Chemical Engineering Commons^™

A Computational Investigation Of The Interstitial Oxidation Thermodynamics Of A Mo-Nb-Ta-W High Entropy Alloy Beyond The Dilute Regime, Adib J. Samin

Faculty Publications

High entropy alloys (HEAs) are promising candidates for high-temperature structural material applications. Oxidation is a major factor that must be accounted for when designing such materials and it is thus important to study the oxidation behavior of HEAs to enable the optimum design of next generation materials. In this study, the thermodynamic behavior of interstitial oxygen in a Mo-Nb-Ta-W high entropy alloy was explored beyond the dilute limit. This was accomplished by sampling configurations of the HEA and HEA-oxygen systems from an isothermal–isobaric ensemble using a series of first-principle-based Monte Carlo simulations. It was found that the interstitial oxygen had …

Machine Learning Based Applications For Data Visualization, Modeling, Control, And Optimization For Chemical And Biological Systems, Yan Ma

LSU Doctoral Dissertations

This dissertation report covers Yan Ma’s Ph.D. research with applicational studies of machine learning in manufacturing and biological systems. The research work mainly focuses on reaction modeling, optimization, and control using a deep learning-based approaches, and the work mainly concentrates on deep reinforcement learning (DRL). Yan Ma’s research also involves with data mining with bioinformatics. Large-scale data obtained in RNA-seq is analyzed using non-linear dimensionality reduction with Principal Component Analysis (PCA), t-Distributed Stochastic Neighbor Embedding (t-SNE), and Uniform Manifold Approximation and Projection (UMAP), followed by clustering analysis using k-Means and Hierarchical Density-Based Spatial Clustering with Noise (HDBSCAN). This report focuses …

Influence Of The Shaping Process On The Tensile Properties Of Steel Reinforcement Bars Carbon Steel Grades Bjtp24 And Bjts40, Nuraziz Handika, Ridha Amalia Idhar, Jessica Sjah, Essy Arijoeni, Elly Tjahjono

Makara Journal of Technology

According to the current applicable national standard in Indonesia, i.e. SNI 07 2529 1991, in addition to the limitation on the loading rate, the steel bar must be reduced, formed, or lathed, as part of the shaping process of samples. This study determined and compared the effect of the shaping process on the yield strength, ultimate strength, and percent elongation by conducting tensile tests of steel bar grade BJTS40, i.e. deformed bar type of steel, and grade BJTP24, i.e., plain bar type of steel. Three diameters of the deformed bar (BJTS40) and one diameter of the plain bar (BJTP24) were …

A Density Functional Theory Study On Using Montmorillonite To Reduce Air Pollution, Triati Dewi Kencana Wungu, Meqorry Yusfi, Suprijadi Suprijadi

Makara Journal of Technology

In this study, density functional theory (DFT) method is used to investigate the possibility of using a smectite clay mineral called montmorillonite (MMT) in reducing heavy metals, such as Cd, through Cd adsorption. The mechanism of Cd adsorption in MMT is observed theoretically, and the tetrahedrally isomorphic substitution on the upper layer of MMT is considered to observe the role of Al and Fe in strengthening Cd adsorption. Two types of MMT are modeled in this study: Al-MMT and Fe-MMT. The Al-MMT means that Al substitutes one atom in the upper tetrahedral layer of MMT, while Fe-MMT means that Fe …

Ionic Conductiviy Of Alginate-Nh4cl Polymer Electrolyte, Nurhasniza Mamajan Khan, Noor Saadiah Mohd Ali, Ahmad Faizrin Ahmad Fuzlin, Ahmad Salihin Samsudin

Makara Journal of Technology

This study aims to produce a solid biopolymer electrolyte (SBE) by doping ammonium chloride (NH4Cl) into alginate. Solution casting was used to prepare the alginate–NH4Cl SBE system. Electrical impedance spectroscopy was performed to analyze the electrical properties of the SBE under the applied frequency range of 50 Hz–1 MHz. The incorporation of 8 wt.% NH4Cl enhances the ionic conductivity of the SBE up to 3.18 × 10-7 S/cm at ambient room temperature. Fourier transform infrared spectroscopy shows that complexation occurs between the hydroxyl (-OH), carboxylate (COO-) and ether linkage (C-O-C) functional groups due to the formation of inter- and intra-molecular …

Use Of Viscoplastic Damper For Improving The Resistance Of Steel Frames To Blast Loading, Gholamreza Abdollahzadeh, Hadi Faghihmaleki, Hamed Hamidi Jamnani, Atefeh Ebrahimi Bardar

Makara Journal of Technology

In this paper, we evaluated the effect of viscoplastic dampers on the response of steel frames under blast loading. We used SAP2000 software and link elements to investigate the responses of nine-story steel frames with and without dampers. The proposed viscoplastic damper is a new type of viscous damper. The application of this damper is based on the availability of its constituent materials. The damper acts as a viscoelastic damper at low levels of vibration, but it acts as a combination of viscoelastic operator and metal-yielding device at extreme levels of vibration. With respect to the height of the structure, …

Influence Of Lithium Bromide On Electrical Properties In Bio-Based Polymer Electrolytes, Ahmad Faizrin Fuzlin, Bouchta Sahraoui, Ahmad Salihin Samsudin

Makara Journal of Technology

This research presents the influence of lithium bromide (LiBr) on the electrical properties of alginate in bio-based polymer electrolytes (BBPEs) system. Bio-based alginate was prepared using the solution casting technique with various LiBr compositions. The ionic conductivity and electrical properties of the prepared BBPEs samples were studied using electrical impedance spectroscopy over a frequency range of 50 Hz–1 MHz. A maximum ionic conductivity of 7.46 × 10−5 S cm-1 was obtained for a sample containing 15 wt. % lithium bromide-doped alginate BBPEs at ambient temperature (303 K). The electrical analysis revealed that the most conductive sample based on alginate-LiBr BBPEs …

Mechanical Alloying-Assisted Coating Of Fe–Al Powders On Steel Substrate, Alfian Noviyanto, Sri Harjanto, Wahyu Bambang Widayatno, Agus Sukarto Wismogroho, Muhamad Ikhlasul Amal, Nurul Taufiqu Rochman

Makara Journal of Technology

The coating layer of Fe–Al powders on the steel substrate was prepared by mechanical alloying at room temperature. Fe, Al, and the steel substrates were milled with high-energy ball milling for 32 h with a ball-to-powder ratio of 8 in an argon atmosphere to prevent oxidation during milling. Although mechanical alloying was performed for 32 h, no new phases were observed after mechanical alloying, as analyzed by X-ray diffraction. However, the crystallite size of the milled powders for 32 h decreased by factor two compared with the initial powders. Scanning electron micrographs showed that the coating layers formed >8 h …

Performance Of Free-Space Optical Communication Systems Using Optical Amplifiers Under Amplify-Forward And Amplify-Received Configurations, Ucuk Darusalam, Arockia Bazil Raj, Fitri Yuli Zulkifli, Purnomo Sidi Priambodo, Eko Tjipto Rahardjo

Makara Journal of Technology

With the growth of digital technology in the stage of industrial revolution 4.0, the demand for broadcasting large amounts of information to last mile users has increased. Free-space optical (FSO) communication is one of the telecommunication platforms that has shown immense potential in meeting the demand for information broadcasting. In this work, the performance of FSO communication based on wavelength division multiplexing with a data rate of 80 Gbps is investigated through simulations. The configuration of optical amplifiers in the FSO system is set up on the basis of the amplify-forward and amplify-received configurations to expand the network. The investigation …

Iso 9001:2015 Risk-Based Thinking: A Framework Using Fuzzy-Support Vector Machine, Ralph Sherwin A. Corpuz

Makara Journal of Technology

Risk-based thinking (RBT) is one of the distinct new features of the International Organization for Standardization 9001:2015. Interestingly, the standard does not prescribe any tools. Hence, organizations are puzzled as to the extent of conformance. Some organizations have adopted formal tools. However, these tools seem insufficient in linking the standard into an evidence-based decision support system. To resolve gaps in RBT implementation, this paper proposes a framework based on fuzzy inference system (FIS) and support vector machine (SVM) to automate risk analysis and evaluation, proposal and verification of action plans, and prediction of the feasibility of risks and opportunities according …

Enhancement Of Regeneration Ratio And Thermal Durability For Regenerated Fiber Bragg Grating Based On Pre-Annealing Treatment And Multimaterial Fibers, Nurul Asha Mohd Nazal

Student Works (2020-2029)

Regenerated fiber Bragg grating (RFBG) or also known as regenerated grating (RG) is the creation of the temperature resistant grating through thermal erasure of seed grating (SG) followed by a rebirth of new grating in a annealing process. RG has shown to be a promising fiber Bragg grating component for operation under very high ambient temperature condition. Nonetheless, further investigation and improvement are required to better understand its formation mechanism and to enhance its performance. This study aims to enhance the regeneration ratio and thermal durability of the RG based on pre-annealing treatment and multimaterial fiber. In this work, the …

The Varied Thermal Response Of Magnetic Iron-Oxide Nanoparticles During Induction Heating In Liquid And Solid-Liquid Phase Change Mediums, Joshua Tompkins

Graduate Theses and Dissertations

This study investigates the induction heating response of uncapped iron oxide nanoparticles sonically dispersed as a nanofluid and mechanically distributed in solid phase change materials. The nanoparticles examined have a mean diameter of 14.42 nm and are magnetically heated in an alternating magnetic field at an amplitude of 72.6 kA/m at frequencies of 217, 303, and 397 kHz. Nanoparticle characterization was undertaken through transition electron microscopy, x-ray diffraction, and dynamic light scattering when in suspension. Carrier fluids were characterized through viscosity, heat capacity, and density measurements which were used in the calorimetric calculation of the specific absorption rate (SAR) of …

Microglia Control Vascular Architecture Via A Tgfβ1 Dependent Paracrine Mechanism Linked To Tissue Mechanics, Tejasvi Dudiki, Julia Meller, Gautam Mahajan, Huan Liu, Irina Zhevlakova, Samantha Stefl, Conner Witherow, Eugene Podrez, Chandrasekhar R. Kothapalli, Tatiana V. Byzova

Chemical & Biomedical Engineering Faculty Publications

© 2020, The Author(s). Tissue microarchitecture and mechanics are important in development and pathologies of the Central Nervous System (CNS); however, their coordinating mechanisms are unclear. Here, we report that during colonization of the retina, microglia contacts the deep layer of high stiffness, which coincides with microglial bipolarization, reduction in TGFβ1 signaling and termination of vascular growth. Likewise, stiff substrates induce microglial bipolarization and diminish TGFβ1 expression in hydrogels. Both microglial bipolarization in vivo and the responses to stiff substrates in vitro require intracellular adaptor Kindlin3 but not microglial integrins. Lack of Kindlin3 causes high microglial contractility, dysregulation of ERK …

Atherosclerosis: Pathology, Role Of Sd-Ldl, Particle Size Characterization Of Sd-Ldl With Multiangle Light Scattering, Akshay Sudhakar Ukey

Masters Theses

Atherosclerosis is an inflammatory disease due to the accumulation of lipids in the inner wall of arteries. As per the report of Center of Diseases Control and Prevention (CDC), 1 in every 4 deaths is due to heart diseases each year. Atherosclerosis occurs when artery walls harden by the buildup of cholesterol, forming multiple atherosclerotic plaques within the aorta (4). Out of the modern medicines available to control cholesterol, statin is amongst the foremost widely used because it is both safe and effective in lowering high risk patients (9). However, usage of high statins dosage typically leads to some mild …

Investigation Of Electrospun Nanofibers For Separation Applications, Shu-Ting Chen

Graduate Theses and Dissertations

Electrospun membranes are an attractive alternative to flat sheet membranes as absorbent with numerous advantages like high porosity, large specific surface area and ease of functionalization. This doctoral dissertation focuses on fabricating novel polymeric membrane adsorbents for protein separations and ammonium ion removal. Three distinctly different preparation methods including UV-initiated polymerization, atom transfer radical polymerization, and mixed-matrix formation, have been employed to fabricate the electrospun membranes. Overall, this study aimed to develop electrospun membranes with excellent separation efficiency for application in protein purification and ammonium ion removal.

Chapter 2 details the stepwise development of weak anion exchange membranes and subsequent …

Aldosterone Up-Regulates Voltage-Gated Potassium Currents And Nkcc1 Protein Membrane Fractions, Parveen Bazard, Bo Ding, Harish K. Chittam, Xiaoxia Zhu, Thomas A. Parks, Thomas E. Taylor-Clark, Venkat R. Bhethanabotla, Robert D. Frisina, Joseph P. Walton

Chemical and Biochemical Engineering Faculty Research & Creative Works

Na+–K+–2Cl− Cotransporter (NKCC1) is a protein that aids in the active transport of sodium, potassium, and chloride ions across cell membranes. It has been shown that long-term systemic treatment with aldosterone (ALD) can enhance NKCC1 protein expression and activity in the aging cochlea resulting in improved hearing. In the present work, we used a cell line with confirmed NKCC1 expression to demonstrate that in vitro application of ALD increased outward voltage-gated potassium currents significantly, and simultaneously upregulated whole lysate and membrane portion NKCC1 protein expression. These ALD-induced changes were blocked by applying the mineralocorticoid receptor antagonist eplerenone. However, application of …

Noise And Detectivity Limits In Organic Shortwave Infrared Photodiodes With Low Disorder, Zhenghui Wu, Ning Li, Naresh Eedugurala, Jason D. Azoulay, Dong Seok Leem, Tse Nga Ng

Faculty Publications

© 2020, The Author(s). To achieve high detectivity in infrared detectors, it is critical to reduce the device noise. However, for non-crystalline semiconductors, an essential framework is missing to understand and predict the effects of disorder on the dark current. This report presents experimental and modeling studies on the noise current in exemplar organic bulk heterojunction photodiodes, with 10 donor–acceptor combinations spanning wavelength between 800 and 1600 nm. A significant reduction of the noise and higher detectivity were found in devices using non-fullerene acceptors (NFAs) in comparison to those using fullerene derivatives. The low noise in NFA blends was attributed …

Homotopy Simulation Of Dissipative Micropolar Flow And Heat Transfer From A Two-Dimensional Body With Heat Sink Effect: Applications In Polymer Coating, O. A. Bég, B. Vasu, A. K. Ray, T. A. Beg, A. Kadir, H. J. Leonard, Rama S. R. Gorla

Faculty Publications

Non-Newtonian flow from a wedge constitutes a fundamental problem in chemical engineering systems and is relevant to processing of polymers, coating systems, etc. Motivated by such applications, the homotopy analysis method (HAM) was employed to obtain semi-analytical solutions for thermal convection boundary layer flow of incompressible micropolar fluid from a two-dimensional body (wedge). Viscous dissipation and heat sink effects were included. The non-dimensional boundary value problem emerges as a system of nonlinear coupled ordinary differential equations, by virtue of suitable coordinate transformations. The so-called Falkner-Skan flow cases are elaborated. Validation of the HAM solutions was achieved with earlier simpler models, …

The Use Of Nanoparticles And Electrospun Fibers For Intravaginal Delivery To Treat Viral And Bacterial Infections And Electrophysiological Measurements Of Synthetic Chloride Channels., Farnaz Minooei

Electronic Theses and Dissertations

Female reproductive viral and bacterial infections affect millions of women worldwide. Given the diversity and magnitude of these unmet reproductive health challenges, topical administration of antiretrovirals (ARVs) and antibiotics have emerged as promising approaches to maintain and restore reproductive health. However, currently available intravaginal dosage forms often suffer from low user adherence and the need for frequent, daily administration to achieve therapeutic effect. To address these challenges, the broad goal of this research was to focus on the development of new localized nanoparticle (NP) and electrospun fiber dosage forms to prolong the delivery and enhance the efficacy of active agents …

Utilizing A New Eco-Friendly Drilling Mud Additive Generated From Wastes To Minimize The Use Of The Conventional Chemical Additives, Abo Taleb T. Al-Hameedi, Husam H. Alkinani, Mohammed M. Alkhamis, Shari Dunn-Norman

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The cost of the drilling operation is very high. Drilling fluid presents 15 to 30% of the entire expense of the drilling process. Ordinarily, the major drilling fluids additives are viscosity modifiers, filtration control agents, and partial loss treatments. In this experimental work, full-set measurements under fresh and aged conditions, as well as high-temperature and high-pressure (HTHP) API filtration, were conducted to study the impacts of adding 0.5%, 1.5%, 2.5%, and 3.5% of black sunflower seeds’ shell powder (BSSSP) to spud mud. BSSSP of various grain sizes showed their ability to be invested for viscosity modifying, seepage loss controlling, and …