Chemical Engineering Commons^™

An Experimental And Theoretical Critique Of Flow Model Accuracy, Shannon Ray Chollett

LSU Master's Theses

In today’s exploration and production environment it is required that engineers must collect and use vast amounts of data for flow model construction and calibra- tion, as well as reservoir estimation and optimization. With modern technology, the data volume can be overwhelming. It is necessary that data monitoring and calibration are highly efficient. It is also essential that physical and mathematical models can be tested in repeatable, inexpensive experiments. The experiments described in this thesis will develop and perform verification of algorithms and can generate prior geomodels, collect and process seismic refraction data, collect and process production data, and calibrate …

Displacement Of Heavy Oil By Carbon Dioxide In A Tube, Mohammed Almabrouk Ali Ahmad

Masters Theses

"After using primary and secondary oil recovery methods, about two third of the original oil in place is left behind in the reservoir. Enhanced oil recovery (EOR) methods are being used to recover that oil. CO₂ flooding is one of the EOR methods that is used to recover the oil. The interest here lies in recovery of heavy oils. The dissolution of CO₂ in oil reduces oil viscosity and swells it, making it easier to displace the oil. FLUENT is used to solve the problem of CO₂ displacing heavy oil in a tube. Different velocities/capillary numbers (Ca) and …

Effect Of Lipid Composition On The Physical Properties Of Liposomes: A Light Scattering Study, Rajiv Kumar Yandrapati

Masters Theses

"The aim of this study was to investigate the effect of lipid composition on the physical properties of liposomes. Eight different types of liposomes were prepared for this study. Liposomes consisting of phosphatidylcholine (PC) and cholesterol were prepared in three different compositions 80/20, 50/50 and 20/80 respectively. Similarly liposomes consisting of PC and negatively charged phosphatidylserine (PS) were also prepared in three different compositions 80/20, 50/50 and 20/80 respectively. Two liposomes with the compositions 2:2:1:1 (cholesterol:PC:phosphatidylglycerol (PG): phosphatidylethanolamine (PE) ) which resembles the myelin membrane and 10:5:7.5:16 (PC:PE:PS:cholesterol) which mimics rat's neural membranes were also prepared. The liposomes were prepared …

Hydraulic Fracturing Experiments To Investigate Circulation Losses, Maximiliano Liberman

Masters Theses

"In recent years the oil and gas industry has been drilling more challenging wells due to long deviated wells, drilling through already depleted reservoirs, sub salt wells and increasing water depth. A major challenge these wells create is to prevent fluid loss into the formation and wellbore breakouts by having accurately determined the mud weight operational window. In addition to accurately determine the fracture gradient, additives in the drilling fluid have been used to enhance the fracture gradient in an industry process named wellbore strengthening. In order to study the phenomenon of fracture gradient alteration, a hydraulic fracturing apparatus was …

Evaluation Of The Reagan And Lamotte Sandstones In Southwestern Missouri For Carbon Dioxide Sequestration, Todd Jeffrey Miller

Masters Theses

"Carbon dioxide sequestration has been proposed as a way to reduce anthropogenic carbon dioxide emissions. Several characteristics are required in order for a geologic formation to be suitable for sequestration. There must be an impermeable confining layer to restrain CO₂ migration toward the surface, the porosity and permeability must be high enough to allow for long term injection and substantial storage capacity, and the formation must be strong enough for long term injection to occur without inducing fractures. In this work, The Reagan and Lamotte Sandstones near Springfield, Missouri were evaluated for the potential for carbon dioxide sequestration. The Derby-Doe …

Investigation Of Geosteering In Non-Trivial Geological Settings, Anuroop Pandey

Masters Theses

"The well placement technology has advanced to a stage where we can explore small tolerance targets such as thin reservoirs. Well placement with geosteering, which is the real time adjustment of the well path based on the geological responses to place and maintain the well within the best part of the reservoir, is the technology that has made this progress possible. Geosteering however can get very complex with the increasing heterogeneities of the formations and there is no fixed methodology to devise a steering strategy in such complex geological settings. To accommodate this challenge, we investigated three methods to verify …

Surfactant Enhanced Oil Recovery By Wettability Alteration In Sandstone Reservoirs, Omar Elmofty

Masters Theses

"Recovering more oil from existing oil reservoirs using enhanced oil recovery methods holds the key for meeting future energy demands. Even though wettability is a cornerstone in oil recovery, few studies have focused on increasing oil recovery in sandstone reservoirs through wettability alteration. The objective of this thesis is to prove that altering the wettability of a sandstone rock to preferentially water-wet condition will reduce the remaining oil saturation and thus increase the percentage of recovered oil.

Two commercial surfactants were selected after studying both the phase behavior and the interfacial properties of 30 surfactants with oil and 1.00% sodium …

Geomechanical Characterization Of Reservoir & Cap Rocks For Co₂ Sequestration, Sudarshan Govindarajan

Masters Theses

"Geological sequestration of CO₂ has been identified as one method to reduce global emissions of CO₂ and achieve lower levels of CO₂ concentrations in the atmosphere. Geological formations have to be assessed in terms of their capacity, sealing capabilities and economic feasibility before CO₂ sequestration can commence. Potential leakage of injected CO₂ from the reservoir formation could occur due to natural or injection induced faults or fractures in the reservoir or sealing formations. As part of a potential leakage investigation a geomechanical characterization which refers to the assessment of the in-situ stress conditions, rock strength and stiffness properties of the …

Synthesis Of Nickel Nanoparticles By Gamma-Radiation And Femtosecond Laser Ablation, Vivek Murlidhar Rao

Masters Theses

"Nickel nanoparticles were synthesized by gamma-radiation and femtosecond laser ablation. Aqueous precursors were prepared by uniformly dispersing nickel chloride in a 2:1 ratio of water and isopropanol. Stabilizers employed were Sodium Dodecyl Sulfate (SDS) and Poly Vinyl Pyrrolidone (PVP). Gamma-ray radiolysis of aqueous nickel precursors was investigated as a reducing agent for nickel cations to form atomic seeds for nucleation on multi-walled carbon nanotubes (MWCNTs). 30-60kGy was the dosage used in increments of 10kGy, at a rate of 10kGy/hr. Isopropanol was added to consume the excess of oxidizing species produced by irradiation and form stable secondary radicals. The influence of …

Direct Shear Testing Of Fractured Rocks From Missouri Used To Evaluate Potential Fault Reactivation Induced By Carbon Dioxide Sequestration, Ishan Kumar

Masters Theses

"Geological storage projects of CO₂ are designed to maintain secure storage for thousands of years. Carbon Capture and Storage has been identified as one of the methods which is used to reduce global emission of CO₂ and achieve lower concentration of CO₂ in the atmosphere by capturing the CO₂ from the flue gases and storing it in underground formations. Potential leakage of injected CO₂ from the reservoir to the surface is caused by the reactivation of pre-existing faults and fractures which is caused by the change in the state of stresses and the pore pressure. To avoid damage to the …

Formation Of Amyloid Fibrils By Diblock Peptides, Kunal Mukesh Naik

Masters Theses

"The objective of this study was to identify and then synthesize a series of peptides which were able to form fibrils rich in ß-sheet structure and to study the effect of the presence of surfaces on their formation. We decided to focus our experimental work on a family of peptides containing one "beta-sheet forming amino acid" and one 'alpha-helix forming amino acid'. This selection covers a wide range of hydrophillicites and charges and, by avoiding highly hydrophobic amino acids we can assure that the diblock peptides are soluble in a wide range of concentrations and solvent conditions. Three different diblocks …

Development Of A Shared Earth Model To Investigate Potential For Carbon Dioxide Sequestration In The Springfield Area, Mo, Imowo Celestine Akpan

Masters Theses

"Carbon dioxide (C0₂) sequestration has been extensively implemented and explored predominantly in depleted oil reservoirs and deep saline aquifers where the C0₂ is stored under supercritical conditions. A lesser explored option with great potential is based on injection into shallow reservoirs where the C0₂ may not always be in its denser supercritical state. The research evaluates the potential for injecting C0₂ into saline aquifers at depths of ~550-650 meters and formation temperatures of -22⁰C.

To evaluate injectivity and cap rock integrity, reservoir and geomechanical simulations need to be conducted separately and subsequently coupled. A Shared Earth Model is developed utilizing …

Advanced Nanostructured Electro-Catalysts For Electricity Generation And Biorenewable Alcohol Conversion, Zhiyong Zhang

Dissertations, Master's Theses and Master's Reports - Open

In my Ph.D research, a wet chemistry-based organic solution phase reduction method was developed, and was successfully applied in the preparation of a series of advanced electro-catalysts, including 0-dimensional (0-D) Pt, Pd, Au, and Pd-Ni nanoparticles (NPs), 1-D Pt-Fe nanowires (NWs) and 2-D Pd-Fe nanoleaves (NLs), with controlled size, shape, and morphology. These nanostructured catalysts have demonstrated unique electro-catalytic functions towards electricity production and biorenewable alcohol conversion.

The molecular oxygen reduction reaction (ORR) is a long-standing scientific issue for fuel cells due to its sluggish kinetics and the poor catalyst durability. The activity and durability of an electro-catalyst is strongly …

Admicellar Polymerization Of Calcium Carbonate And Its Performance In Drilling Fluids, Poh Lee Cheah

Electronic Theses and Dissertations

Admicellar polymerization using sodium dodecylsulfate (SDS) template to form ultrafilm polystyrene on commercial calcium carbonate (CaCO3 ) of various particle sizes was studied. Adsorption isotherms of SDS decrease after the critical micelle concentration (CMC) of SDS was observed. This is explained by the phase behavior of SDS with calcium ion. The solubility product constants (Ksp) for calcium dodecylsulfate (Ca(DS) 2) were calculated as 1.55x10?9M3 at 30°C and 8.58x10?9M3 at 50°C. At SDS concentrations above the CMC, precipitation of Ca(DS)2 was governed by the critical ratio of calcium ion concentration bound onto anionic micelles which was 0.22 at 30°C and 0.20 …

Heat Transfer Enhancement In A Straight Channel Via A Rotationally Oscillating Adiabatic Cylinder, Ali Beskok, Mehrdad Raisee, Bayram Celik, Bedri Yagiz, Mohsen Cheraghi

Mechanical & Aerospace Engineering Faculty Publications

Heat convection from the uniformly heated walls of a straight channel in presence of a rotationally oscillating cylinder (ROC) is simulated at Re = 100. Heat transfer enhancement due to vortex shedding from the ROC is investigated. Systematic studies are performed to explore the rotation angle and frequency influences on heat transfer by varying the latter in range of the lock-in regime and the former from 0 to 2 π/3. All simulation results are based on the numerical solutions of two-dimensional, unsteady, incompressible Navier-Stokes and energy equations using an h/p type finite element algorithm. Considering time periodicity of the resulting …

Effect Of Surfactants And Brine Salinity And Composition On Spreading, Wettability And Flow Behavior In Gas-Condensate Reservoirs, Yu Zheng

LSU Doctoral Dissertations

The well-known condensate blockage problem causes severe impairment of gas productivity as the flowing bottom-hole pressure falls below the dew point in gas-condensate reservoirs. Hence, this study attempts to investigate the concept of modifying the spreading coefficient and wettability using low-cost surfactants in the near wellbore region, to prevent the gas flow problems associated with condensate buildup. This study also examines the effect of brine salinity and composition on wettability, spreading and adhesion in condensate buildup regions, to evaluate the ability of brine salinity/composition for enhanced gas productivity in gas-condensate reservoirs. In this study, experiments were performed at both ambient …

Lipid Production From A Louisiana Native Chlorella Vulgaris/Leptolyngbya Sp. Co-Culture For Biofuel Applications, Rong Bai

LSU Doctoral Dissertations

Over the last several decades, microalgae have garnered great interest for biofuel production mainly due to the high lipid productivity and minimum land competition with food crops. In this research, a Louisiana native Chlorella vulgaris/Leptolyngbya sp. co-culture was selected for lipid production. The goal of this work is to improve the lipid productivity and lipid composition of this co-culture via optimizing irradiance and nitrogen levels, lipid extraction method and modeling of pilot photobioreactor (HISTAR). Effects of irradiance and nitrate nitrogen levels on total lipid yield, neutral lipid portion, and fatty acid profile of non-aerated and aerated co-cultures were investigated in …

Strategies For Real Time Reservoir Management, Yuanyuan Shuai

LSU Doctoral Dissertations

Real–time reservoir management is developed to manage a shrinking labor force and rising demand on energy supply. This dissertation seeks good strategies for real–time reservoir management. First, two simulator–independent optimization algorithms are investigated: ensemble–based optimization (EnOpt) and bound optimization by quadratic approximation (BOBYQA). Multiscale regularization is applied to both to find appropriate frequencies for well control adjustment. Second, two gathered EnKF methods are proposed to save computational cost and reduce sampling error: gathered EnKF with a fixed gather size and adaptively gathered EnKF. Finally, oil price uncertainty is forecasted and quantified with three price forecasting models: conventional forecasting, bootstrap forecasting …

An Experimental Investigation Of The Role Of Small Hydrocarbons And Combustion-Generated Nanoparticles On The Formation And Growth Reactions Of Polycyclic Aromatic Hydrocarbons During The Pyrolysis Of A Model-Fuel And Hydrocarbon Gases, Nimesh Bharat Poddar

LSU Doctoral Dissertations

Polycyclic aromatic hydrocarbons (PAH) are an important class of environmental pollutants formed during fuel combustion or pyrolysis. Therefore, an experimental study has been undertaken to better understand the formation and growth pathways of PAH.

To investigate the efficacy of C₃ species as PAH growth agents in the context of solid fuels, pyrolysis experiments have been performed in an isothermal quartz flow reactor in the temperature range of 700–1000 °C and a fixed residence time of 0.3 s. Experiments are performed with the C₃ hydrocarbon, propyne; with catechol (ortho-dihydroxybenzene), a model-fuel representative of aromatic moieties in coal …

Computer Simulations Of Faceted Nanoparticles And Carbon Nanotubes In Liquid Crystals, Shivkumar Shankar Bale

LSU Doctoral Dissertations

The purpose of this research is to investigate the use of liquid crystals (LCs) to manipulate and organize faceted nanoparticles and carbon nanotubes (CNTs). Computer simulations at different levels of detail are used to study these systems. Results from this project will be relevant for potential applications of these systems in displays, nanoscale electronics, electro-optical switches, and in the development of composites with unique mechanical, thermal and/or electronic properties. In this research, two independent but directly related projects were carried out. In the first part of the research, we investigated the torque that develops when faceted nanoparticles, namely cubes and …