Chemical Engineering Commons^™

Development And Evaluation Of A Coaxial Cable Sensing System For Co₂ Sequestration Wellbore Integrity Monitoring, Yurong Li

Doctoral Dissertations

"Downhole monitoring plays a crucial part in geological carbon dioxide (₂) sequestration. Various downhole monitoring technologies have been explored and applied, but they are either expensive or have system longevity issues. To address this issue, a robust and cost-effective downhole sensing system based on distributed coaxial cable sensors is developed and evaluated in laboratory, and a numerical simulation with staged finite element model is conducted to study the feasibility of using the coaxial cable sensing system for monitoring and evaluation of wellbore stability during CO₂ injection.

The real-time distributed sensing system is composed of Fabry-Perot interferometer based …

Advancing Microalgae Culturing Via Bubble Dynamics, Mass Transfer, And Dynamic Growth Investigations, Aastha Ojha

Doctoral Dissertations

"The major hindrances to large scale cultivation of microalgae are the problems associated with the design, operation, and scale-up of airlift photobioreactors (PBRs), due to a lack of a comprehensive understanding of the gas-liquid interaction process in real microalgae cultures. Thus, the overall objective of this work is to advance the fundamental understanding of microalgae culturing via gas holdup, bubble dynamics, mass transfer, and dynamic growth investigations.

First, a four-point optical fiber probe technique was employed to study the local gas holdup, and bubble dynamics properties such as bubble passage frequency, chord length and bubble velocity distribution, and interfacial area …

Analysis And Mitigation Of Wellbore Breakout And Fracturing, Reza Rahimi

Doctoral Dissertations

"Mechanical wellbore integrity problems while drilling are mainly due to wellbore shear failure or tensile failure. To ensure wellbore integrity, breakout and fracture geomechanical analysis is conducted to estimate minimum and maximum drilling fluid densities. Currently, there is no agreement as to which rock failure criterion to use for estimating breakout or fracture criteria to use for analyzing drilling induced fractures. However, when wellbore integrity issues arise while drilling, mitigation strategies can be applied to rectify these problems.

This dissertation analyzes criteria for wellbore breakout and fracturing. Also, mitigation strategies for breakout and fracturing while drilling were experimentally investigated. Thirteen …

Oxidative Dehydrogenation Of Light Alkanes With Carbon Dioxide, Marktus A. Atanga

Masters Theses

”Most experts studying the global ecosystem and climate suggest that rising anthropogenic CO₂ emissions have contributed to significant global climate change in the last half-century. The development of effective strategies that convert CO₂ into energy, fuels, and chemicals are greatly preferable to oceanic or geologic sequestration options because they offer the potential to create new commercially-viable products from renewable carbon feedstock. On the other hand, the selective oxidative dehydrogenation of light alkanes (C₂-C₄) to corresponding olefins, methane reforming, and methane coupling are the major challenges for producing valuable and versatile feedstocks. The oxidative dehydrogenation …

Evaluation Of Highly Viscous Polymeric Fluids And Recrosslinked Degraded Gel, Danlu Zhang

Masters Theses

”This work presents the evaluations of two products. One can be used for hydraulic fracturing to achieve viscosity stable under high shear rate, and the other is potential to be applied to enhance oil recovery from mature oilfield.

The first experiment is to synthesize and evaluate a new polymeric fracturing fluid that can resist high shear rate of 511^-1 with favorable viscosity. Zirconium crosslinked fracturing fluids are lack of self-healing ability after shearing, and the difficulties still exist in maintaining viscous with lower polymer content exposed to high shearing conditions, therefore, the research is trying to develop a new …

Aspen Simulation Of Oil Shale And Biomass Process, Anand Alembath

Masters Theses

"This thesis focuses on design and analysis of two major chemical processes using computer simulation which performs a steady state computation. The objective is to design processes using Aspen simulation to establish optimum operating conditions by performing various simulation runs which are challenging to execute at lab scale.

Increasing energy needs and decline of global oil prices has shifted our focus on commercially developing unconventional and renewable resources. Commercialization of any process relies on developing a process model that identifies different process parameters by performing a steady state mass and heat balance. Aspen simulation is considered an effective process modeling …

Iron Phosphide Nanostructures As An Efficient Bifunctional Catalysts For Water Splitting, Nikitaa Ashokan

Masters Theses

"The first part of this thesis work focuses on developing a bifunctional catalyst for electrochemical water splitting encompassing both oxygen and hydrogen evolution. A highly efficient catalyst is necessary to improve kinetics of the sluggish four electron process for oxygen evolution reaction (OER) and two-electron process for hydrogen evolution reaction (HER). Recently, transition metal phosphides have gained increasing interest in this field because of their good electrical conductivity properties as well as better catalytic activity. Many transition-metal phosphides are being considered for this application and iron phosphide (FeP) has proved to be a good HER catalyst. In this work, we …

Experimental Evaluations Of Selected Sealants To Remediate Co₂ Leakage, Aaron Jeffrey Blue

Masters Theses

"Carbon Dioxide (CO₂) sequestration into porous and permeable brine-filled aquifers is seen as one of the most feasible solutions for reducing the amount of greenhouse gases released into the atmosphere from coal-fired power plants. To safely store the CO₂, it must be trapped under an impermeable rock acting as a seal. One of the concerns with CO₂ sequestration is the generation of new fractures or reopening of existing fractures caused by CO₂ injection in the sealing formation. This project evaluates the potential of sealing these fractures by injecting sealing materials into them. These sealing …

The Impact Of Heat Exchanging Internals On Hydrodynamics Of Bubble Column Reactor, Ahmed Jasim

Masters Theses

"In this study, the impact of configuration and size of vertical heat exchanging internals in bubble columns on gas holdup, specific gas-liquid interfacial area, bubble chord length, and bubble rise velocity were investigated. Three different configurations of internals, each covering 25% of the column's cross-sectional area, were used to simulate the heat exchanging tubes utilized in the F-T process. The First configuration is a circular-like arrangement of 0.5 inch diameter vertical rods, whereas the second is a hexagonal-like arrangement of 0.5 inch diameter vertical rods. The third configuration is also a circular arrangement but of 1 inch diameter vertical rods …

Data Analysis Of Surfactant-Induced Wettability Alteration In Carbonate Reservoirs, Hao Sun

Masters Theses

"Most carbonate formations prove to be oil-wet due to oil aging effect. Therefore it is essential to employ wettability alteration methods for a more effective enhanced oil recovery process. It is confirmed by researchers that surfactant treatment has positive effects on wettability alteration of carbonate rock, from strong oil-wet to intermediate wet or to even weak water-wet. A number of experiments have the same conclusion and yet, a systematic screening guide development with the support of sufficient data analysis is lacking.

This study involves screening guide development for surfactant-induced wettability alteration method. 199 experiments collected from published literatures are analyzed …

Effect Of Reservoirs Heterogeneity On Injection Pressure And Placement Of Preformed Particle Gel For Conformance Control, Ze Wang

Masters Theses

"Preformed particle gels (PPG) have been successfully applied as a plugging agent for plugging fractures and then divert displacing fluid into poorly swept zones. However, PPG propagation and plugging mechanisms through open fractures have not been studied thoroughly.

This work investigated the influence of some factors (particle size, brine concentration, heterogeneity, and brine salinity) on gel injectivity, plugging performance for water flow through open fractures. Five-foot tubes were used to mimic open fractures. Three models were designed to conduct the work, including (1) single fracture with uniform fracture width, (2) single fracture with different widths, and (3) two parallel fractures …

Study On The Applicability Of Relative Permeability Modifiers For Water Shutoff Using Numerical Simulation, Dheiaa Khafief Khashan Alfarge

Masters Theses

"Water production is a challenging problem to be controlled during hydrocarbon-reservoirs production life. Disproportionate Permeability Reduction (DPR) is often used as water shutoff treatment in production wells when other conventional solutions like mechanical isolations are difficult to perform. This study applied numerical simulation methods to diagnose the factors impacting DPR treatment success on macroscopic level and to see when, where and at which conditions DPR treatment can give best results.

This work indicated that the following points should be considered before DPR treatment is executed in any reservoir to get a successful treatment. Firstly, this research explored that DPR performance …

Shale Instability Of Deviated Wellbores In Southern Iraqi Fields, Ahmed Ali Shanshool Alsubaih

Masters Theses

"Wellbore instability problems are the cause for the majority of nonproductive time in the southern Iraqi fields' developments. The most severe problem in terms of effort and disbursement which is referred to a pipe sticking in Tanuma shale formation. Examining the drilling data revealed that this phenomenon was mostly related to the shear failure of the wellbore. Thus, a geomechanical analysis and drilling parameters/ practice optimization analysis were performed on a field in southern Iraq based on data from 45 deviated wells. The geomechanics analysis predicted the suitable drilling fluid density to prevent onset shear failure by using the Mogi-Coulomb …

Mixed Metal Oxide Catalysts Supported On H-Beta For Hydrogenolysis Of Glycerol Into 1,3-Propanediol, Amit Kant

Masters Theses

"Bioglycerol is the by-product which is produced largely from the microbial fermentation, hydrogenolysis of glucose in the mixture of polyols, fatty ester, soap manufacturing process and fatty acid production. Hydrogenolysis of glycerol is one of the most promising ways to convert glycerol and many work has been done towards 1,3-propanediol, 1,2-propanediol and 1-propanol using various metals and mixed-metal oxides such as W, Ru, Rh, Pt, Pd, Cu, Ni and different zeolites have been extensively used as the active components.

It has been well documented that the presence of Bronsted acid sites leads to the formation of acrolein, while Lewis acid …

Evaluating Completion Performance For Gas Wells In The Upper And The Lower Montney Formation, Canada, Omar Qasim Mohammed

Masters Theses

"Identifying the key drivers for success of multiple fractured horizontal wells is not straightforward, especially in unconventional reservoirs like the Montney. Al-Alwani et al. (2015) provided a statistical analysis of Montney completions based on publicly available data. They showed that for the entire well population, cumulative gas recovery per stage, declines as the number of completed stages increase. However, their statistical analysis did not differentiate between completions in the Upper/Middle/Lower Montney, and did not include perforation cluster data.

This work documents the statistical analysis of 296 cased-hole horizontal gas well completions reported in the Upper and the Lower Montney. The …

Fluid Flow Through Deformation Band, Huining Zhang

Masters Theses

"Cataclastic deformation bands, which are common in porous sandstone, have the potential to restrict fluid flow. Geological studies have shown that permeability of deformation band shear zones can be one to five orders of magnitude less than for the sandstone host rock. However, recent studies based on simplified analytical estimates have shown that fluid flow in jointed deformation bands may not be retarded since joints play an important role in conducting fluids. In this study, 2 dimensional finite element analysis (FEA) is used to simulate the total discharge flow rate through jointed deformations. Variations of single planar and conjugate jointed …

Mitigation Of Wellbore Instability In Deviated Wells By Using Geomechanical Models And Mpd Technique, Husam Raad Abbood

Masters Theses

"During drilling operations for the E oilfield in the Mishrif formation in southern Iraq, stuck pipe presents a significant wellbore stability problem for deviated wells. In this study, two solutions are utilized to address this problem. The first approach is a 1-D Geomechanical model of the Mishrif formation compiled based on the state of stress and rock strength parameters. It is utilized to assess the contribution of borehole collapse leading to the stuck pipe problems. The results of this study show that wells characterized by stuck pipe are drilled along azimuths which promote wellbore collapse. Three different failure criteria, the …

Design, Scale-Up, Six Sigma In Processing Different Feedstocks In A Fixed Bed Downdraft Biomass Gasifier, Sai Chandra Teja Boravelli

Masters Theses

"This thesis mainly focuses on design and process development of a downdraft biomass gasification processes. The objective is to develop a gasifier and process of gasification for a continuous steady state process. A lab scale downdraft gasifier was designed to develop the process and obtain optimum operating procedure.

Sustainable and dependable sources such as biomass are potential sources of renewable energy and have a reasonable motivation to be used in developing a small scale energy production plant for countries such as Canada where wood stocks are more reliable sources than fossil fuels. This thesis addresses the process of thermal conversion …

An Investigation Of Plugging And Increasing Oil Recovery In Sandstone Porous Media By Micrometer-Size Particle Gel, Haifeng Ding

Masters Theses

"Micrometer-size particle gel (microgel) has been developed and successfully applied to improve conformance in mature reservoirs. However, quite few researches have been published to address on their effect on oil recovery and rock permeability modification.

This work conducted a series of core flooding experiments to investigate the injectivity, plugging efficiency and improving oil recovery potentials of a couple of microgels synthesized in our lab.

First, this work studied the impact of permeability and crosslinker concentration on PAM type microgel treatment. Results shows that microgel treatment would have a less plugging efficiency in lower permeability rocks, which could be caused by …

Impact Of Repeated Cyclic Production Scheme On Eur In Low-Permeability Reservoirs, Samarth Gupte

Masters Theses

"Productivity in low-permeability reservoirs declines quickly compared to conventional reservoirs. These tight reservoirs have very high initial oil production rates but as soon as the oil near the fractured area is recovered, the production declines rapidly making economic oil and gas production a challenge for the industry. This study investigates the impact of repeated shut-in/production cycles on the ultimate recovery of oil in such environments.

A reservoir model with multiple fractured horizontal well having 30 transverse fractures is created using CMG. Reservoir permeability is varied over the range of 0.000001 md to 10 md and shut-in/production cycles of 2-weeks, 1-month, …