Chemical Engineering Commons^™

Graphite Particles Modified By Zno Atomic Layer Deposition For Li-Ion Battery Anodes, Ahmad Helaley, Han Yu, Xinhua Liang

Chemical and Biochemical Engineering Faculty Research & Creative Works

Graphite, with a modest specific capacity of 372 mA h g−1, is a stable material for lithium-ion battery anodes. However, its capacity is inadequate to meet the growing power demands because the formation of an irregular solid electrolyte interphase (SEI) can result in unstable performance. In this research, we used a few cycles of atomic layer deposition (ALD) to deposit ZnO on graphite particles as an anode with improved electrochemical stability. Transmission electron microscopy revealed that ZnO was in the form of nanoparticles due to the inert surface properties of graphite and only a few cycles of ALD. Electrochemical characterization …

Experimental Investigation Of Heat Transfer Behavior In Spouted Bed Reactors Under Different Operating Conditions, Hasan A. Abdulwahab, Abbas J. Sultan, Amer A. Abdulrahman, Hasan Sh Majdi, Haydar A.S. Aljaafari, Zahraa W. Hasan, Laith S. Sabri, Bashar J. Kadhim, Jamal M. Ali, Muthanna H. Al-Dahhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

Abstract: Spouted bed reactors (SBRs) are highly valued for their effectiveness in chemical and biochemical processes due to their mixing and heat transfer capabilities. Understanding the heat transfer mechanisms in these reactors is necessary. This research delves into the heat transfer behavior of SBRs, which plays a role in enhancing their performance under operational conditions. The study conducted experiments to measure the heat transfer coefficient (HTC) at varying gas velocities (ranging from 0.32 to 0.74 m/s) at radial positions (r/R = 0, ±0.28, ±0.56, and ±0.85) and axial levels (H/D = 0.8, 2.1, and 3.5) within the spouted bed (SB) …

Incorporating Insulin Into Alginate-Chitosan 3d-Printed Scaffolds: A Comprehensive Study On Structure, Mechanics, And Biocompatibility For Cartilage Tissue Engineering, Afsaneh Jahani, Mohammad Sagdegh Nourbakhsh, Ali Moradi, Marzieh Mohammadi, Lobat Tayebi

Electrical & Computer Engineering Faculty Publications

Osteoarthritis is a leading cause of disability worldwide, challenging current treatments to limited cartilage self-healing capacity. Cartilage tissue engineering (CTE) integrates cells, scaffolds, and signaling molecules, with Insulin being utilized as a differentiation biomolecule due to cost-effectiveness, dose-dependent influence on chondrogenesis, suitable biological activity, and ability to activate relevant receptors. Yet, administering differentiation biomolecules through conventional scaffolds poses a persistent challenge. Alginate (Alg) is commonly employed in CTE for its biocompatibility, though it lacks sufficient mechanical properties. Chitosan (Cs), while enhancing scaffold mechanical properties, but does not independently provide optimal support for chondrogenesis. While Alg-Cs scaffolds have garnered attention, challenges …

Pla Polymer Binder In Core Production - Influence On Final Casting Dimensions, Artur Soroczyński, Krzysztof Rechowicz

Virginia Digital Maritime Center (VDMC) Faculty Publications

The foundry industry is seeking an ecological alternative to synthetic molding resins. This study evaluates the technological properties of core sands bonded with biodegradable polylactide (PLA). Cores prepared on a 2% quartz sand matrix were subjected to casting processes using two alloys with extremely different pouring temperatures: gray cast iron (approx. 1200 °C) and AK11 silumin (approx. 710 °C). The research methodology included macroscopic assessment, dimensional analysis using 3D scanning (GOM Inspect), and qualitative knock-out assessment supported by numerical temperature field simulation. The results showed that the high crystallization temperature of cast iron leads to complete thermal degradation of the …

Numerical Modelling And Co-Optimization Of Gasoline Fuels For Gasoline Compression Ignition Using Multi Component Approach, Ashwin Karthik Purushothaman

Dissertations, Master's Theses and Master's Reports

Future mobility is expected to rely on a broad spectrum of powertrain technologies, including battery electric vehicles (BEVs), hybrid electric vehicles (HEVs), fuel cell electric vehicles (FCEVs) and traditional internal combustion engine (ICE) vehicles. Despite the shift toward electrification, internal combustion engines are projected to remain a key component of future powertrains, either as the primary power source or as range extenders to generate electricity in hybrid systems. As such, significant research efforts continue to focus on enhancing the efficiency and reducing the emissions of ICEs to meet increasingly stringent regulatory and environmental targets. Gasoline compression ignition (GCI) has been …

Cfd Analysis Of Hydrodynamic Cavitation Through An Orifice: Influence Of Different Inlet Pressures And Number Of Orifice Holes, Lemthong Chanphavong, Vongsavanh Chanthaboune, Keophousone Phonhalath

ASEAN Journal on Science and Technology for Development

Hydrodynamic cavitation (HC) is considered an energy-efficient process with high potential for utilization in many chemical processes. This study presents a computational fluid dynamics (CFD) analysis of cavitating flow through an orifice with a constant flow area. The Reynolds-Averaged Navier-Stokes (RANS) equations, coupled with turbulence and cavitation models, are employed to capture the complex flow behaviors. The effects of inlet pressures and number of orifice-holes on cavitation behavior are investigated. Result of the numerical simulation is validated with the existing experimental data from the literature. The CFD study revealed that cavitation initiates just behind the inlet edge of the orifice …

Thermo-Rheological And Tribological Properties Of Low- And High-Oleic Vegetable Oils As Sustainable Bio-Based Lubricants, Abiodun Saka, Tobechukwu K. Abor, Anthony C. Okafor, Monday U. Okoronkwo

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Vegetable oil-based lubricants have attracted increased research attention in recent decades as sustainable alternatives to conventional petroleum-based lubricants in metal machining. However, more studies are required to fully elucidate the thermo-rheological and tribological properties. This study presents an investigation of the thermo-rheological and tribological properties of different vegetable oils, including low- and high-oleic soybean oil, high-oleic sunflower, safflower, and canola oils. The lubricity, and evolution of viscosity and thermodynamic properties as a function of temperature were investigated to obtain important parameters including the viscosity index, flow behavior index, flow activation energy, specific heat capacity, thermal conductivity, coefficient of friction, contact …

Multi-Scale Dynamic Modeling, Validation, And Uncertainty Quantification Of Radial Flow Fixed Bed Contactors For Co2 Capture, Ana Flávia De Alencar Arraes Monteiro

Graduate Theses, Dissertations, and Problem Reports (ETD)

One of the key sources of carbon dioxide emissions to the environment is fossil fuel combustion for power generation. Post-combustion CO2 capture using amine-based solvents is currently the most matured process. However, amines are corrosive and lead to degradation products at even moderate temperatures generating environmental pollutants, and require high energy for regeneration. Solid sorbents are a promising alternative. They possess lower regeneration energy, thermal stability, and have highly tunable porous structures with large surface area that can help in achieving high loading and high adsorption rates. This work focuses on mathematical modeling of CO2 adsorption/desorption processes using solid sorbents. …

Modeling And Simulation Of A Process For Upcycling Of Low-Density Polyethylene Plastic Waste To Ethylene, Xiaoyan Wang

Graduate Theses, Dissertations, and Problem Reports (ETD)

Ethylene is one of the most widely produced petrochemicals, with an estimated global output of 180 million metric tons in 2022. Approximately 82 million metric tons of ethylene are used annually for plastic production, primarily for polyethylene (PE), as well as polypropylene (PP) and polyvinyl chloride (PVC). The CO₂ emissions associated with PE production were approximately 14 million metric tons in 2022. Globally, an estimated 70 million metric tons of PE are produced and consumed each year, with the majority (~79%) ending up in landfills or the environment.

This project proposes a novel process in which waste low-density polyethylene (LDPE) …

Microwave-Assisted Reduction Of Critical Metal Oxides From E-Waste Mixture, Kurundu Shavinka Jayasekera

Graduate Theses, Dissertations, and Problem Reports (ETD)

The efficient recovery of critical metals such as tantalum (Ta), manganese (Mn), gallium (Ga), and indium (In) from electronic waste (e-waste) is essential for resource sustainability and environmental protection. This research uses microwave-assisted treatment to investigate the carbothermal reduction of these four specific metals from their oxides in a simulated e-waste mixture, with carbon black serving as both a microwave coupling and reduction agent. Microwave processing is used specifically because it offers a rapid and energy-efficient alternative to conventional thermal methods, with the benefits of intrinsic heating and selective heating of materials. The first experiments centered on understanding the effects …

Augmentation And Hybridization Of Conventional Forms Of Process Control With Advanced Control Methods, Daniel Paul Beahr

Graduate Theses, Dissertations, and Problem Reports (ETD)

Within the last decade in the field of process control, there has developed a distinct gap between the technological advancements of today and the well-established theory that has preceded it. This is most evident where the novel developments and structures often outpace the necessary guarantees and strong foundation required to ensure the possibility of widespread adoption. Therefore, the goals of this work are to broadly integrate those novel advanced control methods into the field of process control in such a way to increase the applicability and encourage implementation.

The first portion of this work seeks to further explore the nature …

Modeling And Simulation Of Carbon-Neutral Strategies For Methanol Production, Omar Almaraz Barrios

Graduate Theses, Dissertations, and Problem Reports (ETD)

Methanol is a versatile chemical that can be used as a fuel, a solvent, a feedstock for other chemicals, and a hydrogen carrier. Methanol production from natural gas, which is mainly composed of methane, is a well-established process that involves steam reforming, methanol synthesis, and methanol purification. However, this process is energy-intensive and emits large amounts of carbon dioxide, which contributes to global warming and climate change. Therefore, there is a need for alternative methods of methanol production that are more efficient and environmentally friendly. The overall objective of this research is to develop simulation models of two novel methanol …

Development, Synthesis And Characterization Of Advanced Low- Cobalt And High-Nickel Cathode Materials For Lithium-Ion Batteries, Arjun Patel

Theses and Dissertations

This dissertation focuses on the improvement of structural and electrochemical stability of active materials for lithium-ion batteries. It explores the modification strategies to mitigate the issues related to Ni-rich cathode materials, along with the continuous production of cathode precursors using a slug flow reactor to improve the quality of the product.

The First part of the dissertation examines the effect of substitution of cobalt with aluminum and iron on the electrochemical stability of Ni-rich lithium nickel cobalt manganese oxide (NCM) materials. This study investigates how Al and Fe doping work and how they impact the performance and stability of these …

Integrating Medical Plastic Waste Pyrolysis And Circular Economy For Environmental Sustainability, Attia Attia, Mohamed Bassyouni Prof., Reem Nasser Eng., Moataz El-Bagoury Eng., Islam Shaker Eng., Yasser Elhenawy Prof., Dina Aboelela Dr.

Biochemical Engineering

A critical assessment of pyrolysis technologies and reactor designs was discussed, highlighting various reactor configurations. This study explored the influence of catalysts, temperature, heating rate, and residence time on the pyrolysis process, and addressed their effects on product distribution and composition. Safety considerations and strategies for mitigating the potential environmental impacts of pyrolysis were presented. Comparative analyses of the environmental impacts of traditional waste disposal methods versus pyrolysis-based approaches provided insights into the potential reduction of greenhouse gas emissions and other pollutants. The circular economy approach was explored in the context of medical plastic waste pyrolysis. The potential for closing …

Investigations Of Conjugate Heat Transfer And Fluid Flow In Partitioned Porous Cavity Using Darcy-Forchheimer Model: Finite Element-Based Computations, Nasir Yasin, Shafee Ahmad, Muhammad Umair, Zahir Shah, Narcisa Vrinceanu, Ghadah Alhawael

Mathematics & Statistics Faculty Publications

The conjugate heat transfer and fluid flow has vast applications in thermal engineering, particularly for cooling in thermal devices, and automobile engines. This study investigates conjugate heat transfer in 2D enclosures, featuring thin solid fins attached to a porous bottom wall. The porous medium is considered isotropic and homogeneous by the Darcy-Forchheimer model, with fluid phases in local thermal equilibrium. The boundary conditions at the porous fluid interface ensure continuity of the velocities, stresses, temperature, and heat flux. The phenomenon is mathematically modelled by obtaining a set of partial differential equations. The finite element method (FEM) is used to perform …

Using Preformed Particle Gels To Control Transport In Geothermal Reservoirs: Mathematical Modeling, Philip Winterfeld, Baojun Bai, Yu Shu Wu

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

We are developing swellable Preformed Particle Gels (PPG), which can control preferential fluid and heat flow through fracture networks to increase the performance of EGS reservoirs. Part of this development is a mathematical model and numerical simulator to simulate PPG treatments by considering coupled thermal-hydraulic-mechanical effects, and gel swelling kinetics and plugging efficiency, from which an optimized gel treatment design and operation can be achieved. The starting point for our mathematical model is the TOUGH2-CSM formulation and code. The TOUGH2-CSM fluid and heat flow formulation is based on the TOUGH2 one for multiphase, multicomponent, and multi-porosity systems, with the latter …

Predictive Modeling For Optimal Gel Treatment Design In Brownfields Using Ensemble Machine Learning And Data Upsampling Via Generative Ai, Munqith Aldhaheri, Baojun Bai, Mingzhen Wei

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Efficiently designed gel treatments play a vital role in extending the lifespan of brownfields through rejuvenating oil production. Recently, a three-mode mathematical methodology named the VCR approach has been proposed for designing effective treatments. To optimize this approach, it is crucial to determine the appropriate design mode systematically rather than relying solely on the intuitive judgments of field operators. This study introduces an advanced methodology for predicting the optimal design type of gel treatments using 12 reservoir and production variables. The methodology integrates ensemble machine-learning (EML) models with historical data from 65 field projects across 11 countries (1985-2020). The Random …

Identifying Potential Risk Areas Close To The Oil And Gas Pipelines Due To Subsidence In Qazvin Plain, Mahmoud Rajabi, Sanaz Vajedian, Ryan Smith, Neil Grigg, Hossein Nahavandchi, Mehdi Goli

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Surface displacement caused by natural and anthropogenic activities poses a significant risk to subsurface pipelines, particularly in areas experiencing subsidence. Stress and strain induced by deformation can lead to pipeline buckling and potential vulnerability. This study applies a multidisciplinary approach integrating interferometric synthetic aperture radar (InSAR) deformation analysis, well data, and geological context to assess the risk to oil and gas pipelines in Iran's Qazvin plain. The focus is on evaluating the impact of an unconfined aquifer, which has a lower risk of subsidence compared to a confined aquifer, on pipeline infrastructure. We analyzed multitemporal Sentinel-1 data collected between 2014 …

Computational Modeling Of The Heat Treatment Of White Oak Bound For Spirit Maturation, Kate E. Mclarney-Popham

Theses and Dissertations--Chemical and Materials Engineering

Maturation of distilled spirits in white oak barrels is a long standing practice known to have great impact on spirit character. Much of this impact can be controlled by the thermal modification of the barrel, since thermal degradation of the wood determines what wood compounds are available to interact with the spirit during maturation. In this work, a computational model for the thermal degradation of wood was developed and, with flavor compound data from literature, was used to investigate the effect of heat treatment on lignin-derived flavor compounds. The computational model in this work accounted for three solid species, three …

The Optimization And Manufacturing Scale-Up Of Polymeric Membranes Using Eco-Friendly Solvents, David Lu

Theses and Dissertations--Chemical and Materials Engineering

Polymeric membranes have become a prominent technology applied in water filtration due to the lower cost, energy input, and simpler manufacturing process relative to other separation technologies. However, the environmental impact of polymeric membrane fabrication remains a hindrance due to the use of hazardous solvents derived from fossil fuels (e.g., DMAc, NMP, DMF) that pose a risk to the environment and human health. Whereas recent studies have demonstrated the proof-of-concept of polymeric membrane derived from eco-friendly solvents, the next steps of optimizing and upscaling the production of these membranes remains understudied and a gap between lab-scale studies and the path …