlight, 2023 University of Maine
Efficient Sintering Of Lunar Soil Using Concentrated Sunlight, Diprajit Biswas
Electronic Theses and Dissertations
Construction material is one crucial need for long-term habitation on the moon. When concentrated for high heat flux, solar radiation can heat lunar soil or regolith until it sinters at temperatures above 900°C. The solid, sintered soil simulant can be used as construction material. This work explores the conditions leading to effective lunar soil sintering for both direct and indirect irradiated sintering. Lunar soil simulants were sintered using concentrated light from a xenon-arc lamp with varying heat flux intensity. During direct sintering of LHS-1, a sintering range of 860°C-1140°C corresponding to a peak heat flux of 105-120 kW/m2 was identified …
The Influence Of Heat And Mass Transfer On The Setting Rate Of Adhesives Between Porous Substrates, 2023 The University of Maine
The Influence Of Heat And Mass Transfer On The Setting Rate Of Adhesives Between Porous Substrates, Mubarak Mohammed Khlewee
Electronic Theses and Dissertations
The dynamic penetration of fluid into a porous media where other changes are occurring such as temperature or concentration is of interest to a number of situations. However, little experimental and theoretical analysis of this situation is found in the literature where most of the previously published works have studied the penetration with constant physical properties, where there is no change of the fluid as it enters the pores. This situation is important in the setting of adhesives in porous medium such as in the setting of hot melt and water-based adhesives in the production of paper based packaging. The …
The Study Of Corrosion On Additive-Manufactured Metals., 2023 University of Louisville
The Study Of Corrosion On Additive-Manufactured Metals., Braydan Daniels
Electronic Theses and Dissertations
The purpose of this study was to investigate and compare the corrosion mechanisms between wrought and additive-manufactured (3D-printed) copper and stainless steel. The experimental procedure consisted of measuring the open circuit potential, electrochemical impedance spectroscopy, linear sweep voltammetry, Tafel analysis, surface topology, and scanning electron microscopy for each metal within salt water, tap water, sulfuric acid, and synthetic body fluid (excluding copper in synthetic body fluid).
Overall, printed stainless steel was more corrosion-resistant than wrought stainless steel in tap water and synthetic body fluid based on OCP, LSV, and surface topology results. Additionally, printed copper was more corrosion-resistant than wrought …
Heat Transfer From Plates, 2023 University of Arkansas, Fayetteville
Heat Transfer From Plates, Leanza Trevino
Chemical Engineering Undergraduate Honors Theses
The purpose of this honors thesis is to create an experiment for the CHEG Lab I course. This is a continuation of work done by Alexa Moreno. She created an experiment to model free convection of a horizontal plate. In this report, free and forced convection of a vertical and horizontal plate, respectively are modeled. This report explains the motivation for creating this heat convection experiment, the results of performing the experiment, and provides recommendations for future work on this experiment. Lab handouts are included in the Appendix.
Bridging The Gap Between Phase Behavior And Processing For Renewable And Refinable Carbonaceous Precursors, 2023 Clemson University
Bridging The Gap Between Phase Behavior And Processing For Renewable And Refinable Carbonaceous Precursors, Graham Tindall
All Dissertations
As a category of materials, engineered carbons, specifically carbon fibers, are first-in-class for properties such as modulus, specific strength, and thermal resilience; however, the inability to directly process atomic carbon necessitates the development and optimization of carbonaceous precursors. Because the structure and properties of carbon are highly dependent on the precursors and requisite processing, numerous materials have been investigated as feedstocks for large-scale production. Although cellulose and rayon were among the first investigated, polyacrylonitrile (PAN) is the current hegemon of carbon fiber precursors. PAN feeds 90% of this market, but it is neither inexpensive nor renewable. Because a significant fraction …
Probing The Structure Of Water On Surfaces: From Water Absorption To Ice Nucleation, 2023 Clemson University
Probing The Structure Of Water On Surfaces: From Water Absorption To Ice Nucleation, Jiarun Zhou
All Dissertations
Water, essential for all life forms, is the most abundant, simple, yet mysterious molecule in the world. This molecule, consisting of only three atoms, behaves in unexpectedly different ways with the change of environment. In the past, studies of water under different conditions (temperature, pressure, on the surfaces, with confinement) have been conducted using experimental and computational methods. However, the influence of a given environment on water properties is yet to be fully understood. This dissertation studies water at complex interfaces (surfaces with various chemistry and physics properties) in both the liquid and crystalline states. Various heterogeneous systems used to …
A Molecular Dynamics Study Of Structural Modifications Of Perarylphosphonium Based Ionic Liquids On The Melting Point, 2023 University of South Alabama
A Molecular Dynamics Study Of Structural Modifications Of Perarylphosphonium Based Ionic Liquids On The Melting Point, Johnathan Anderson
<strong> Theses and Dissertations </strong>
Several perarylphosphonium based mesothermal ionic liquids (ILs) have been shown to be stable at high temperatures for prolonged periods of time and with high heat capacities making them good candidates for use in many processes such as usage as a heat transfer fluid, as an absorbent for separation of aromatics from aliphatics, and as a solvent for high temperature reactions. Many, however, have melting points above 100o C, limiting their use. Recently, it was shown that the melting point of an IL can be lowered by simply increasing the dipole moment of the cation or by structurally rigidifying the …
Non-Equilibrium Colloidal Phenomena In Magnetic Fields And Photoillumination: From Controlling Living Microbots To Understanding Microplastics, 2023 Louisiana State University and Agricultural and Mechanical College
Non-Equilibrium Colloidal Phenomena In Magnetic Fields And Photoillumination: From Controlling Living Microbots To Understanding Microplastics, Ahmed Al Harraq
LSU Doctoral Dissertations
Colloids are a ubiquitous class of materials composed of microscopic particles suspended in a continuous phase which are found in everyday products and in nature. Colloids are also useful models for studying the spontaneous arrangement of matter from individual building blocks to mesophases. Standard treatment of colloid science is based on the assumption of equilibrium conditions, as defined in traditional thermodynamics. However, novel assembly mechanisms and motility are unlocked by pushing colloids away from equilibrium using external energy. In addition, many colloids in nature and in industrial applications exchange energy and mass with the surrounding environment thus behaving in a …
Supplementary Code For "Chain Trajectories, Domain Shapes And Terminal Boundaries In Block Copolymers", 2023 University of Massachusetts Amherst
Supplementary Code For "Chain Trajectories, Domain Shapes And Terminal Boundaries In Block Copolymers", Benjamin R. Greenvall, Michael S. Dimitriyev, Gregory M. Grason
Data and Datasets
Supplementary code used for the publication "Chain trajectories, domain shapes and terminal boundaries in block copolymers" by Benjamin R. Greenvall, Michael S. Dimitriyev, and Gregory M. Grason. Includes code for extracting and analyzing polar order and chain trajectories from self-consistent field calculations of block copolymers.
Fugacity-Based Lattice Boltzmann Method For Multicomponent Multiphase Systems, 2023 Old Dominion University
Fugacity-Based Lattice Boltzmann Method For Multicomponent Multiphase Systems, Muzammil Soomro, Luis F. Ayala, Cheng Peng, Orlando M. Ayala
Engineering Technology Faculty Publications
The free-energy model can extend the lattice Boltzmann method to multiphase systems. However, there is a lack of models capable of simulating multicomponent multiphase fluids with partial miscibility. In addition, existing models cannot be generalized to honor thermodynamic information provided by any multicomponent equation of state of choice. In this paper, we introduce a free-energy lattice Boltzmann model where the forcing term is determined by the fugacity of the species, the thermodynamic property that connects species partial pressure to chemical potential calculations. By doing so, we are able to carry out multicomponent multiphase simulations of partially miscible fluids and generalize …
More On The Demons Of Thermodynamics, 2023 University of San Diego
More On The Demons Of Thermodynamics, Daniel P. Sheehan, Garret Moddel, James W. Lee
Chemistry & Biochemistry Faculty Publications
No abstract provided.
Evaluating The Impact Of Increased Cycling On Thermal Power Plants Due To Wind Energy Penetration In The Midwest: A Case Study, 2023 South Dakota State University
Evaluating The Impact Of Increased Cycling On Thermal Power Plants Due To Wind Energy Penetration In The Midwest: A Case Study, Joscelyne Larson
Electronic Theses and Dissertations
One of the most significant shifts in the mix of U.S. electricity generation over the past few years has been the rapid expansion of renewable energy resources, especially solar and wind. However, fossil fuels are still necessary to fulfill the world’s energy requirements. Despite efforts to increase the use of renewable energy sources, these sources can be at times unreliable, causing countries around the world to continue to rely on base load units such as coal and natural gas. This decrease in fossil fuels and increase in renewable energy sources presents many complex issues in terms of power system planning, …