Chemical Engineering Commons^™

Influence Of Aerosols During Amine-Based Co2 Capture: Evolution And Control, David Immanuel Arthur Dhanraj

McKelvey School of Engineering Graduate Student Theses & Dissertations

Driven by escalating concerns on global warming and climate change, significant efforts have recently been initiated to reduce atmospheric CO2 concentration. Power generation from fossil fuels is the largest source of anthropogenic CO2. The US government has incentivized carbon capture through Section 45Q Tax code, which provides US$50/tCO2 (per metric ton) of qualified carbon dioxide captured and sequestered, as tax credits. The cost for carbon capture, transport and sequestration is US$75 – 150/t CO2, with the state-of-the-art capture technology costing between US$20 – 100/t CO2. Amine based post-combustion CO2 capture is the most economic technology suited for large power plants. …

Droplet And Particle Dynamics In Aerosol Reactors And Environmental System, Sukrant Dhawan

McKelvey School of Engineering Graduate Student Theses & Dissertations

Aerosol science and engineering is an enabler for continual advances in nanomaterial synthesis. The spray-based techniques have been used extensively for the large-scale production of nanoparticles. Synthesis of particles with a desired the size and morphology is of key importance for exploiting their properties for their use in several emerging technologies. In contrast to useful nanomaterials, the aerosols from industrial flue gas, dust, indoor cooking, pathogens, and wildfire etc. are harmful to human health. It is important to understand how these harmful aerosols travel through the environment and potentially impact the health. It is also very critical to improve the …

Direct Activation Of Light Alkanes To Value-Added Chemicals Using Supported Metal Oxide Catalysts, Md Ashraful Abedin

LSU Doctoral Dissertations

One of the most challenging aspects of modern-day catalysis is the conversion of methane. Direct conversion of methane via dehydroaromatization (MDHA) is a well-known process which can produce valuable hydrocarbons. Mo oxide supported on ZSM-5/MCM-22 has been studied extensively in recent years for MDHA. Mo carbides are responsible for activating methane by forming CHx species. These are dimerized into C2Hy and oligomerized on ZSM-5/MCM-22 Brønsted acid sites to form aromatics. Sulfated zirconia (SZ) supported Mo catalyst contains the acid sites necessary to produce benzene in MDHA. Here, sulfated hafnia (SH), a homologous oxide like SZ, has been proposed to provide …

Rapid Computation Of Effective Conductivity Of 2d Composites By Equivalent Circuit And Spectral Methods., Ben J. Ransom, Dean R. Wheeler

Faculty Publications

This work presents models for homogenizing or finding the effective transport or mechanical properties of microscale composites formed from highly contrasting phases described on a grid. The methods developed here are intended for engineering applications where speed and geometrical flexibility are a premium. A canonical case that is mathematically challenging and yet can be applied to many realistic materials is a 4-phase 2-dimensional periodic checkerboard or tiling. While analytic solutions for calculating effective properties exist for some cases, versatile methods are needed to handle anisotropic and non-square grids. A reinterpretation and extension of an existing analytic solution that utilizes equivalent …

Kinetic Modeling Study Of Laminar Burning Velocity Of Gasoline–Ethanol–Methanol Blends At Elevated Temperature And Pressure, Ahmad Syihan Auzani, Cahyo Setyo Wibowo, Riesta Anggarani, Yulianto Sulistyo Nugroho, Bambang Sugiarto

Makara Journal of Technology

Gasoline–ethanol–methanol (GEM) blends have been considered to replace pure gasoline as spark ignition engine fuel. Their physical and chemical properties and performance and emission measurements from real engines have been reported previously. However, a fundamental study that can explain the unique results of GEM compared with those of pure gasoline is lacking. This study aims to compare the laminar burning velocity of GEM blends at different mixtures, equivalence ratios, temperatures, and pressures with that of pure gasoline. A laminar flame propagation model and reaction mechanisms from the literature were were for a numerical simulation. In this study, the chemical components …

Music Information Retrieval Based On Active Frequency, Hardianto Wibowo, Wildan Suharso, Yufis Azhar, Galih Wasis Wicaksono, Agus Eko Minarno, Dani Harmanto

Makara Journal of Technology

Music is the art of combining frequencies. A balance of frequencies gives rise to a harmonious tone. Several features of music can be analyzed, and they include sociocultural background, lyrics, mood, tempo, rhythm, harmony, melody, timbre, and instrumentation. In this study, we use the frequency of instrumentation as a feature for classification because each instrument has a frequency range. To test this frequency range, we use five music genres and one music playing skill. The five genres are dangdut, electronic dance music (EDM), metal, pop/rock, and reggae. The music playing skill is acoustic. Active frequencies are tested using the k-nearest …

Predictive Delivery Man Assignment Problem Using Deep Learning, Rahmadini Payla Juarsa, Taufik Djatna

Makara Journal of Technology

Dispatching is a critical part in current online shopping. It relates to how the delivery man assignment should minimize cost along with the service from a source to an end customer with an appropriate scheduled time. The problem arises as neither enough products to deliver nor delivery men are available for dispatch, resulting in suboptimal service and a waste of money. The study aimed to formulate the cost of restaurant dispatching for inducing a deep learning-based solution with the gated recurrent unit recurrent neural network to receive hourly order data and to engage the result for near feature delivery man …

Effect Of Arc Plasma Sintering On The Structural And Microstructural Properties Of Fe-Cr-Ni Austenitic Stainless Steels, Parikin Parikin, M. Dani, A. Dimyati, N. D. Purnamasari, B. Sugeng, M. Panitra, A. Insani, T. H. Priyanto, S. Mustofa, Syahbuddin Syahbuddin, A. Huang

Makara Journal of Technology

X-ray diffraction techniques were performed to determine the actual crystal structure of A2 austenitic stainless steel (ASS) as-cast and A2 ASS after arc plasma sintering (APS) for 2 s. Computations were conducted on the basis of the Bragg arithmetic formula by comparing the S2 arithmetic with the interplanar spacing. The Bragg arithmetic formula is a simple series for the determination of the crystalline phase of materials based on the Miller indices of cubic shapes or other shapes. A2 ASS as-cast was identified to have a crystal structure of face-centered cubic with lattice parameter a = 3.58 Å. A similar crystal …

Comparison Of Concrete And Steel Jacket Methods For Reinforcing A Concrete Bridge Pier By Numerical And Experimental Studies, Hadi Faghihmaleki

Makara Journal of Technology

Various rehabilitation and strengthening procedures have been developed in recent decades. A study to determine which methods can be implemented to increase the useful life of the bridge before strengthening must be performed. In this study, the seismic behavior of a reinforced concrete bridge pier with dimension 3.5 × 3.5 m, which was reinforced by two steel and a concrete jacket, was investigated. Nonlinear geometric models and materials were analyzed to estimate the seismic parameters of the pier. Results show an increase in energy absorption, ultimate strength, and ductility for the steel jacket, as well as a greater increase in …

Trend Significance Levels Of Rain Onset And Cessation And Lengths Of The Wet And Dry Seasons In Epe, Lagos State, Nigeria, Adekunle Adedeji Alli, Olorunwa Eric Omofunmi

Makara Journal of Technology

This study aims to reduce crop failure resulting from a dry spell, which is the first occurrence of unsustainable rainfall that deceives farmers into planting. Thus, trends need to be tested using hypothesis, kurtosis, and other statistics to analyze the risks associated with unstable planting calendars and their possible mitigation strategies. The daily rainfall data from 1982 to 2018 were obtained from the archive of NASA/POWER SRB/FLASH, and the research location is Epe, Lagos State, Nigeria, which lies at latitude 6.585° N and longitude 3.962° E. Microsoft Excel was used to perform the tests. Results show that the null hypothesis …

Improvement Of Electrical Properties Of Cmc-Pva Doped With Various Contents Of Lino3 As An Application For Hybrid Polymer Electrolytes, Amalia Zulkifli, Norfatihah Mazuki, Ahmad Salihin Samsudin

Makara Journal of Technology

The present work was carried out with the development of hybrid polymer electrolytes (HPEs) by using carboxymethyl cellulose (CMC)–polyvinyl alcohol (PVA) doped with different contents of lithium nitrate (LiNO3) for the determination of their structural and conduction properties. The structural analysis was conducted by using Fourier transform infra-red spectroscopy and showed the interaction between the blend host polymer and ionic dopant, which formed via the coordinating site of CMC-PVA and Li+-NO3−. The complexes of CMC-PVA doped LiNO3 led to an increment in ionic conductivity, as observed by electrical impedance spectroscopy, and the sample containing 20 wt% LiNO3 obtained the highest …

Wetting And Drying Dynamics For Tio2 With Pbs Quantum Dots., Kelly M. Lee

Electronic Theses and Dissertations

Initial solar cells utilized silicon and alloys for their economic viability. Photoelectrochemical photovoltaic cells were discovered with technological advancement which increased solar efficiency and further improved economic feasibility leading to quantum dot sensitized solar cells. Lead sulfide quantum dots and titanium dioxide were studied for wetting and drying effects. Zeta potential, pH values, SEM, and optical microscopes quantified or observed the colloidal suspension and dried sample behavior. Combined mixtures of lead sulfide and titania were dried at 3.6 pH and 12.56 pH values. This due to the observed zeta potential isoelectric point of titania, and behavior showed increased stability occurring …

The Study Of Copper Corrosion Mechanisms Using Electrochemical Experimental Techniques., Evan Grimm

Electronic Theses and Dissertations

The purpose of this study was to discover and thoroughly explain the corrosion mechanisms of copper in saltwater, tap water and deionized water, and to apply these methods and findings when testing the corrosion mechanisms of other materials. The experimental procedure consisted of measuring the open circuit potential, electrochemical impedance spectroscopy, linear sweep voltammetry, and Tafel analysis.

The copper was found to corrode at a greater rate in saltwater, followed by tap water then deionized water, with a larger difference between saltwater and tap water than between tap water and deionized water. Each reaction was found to be both kinetically …

In Vitro Osteogenic Performance Of Two Novel Strontium And Zinc-Containing Glass Polyalkenoate Cements, Daniella Marx, Alireza Rahimnejad Yazdi, Marcello Papini, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

Glass polyalkenoate cements (GPCs) are under investigation as potential bone adhesives, as they may provide an alternative to polymethylmethacrylate-based cements. GPCs containing strontium (Sr) and zinc (Zn) in place of aluminum (Al) are of particular interest because these ions are known stimulators of osteoprogenitor differentiation. GPCs have been manufactured from a novel bioactive glass (SiO2:0.48, ZnO:0.36, CaO:0.12, SrO:0.04) in the past, but, while such materials have been assessed for their influence on viability, their influence on osteogenic function has not been investigated until now. For this study, two GPCs were formulated from the same glass precursor evaluated in previous studies. …

The Effects Of Ceria Loading On Three-Way Catalysts For Passive Scr Operation, Calvin R. Thomas, Josh A. Pihl, Vitaly Y. Prikhodko, Michelle K. Kidder, Jochen A. Lauterbach, Todd J. Toops

Faculty Publications

Passive SCR systems, which employ both a three-way catalyst and SCR catalyst, are effective for the reduction of nitrogen oxide (NOx) emissions from lean burn gasoline engines. However, questions remain regarding the effect of three-way catalyst formulations on their performance in these systems. Here, Pd/CeOx/Al2O3 catalysts with variable CeOx loading were synthesized, characterized, and evaluated to determine the effects of CeOx on catalyst performance. While a small amount of ceria was beneficial for promoting essential reactions, excess ceria was detrimental due to the increase in oxygen storage capacity. Additionally, insights into potential reaction pathways for NH3 production were determined.

Methane Emission Treatment And Potential Upcycling Using Methylomicrobium Alcaliphilum, Jace Parkinson

All Graduate Plan B and other Reports, Spring 1920 to Spring 2023

Anthropogenic methane emissions are harmful to the environment and can be difficult to treat. Use of M. alcaliphilum for bioremediation of methane looks to be one of the most promising methods of reducing the negative environmental impacts of methane emissions while simultaneously providing an economic incentive. Successful bioreactor design for M. alcaliphilum based methane treatment requires biokinetic constants and microbial growth information. Methods were established for determining biokinetic constants, including growth rate, biomass yield, specific methane consumption rate, and a correlation between methane oxidation and carbon dioxide production for M. alcaliphilum. Values determined for these constants were used to …

The Effects Of Ceria Loading On Three-Way Catalysts For Passive Scr Operation, Calvin R. Thomas, Josh A. Pihl, Vitaly Y. Prikhodko, Michelle K. Kidder, Jochen A. Lauterbach, Todd J. Toops

Faculty Publications

Passive SCR systems, which employ both a three-way catalyst and SCR catalyst, are effective for the reduction of nitrogen oxide (NOx) emissions from lean burn gasoline engines. However, questions remain regarding the effect of three-way catalyst formulations on their performance in these systems. Here, Pd/CeOx/Al2O3 catalysts with variable CeOx loading were synthesized, characterized, and evaluated to determine the effects of CeOx on catalyst performance. While a small amount of ceria was beneficial for promoting essential reactions, excess ceria was detrimental due to the increase in oxygen storage capacity. Additionally, insights into potential reaction pathways for NH3 production were determined.

Mixed Metal Oxide Nanowires Via Solid State Alloying., Veerendra Atla

Electronic Theses and Dissertations

Mixed metal oxide materials with composition control find applications in energy conversion and storage processes such as heterogenous catalysis, photoelectrochemical catalysis, electrocatalysis, thermal catalysis, and lithium-ion batteries. Mixed metal oxides and/or complex oxides with composition control and in one-dimensional form as nanowires could be interesting to various catalysis applications due to control on single crystal surfaces, active sites, acidity versus basicity site density, and oxygen vacancies. The major challenge is to synthesize mixed metal oxide nanowires beyond binary oxides with composition control. In this dissertation, solid state alloying of binary oxide nanowires with solid and liquid precursors is studied to …

Aggregation Dynamics Of Bulk Nanoparticle Haloing Systems And The Influence Of Non-Ambient Temperatures., Marzieh Moradi

Electronic Theses and Dissertations

One of the methods of assembling colloids into 3D crystal structures is through the use of nanoparticle haloing. Nanoparticle haloing is a stabilization mechanism in binary particle suspensions possessing both a size and charge asymmetry, with which the nanoparticles aid in the bulk suspension’s stability. By altering the volume fractions of nanoparticles, it is possible to control the effective repulsion between the microparticles. Understanding the colloidal interactions and aggregate crystallinity as a function of nanoparticle concentration, temperature, and time are key challenges in developing future materials and designing crystalized 3D colloidal systems. In this study, we investigated the effect of …

Exploring Meerwein-Ponndorf-Verley Reactions Using Metal Organic Framework Catalysts., Yuehan Zhou

Electronic Theses and Dissertations

The Meerwein–Ponndorf–Verley (MPV) reaction is a reaction that is used to reduce aldehydes and ketones to the corresponding alcohols with the added use of catalysts. The common metal triflate catalysts used in MPV reduction incur tremendous environmental hazards and high operational costs. The use of Metal-Organic Frameworks (MOFs) as catalysts can be an alternative due to MOFs’ extraordinarily high surface areas, ultrahigh porosities, tunable pore sizes, modifiable internal surfaces, and numerous framework structures. Moreover, using MOFs as catalysts for MPV hydrogenation is economically viable due to low operational and material costs. This study involves using MOF-808 (Hf) in the MPV …