Chemical Engineering Commons^™

Evaluation Of Phosphorous Removals By Biochar Supported Nano-Scale Zero-Valent Iron, Maria S. Rossetti

Chemical Engineering Undergraduate Honors Theses

This study evaluated the effectiveness of biochar-supported nano-scale zero-valent iron (nZVI/BC) in removing phosphorus (P) from water. Samples of nZVI/BC were prepared using aqueous nanoparticles synthesis techniques, and were mixed with a stock phosphorus solution. To determine P reductions water samples were tested for P content using the ascorbic acid method. This procedure was repeated for samples of stock P solution, zero-valent iron (ZVI), biochar, and ZVI/BC. nZVI/BC reduced P content by 86% whereas ZVI, biochar, and ZVI/BC removed 6%, -23%, and 17% respectively. This suggests that nZVI/BC has the potential to be an effective method of stormwater remediation.

Polyisobutylene Telechelic Prepolymers By In Situ End-Quenching And Post-Polymerization Modifications, Bin Yang

Dissertations

This volume focuses on the development of telechelic polyisobutylene (PIB) prepolymers by combining end-capping of living carbocationic polymerization of isobutylene (IB) with suitable reactants and post-polymerization modifications. Alkylation kinetics of PIB tert-chloride with alkoxybenzenes using either TiCl₄ or AlCl₃ were investigated. Quantitative para-position end-capped products were only achieved if the alkoxybenzene/AlCl₃ molar ratio was greater than unity; while no such molar ratio is required for TiCl₄, but the alkylation rate was slower than AlCl₃ under the same conditions. Photopolymerization kinetics analysis of PIB triphenol tri(meth)acrylates with low and high M_ns, …

Analyzing Potential Benefits Of Heat Integration Designs For A Dtbp Production Plant, Paul Stanzione

Senior Theses

This thesis looks at the implementation of various heat integration designs for a ditertiary butyl peroxide (DTBP) production plant. Heat integration, also known as process integration, is a common industrial practice in the chemical process industry to reduce utility costs. Heat integration is commonly analyzed using pinch technology, which focuses producing a heat exchanger design that pairs hot streams with excess energy with cold streams that need to be heated. These designs usually cut utility costs, but they also require the building of more heat exchangers to place within the process.

Beer, Booze, And Biofuels: An Introduction To Chemical Engineering, Kayla Revelle, Jacob Lambert, Kelly Kopchak

Senior Theses

The goal of this thesis project was to provide the layout, curriculum, and scheduling for an introductory course regarding chemical engineering for non-majors. Throughout the course of our studies in chemical engineering and engineering in general it had come to our attention that there were many myths regarding the classes and curriculum. We had heard countless times things such as “I am glad I’m not an engineering major”, “those classes seem so hard and boring”, or “It’s all math”. The purpose of this project and class was to dispel those myths and show non-majors what chemical engineering is all about. …

Sec-Butanol From Crude Butene Feedstock Plant Design, Samantha How, Jacob Przywara, Bryce Robbins, Gavino Valdez

Senior Theses

Sec-butanol, C4H10O, is a flammable alcohol that is widely used as a fuel additive or as a reactant to make butanone, an industrial solvent. A hydration reaction between n-butenes and water, catalyzed by sulfuric acid, is a commonly used process in producing sec-butanol. However, a more challenging reaction and separation scheme is presented with a crude feedstock of butenes because of the abundance of azeotropes produced by side reactions. The development of a new plant design is relevant to industrial chemical plants that produce large amounts of crude butene side products, and can be useful by increasing plant efficiency and …

Data Driven Discovery Of Materials Properties., Fadoua Khmaissia

Electronic Theses and Dissertations

The high pace of nowadays industrial evolution is creating an urgent need to design new cost efficient materials that can satisfy both current and future demands. However, with the increase of structural and functional complexity of materials, the ability to rationally design new materials with a precise set of properties has become increasingly challenging. This basic observation has triggered the idea of applying machine learning techniques in the field, which was further encouraged by the launch of the Materials Genome Initiative (MGI) by the US government since 2011. In this work, we present a novel approach to apply machine learning …

Assessing The Effects Of Sensitizing Tungsten Oxide With Zinc Telluride, Chengeto Kazuva

Theses and Dissertations

This thesis is a comparison study of the performance of plain tungsten oxide (WO₃) thin films and tungsten oxide thin films sensitized with zinc telluride (ZnTe) as photoelectrocatalysts. Tungsten oxide and zinc telluride are semiconductors which were prepared on indium tin oxide (ITO) coated glass, and subsequently studied for water splitting applications. The main method of synthesis employed was electrochemical deposition. Tungsten oxide thin films were deposited from a precursor solution of peroxotungstic acid while the zinc telluride thin films were deposited from a solution containing dissolved zinc sulfate heptahydrate, sulfuric acid and tellurium dioxide. Surface morphology, film composition and …

Production Of Mesophase Pitch From Gasified Lignin-Derived Tars, Adedayo O. Idowu

Theses and Dissertations

Lignin tars are created as a by-product of lignin gasification. Significant effort has gone into minimizing tar production. However, no process has been shown to completely eliminate its formation. As a result, the tar is being used to manufacture low value products such as asphalt, or is being used as a fuel in fixed combustion systems.

The research presented here is part of an effort to increase the viability of using lignocellulosic biomass as a feedstock to produce high value products. We tested the postulate that tars derived from lignin could be processed into a mesophase pitch allowable for conversion …

Oil Recovery By Surfactant Flooding; Sensitivity Analysis To Technical Parameters And Economic Analysis, Hadel Mohsen Moustafa

Theses

Various enhanced oil recovery methods including miscible gas injection, chemical, thermal and other methods are applied at the third phase of production after the primary and secondary recovery have been exhausted. Surfactant flooding is one of the chemical methods that is capable of recovering more oil by decreasing the IFT and/or wettability alteration.This piece of work aims to asses and select the development options using surfactant process that maximize oil recovery for a synthetic reservoir model by optimizing technical and economic analysis.

Reservoir simulation study using ECLIPSE 100 was used to study the different development options of surfactant flooding applied …

Evaluation Of Electrocoagulation For Chloride And Ammonium Removal From The Reject Brine Effluent Pretreated By Solvay Process, Miada Abubaker Ali

Theses

Excessive use of desalination, due to the increase in freshwater demand, results in large productions of reject brine. Therefore, the development of an efficient treatment process of the reject brine becomes vital. The Solvay process is one of the main treatment technologies, wherein NH₃ is introduced to convert soluble Na⁺ into insoluble NaHCO₃. However, in this process, Cl^- is not removed and NH₄⁺ is introduced, and therefore electrocoagulation has been proposed for their removal. The experiment was designed using Minitab with different initial concentrations of chloride (7400 – 32600 mg/l), current densities (0.033 …

Recent Progress In Template-Assisted Synthesis Of Nitrogen-Doped Porous Carbons For Oxygen Electroreduction, Wenhan Niu, Ligui Li, Shaowei Chen

Journal of Electrochemistry

Nitrogen (N)-doped porous carbons are potential alternatives to precious metal catalysts for oxygen reduction reaction (ORR) at the cathodes of proton exchange membrane fuel cells and metal-air batteries. Template-assisted synthesis has been used extensively as a robust and versatile method in the preparation of such carbon catalysts, where the ORR activity has been found to be dependent on various structural parameters, such as the concentrations and molecular configurations of the dopants, and the porosity, surface accessibility and electrical conductivity of the carbon materials. In this review, we summarize recent progress in this area of research focusing on the design, preparation …

Impact Of Nafion Loading And Anion Adsorption On The Synthesis Of Pt Monolayer Core-Shell Catalysts, Lijun Yang, Dustin Banham, Elod Gyenge, Siyu Ye

Journal of Electrochemistry

Carbon supported palladium (Pd) nanoparticles were used as a model core material for the synthesis of platinum (Pt) monolayer core-shell catalysts using rotating disk electrode method and a copper (Cu) under potential deposition technique. The impact of Nafion on the synthesis process was revealed by electrochemical testing with various Nafion contents. The existence of Nafion influenced the Cu under potential deposition, galvanic replacement and eventually the oxygen reduction reaction activity of the core-shell catalyst. However, as long as the Nafion content was less than 5 wt% in the test film, adding Nafion could help to bind catalyst onto the surface …

Designing Pt-Skin Of Pt-Based Bimetallic Electrocatalysts For Oxygen Reduction Reaction, Binwei Zhang, Yunxiao Wang, Yanfei Xu, Huakun Liu, Shixue Dou

Journal of Electrochemistry

In the past decade, great advancement has been made in the development of nanocatalysts for energy conversion and storage. Pt-skin of Pt-based bimetallic has shown a great potential in the tuning the electronic structures of electrocatalytically active materials toward oxygen reduction reaction. Here, we offer a brief overview of the recent research on the design and preparation of catalysts. Our focus is paid on the systematic studies of preparation and performance of Pt-skin catalysts towards oxygen reduction reaction.

Comparative Studies Of Fe, Ni, Co And Their Bimetallic Nanoparticles For Electrochemical Water Oxidation, Maduraiveeran Govindhan, Brennan Mao, Aicheng Chen

Journal of Electrochemistry

The design of efficient, durable, and earth-abundant electrocatalysts via environmentally compatible strategies for the oxygen evolution reaction (OER) is a vital for energy conversion processes. Herein we report a facile approach for the fabrication of low-cost and earth abundant metal catalysts, including iron (Fe), nickel (Ni), cobalt (Co), CoNi, and CoFe nanoparticles (NPs) on titanium (Ti) substrates through a one-step electrochemical deposition. Field-emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD) spectrocopy, X-ray photoelectron spectroscopy (XPS), and electrochemical techniques were employed to characterize these nanoparticles. Our electrochemical results revealed that among the five synthesized nanomaterials, the …

Comparison Of Oxygen Reduction Reaction Activity Of Pt-Alloy Nanocubes, Yongan Tang, Lin Dai, Shouzhong Zou

Journal of Electrochemistry

Alloying Pt with the first row non-noble transition metals has been demonstrated to increase the catalytic activity toward oxygen reduction reaction (ORR), which is the cathode reaction of the proton exchange membrane fuel cells (PEMFCs) and metal-air batteries. However, how much the ORR activity improvement comes from the alloying elements remains controversial. In this paper, the nanocubes of PtMn, PtFe, PtCo, and PtNi with the similar size and composition were prepared and their ORR activities were explored, in order to investigate the effects of alloying elements on the catalytic activity. The use of cubic shape particles minimizes the contribution to …

Electrodeposition Of Ruo2 Layers On Tio2 Nanotube Array Toward Co2 Electroreduction, Bei Jiang, Lina Zhang, Xianxian Qin, Wenbin Cai

Journal of Electrochemistry

RuO₂/TiO₂ composite materials have multitude of electrocatalytic applications including but not limited to CO₂ reduction reaction (CO₂RR). RuO₂/TiO₂ electrodes were previously prepared by repetitive coating and thermal decomposition (TD) of a Ru(III) precursor solution on Ti substrate. In this work, electrochemical potential cycling is applied to deposit amorphous RuO₂ (α-RuO₂) layers onto TiO₂ nanotube array (TNA) (RuO₂^CV/TNA) preformed on Ti foil. SEM, GIXRD, and voltammetry are applied to characterize the structures of the resulting RuO₂^CV/TNA. Ru loading on the RuO_{2 …}

Conference Program, Antonio Moreira, David Robinson

Regulatory Sciences for Biologics and Vaccines: Accelerating Development and Enabling Manufacturing Innovation

No abstract provided.

Design Of 3d Macroporous Inverse Opal Tio2 Binary And Ternary Composites Sensitized With Gold Nanoparticles And Cds Quantum Dots For Photocatalysis, Daniel A. Corella

Master of Science in Chemical Sciences Theses

Materials composed of titanium (IV) oxide (TiO₂) have received enormous scientific interest due to titania’s abundance, non-toxicity, and photocatalytic proficiency, however its large band gap limits its applicability under ambient conditions. Various attempts have been made to incorporate titania into composite systems to sensitize it for activity under a broader range of wavelengths. One such method includes utilizing narrow band gap semiconductors to form an electron transfer process analogous to photosynthesis referred to as a Z-scheme. Z-scheme systems can catalyze the decomposition of aqueous pollutants via generation of reactive oxygen species after input of sunlight. This work reports …

Probing The Effects Of Surface Hydrophobicity And Tether Orientation On Antibody-Antigen Binding, Derek B. Bush, Thomas A. Knotts Iv

Faculty Publications

Antibody microarrays have the potential to revolutionize molecular detection for many applications, but their current use is limited by poor reliability, and efforts to change this have not yielded fruitful results. One difficulty which limits the rational engineering of next-generation devices is that little is known, at the molecular level, about the antibody-antigen binding process near solid surfaces. Atomic-level structural information is scant because typical experimental techniques (X-ray crystallography and NMR) cannot be used to image proteins bound to surfaces. To overcome this limitation, this study uses molecular simulation and an advanced, experimentally validated, coarse-grain, protein-surface model to compare fab-lysozyme …

Sophorolipid Butyl Ester Diacetate Does Not Affect Macrophage Polarization But Enhances Astrocytic Glial Fibrillary Acidic Protein Expression At Micromolar Concentrations In Vitro, Alexis M. Ziemba, Manoj K. Gottipati, Filbert Totsingan, Cheryl M. Hanes, Richard A. Gross, Michelle R. Lennartz, Ryan J. Gilbert

Chemical and Biochemical Engineering Faculty Research & Creative Works

Peritoneal macrophages (PMACs) and spinal cord astrocytes were exposed to varying concentrations of soluble sophorolipid butyl ester diacetate (SLBEDA) in vitro. Macrophages and astrocytes demonstrated no decrease in viability in response to SLBEDA. Studying pro- and anti-inflammatory genes, PMACs did not show a shift toward a pro-inflammatory phenotype. However, at higher concentrations (3 and 30 μM), astrocytes showed an increase in their expression of glial acidic fibrillary protein. This novel category of compounds poses low risk to PMAC and astrocyte viability; however, the effect on PMAC polarization and astrocyte reactivity requires more elucidation.