Chemical Engineering Commons^™

Carbon Dioxide - Heavy Oil Systems: Thermodynamics, Transport And Interfacial Stability, Truynh Quoc My Duy Tran

Doctoral Dissertations

"Conventional oil recovery leaves behind around 67% of original oil in place for light oils and all of it for heavy oils. The carbon dioxide flooding process is the cheapest among the recovery methods for the next stage. The interest here lies in recovering heavy oil. When CO₂ dissolves in oil, it increases the volume of oil, squeezes it out of narrow capillaries and the viscosity of oil drops by up to an order of magnitude. Starting with the available data with and without CO₂ in heavy oil, the free volume theory is used to predict these physical …

A Protocol For Rheological Characterization Of Hydrogels For Tissue Engineering Strategies, Jonathan M. Zuidema, Christopher J. Rivet, Ryan J. Gilbert, Faith A. Morrison

Chemical and Biochemical Engineering Faculty Research & Creative Works

Hydrogels are studied extensively for many tissue engineering applications, and their mechanical properties influence both cellular and tissue compatibility. However, it is difficult to compare the mechanical properties of hydrogels between studies due to a lack of continuity between rheological protocols. This study outlines a straightforward protocol to accurately determine hydrogel equilibrium modulus and gelation time using a series of rheological tests. These protocols are applied to several hydrogel systems used within tissue engineering applications: agarose, collagen, fibrin, Matrigel™, and methylcellulose. The protocol is outlined in four steps: (1) Time sweeps to determine the gelation time of the hydrogel. (2) …

Effect Of Magnetic Nanoparticle Heating On Cortical Neuron Viability, Christopher J. Rivet, Yuan Yuan, Ryan J. Gilbert, Diana Andra Borca-Tasciuc

Chemical and Biochemical Engineering Faculty Research & Creative Works

Purpose: Superparamagnetic iron oxide nanoparticles are currently approved for use as an adjunctive treatment to glioblastoma multiforme radiotherapy. Radio frequency stimulation of the nanoparticles generates localized hyperthermia, which sensitizes the tumor to the effects of radiotherapy. Clinical trials reported thus far are promising, with an increase in patient survival rate; however, what are left unaddressed are the implications of this technology on the surrounding healthy tissue. Methods and materials: Amino silane-coated iron oxide nanoparticles suspended in culture medium were applied to chick embryonic cortical neuron cultures. Cultures were heated to 37 °C or 45 °C by an induction coil system …

Impact Of Slickwater Fracturing Fluid Compositions On The Petrophysical Properties Of Shale And Tightsand, Yongpeng Sun

Doctoral Dissertations

"A tight reservoir always requires hydraulic fracturing before production to increase production rate. The additives in hydraulic fluids are highly considerable for a successful stimulation. A friction reducer is often used to reduce the flowing friction in the wellbore during hydraulic fracturing. Extensive researches have been conducted to examine the extent it can reduce the fluid friction in tubings; however, no research has been reported on its behavior in a reservoir, which is related to the fracture extension. A breaker is also pumped into the formation to degrade the friction reducer. However, it is not clear that what is the …

Preformed Particle Gel Transport Through Fractures, Hao Zhang

Doctoral Dissertations

"Polymer gel treatment is one of the most cost-effective methods to control water production in mature oil fields. The main objective of gel treatments is to reduce water or gas flow through high-permeability channels or fractures without damaging productive zones. Preformed particle gels (PPGs) have been applied for conformance control because they can overcome some potential drawbacks inherent in an in-situ gelation system.

In this study, lab experiments were performed to quantify PPG propagation through fractures and fracture-like channels by using screen models and open fracture models. The main findings in these experiments can guide the selection of best particle …

Study And Pilot Test On A Novel Eor Method - Coupling Ppg Conformance Control And Surfactant Flooding, Farag Awadh Muhammed

Doctoral Dissertations

"The interest in enhanced oil recovery (EOR) methods has re-emerged in recent years; however, significant challenges remain for the widespread deployment of these methods. One major downside to the successful application of EOR technologies in mature reservoirs is conformance problems (e.g. heterogeneity). To mitigate these problems, a novel EOR method which couple preformed particle gel (PPGs) conformance treatment with traditional surfactant flooding in one process is introduced.

This dissertation provides a comprehensive study for the proposed method. A series of laboratory tests were carried out to understand the chemical interaction between PPGs and surfactants. A new method to evaluate PPGs …

Metathesis Reaction Of Ethylene And 2-Butene On Molybdenum-Based Catalysts, Benjamas Netiworaruksa

Chulalongkorn University Theses and Dissertations (Chula ETD)

This dissertation studies and develops the supported molybdenum catalyst for metathesis reaction of ethylene and 2-butene to produce propylene. It was found that the major factor affecting the catalytic performance for metathesis reaction is the catalyst support. From this study, it was firstly revealed that the suitable support for molybdenum-based catalyst is the mixed support of alumina and zeolite. The catalyst containing alumina support prepared from aluminium nitrate physically mixed with HBeta support could provide high selectivity of propylene. The optimum ratio of the composite support of alumina and zeolite was 3:1. However, the most optimum support obtaining propylene selectivity …

การประมาณค่าสภาพด่างฟีนอล์ฟทาลีนและค่าสภาพกรดรวมในกระบวนการเตรียมพื้นผิวชิ้นงานด้วยวิธีการถดถอยบางส่วนกำลังสองน้อยที่สุด, ชลธร ช้างพิงงา

Chulalongkorn University Theses and Dissertations (Chula ETD)

ในกระบวนการเคลือบสี กระบวนการเตรียมพื้นผิวชิ้นงาน (Pretreatment process) เป็นการดำเนินงานที่สำคัญมากงานหนึ่ง ประกอบด้วยขั้นตอนการล้างด่าง (Degreasing step) เพื่อล้างเอาฝุ่นรวมถึงคราบไขมันออกจากชิ้นส่วนผลิตภัณฑ์ และขั้นตอนการเคลือบผิวโลหะ (Coating step) เพื่อเพิ่มพฤติกรรมการต้านทานการกัดกร่อนของโลหะ กระบวนการนี้ใช้สารเคมีเป็นจำนวนมาก ส่งผลให้เกิดมลภาวะทางน้ำ และเกิดค่าใช้จ่ายที่เกี่ยวข้องในการบำบัดน้ำเสีย ความสามารถในการควบคุมเข้มข้นของสารละลายในกระบวนการเตรียมพื้นผิวชิ้นงานให้อยู่ในช่วงที่เหมาะสมก่อให้เกิดการใช้สารเคมีอย่างมีประสิทธิผล และส่งผลถึงคุณภาพของผลิตภัณฑ์ ความเข้มข้นของสารทำความสะอาดในบ่อล้างไขมันสามารถตรวจวัดได้ด้วยการไตเตรทค่าสภาพด่างฟีนอล์ฟทาลีน (Phenolphthalein Alkalinity: P-Alkalinity) และความเข้มข้นของสารละลายบ่อการเคลือบผิวสามารถตรวจวัดได้โดยการไตเตรตค่าสภาพกรดรวม (Total-Acidity) กระบวนการนี้ทำโดยคนนำมาซึ่งความผิดพลาดที่ไม่น่าพอใจ ดังนั้นการควบคุมความเข้มข้นของสารละลายในบ่อทั้งสองจึงกลายเป็นเรื่องที่ยากมากื งานวิจัยนี้จึงมุ่งเน้นการประมาณค่าสภาพด่างฟีนอล์ฟทาลีน และค่าสภาพกรดรวม ซึ่งแสดงถึงความเข้มข้นของสารละลายในบ่อล้างไขมันและบ่อเคลือบผิวตามลำดับ โดยอาศัยตัวแปรที่วัดค่าได้ ค่าความเป็นกรด-ด่าง ค่าสภาพการนำไฟฟ้า ค่าความหนาแน่น และอุณหภูมิ กระบวนเตรียมพื้นผิวชิ้นงานของโรงงานแห่งหนึ่งในอุตสาหกรรมผลิตเครื่องปรับอากาศจะนำมาใช้เป็นกรณีศึกษา วิธีการประมาณนี้จะอาศัยหลักการทางสถิติ และวิธีการถดถอยบางส่วนกำลังสองน้อยที่สุด (Partial Least Squared Regression: PLS) งานวิจัยพบว่าวิธีนี้จะให้ค่าประมาณสภาพด่างฟีนอล์ฟทาลีน และค่าสภาพกรดรวมที่มีค่าความคลาดเคลื่อนสูงสุดอยู่ที่ร้อยละ 7.45 และ 4.29 ตามลำดับ

อิทธิพลของสารต้านจุลินทรีย์ซิงค์ออกไซด์และคาร์วาครอลต่อสมบัติของบรรจุภัณฑ์อาหารที่เตรียมจากพอลิบิวทิลีนซัคซิเนต, ศสิณี วิบูรณวงศ์

Chulalongkorn University Theses and Dissertations (Chula ETD)

พอลิบิวทิลีนซัคซิเนต (PBS) เป็นพลาสติกย่อยสลายได้ทางธรรมชาติกลุ่มพอลิเอสเทอร์ ที่มีสมบัติใกล้เคียงกับพลาสติกจากปิโตรเคมี งานวิจัยนี้มุ่งพัฒนาฟิล์มบรรจุภัณฑ์อาหาร PBS ที่สามารถต้านเชื้อจุลินทรีย์ได้โดยการเติมสารต้านจุลินทรีย์ 2 ชนิด คือ ซิงค์ออกไซด์ (ZnO) ซึ่งจัดอยู่ในกลุ่มสารต้านจุลินทรีย์จากสารเคมี และคาร์วาครอล (Carvacrol) ซึ่งเป็นสารต้านจุลินทรีย์จากธรรมชาติ งานวิจัยนี้ศึกษาอิทธิพลของปริมาณสารต้านจุลินทรีย์แต่ละชนิด ร้อยละ 2, 4, 6, 8 และ10 โดยน้ำหนัก ต่อการยับยั้งเชื้อ E.coli (แบคทีเรียแกรมลบ) และ S.aureus (แบคทีเรียแกรมบวก) พร้อมทั้งศึกษาอิทธิพลของความหนาของฟิล์ม PBS ที่ผสมสารต้านเชื้อจุลินทรีย์แต่ละชนิด ระดับความหนา 50 75 และ 100 ไมโครเมตร ต่อสมบัติเชิงกลและการยับยั้งเชื้อ ผลการทดสอบบริเวณยับยั้งเชื้อ (Clear zone) ด้วยวิธีการแพร่ในอาหารเลี้ยงเชื้อแบบแข็ง (Agar diffusion method) พบว่า เริ่มพบบริเวณยับยั้งเชื้อ S.aureus และพบบริเวณยับยั้งเชื้อ E.coli เมื่อเติม ZnO ร้อยละ 6 โดยน้ำหนัก สำหรับฟิล์มหนา 50 ไมโครเมตร ในทำนองเดียวกัน เริ่มพบบริเวณยับยั้งเชื้อ S.aureus เมื่อเติม Carvacrol ร้อยละ 4 โดยน้ำหนัก แต่เริ่มพบบริเวณยับยั้งเชื้อ E.coli เมื่อเติม Carvacrol ร้อยละ 6 โดยน้ำหนัก ผลการทดสอบสมบัติเชิงกล พบว่า ฟิล์ม PBS/ZnO มีระยะยืด ณ จุดขาดและความต้านทานแรงกระแทกลดลง เมื่อปริมาณ ZnO มากขึ้น เพราะอนุภาค ZnO เป็นสารอนินทรีย์ที่มีความแข็งมากกว่า PBS และ ZnO มิได้สร้างพันธะยึดติดกับ PBS ดังยืนยันโดยผลทดสอบ FTIR การตรวจดูระดับจุลภาค พบ ZnO จับตัวเป็นกลุ่มก้อนเมื่อปริมาณ ZnO …

Effect Of Additives In Lubricant On Cobalt-Iron Alloy Lapping, Wiraya Anamnart

Chulalongkorn University Theses and Dissertations (Chula ETD)

To maintain this flying height of read-write head (called slider) at 12 nm across the disk, read and writer elements will be lapped to meet designed surface roughness, surface topography, as well as magnetic property. The writer element was made from cobalt-iron alloy (CoFe). Final lapping process of sliders uses lubricant to control surface morphology and to avoid corrosion. The aim of this study was to determine the effect of additives on corrosion protection of CoFe. The corrosion was studied by potentiostat technique and atomic force microscopy (AFM). Water content was determined by Karl Fischer method. Thin film passivation was …

Studies Of Influencing Factors For Shale Gas Reservoir Performance, Jiaqi Wang

Masters Theses

"Shale gas resource plays a significant role in energy supply worldwide. For economic production of shale gas, technologies of horizontal well and hydraulic fracturing are used for shale gas reservoirs. Therefore, the productivity of the shale gas reservoirs will be influenced by both reservoir condition, and hydraulic fracture properties.

In this thesis, parameters that will influence shale gas production were classified into two categories: reservoir properties and hydraulic fracture properties. Published shale gas simulation studies were surveyed for determining the typical ranges of those properties. CMG-GEM was employed to finish the reservoir simulation work, and CMG-CMOST was used to complete …

Computational Fluid Dynamics (Cfd) Modeling Of Proppant Transport In A Plug-And-Perf Completion With Different Perforation Phasing, Jinlin Zhang

Masters Theses

"Perf-and-plug is a completion technique commonly used in multistage fracturing. Fracture performance modeling assumes that fluid and proppant distributes uniformly among all perforations along the length of the wellbore in a plug and perf completion Crespo et al. (2012) has conducted a limited proppant flow experiment using a 63 foot stage, and three 0.42 inch, zero phased simulated perforations. His work demonstrates proppant does not distribute evenly, but the work is limited to a single perforation scheme.

In this study, Computational Fluid Dynamics (CFD) software has been used to simulate proppant transport and distribution in a single stage of a …

Gold-Magnetite Nanoparticle-Biomolecule Conjugates: Synthesis, Properties And Toxicity Studies, Akshay Pariti

Masters Theses

"This thesis study focuses on synthesizing and characterizing gold-magnetite optically active magnetic nanoparticle and its conjugation with biomolecules for biomedical applications, especially magnetic fluid hyperthermia treatment for cancerous tissue. Gold nanoparticles have already displayed their potential in the biomedical field. They exhibit excellent optical properties and possess strong surface chemistry which renders them suitable for various biomolecule attachments. Studies have showed gold nanoparticles to be a perfect biocompatible vector. However, clinical trials for gold mediated drug delivery and treatment studied in rat models identified some problems. Of these problems, the low retention time in bloodstream and inability to maneuver externally …

Evaluation Of Prosper For Modeling Long Lateral Gas Well Productivity In Toe Up, Toe Down, Horizontal Well Geometry, Abdussalam Mahmoud Mohamed

Masters Theses

"Most horizontal wells are not truly horizontal and may be drilled 'toe-up' or 'toe-down' to follow geological formations or in an attempt to keep the well from loading up. Challenges in directional drilling may also lead to horizontal gas wells with undulating wellbore profiles. This wellbore profile creates natural traps for heavy fluids in the lows and light fluid in the highs, which may result in chocked production. Hence, there is an interest in determining the best wellbore trajectory - toe-up, horizontal, or toe-down - for well unloading.

This study evaluates the capability of the well productivity software PROSPER to …

The Effect Of Using Different Rock Failure Criteria In Wellbore Stability Analysis, Reza Rahimi

Masters Theses

"Determination of the appropriate drilling fluid density by rock failure analysis is an essential step to control wellbore instability. To determine wellbore failure stresses, the rock strength has to be known, an appropriate constitutive model has to be selected, and finally an accurate rock failure criterion must be chosen. Linear-poro elastic modeling of the mechanical wellbore failure is the most common approach to investigate wellbore instability. Numerous failure criteria have been used for the rock failure analysis but there is not any commonly accepted agreement of which failure criteria to use. Rock failure criteria differ in two main characteristics. First, …

Coke Deposition On Wox/Sio2 Catalyst Physically Mixed With Magnesium Oxide For Metathesis Reaction Of Ethylene And 2-Butene, Thidaya Thitiapichart

Chulalongkorn University Theses and Dissertations (Chula ETD)

The presence of MgO physically mixed with silica supported tungsten oxide catalysts was investigated in metathesis reaction using ethylene and trans-2-butene as feeds. Adding MgO could enhance the conversion of trans-2-butene and propylene yield, comparing with a catalyst mixed with SiO2 as a referenced one. However, the presence of MgO with silica supported tungsten oxide catalysts surprisingly elevated the coke deposition. The coke precursor was formed by MgO from isomerization of undesired products like C5+ and moved to deposit on the acid sites of silica supported tungsten oxide catalysts which is a coke site of the catalysts. Furthermore, the distance …

Modification Of W/Sio₂ Catalysts By Second Metal For Metathesis Of Ethylene And 2-Butene, Narongrat Poovarawan

Chulalongkorn University Theses and Dissertations (Chula ETD)

In this thesis, the main goals were to study the effect of the dispersion of the tungsten active phase and the modification of WO3/SiO2 catalyst by a second metal for metathesis reaction of the mixture of cis/trans-2-butene and ethylene. The silica supported tungsten catalyst was used as the base catalyst and lanthanum, cerium, yttrium were used as the second metal in this study. It was found that the dispersion of the tungsten active phase would affect the catalytic performance of the WO3/SiO2 catalyst, when the mixture of cis/tran-2-butene was use as feed.The second metal was used to midify the dispersion …

Comparison Of Role Of Nano-Sized Extra Supports On Pt-Based Catalyst For Propane Dehydrogenation And Wox-Based Catalyst For Propene Metathesis, Adisak Guntida

Chulalongkorn University Theses and Dissertations (Chula ETD)

In this thesis, the role of nano-sized extra supports was studied. The different types of nano-sized supports (ZrO2, TiO2, Al2O3, and SiO2) were physically mixed with WOx-based catalysts for propene metathesis reaction and Pt-based catalysts for propane dehydrogenation reaction as extra support. The dispersions of active sites were improved in both metathesis and dehydrogenation catalysts by the addition of nano-sized extra supports. The migration of active sites from the main catalyst onto the nano-sized extra support during thermal treatment via thermal spreading is a key for this improvement. The surface energy of nano-sized extra support and concentration of metal active …

Suitable Catalyst Bed Arrangement Of Silica-Based Supported Tungstenand Hydrotalcite Catalysts For Propylene Production From 1-Butene, Sirada Sripinun

Chulalongkorn University Theses and Dissertations (Chula ETD)

The research studied the design of suitable catalyst beds of hydrotalcite and the modified silica supported tungsten for propylene production from 1-butene. The study started with performing reactions at various values of gas hourly space velocity, feed composition and temperature. Then the reaction rate expressions for each catalyst were determined. It was found that the models could predict well the experimental results. The models were further used to simulate the reaction performance of reactors packed with different catalyst beds. The performance was shown in terms of molar flow rate of propylene and yield of propylene. The performance of the catalyst …

The Effects Of Additives In Ethylene Glycol Based Lubricant On Slider Lapping Process, Patara Paranusorn

Chulalongkorn University Theses and Dissertations (Chula ETD)

Lapping process is a key technology in magnetic recording head manufacturing process. Thin film of metal alloys and metal oxides are fabricated on ceramic substrate called wafer to create the recording heads. In order to control surface properties of the recording head, the precise chemical mechanical nano grinding process is used. In this process the recording heads are treated to achieve the designed surface properties by using lubricants to control the selectivity of material removal. The aim of this study was to determine the effects of additives in ethylene glycol based lubricant on the selectivity of material removal of slider …