Chemical Engineering Commons^™

Synthesis And Characterization Of Extractive Scintillating Resin For Ultra-Trace-Level Quantification Of Uranium In Aqueous Media, C Duval, V Bliznyuk, A Seliman, T Devol, S Husson

Graduate Research and Discovery Symposium (GRADS)

The detection and quantification of radionuclides in aqueous media is of interest to both the Environmental Protection Agency, for matters of public health, and international organizations like the Comprehensive Test Ban Treaty Organization, that use environmental samples to investigate claims of illicit nuclear activities. The current method of quantification involves batch style analytical techniques which utilize bulky instruments. Portable, flow cell detectors utilizing extractive scintillating resin with physically sorbed extractants and fluorophores have been developed; however, this resin shows poor long term stability as the active components leach from the resin over time. There is a need to develop chemically …

Roll-To-Roll Synthesis Of Vertically Aligned Carbon Nanotubes For Electrical Double Layer Capacitors, Margarita R. Arcila-Velez, Jingyi Zhu, Anthony Childress, Mehmet Karakaya, Ramakrishna Podila, Apparao M. Rao, Mark E. Roberts

Graduate Research and Discovery Symposium (GRADS)

No abstract provided.

Effect Of Surface Parameters On Interfacial Water Film Behavior, Brittany Glatz, Luke Rhym, Sapna Sarupria

Graduate Research and Discovery Symposium (GRADS)

Vapor-to-liquid and liquid-to-solid transitions on mineral surfaces are the primary pathways for phase transitions in atmospheric water. These phase transitions affect the microphysics of clouds and have significant effects on the weather and climate. Our overall goal is to elucidate the mechanisms through which surfaces affect these transitions, and develop predictive abilities to correlate surface properties to the thermodynamics and kinetics of the phase transitions. In this work, we use molecular dynamics simulations to study the structure, and dynamics of water near kaolinite-like surfaces. Kaolinite is the most abundant mineral dust in the atmosphere. We specifically investigate the effect of …

Carbon Fibers Derived From Pan/Bio-Based Bicomponent Precursor, Jing Jin

Graduate Research and Discovery Symposium (GRADS)

No abstract provided.

Optimization Of Pyrochlore Catalysts For Dry Reforming Of Methane, Felipe Polo-Garzon, Ming He, David A. Bruce

Graduate Research and Discovery Symposium (GRADS)

No abstract provided.

Fabrication And Analysis Of Soy Flour Filled Polyethylene Fibers, Ozgun Ozdemir, Sam Lukubira, Amod Ogale, Paul Dawson

Graduate Research and Discovery Symposium (GRADS)

Fibers composed of soy flour (soy) and linear low density polyethylene (PE) were produced by melt spinning method. The mixing time of soy flour and PE was adjusted to get better dispersion of soy flour inside the matrix. The inclusion of soy decreased tensile modulus by 35% and tensile strength by 30% of the fibers compared with 950 MPa and 43 MPa, respectively, for PE fibers. Strain to failure for soy-PE fibers was 292% where PE fibers have strain to failure at 513%. Tensile properties of soy-PE fibers are comparable to those of pure PE. Even washing did not deteriorated …

Study And Development Of Sulfated Zirconia Based Proton Exchange Fuel Cell Membranes, Brittany Wilson Kemp

Doctoral Dissertations

With the increasing consumption of energy, fuel cells are among the most promising alternatives to fossil fuels, provided some technical challenges are overcome. Proton exchange membrane fuel cells (PEMFCs) have been investigated and improvements have been made, but the problem with Nafion®, the main membrane for PEMFCs, has not been solved. Nafion® restricts the membranes from operating at higher temperatures, thus preventing them from working in small electronics. The problem is to develop a novel fuel cell membrane that performs comparably to Nafion® in PEMFCs.

The membranes were fabricated by applying sulfated zirconia, via template wetting, to porous alumina membranes. …

Engineering Cell-Free Systems For Vaccine Development, Self-Assembling Nanoparticles And Codon Reassignment Applications, Mark T. Smith

Theses and Dissertations

This dissertation reports on the technology of cell-free protein synthesis (CFPS) including 1) stabilized lyophilized cell-free systems and 2) enhanced heterogeneous cell extracts. This work further considers applications of CFPS systems in 1) rapid vaccine development, 2) functional virus-based nanoparticles, 3) site-specific protein immobilization, and 4) expanding the language of biology using unnatural amino acids. CFPS technology is a versatile protein production platform that has many features unavailable in in vivo expression systems. The primary benefit cell-free systems provide is the direct access to the reaction environment, which is no longer hindered by the presence of a cell-wall. The “openness" …

Dynamic Characteristic Identification Of Seismic-Excited Multi-Story Buildings Through Response-Only Technique, Agung Budipriyanto, Priyo Suprobo

Makara Journal of Technology

Identifying dynamic characteristics of civil engineering structures is still a challenging task. It intends to assess behavior of the structures under time-dependent loads. This paper discusses a methodology suitable for identifying the characteristics of multi-story buildings using only their measured response under earthquake ground excitations. Appropriateness of technique used for structural identification was corroborated through coherence of the structure’s responses. The methodology was applied for identifying the characteristics of 14-story and 20-story office buildings located in a high seismic region. Responses of these two buildings recorded during three different seismic ground motions were investigated. The buildings’ response spectral densities and …

Performance Evaluation Of An Optimized Floating Breakwater In Oblique Waves With A Higher-Order Boundary Element Method, Faisal Mahmuddin, Masashi Kashiwagi

Makara Journal of Technology

In the previous study, the optimal performance of a two-dimensional (2D) floating breakwater shape was obtained. The performance of this shape was also confirmed with a model experiment in a towing tank. Moreover, the shape’s performance in three dimensions (3D) was investigated in a subsequent study. However, to predict the shape’s performance in a real application more accurately, the shape’s characteristics in oblique waves must also be evaluated. In this study, the performance and characteristics of the model (hydrodynamic forces, body motions, wave elevations, and drift forces) are computed using a higher-order boundary element method (HOBEM). The HOBEM, which is …

Cztsse Thin Film Solar Cells : Surface Treatments, Chinmay S. Joglekar

Open Access Theses

Chalcopyrite semiconducting materials, specifically CZTS, are a promising alternative to traditional silicon solar cell technology. Because of the high absorption coefficient; films of the order of 1 micrometer thickness are sufficient for the fabrication of solar cells. Liquid based synthesis methods are advantageous because they are easily scalable using the roll to roll manufacturing techniques.

Various treatments are explored in this study to enhance the performance of the selenized CZTS film based solar cells. Thiourea can be used as a sulfur source and can be used to tune band gap of CZTSSe. Bromine etching can be used to manipulate the …

Mechanistic Study Of The Hydrothermal Reduction Of Palladium On The Tobacco Mosaic Virus, Oluwamayowa Oluwarotimi Adigun

Open Access Theses

Synthesis of nanorods and nanowires is becoming more and more important due to interest in them in a wide range of disciplines. The genetically engineered tobacco mosaic virus (TMV1Cys) provides a template for synthesis of uniform metal nanorods at mild operating conditions and without the use of any expensive technology compared to conventional synthetic methods. The discovery of the hydrothermal synthetic scheme has allowed the production of higher quality nanorods on the TMV template. However, the mechanism for reduction and growth in this process is still not understood. In this paper, the mechanism of synthesis for producing uniform, controllable palladium …

Recruitment Of The Adaptor Protein Grb2 To Egfr Tetramers, Noga Kozer, Dipak Barua, Christine Henderson, Eduoard C. Nice, Antony W. Burgess, William S. Hlavacek, Andrew H. A. Clayton

Chemical and Biochemical Engineering Faculty Research & Creative Works

Adaptor protein Grb2 binds phosphotyrosines in the epidermal growth factor (EGF) receptor (EGFR) and thereby links receptor activation to intracellular signaling cascades. Here, we investigated how recruitment of Grb2 to EGFR is affected by the spatial organization and quaternary state of activated EGFR. We used the techniques of image correlation spectroscopy (ICS) and lifetime-detected Förster resonance energy transfer (also known as FLIM-based FRET or FLIM-FRET) to measure ligand-induced receptor clustering and Grb2 binding to activated EGFR in BaF/3 cells. BaF/3 cells were stably transfected with fluorescently labeled forms of Grb2 (Grb2-mRFP) and EGFR (EGFR-eGFP). Following stimulation of the cells with …

Synthesis And Characterization Of Soy-Based Polyurethane Foam With Utilization Of Ethylene Glycol In Polyol, Flora Elvistia Firdaus

Makara Journal of Technology

The use of vegetable oils on replacing petroleum has attracted attention of many researchers. The chemical structure of vegetable oils are different from petrochemicals, so the structure of soybean oil has to be chemically modified through its unsaturated fatty acid chain in triglyceride. A two step process was conducted for the preparation of soy-polyol in designated temperatures; 50 °C, 60 °C, and 70 °C. Ethylene glycol (EG) as co-reagent was taking part in soy-polyol synthesis, and the soy-polyol was used as a sole polyol for polyurethane synthesis. Referred to the previous study, the existence of EG in polyurethane synthesis can …

Performances Of Free-Space Optical Communication System Over Strong Turbulence, Ucuk Darusalam, Purnomo Sidi Priambodo, Harry Sudibyo, Eko Tjipto Rahardjo

Makara Journal of Technology

We report an experimental of free-space optical communication (FSOC) system that use tube propagation simulator (TPS) as the turbulence medium. The FSOC system use wavelength of 1550 nm at the rate transmission of 1000 Mbps and amplified with EDFA at the output of +23 dBm. Index structure of 10-15–10-13 as the representation of atmosphere index turbulences are used for simulation of intensity distribution model or scintillation. The simulation use gammagamma and K model as well. The beam wave propagation models used in simulation are plane wave, spherical wave and Gaussian wave. Spherical wave achieves highest performance via gamma-gamma in strong …

Preparations Of Nanostructured Silicide Bundles And Oxide Arrays, Hirokazu Tatsuoka, Wen Li, Erchao Meng, Daisuke Ishikwa, Kaito Nakane, Shingo Oda, Tomoji Matsushita, Natsuki Kurebayashi

Makara Journal of Technology

A variety of nanostructured silicide bundles and oxide nanowire arrays with abundant, non-toxic materials we are prepared. The CrSi2 nanowire and Mg2Si/MgO composite nanowire bundles were synthesized using a Si substrate and a SiOx nanofiber bundle, respectively. The hexagonal MoSi2 nanosheet bundles were also synthesized using a MoS2 layered material as a template. In addition, ZnO, CuO/Cu2O and a-Fe2O3 nanowire arrays were prepared on semiconductor or metallic substrates. The growth phenomena and the structural properties of the nanostructured materials awere investigated. In addition, the preparations of axial and radial nanowire structures weare examined.

Bioethanol Production From Iles-Iles And Sorghum Starch As Raw Materials (Effect Of Cacl 2 Addition And Saccharification Time), Kusmiyati Kusmiyati, Ali Mahmudi

Makara Journal of Technology

Bioethanol produced from agricultural sources is one alternative energy that has been developed to substitute for petroleum. However, the use of food sources such as corn and cassava to produce bioethanol still face obstacles that lead to the scarcity of food and an increase in food prices. The aim of this study was to produce bioethanol from sorghum and iles-iles, which are not used by humans as food, especially in Indonesia. For both materials, the variables studied were saccharification time (4, 8, 24, and 48 h) and concentration of CaCl2 added to the liquefaction slurry (0, 100, 200, 300, and …

The Effect Of Zephyr Layer Orientation On Zephyrboard Made From Oil Palm Petiole, Lusita Wardani, Muhamad Yusram Massijaya, Yusuf Sudo Hadi, I Wayan Darmawan

Makara Journal of Technology

It is very important to utilize oil palm petiole for the production of zephyr boards. This study aimed to analyze the effect of layer orientation on zephyr board quality. Zephyr boards were made with three coating patterns (A = cross perpendicular, B= combine A and C, and C= paralell) and five zephyr layers using urea formaldehyde adhesive. They were pressed for 20 min at a pressure of 25 kgf/cm² and a temperature 120 ºC, to a target density of 0.80 g/cm³ and a size of 300 mm X 300 mm X 12 mm. Our results showed that the physical and …

Development And Utilization Of A Pair Of Sol-Gel Entrapped Lipases For Biodiesel Production From High Free Fatty Acid Oils, Cory M. Schwartz

Department of Chemical and Biomolecular Engineering: Dissertations, Theses, and Student Research

Biodiesel, which consists of fatty acid alkyl esters, is one of the most widely adopted and successful renewable fuels. Traditional physiochemical biodiesel production methods require high cost refined feedstocks, and so alternative methods of catalysis and feedstocks have been explored. This research investigated the use of polysiloxane entrapped lipases to catalyze the production of biodiesel from low cost feedstocks.

In this work, lipase from Burkholderia cepacia (lipase PS) and lipase B from Candida antarctica (CalB) were separately entrapped using sol-gel chemistry. Optimal reaction conditions for the esterification of free fatty acids by immobilized CalB with methanol were determined. Immobilized CalB …

Viologen Oxidation Properties, Adam Read, Dr. William Pitt

Journal of Undergraduate Research

The world always stands in need of a more efficient and low cost energy sources. Fuel cells present an environmentally friendly source of energy that could potentially replace the current fossil fuels that are now used. In addition fuel cells are normally light weight and have the ability to work in isolated regions where power is not easily accessible. Fuel cells have shown great potential but as of yet are not an economically favorable energy source due to high cost. One of the main reasons for this is the high cost of platinum which is commonly used as a catalyst. …