Chemical Engineering Commons^™

Investigation Of Degradation Of Amine Sorbent, Elijah Arendt

Williams Honors College, Honors Research Projects

The purpose of this study is to investigate the performance of amine-grafted sorbents, specifically when they are degraded at 120°C. This study varied the amine source and the amount of it in the sorbent. The additive type and the amount of it was also manipulated. The performance of sorbents is characterized by CO₂ capture capacity, which is the amount (in mmol) of CO₂ captured per gram of sorbent at 40°C. The best performing sorbents are ones that maintain their CO₂ capture capacity after degradation. When the amount of additive was manipulated, the sorbents containing 2% b.w. and …

Passivation And Potential Fluctuation Of Az31b Alloy In Alkaline Environments, Ana C. Bacco

Williams Honors College, Honors Research Projects

Magnesium (Mg) alloys are used in many industries because of their distinctive properties, but their high chemical reactivity and poor oxide film protection make them inferior. This project focused on investigating the effects of secondary phases and intermetallic particles (IMPs) on the corrosion behavior of AZ31B Mg alloy. The test solution was chloride free NaOH with varying pH levels between 10-14, as well as testing under deaerated conditions. The open circuit potential (OCP) measurements using AZ31B in static NaOH solutions showed potential fluctuation between approximately -1.6 V_SCE (active state) and -0.4 V_SCE (passive state) during the 24-h immersion. …

Prediction Of Vapor/Liquid Equilibrium Behavior From Quantum Mechanical Data, Marshall J. Gnap

Williams Honors College, Honors Research Projects

MOSCED (Modified Separation of Cohesive Energy Density) is a particularly attractive model for activity coefficients because it offers intuitive insights into how to tune solvent-solute interactions to achieve optimized formulations. Unfortunately, only 133 compounds have been characterized with the MOSCED method. Furthermore, there is no convenient method for extending MOSCED predictions to new compounds. The hypothesis of the present research is that the surface charge density of a molecule, once normalized over the molecule surface area, provided graphically by a σ-profile from density functional theory (DFT) computations, can be used to estimate the parameters used in the MOSCED model. DFT …

Stress Corrosion Cracking Evaluation Of Carbon Steel In Biodiesel And The Effect Of Ultrasonic Nanocrystal Surface Modification (Unsm) On 304 Stainless Steel, Josh Geyer

Williams Honors College, Honors Research Projects

The project that was performed was stress corrosion cracking (SSC) of carbon steel in biodiesel, petroleum diesel and a mixture. The project also included the effect of Ultrasonic Nanocrystal Surface Modification (UNSM) on 304 stainless steel. It included the assembly of a slow strain rate (SSR) machine and carrying out testing using the SSR machine. The assembly of the machine will require purchasing and building a stand to house the electrical equipment which includes the computer, actuator control panel and the actuator power supply. The assembly will also include designing and purchasing the connections to connect the actuator to the …

Investigation Of Parameters Enabling Admicellar Reversible Addition-Fragmentation Chain Transfer (Raft) Polymerization, Poh Lee Cheah

Electronic Theses and Dissertations

To date, enormous studies on admicellar polymerization have been recorded since the initial reports in the 1980’s. This technique which offered the advantage of using inexpensive materials and facile procedures, proven to be a successful surface modification technique. Nevertheless, one has to tailor every particular case due to the contribution of various factors in the process. Therefore, understanding the fundamentals parameters affecting the characteristics of polymer formed by admicellar polymerization have become a great interest. The effect of oxygen on the requisite amount of initiator and the polymer formed through the admicellar polymerization of styrene on silica particles was studied …

An Integrated Completion And Reservoir Modeling Methodology For Horizontal Shale Wells: A Montney Formation Example, Rashid S. Kassim, Larry K. Britt, Shari Dunn-Norman, Bryan Lang

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The Montney Formation is one of the largest unconventional resources in North America covering from southwestern Alberta to northeast British Columbia. The Montney Formation has natural gas, natural gas liquids (NGL) and oil from conventional and unconventional reservoirs. The first multiple fractured horizontal well (MFHW) was drilled in 2005. However, since the first MFHW, different methods were proposed to optimize completion designs in the Montney Formation. Some of the optimized completions utilized the "operational effectiveness" of high-rate slick-water fracture designs while other designs utilized energized fracturing fluids. What has been missing was an integrated methodology that utilizes all available data …

Modeling Gas Inflow For Extremely Low Permeability Shale Using Cfd, Chatetha Chumkratoke

Doctoral Dissertations

"Computational fluid dynamics (CFD) has been used to model 2-D well inflow over a range of permeabilities to study the impact of various well completion strategies (Augustine, 2011). Augustine's 2-D model was subsequently extended for 3-D flow by Thepporprapakorn (2013), for gas flow in the permeability range of tight gas (0.01 mD).

This work presents a 3-D CFD model of gas inflow valid for extremely low ranges of permeability (0.00001 mD). In extremely low permeability, gas flow is complex and includes flow from fractures, flow through porous media, and diffusive gas transport. Diffusive gas transport is important when strong density …

Antibacterial Properties Of Poly (Octanediol Citrate)/Gallium-Containing Bioglass Composite Scaffolds, Ehsan Zeimaran, Sara Pourshahrestani, Ivan Djordjevic, Belinda Pingguan-Murphy, Nahrizul Adib Kadri, Anthony W. Wren, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

Bioactive glasses may function as antimicrobial delivery systems through the incorporation and subsequent release of therapeutic ions. The aim of this study was to evaluate the antimicrobial properties of a series of composite scaffolds composed of poly (octanediol citrate) with increased loads of a bioactive glass that releases zinc (Zn²⁺) and gallium (Ga³⁺) ions in a controlled manner. The antibacterial activity of these scaffolds was investigated against both Gram-positive (Staphylococcus aureus) and Gram-negative (Escherichia coli) bacteria. The ability of the scaffolds to release ions and the subsequent ingress of these ions into hard tissue was evaluated …

Inorganic Hemostats: The State-Of-The-Art And Recent Advances, Sara Pourshahrestani, Ehsan Zeimaran, Ivan Djordjevic, Nahrizul Adib Kadri, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

Hemorrhage is the most common cause of death both in hospitals and on the battlefield. The need for an effective hemostatic agent remains, since all injuries are not amenable to tourniquet use. There are many topical hemostatic agents and dressings available to control severe bleeding. This article reviews the most commonly used inorganic hemostats, subcategorized as zeolite and clay-based hemostats. Their hemostatic functions as well as their structural properties that are believed to induce hemostasis are discussed. The most important findings from in vitro and in vivo experiments are also covered.

Toward The Synthesis And Characterization Of Pb-Doped Zns Nanocrystals For Solar Energy Applications, Allison Durr

Online Theses and Dissertations

Efficient and affordable energy conversion and energy storage technologies are required to meet society’s increasing demands. Semiconductor nanocrystals are particularly attractive materials for solar energy conversion applications, as their tunable optoelectronic properties can be manipulated to both optimize the absorbance of solar photons and to afford desirable electronic properties. Further tunability of binary semiconductor nanocrystal systems can be realized through substitutional doping. However, doping can be difficult, as the dopants can cause significant lattice strain in the host crystals. Lead-doped ZnS nanocrystals are one promising material for the conversion of solar photons into storable fuels such as hydrogen gas. The …

Thermal Responsive Release Of A Model Drug, Rhoadmine B, From Alginate Bead System, Heather F. Fairbairn Miss

Williams Honors College, Honors Research Projects

Smart drug delivery systems have garnered increased interest in the biomedical community during recent years. Investigation into thermal, pH, and light responsive delivery systems allows for targeted drug release systems to be developed. For this project, thermal responsive release behavior was investigated for the purpose of tuning release systems to achieve 60% release in a specified time by varying the content of thermal responsive polymer. To investigate this, the release profile of a model small hydrophilic drug (rhodamine B) from polymeric alginate beads that have been modified by the addition of thermal responsive poly(N-isopropylacrylamide) (PNIPAAm). It was determined that when …

Rational Synthesis To Optimize Ruthenium-Based Biomass Conversion Catalysts, Shuo Cao

Theses and Dissertations

With worldwide petroleum resources dwindling and greenhouse gas emissions rising, it is urgent to find renewable replacements for petroleum-derived products. A biomass-derived chemical with high potential as a platform intermediate, γ-valerolactone (GVL) can be readily synthesized by hydrogenation of levulinic acid (LA), itself a common biomass intermediate, using supported Ru catalysts. Overall, vapor phase hydrogenation is more energy sensitive as the higher boiling point of LA (~245°C) and requires a high energy input, comparable to liquid phase hydrogenation, which is more economical. To date the literature on many novel biomass conversion processes such as the hydrogenation of LA to GVL …

Design And Development Of A High-Temperature High-Pressure Rolling Ball Viscometer/Densimeter And Evaluation Of Star Polymer-Solvent Mixtures, Matthew Stanton Newkirk

Theses and Dissertations

Modern automotive applications such as transmission clutch plates, combustion chambers, diesel fuel injector tips, and axle gears and friction plates operate at temperatures that can exceed 250°C and pressures of 40,000 psia. Industrial practice is to add homopolymers and copolymers to base oils to modify bulk fluid viscosity and frictional properties for these demanding applications. However, designing polymeric additives for lubricants and predicting their performance is limited by the lack of available high-temperature high-pressure (HTHP) viscosity and density data needed to test contemporary lubricity models. Thus, a major objective of this thesis is the design, development, and commissioning of a …

A Theoretical Simulation Of The Settling Of Proppants In A Hydraulic Fracturing Process, Nisreen Alseamr

Theses and Dissertations

Hydraulic fracturing is a process for the extraction of hydrocarbons from underground formations. It involves pumping a specialized fluid into the wellbore under high pressures to form and support fractures in the rock. Fracturing stimulates the well to increase the production of oil and the natural gas which are the pillars of the energy economy. Key to this process is the use of proppants, which are solid materials used to keep the fractures open. Understanding the transport of proppant particles through a fluid is important to improve the efficiency and reduce environmental impact of fracturing. An increase of the settling …

Development Of Novel High-Throughput Methodologies To Evaluate The Thermal Stability Of High-Temperature Thin-Film Crystals For Energy Applications, Jonathan Kenneth Bunn

Theses and Dissertations

High temperature materials are used in a variety of energy applications such as jet turbines, high temperature sensors, and solid oxide fuel cells (SOFCs). Discovery of new materials and their optimization represents a difficult engineering challenge, as the materials have to be designed to have a high figure of merit during intense high temperature operations.

The large number of engineering considerations involved in the identification and optimization of such materials makes traditional one-by-one material investigations prohibitively time consuming. The time needed to explore large parameter domains can be significantly decreased through the use of high-throughput experimentation (HTE). HTE is an …

Numerical Analysis Of Flexural Slip During Viscoelastic Buckle Folding, Davi Rodrigues Damasceno

Masters Theses

"Flexural slip is considered to be an important folding mechanism contributing in the development of different folds such as chevron, and kink-band buckle folds. Various filed studies have provided a general conceptual and qualitative understanding of flexural slip. However, quantitative evidence of the importance of the flexural slip mechanism during fold evolution is sparse, as the actual amount of surface parallel displacement, and timing, is difficult to measure accurately, due to the lack of suitable strain markers.

In this study 2D finite element analysis is used to overcome these disadvantages and to simulate flexural slip during viscoelastic buckle folding. Variations …

Data Analysis Of Surfactant-Induced Wettability Alteration In Carbonate Reservoirs, Hao Sun

Masters Theses

"Most carbonate formations prove to be oil-wet due to oil aging effect. Therefore it is essential to employ wettability alteration methods for a more effective enhanced oil recovery process. It is confirmed by researchers that surfactant treatment has positive effects on wettability alteration of carbonate rock, from strong oil-wet to intermediate wet or to even weak water-wet. A number of experiments have the same conclusion and yet, a systematic screening guide development with the support of sufficient data analysis is lacking.

This study involves screening guide development for surfactant-induced wettability alteration method. 199 experiments collected from published literatures are analyzed …

Discrete Model For Cancer Tumor Growth And Effect Of Chemotherapy, Karim Virani

Dissertations and Theses

Many mathematical models have focused on growth of a single tumor with their spreading rate with some have included its metastasis. Some of the earlier models focus on exponential growth and its shift with time on to a linear model. The Gompertzian model involves a quadratic terms and that limit growth. We looked into Iwata et al paper it discusses a different model and takes into account the growth and metastasis of a tumor population but does not look into tumor shrinking or chemotherapy. Our new model focuses on the extending Iwata et al model to take into account tumor …

An Injectable Stem Cell Delivery System For Treatment Of Musculoskeletal Defects, Shirae Leslie

Theses and Dissertations

The goal of this research was to develop a system of injectable hydrogels to deliver stem cells to musculoskeletal defects, thereby allowing cells to remain at the treatment site and secrete soluble factors that will facilitate tissue regeneration. First, production parameters for encapsulating cells in microbeads were determined. This involved investigating the effects of osmolytes on alginate microbead properties, and the effects of alginate microbead cell density, alginate microbead density, and effects of osteogenic media on microencapsulated cells. Although cells remained viable in the microbeads, alginate does not readily degrade in vivo for six months. Therefore, a method to incorporate …

Nitrogen Gas Flooding For Naturally Fractured Carbonate Reservoir: Visualisation Experiment And Numerical Simulation, Zhaojie Song, Jirui Hou, Zhongchun Liu, Fenglan Zhao, Shijun Huang, Yong Wang, Jieheng Wu, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Tahe Naturally Fractured Carbonate Reservoir has implemented nitrogen gas flooding since 2013, with daily oil production of 7580 bbls and oil recovery increment of 0.83% by the end of 2015. However, the presence of fractures significantly affects gas swept volume and production performance, so large amount of oil reserves is poorly flooded due to gas channeling through fractures. The fluid flow mechanisms in fractured models were discussed in order to improve field gas flooding efficiency. Based on the geological constrains of Tahe Oilfield, fractured models with different apertures were fabricated using acrylic glass to model carbonate matrix wettability and for …