Chemical Engineering Commons^™

The Gaussian Orthogonal Laplacianfaces Modelling In Feature Space For Facial Image Recognition, Arif Muntasa

Makara Journal of Technology

Dimensionality reduction based on appearance has been interesting issue on the face image research fields. Eigenface and Fisherface are linear techniques based on full spectral features, for both Eigenface and Fisherface produce global manifold structure. Inability of them in yielding local manifold structure have been solved by Laplacianfaces and further improved by Orthogonal Laplacianfaces, so it can yield orthogonal feature vectors. However, they have also a weakness, when training set samples have non-linear distribution. To overcome this weakness, feature extraction through data mapping from input to feature space using Gaussian kernel function is proposed. To avoid singularity, the Eigenface decomposition …

Series-Interconnected Plastic Dye-Sensitized Solar Cells Prepared By Low- Temperature Binder-Free Titania Paste, Erlyta Septa Rosa, Lia Muliani, Shobih Shobih, Jojo Hidayat, Brian Yuliarto

Makara Journal of Technology

The aim of this research is to study dye-sensitized solar cells (DSSC). This was implemented on a flexible polyethylene terephthalate (PET) substrate using a mixture of transparent and scattered mesoporous anatase-titania as the electron transport layer for the photoelectrode. This mixture of anatase titania performed a dual function of light scattering and efficient dye absorption. In this study, a porous nano-TiO2 film was prepared on indium tin oxide (ITO) coated polyethylene terephthalate (PET) by using a binder-free titania paste; on it, a DSSC was fabricated. The paste which contained a mixture of TiO2 nanoparticles, acid chloride, and ethanol was printed …

Does A Plastron Improve Heat Transfer?, Madani A. Khan, Jeffrey Alston, Andrew Guenthner

STAR Program Research Presentations

Superamphiphobic surfaces strongly repel both water and oils. In this work, aluminum coupons are processed by sanding with various grit of sand paper to impart microscale roughness. Subsequent submersion of the aluminum substrate in boiling water grows nanoscale grass-like structures. The oxide layer of Al is slightly soluble in water. During a fast diffusion/equilibrium, Al₂O₃ nanograss grows on the surface. A low energy coating is then deposited on the surface. The micro and nanoscale features create re-entrant structures that trap air enabling contact liquid to be in a Cassie-Baxter state. Superamphiphobicity of the samples were confirmed by …

High-Productivity Membrane Adsorbers: Polymer Surface-Modification Studies For Ion-Exchange And Affinity Bioseparations, Heather Chenette

All Dissertations

This Dissertation centers on the surface-modification of macroporous membranes to make them selective adsorbers for different proteins, and the analysis of the performance of these membranes relative to existing technology. Traditional chromatographic separations for the isolation and purification of proteins implement a column packed with resin beads or gel media that contain specific binding ligands on their exposed surface area. The productivity of this process is balanced by the effective use of the binding sites within the column and the speed at which the separation can take place, in addition to the need to maintain sufficient protein purity and bioactivity. …

Persistent Hepatic Structural Alterations Following Nanoceria Vascular Infusion In The Rat, Michael T. Tseng, Qiang Fu, Khoua Lor, G. Rafael Fernandez-Botran, Zhong-Bin Deng, Uschi M. Graham, D. Allan Butterfield, Eric A. Grulke, Robert A. Yokel

Chemistry Faculty Publications

Understanding the long-term effects and possible toxicity of nanoceria, a widely utilized commercial metal oxide, is of particular importance as it is poised for development as a therapeutic agent based on its autocatalytic redox behavior. We show here evidence of acute and subacute adverse hepatic responses, after a single infusion of an aqueous dispersion of 85 mg/kg, 30 nm nanoceria into Sprague Dawley rats. Light and electron microscopic evidence of avid uptake of nanoceria by Kupffer cells was detected as early as 1 hr after infusion. Biopersistent nanoceria stimulated cluster of differentiation 3⁺ lymphocyte proliferation that intermingled with nanoceria-containing …

Hydraulic Fracturing Water Recycle Through Optimal Ultrafiltration And Nanofiltration Membranes System Design, Long Tran

Graduate Theses and Dissertations

Innovations in hydraulic fracturing technology have created opportunities for petroleum and natural gas production. This technology injects water, sand, and additives to create fissures in rock formations and discharge oil and gas to the surface. The average amount of water used per well is approximately 4.4 million gallons. The large water demand and the complexities involved in wastewater treatment make this process very expensive and not sustainable as far as water use is concerned. Flexible membrane technology has not been developed to process fracking water for re-use across the U.S. The objective of this project is to compare and analyze …

Integrating 3d Layered Manufacturing With Photonic Sintering, Precision Machining And Smart Coating Techniques For Rapid Casting Applications, Hemant Bohra

Dissertations

Developments in rapid casting technologies have led to a new era of inclusion of 3D printing. Three-Dimensional (3D) printing provides the flexibility and ease of reproducing a sand mold directly from CAD models, eliminating patterning steps, thus reducing the process time for creating prototypes. In addition to minimizing processing steps, 3D printing provides the advantages of higher precision and the ability to produce complex shaped sand molds, but it simultaneously possesses some limitations and concerns related to throughput, safety and logistics.

This study proposes an alternative method for creating sand molds by introducing a hybrid rapid prototyping approach to overcome …

A Soft Condensed Matter Approach Towards Mathematical Modelling Of Mass Transport And Swelling In Food Grains, Michael Chapwanya, N. Misra

Articles

Soft condensed matter (SCM) physics has recently gained importance for a large class of engineering materials. The treatment of food materials from a soft matter perspective, however, is only at the surface and is gaining importance for understanding the complex phenomena and structure of foods. In this work, we present a theoretical treatment of navy beans from a SCM perspective to describe the hydration kinetics. We solve the transport equations within a porous matrix and employ the Flory–Huggin’s equation for polymer–solvent mixture to balance the osmotic pressure. The swelling of the legume seed is modelled as a moving boundary with …

Replacement Of Solvent Based Ink By Water Based Inks For Gravure Presses With Low Efficiency Ink Driers, Viraj Suresh Dalvi

Masters Theses

Rotogravure printing of decorative laminates, wall coverings, or vinyl floorings process often uses solvent based inks. The main constraining factor with solvent based ink is presence of volatile organic compounds (VOC’s). Due to the environmental norms on Volatile Organic Compounds (VOCs), and restrictions on using solvent based inks, the ink industry came up with water based ink as more environmentally friendly alternative. Organizations which print decorative laminates, wall coverings, or vinyl floorings with solvent based inks have gravure printing infrastructure, which is often equipped with low efficiency driers capable of drying solvent based inks. In order to comply with environmental …

Self-Supported Printed Multi-Layer Capacitors, Michael James Joyce

Masters Theses

The increasing demand for miniaturized electronic devices has increased the need for rechargeable micro-power sources. Although lithium and lithium ion batteries have been utilized in these applications since the late 1990s, other energy harvesting technologies, such as thermal, mechanical, and solar, are now being used to augment batteries to enable systems to be self-powered. However, the lifetime of any battery is finite, which may be a major problem when the application is in a permanent structure or medical implant device. For power or significant energy storage applications, printed multilayer capacitors or supercapacitors are being explored as an enhancement, or replacement …

Interfacial Interactions Between Carbon Nanoparticles And Conjugated Polymers, Yanqi Luo

Master's Theses

Conjugated polymer based electronics, a type of flexible electronic devices, can be produced from solution by traditional printing and coating processes in a roll-to-roll format such as papers and graphic films. This shows great promise for the emerging energy generation and conversion. The device performance of polymer electronics is largely dependent of crystalline structures and morphology of photoactive layers. However, the solution crystallization kinetics of conjugated polymers in the presence of electron acceptor nanoparticles has not been fully understood yet. In this study, solution crystallization kinetics of poly (3-hexylthiophene) in the presence of carbon nanotubes and graphene oxide has been …

Fundamental Investigations Of Clay/Polymer Nanocomposites And Applications In Co-Extruded Microlayered Systems, Jeremy John Decker

Dissertations

The second and fourth generations of hydroxylated dendritic polyesters (HBP2, HBP4) were combined with unmodified sodium montmorillonite clay (Na+MMT) in water to generate a broad range of polymer clay nanocomposites from 0 to 100% wt/wt Na+MMT. X-ray diffraction (XRD) and transmission electron microscopy (TEM) were used to investigate intercalation states of the clay galleries. It was shown that interlayer spacings were independent of generation number and changed over the composition range from 0.5 nm to 3.5 nm in 0.5 nm increments that corresponded to a flattened HBP conformation within the clay tactoids.

The HBP4/Na+MMT systems were investigated to study the …

Improved Efficiency Organic Photovoltaic Cells Through Morphology Control And Process Modification, Qi Wu

Dissertations

Organic photovoltaic (OPV) cells have drawn great attention due to the potential to produce flexible, light weight, affordable solar cells using polymer organic photovoltaic materials; however, the current power conversion efficiency achieved for these systems is too low for widespread implementation of the technology. Morphology and phase separation are key factors determining the performance of organic photovoltaic cells. Precise control of the size and distribution of the phase-separated photoactive domains is necessary for optimum photon-electron conversion. Polyhedral oligomeric silsesquioxane (POSS) nanostructered chemicals have the potential to provide enhanced control of morphology, crystallinity, and phase dispersion in polymeric blend systems. In …

Fluorine Containing Uv-Curable Materials For Advanced Transport Applications, James Thomas Goetz

Dissertations

The characterization of structure, thermal, gas transport, and free volume properties of two unique UV cured polymeric systems are studied and reported. In the initial pursuit of waterproof high water vapor transport membranes, it became apparent that the UV curing of fluorinated materials yielded routes to develop unique materials that fundamentally challenge conventional models for free volume and light gas transport behavior. UV-curing provides a means to rapidly “lock-in” morphologies that are accessible in the small molecule, monomer phase but rapidly become kinetically inaccessible when constraints such as covalent bonding and cross linking limit motion in the polymer system. This …

An Investigation Of Heat Transfer Enhancement In Nanofluids Containing Core And Shell Nanoparticles., Cory Adam Milligan

Electronic Theses and Dissertations

The purpose of this research is to determine the differences in heat transfer enhancement of poly alpha olefin oil after the addition of two types of carbon coated nanoparticles, specifically carbon coated cobalt and carbon coated copper nanoparticles. The carbon shell allows for the nanoparticles to be homogenously dispersed in the oil and remain stable throughout the experimental procedure. The nanofluids were prepared in concentrations of 0.5, 1.0, and 1.5 wt%. A constant surface heat flux testing rig is used to determine the heat transfer coefficients of the base fluids and the nanofluids. Inlet temperatures to the heat transfer section …

Investigation Of Stabilization Mechanisms For Colloidal Suspension Using Nanoparticles., Qingwen He

Electronic Theses and Dissertations

Over the past decade, charged nanoparticles have been found to enhance the stability of colloidal suspensions. One promising explanation of this stabilization mechanism is “Nanoparticle Haloing”- the formation of a non-adsorbing nanoparticle layer surrounding neutral colloids that would induce an effective electrostatic repulsion between them. The objective of this work was to investigate the effect of additional charged nanoparticles on the interaction between neural colloids in nanoparticle-regulated complex fluids. Firstly, colloidal probe Atomic Force Microscopy (CP-AFM) is used to directly measure the interaction force in such system with nanoparticle volume fractions varying from 10-6 to 10-2. It is found that …

Application Of Membrane Processes For Concentration And Separation Of Sugar Streams In Biofuel Production, Mohammadmahdi Malmali

Graduate Theses and Dissertations

The overall objective of this study was identification and development of a sugar concentration/separation membrane filtration unit to improve the bioconversion of lignocellulosic biomass into chemicals and fuels. This thesis is divided into three main parts. The first part is about our studies on the use of nanofiltration membranes for concentration of sugars in a lignocellulosic biomass hydrolysate. In addition, the feasibility of simultaneous removal of acetic acid, 5-(hydroxymethyl)furfural and furfural from the hydrolysate has also been investigated. The results obtained indicate that both concentration of sugars and removal of hydrolysis degradation products is feasible. However, careful selection of the …

Photo-Sensitivity Of Large Area Physical Vapor Deposited Mono And Bilayer Mos2, Baoming Wang, Christopher Muratore, Andrey A. Voevodin, M. Amanul Haque

Chemical and Materials Engineering Faculty Publications

We present photosensitivity in large area physical vapour deposited mono and bi-layer MoS2 films. Photo-voltaic effect was observed in single layer MoS2 without any apparent rectifying junctions, making device fabrication straightforward. For bi-layers, no such effect was present, suggesting strong size effect in light-matter interaction. The photo-voltaic effect was observed to highly direction dependent in the film plane, which suggests that the oblique deposition configuration plays a key role in developing the rectifying potential gradient. To the best of our knowledge, this is the first report of any large area and transfer free MoS2 photo device with performance comparable to …

Production Of Recombinant Human Coagulation Factor Ix By Transgenic Pig, Weijie Xu

Department of Chemical and Biomolecular Engineering: Dissertations, Theses, and Student Research

Hemophilia B is the congenital bleeding disorder caused by deficiency in functional coagulation factor IX (FIX) and about 28,000 patients worldwide in 2012. And current treatment is restricted to protein-replacement therapy, which required FIX concentrates for patients’ life-time. Approximately 1 billion units FIX were consumed in 2012. However, still about 70-80% patients, mostly in developing countries, received inadequate or no treatment because of the unavailable and/or unaffordable FIX concentrates. Considering safety reasons, e.g. transmission of blood-borne diseases, the recombinant human FIX (rFIX) is recommended other than the plasma-derived FIX. However, only one rFIX is currently available on the market. The …

Opto-Electronic Devices With Nanoparticles And Their Assemblies, Chieu Van Nguyen

Department of Chemical and Biomolecular Engineering: Dissertations, Theses, and Student Research

Nanotechnology is a fast growing field; engineering matters at the nano-meter scale. A key nanomaterial is nanoparticles (NPs). These sub-wavelength (< 100nm) particles provide tremendous possibilities due to their unique electrical, optical, and mechanical properties. Plethora of NPs with various chemical composition, size and shape has been synthesized. Clever designs of sub-wavelength structures enable observation of unusual properties of materials, and have led to new areas of research such as metamaterials. This dissertation describes two self-assemblies of gold nanoparticles, leading to an ultra-soft thin film and multi-functional single electron device at room temperature. First, the layer-by-layer self-assembly of 10nm Au nanoparticles and polyelectrolytes is shown to behave like a cellular-foam with modulus below 100 kPa. As a result, the composite thin film (~ 100nm) is 5 orders of magnitude softer than an equally thin typical polymer film. The thin film can be compressed reversibly to 60% strain. The extraordinarily low modulus and high compressibility are advantageous in pressure sensing applications. The unique mechanical properties of the composite film lead to development of an ultra-sensitive tactile imaging device capable of screening for breast cancer. On par with human finger sensitivity, the tactile device can detect a 5mm imbedded object up to 20mm below the surface with low background noise. The second device is based on a one-dimensional (1-D) self-directed self-assembly of Au NPs mediated by dielectric materials. Depending on the coverage density of the Au NPs assembly deposited on the device, electronic emission was observed at ultra-low bias of 40V, leading to low-power plasma generation in air at atmospheric pressure. Light emitted from the plasma is apparent to the naked eyes. Similarly, 1-D self-assembly of Au NPs mediated by iron oxide was fabricated and exhibits ferro-magnetic behavior. The multi-functional 1-D self-assembly of Au NPs has great potential in modern electronics such as solid state lighting, plasma-based nanoelectronics, and memory devices.

Adviser: Ravi F. Saraf