3d Printed Bone Supplement Materials,
2016
Western Michigan University
3d Printed Bone Supplement Materials, Azem Khalifa Yahamed
Dissertations
Three-dimensional (3D) printing is an advanced rapid technology that can be used to make human bone substitutes with exact shape and designed structures, based on models created from actual individual bone medical Digital Imaging and Communications in Medicine (DICOM) images. Biocompatible polymers have been selected for 3D printing of human bone structures. The thermoplastics were 3D printed with Fused Deposition Modeling (FDM) are Acrylate Butadiene Styrene (ABS), Polylactic Acid (PLA) and ULTEM 9085 (a polyetherimide). The polyamide PA 2200 was 3D printed using Selective Laser Sintering (SLS). Digital ABS (a crosslinked acrylic polymer) was 3D printed using PolyJet Technology. These …
Mitigating Transients And Azeotropes During Natural Gas Processing,
2016
Brigham Young University - Provo
Mitigating Transients And Azeotropes During Natural Gas Processing, Edris Ebrahimzadeh
Theses and Dissertations
Cryogenic carbon capture process can be used to efficiently eliminate CO2 emissions from fossil-fueled power plants. The energy-storing embodiment of cryogenic carbon capture (ES-CCC) integrates energy storage with cryogenic carbon capture and uses natural gas as a refrigerant. ES-CCC captures CO2 from slowly varying or steady-state sources even as it absorbs and replaces large amounts of energy on the grid for energy storage. These large transients occur in the LNG generation as the process moves through energy storing to energy recovery operations. Additionally, raw natural gas often includes CO2 that forms an azeotrope with ethane. Breaking this azeotrope and separating …
Texture Analysis Using The Neutron Diffraction Method On The Non Standardized Austenitic Steel Process By Machining,Annealing, And Rolling,
2016
Center of Science and Technology for Advanced Materials, National Atomic Energy Agency/BATAN, Puspiptek Serpong, Banten 15314, Indonesia
Texture Analysis Using The Neutron Diffraction Method On The Non Standardized Austenitic Steel Process By Machining,Annealing, And Rolling, Tri Hardi Priyanto, Parikin Parikin, Meijuan Li
Makara Journal of Technology
Austenitic steel is one type of stainless steel which is widely used in the industry. Many studies on austenitic stainless steel have been performed to determine the physical properties using various types of equipment and methods. In this study, the neutron diffraction method is used to characterize the materials which have been made from minerals extracted from the mines in Indonesia. The materials consist of a granular ferro-scrap, nickel, ferro-chrome, ferro-manganese, and ferro-silicon added with a little titanium. Characterization of the materials was carried out in three processes, namely: machining, annealing, and rolling. Experimental results obtained from the machining process …
Investigation Of The Use Of A Plasticizer-Polymer Sensor Coating With Improved Long-Term Stability In The Liquid Phase,
2016
Marquette University
Investigation Of The Use Of A Plasticizer-Polymer Sensor Coating With Improved Long-Term Stability In The Liquid Phase, Laura Jeanne Alderson
Master's Theses (2009 -)
Benzene is one of the volatile organic compounds present in crude oil and gasoline. Leakage from underground storage tanks or hazardous waste sites can introduce benzene contamination into nearby groundwater. Benzene is a known carcinogen and its exposure is limited by the Environmental Protection Agency to 5 parts per billion (ppb) in drinking water. Early, accurate detection of the presence of benzene contamination in groundwater supplies is extremely important. Shear horizontal surface acoustic wave (SH-SAW) devices with a chemically sensitive coating can be used for the detection of volatile organic compounds in liquid, such as BTEX (benzene, toluene, ethylbenzene and …
The Role Of Poly(Acrylic Acid) In Conventional Glass Polyalkenoate Cements,
2016
Missouri University of Science and Technology
The Role Of Poly(Acrylic Acid) In Conventional Glass Polyalkenoate Cements, Adel M.F. Alhalawani, Declan J. Curran, Daniel Boyd, Mark R. Towler
Chemical and Biochemical Engineering Faculty Research & Creative Works
Glass polyalkenoate cements (GPCs) have been used in dentistry for over 40 years. These novel bioactive materials are the result of a reaction between a finely ground glass (base) and a polymer (acid), usually poly (acrylic acid) (PAA), in the presence of water. This article reviews the types of PAA used as reagents (including how they vary by molar mass, molecular weight, concentration, polydispersity and content) and the way that they control the properties of the conventional GPCs (CGPCs) formulated from them. The article also considers the effect of PAA on the clinical performance of CGPCs, including biocompatibility, rheological and …
Maneuverability Of Ships With Small Draught In Steady Wind,
2016
Department of Naval Architect, Faculty of Engineering, Universitas Hasanuddin, Makassar 90245, Indonesia
Maneuverability Of Ships With Small Draught In Steady Wind, Daeng Paroka, Andi Haris Muhammad, Syamsul Asri
Makara Journal of Technology
Wind force and moment may force a ship to drastically decrease its speed and use a large drift angle as well as a large rudder angle in order to maintain its course. Ships with a small draught might have more risk in maneuvering to its point of view compared with a ship with a larger draught. This paper discusses maneuverability of a ship with a small draught in steady wind. The effect of wind on ship speed, drift angle, and rudder angle are investigated in a steady state condition. Five different ratios of wind velocity to ship speed from 1.0 …
Low-Temperature Artificial Maturation Studies Of Type Ii And Type Iii Kerogens: Implications For Biogenic Gas Production,
2016
Old Dominion University
Low-Temperature Artificial Maturation Studies Of Type Ii And Type Iii Kerogens: Implications For Biogenic Gas Production, Albert Willy Nguena Kamga
Chemistry & Biochemistry Theses & Dissertations
Ancient organic matter (OM) in shales and coals, known mainly as Type II and Type III OM are known to produce both biogenic, thermogenic gas and oil. In this dissertation, mild artificial maturation, via closed system pyrolysis, is employed to determine the thermal reactivity of Type II and Type III OM beyond diagenesis. We select three Type II kerogens: i) Type II kerogen isolated from recent cores (3.3 Ma, Ro = 0.28) recovered from an upwelling basin in Namibia, Africa referred to as ODP Sediment, ii) Type II-S isolated from sediments (150 Ma, Ro = 0.38) recovered from an outcrop …
Thermal Microfluidic Devices; Design, Fabrication And Applications,
2016
Marquette University
Thermal Microfluidic Devices; Design, Fabrication And Applications, Benyamin Davaji
Dissertations (1934 -)
This thesis investigates the thermal actuation and temperature measurement methods in microfluidic devices. We designed and fabricated microfluidic devices with various functionalities such as: bio sensing, particle counting, microscale calorimetry, and cellular temperature measurement. All of these functionalities use thermal measurement methods. When quantitative measurements are required, the label-free nature of thermal measurement methods, along with its simple readout, make it a powerful candidate for lab on a chip and bio sensing/detection applications. In this work, thermal measurement methods are used to characterize bio-samples, measure concentrations, study thermal responses, and even perform particle cytometry. However, thermal measurement methods are known …
A Comparison Of American, Norwegian, And Russian Standards In Calculating The Wall Thickness Of Submarine Gas Pipeline,
2016
Department of Chemical Engineering, Faculty of Engineering, Universitas Indonesia, Depok 16424, Indonesia
A Comparison Of American, Norwegian, And Russian Standards In Calculating The Wall Thickness Of Submarine Gas Pipeline, Cindy Dianita, Tatyana Vladimirovna Dmitrieva
Makara Journal of Technology
One of the key issues in the pipeline design is wall thickness calculation. This paper highlights a comparison of wall thickness calculation methods of submarine gas pipeline based on Norwegian Standard (DNV-OS-F101), Indonesian Standard SNI 3474 which refers to American Standard (ASME B31.8), and Russian Standard (VN39-1.9-005-98). A calculation of wall thickness for a submarine gas pipeline in Indonesia (pressure 12 MPa, external diameter 668 mm) gives the results of 18.2 mm (VN39-1.9-005-98), 16 mm (ASME B31.8), and 13.5 mm (DNV-OS-F101).The design formula of hoop stress due to internal pressure is interpreted in different ways for every standard. Only Norwegian …
Novel Nitroxyl Radical Synthesis,
2016
University of Nebraska-Lincoln
Novel Nitroxyl Radical Synthesis, Max Meier
UCARE: Research Products
The purpose of this research is to synthesize a novel compound, 2,2,6,6-dispirocyclobutylpiperidine- 4-one (P), for use as an oxidation reactant to form the corresponding nitroxyl radical. This is to be conducted using a reliable method for a variety of 2,2,6,6-tetrasubstituted piperidine-4-one compounds as detailed by Sakai et al. [3]. Sakai uses a variety of 6-member cyclic ketones, which are quite stable. It was attempted to use 4-member cyclic ketones to research the effectiveness of 2,6-substitution using a less stable carbonyl compound. Cyclobutanone and 3-oxycetanone were used as candidates for this reaction. Both are delicate, expensive ketones.
Closing A Synthetic Carbon Cycle: Carbon Dioxide Conversion To Carbon Monoxide For Liquid Fuels Synthesis,
2016
University of South Florida
Closing A Synthetic Carbon Cycle: Carbon Dioxide Conversion To Carbon Monoxide For Liquid Fuels Synthesis, Yolanda Andreina Daza
USF Tampa Graduate Theses and Dissertations
CO2 global emissions exceed 30 Giga tonnes (Gt) per year, and the high atmospheric concentrations are detrimental to the environment. In spite of efforts to decrease emissions by sequestration (carbon capture and storage) and repurposing (use in fine chemicals synthesis and oil extraction), more than 98% of CO2 generated is released to the atmosphere. With emissions expected to increase, transforming CO2 to chemicals of high demand could be an alternative to decrease its atmospheric concentration. Transportation fuels represent 26% of the global energy consumption, making it an ideal end product that could match the scale of CO …
Early Acidification Of Mars And The Potential Implications For Biology,
2016
Missouri University of Science and Technology
Early Acidification Of Mars And The Potential Implications For Biology, Sarah Stewart Johnson, D. Goerlitz, Kathleen C. Benison, Melanie R. Mormile, D. W. Ming
Biological Sciences Faculty Research & Creative Works
A leading paleoclimate theory for Mars, based on the identification of phyllosilicate minerals in ancient terrains, posits that the first several million years of the planet’s history were dominated by neutral to alkaline pH. However, evidence is mounting for the consideration of an alternate hypothesis: that some smectites on Mars formed under acidic conditions, and that the early surface of Mars may not have been subject to circum-neutral pH conditions, at least not uniformly. Work on shergottitic liquids suggests that up to 2400 ppm of sulfur could have degassed from martian magma, supplying more than enough sulfur for the planet’s …
Conversion Of Landfill Gas To Liquid Hydrocarbon Fuels: Design And Feasibility Study,
2016
University of South Florida
Conversion Of Landfill Gas To Liquid Hydrocarbon Fuels: Design And Feasibility Study, Ryan Alexander Kent
USF Tampa Graduate Theses and Dissertations
This paper will discuss the conversion of gas produced from biomass into liquid fuel through the combination of naturally occurring processes, which occur in landfills and anaerobic digesters, and a gas-to-liquids (GTL) facility. Landfills and anaerobic digesters produce gases (LFG) that can be converted into syngas via a Tri-reforming process and then synthesized into man-made hydrocarbon mixtures using Fischer-Tropsch synthesis. Further processing allows for the separation into liquid hydrocarbon fuels such as diesel and gasoline, as well as other middle distillate fuels. Conversion of landfill gas into liquid fuels increases their energy density, ease of storage, and open market potential …
A Continuous Formulation For Logical Decisions In Differential Algebraic Systems Using Mathematical Programs With Complementarity Constraints,
2016
University of Utah
A Continuous Formulation For Logical Decisions In Differential Algebraic Systems Using Mathematical Programs With Complementarity Constraints, Kody M. Powell, Ammon N. Eaton, John Hedengren, Thomas F. Edgar
Faculty Publications
This work presents a methodology to represent logical decisions in differential algebraic equation simulation and constrained optimization problems using a set of continuous algebraic equations. The formulations may be used when state variables trigger a change in process dynamics, and introduces a pseudo-binary decision variable, which is continuous, but should only have valid solutions at values of either zero or one within a finite time horizon. This formulation enables dynamic optimization problems with logical disjunctions to be solved by simultaneous solution methods without using methods such as mixed integer programming. Several case studies are given to illustrate the value of …
A Continuous Formulation For Logical Decisions In Differential Algebraic Systems Using Mathematical Programs Of Complementarity Constraints,
2016
University of Utah
A Continuous Formulation For Logical Decisions In Differential Algebraic Systems Using Mathematical Programs Of Complementarity Constraints, Kody Powell, Ammon N. Eaton, John Hedengren, Thomas F. Edgar
Faculty Publications
This work presents a methodology to represent logical decisions in differential algebraic equation simulation and constrained optimization problems using a set of continuous algebraic equations. The formulations may be used when state variables trigger a change in process dynamics, and introduces a pseudo-binary decision variable, which is continuous, but should only have valid solutions at values of either zero or one within a finite time horizon. This formulation enables dynamic optimization problems with logical disjunctions to be solved by simultaneous solution methods without using methods such as mixed integer programming. Several case studies are given to illustrate the value of …
Modified Yttrium Hydroxide/Mc Nylon Nanocomposites And Scaling Effects In Multilayer Polyethylene Films,
2016
University of South Florida
Modified Yttrium Hydroxide/Mc Nylon Nanocomposites And Scaling Effects In Multilayer Polyethylene Films, Jia Chen
USF Tampa Graduate Theses and Dissertations
In this thesis, monomer casting (MC) nylon was synthesized. MC nylon could replace nonferrous metals in certain applications, including gears, wheels, and other moving parts. However, compared with metals, MC nylon products have poor strength and stiffness, and crack easily, especially at low temperatures. In addition, the dimensional stability of MC nylon is poor, especially in the large casting nylon products, causing significant internal stresses due to shrinkage. Thus, MC nylon cracks easily when cast and molded. The yttrium hydroxide particles were modified by stearic acid and dispersed in the caprolactam. The polymerization time was short due to fast anionic …
Pathways To Ultra-Low Platinum Group Metal Catalyst Loading In Proton Exchange Membrane Electrolyzers,
2016
Case Western Reserve University
Pathways To Ultra-Low Platinum Group Metal Catalyst Loading In Proton Exchange Membrane Electrolyzers, Julie N. Renner
Faculty Scholarship
Hydrogen is one of the world's most important chemicals, with global production of about 50 billion kg/year. Currently, hydrogen is mainly produced from fossil fuels such as natural gas and coal, producing CO2. Water electrolysis is a promising technology for fossil-free, CO2-free hydrogen production. Proton exchange membrane (PEM)-based water electrolysis also eliminates the need for caustic electrolyte, and has been proven at megawatt scale. However, a major cost driver is the electrode, specifically the cost of electrocatalysts used to improve the reaction efficiency, which are applied at high loadings (>3 mg/cm2 total platinum group metal (PGM) content). Core-shell catalysts …
Large-Area Graphene-Based Nanofiltration Membranes By Shear Alignment Of Discotic Nematic Liquid Crystals Of Graphene Oxide,
2016
Monash University, Australia
Large-Area Graphene-Based Nanofiltration Membranes By Shear Alignment Of Discotic Nematic Liquid Crystals Of Graphene Oxide, Abozar Akbari, Phillip Sheath, Samuel T. Martin, Dhanraj B. Shinde, Mahdokht Shaibani, Parama Chakraborty Banerjee, Rachel Tkacz, Dibakar Bhattacharyya, Mainak Majumder
Chemical and Materials Engineering Faculty Publications
Graphene-based membranes demonstrating ultrafast water transport, precise molecular sieving of gas and solvated molecules shows great promise as novel separation platforms; however, scale-up of these membranes to large-areas remains an unresolved problem. Here we demonstrate that the discotic nematic phase of graphene oxide (GO) can be shear aligned to form highly ordered, continuous, thin films of multi-layered GO on a support membrane by an industrially adaptable method to produce large-area membranes (13 × 14 cm2) in < 5 s. Pressure driven transport data demonstrate high retention (> 90%) for charged and uncharged organic probe molecules with a hydrated radius above 5 Å as well as modest (30–40%) retention of …
Biopolymeric Mucin And Synthetic Polymer Analogs: Their Structure, Function And Role In Biomedical Applications,
2016
University of Kentucky
Biopolymeric Mucin And Synthetic Polymer Analogs: Their Structure, Function And Role In Biomedical Applications, Sundar Prasanth Authimoolam, Thomas D. Dziubla
Chemical and Materials Engineering Faculty Publications
Mucin networks are viscoelastic fibrillar aggregates formed through the complex self-association of biopolymeric glycoprotein chains. The networks form a lubricious, hydrated protective shield along epithelial regions within the human body. The critical role played by mucin networks in impacting the transport properties of biofunctional molecules (e.g., biogenic molecules, probes, nanoparticles), and its effect on bioavailability are well described in the literature. An alternate perspective is provided in this paper, presenting mucin’s complex network structure, and its interdependent functional characteristics in human physiology. We highlight the recent advances that were achieved through the use of mucin in diverse areas of bioengineering …
High Temperature Electrochemical Engineering And Clean Energy Systems,
2016
Savannah River National Laboratory
High Temperature Electrochemical Engineering And Clean Energy Systems, Brenda L. Garcia-Diaz, Luke Olson, Michael Martinez-Rodriguez, Roderick Fuentes, Hector Colon-Mercado, Josh Gray
Journal of the South Carolina Academy of Science
Global power demand is projected to more than double by 2050 and meeting this increased power demand will require maintaining or increasing power output from all existing energy sources while adding a large amount of new capacity. The power sources that have the greatest opportunity to fulfill this demand gap over this time period are clean energy sources including solar and nuclear power. One of the areas of expertise that SRNL has been applying to help with a variety of clean energy technologies is in high temperature electrochemistry. Savannah River National Laboratory (SRNL) in collaboration with industrial and university partners …
