Chemical Engineering Commons^™

Impact Of Glass Powder As A Sustainable Material On The Workability, Strength, And Durability Properties In High-Performance Basalt Fiber Reinforced Concrete: A Statistical Analysis, Ahmed Fathi Mohamed Salih

Journal of Sustainable Construction Materials and Technologies

The global construction sector is increasingly challenged to balance environmental sustainability with the growing demand for durable, high-performance materials. As cement production continues to be a major source of anthropogenic CO2 emissions, the incorporation of alternative, low-impact binders has become a key strategy for reducing the environmental footprint of concrete. In this context, glass powder (GP)—a finely ground industrial by-product rich in amorphous silica—has emerged as a promising partial replacement for Portland cement. Its pozzolanic reactivity contributes to improved hydration and matrix densification, while its use also supports circular economy principles by diverting waste glass from landfills. At the same …

Interfacial Chemistry Involved In Selective Separation Of Nmc/Lmo And Lco/Lmo Binary Cathode Materials By Froth Flotation Using Oleic Acid, Richard Kofi Oboh, Kaiwu Huang, Seoung Bum Son, Lei Pan

Michigan Tech Publications

The variability in cathode compositions within recycled lithium-ion battery (LIB) feedstocks poses a significant challenge to efficient downstream refining processes. This study demonstrates the feasibility of using froth flotation with oleic acid as a collector to selectively separate lithium nickel-manganese-cobalt oxide (NMC) and lithium cobalt oxide (LCO) from lithium manganese oxide (LMO) materials. Laboratory-scale flotation tests achieved an 80% separation efficiency in a single stage, producing a froth product with >90% purity of NMC/LCO at approximately 90% yield. Concurrently, the LMO materials were enriched in the sink product with ∼90% purity and ∼90% yield. This approach was further validated using …

Molecular Origins Of Non-Frozen Water In Polyelectrolyte Brushes, Ali Dhinojwala, Saveen Jayaweera, Md Golam Kibria, George Mallinos

University Research

Polyelectrolyte brushes (PEBs) are promising coatings for reducing ice adhesion and regulating water freezing at interfaces, yet direct measurements of nonfrozen water retention at subzero temperatures remain scarce. Here, we investigate the freezing behavior of water confined in poly([2-(methacryloyloxy)ethyl]trimethylammonium) (PMETA) brushes with chloride, iodide, and sulfate counterions using a custom-built low-temperature attenuated total reflectance infrared spectroscopy system. Furthermore, we quantify the fraction of water that was present within the brush that does not freeze as well as the changes in polymer volume fraction within the brush as a function of temperature. Spectroscopic analysis of water vibrational modes reveals that PMETA …

Beyond Catalysts And Membranes: Using Cell Assembly And Operating Strategies To Significantly Improve The Performance Of Aem Electrolyzers, Mahmoud Amirsalehi, Venkata Sai Sriram Mosali, Mohammed Al-Murisi, Shaghayegh Bashiri, Hari Gopi, Pongsarun Satjaritanun, Benjamin Britton, Karen Swider-Lyons, Mustain E. William

Faculty Publications

Green hydrogen, produced through water electrolysis, is a key enabler of a low-carbon energy future, and anion exchange membrane electrolyzers (AEMELs) have emerged as a promising technology due to their potential for ultra-low-cost operation. However, achieving low cell voltage at high current densities and maintaining long-term durability remain key AEMEL challenges. To address these issues, most research efforts to date have focused on developing advanced catalysts and membranes. In contrast, the influence of non-material factors, such as cell assembly parameters and operating conditions, remains underexplored, even though they can significantly impact performance. This study investigates how such variables affect AEMEL …

Pid Control For Lower Limb Exoskeletons: A Framework Evaluation, Javlonbek Rakhmatillaev, Vytautas Bučinskas

Chemical Technology, Control and Management

This research provides a detailed guideline for implementing and evaluating Proportional Integral Derivative (PID) control frameworks in lower limb rehabilitation exoskeleton robotics. It examines the role of control systems within rehabilitation robotics, outlines the principles of PID control, describes exoskeleton architecture, explores applications of PID control, reviews optimization strategies, presents experimental validations, and considers future developments in the field. The proposed control framework incorporates aspects of mechanical design, actuator and sensor selection, and PID-based control algorithms, thereby promoting safe, accurate, and individualized rehabilitation support. Recommendations and effective guidance for future work are also presented.

Review Of Modern Methods For Identification, Forecasting, And Intelligent Control Of Wastewater Biological Treatment Processes, Mirkhalil Agzamovich Ismailov, Boburbek Zokirjon O'G'Li Mannobjonov

Chemical Technology, Control and Management

This article presents a comprehensive review of contemporary approaches to the automation and intelligent control of wastewater biological treatment processes. Particular emphasis is placed on the digitalisation of wastewater treatment plants, ranging from the implementation of automated process control systems (APCS/SCADA-based solutions) to the application of predictive algorithms and the development of digital twins of bioreactors.

Special attention is devoted to mathematical models that underpin the control of bioprocesses. The evolution of the most widely used activated sludge models—ASM1, ASM2d, and ASM3—is examined, as these models describe key processes such as microbial community growth, nitrification, denitrification, and phosphorus removal. It …

Analysis Of The Carbonization Process Of Ammoniated Brine In Ammonia-Soda Production, Nadirbek Rustambekovich Yusupbekov, Djalolitdin Paxritdinovich Mukhitdinov, Fotima Faxritdinovna Iskhakova

Chemical Technology, Control and Management

The work provides an analytical review of the current state of modeling and controlling the carbonization process of ammoniated brine. It analyzes modern methods of mathematical, simulation, and intelligent modeling of heat and mass transfer, hydrodynamics, carbonation kinetics, and crystallization. The paper considers the potential of using digital twins, neural network models, fuzzy logic devices, and hybrid models to improve forecasting accuracy and the adaptability of process solutions. Modern carbonation process control strategies are also considered. A detailed analysis is provided of predictive control (MPC), neuro-fuzzy controllers, decentralized and multivariate control systems that ensure stable column operation under disturbances, optimize …

Synthesis Of An Adaptive Synergistic Fuzzy Discrete Controller For Nonlinear Systems, Isamidin Xakimovich Sidikov, Gulruxsor Murot Qizi Nashvandova, Feruzakhon Botirxon Qizi Sodiqova

Chemical Technology, Control and Management

The paper considers the issues of synthesizing an adaptive fuzzy synergetic controller with discrete time for nonstationary nonlinear dynamic objects. The proposed approach is based on the integrated use of synergetic control principles and fuzzy logic methods, which ensure the formation of a control law for nonlinear dynamic objects that provides asymptotic stability of the control system. Such a hybrid combination makes it possible to guarantee the asymptotic stability of the closed-loop system and to shape the required dynamic behavior of the object over a wide range of operating modes. In addition, this approach provides the ability to adapt to …

Algorithms Of Stable Adaptive Observation Of A Multidimensional Undefinite Object, Tursunova Sadoqat Abdusalom Qizi

Chemical Technology, Control and Management

This article presents an algorithm for simultaneously estimating the parameters and state coordinates of a multidimensional control object when some of its state variables are not directly measured. The inability to measure all state variables (coordinates) of an object is a well-known drawback of identification schemes. Such conditions require the construction of adaptive state observers. This work demonstrates that when identifying the parameters of a mathematical model for an uncertain multidimensional object, the asymptotic stability of the object and the convergence of its parameters to the model parameters are ensured, provided the input vector is sufficiently informative. The construction of …

Adaptive-Robust Control Of Dynamic Systems Using Generalized Predictive Methods, Shuxrat Tulyaganov

Chemical Technology, Control and Management

This paper considers an approach to adaptive-robust control of dynamic systems using generalized anticipation, where the object is described by a locally linearized model. Known self-tuning algorithms show insufficient stability to inaccurate selection of delay or model order. A generalized predictive control approach is suggested, with simulation outcomes showing superiority over traditional methods like generalized minimum variance control and pole assignment.This sliding horizon algorithm is based on predicting future system output signals several steps ahead, based on assumptions about subsequent control actions. One effective assumption is the presence of a “control horizon,” beyond which control signal increments are assumed to …

Physical And Chemical Study Of Interaction In The Urea–Valine System For The Creation Of Modified Liquid Nitrogen Fertilizers, Suvonkul Erkhanovich Nurmonov, Saydullo Khamidovich Azimov

Chemical Technology, Control and Management

This study reports the results of a comprehensive physicochemical investigation of the urea–L-valine binary system, conducted to validate its potential as a modified base for liquid nitrogen fertilizers.

By utilizing the methods of isomolar series, visual-polythermal analysis, X-ray phase (XRD) and single-crystal X-ray diffraction (SC-XRD), synchronous thermal analysis (TGA/DTA), and FT-IR spectroscopy, it was determined that the interaction between components in both aqueous solutions and the solid phase results in the formation of molecular associates stabilized by hydrogen bonds, without the formation of new stoichiometric compounds.

The concentration and temperature limits of the system's stability were defined, revealing a reduction …

Inductive Transducers For Measuring Vibrations, S.F. Amirov, A.Kh. Sulliev, A.A. Shoimkulov

Chemical Technology, Control and Management

A new design of an induction transducer has been developed for measuring linear and torsional vibrations in different directions with high sensitivity by constructing an inertial element consisting of four mutually perpendicular sectors and making the masses of two adjacent sectors different from the masses of the other two adjacent sectors. By constructing an inertial element in the form of a sector with two mutually diametric magnetic cores and different masses, and placing it between the horizontal and vertical axes, a design of an induction transducer has been developed that highly sensitively measures linear and torsional vibrations in different directions, …

Analytical Method For Investigating Nonlinear Magnetic Circuits Of Measuring Transducers With A Standard Parameter Distribution Structure, Javhar Sulton O'G'Li Fayzullayev

Chemical Technology, Control and Management

The article proposes a new analytical method for investigating magnetic circuits with distributed parameters and nonlinear magnetic coupling. The method is based on introducing into the system of nonlinear differential equations of such circuits the condition that the second derivative of the magnetic flux with respect to the circuit length is equal to zero, as well as on assuming that one of the geometric parameters of the studied magnetic circuit – the value of the air gap between ferromagnetic cores, their thickness, width, or the linear value of the number of turns of the distributed excitation winding – is a …

Research Of Logic Elements Based On Complementary Bipolar Transistors, Nodira Batirdjanovna Alimova, Nilufar Baxtiyorovna Gulyamova

Chemical Technology, Control and Management

Important parameters for any type of inverter – a NOT logic gate – are the power consumption during switching and the supply voltage. The proposed connection of complementary (two different types) bipolar transistors reduces the current consumption and supply voltage by simultaneously using the cutoff and saturation modes of the bipolar transistors. It has been theoretically and experimentally established that an inverter using complementary bipolar transistors operates at low supply voltages, approximately 0.7 V. Power consumption is virtually independent of the inverter's static state. A method for calculating the transfer characteristic of an inverter using complementary bipolar transistors is developed, …

The Main Errors Of The Ultrasonic Sensor In Measuring Water Flow In Open Channels, Anvar Urolovich Djalilov

Chemical Technology, Control and Management

This article analyzes the use of ultrasonic sensors in measuring water flow and the main errors that may occur in this process. In the conducted scientific research, a time-pulse ultrasonic sensor was tested. The absolute, relative and repeatability errors of the sensor during water flow measurement were studied. The absolute error represents the largest difference between the value recorded by the sensor and the real value, affecting the overall accuracy of the measurement system. This error can vary depending on environmental factors, the design and operating principles of the sensor. During the experiment, the performance of this sensor was …

Cultivation Of Arthrospira Platensis (Spirulina) In Food-Based Industrial Wastewater For High-Yield Phycocyanin Extraction, Pavithira Sathinathan

Student Works (2020-2029)

Arthrospira platensis (Spirulina) is a filamentous cyanobacterium valued for its nutritional profile, particularly the pigment–protein phycocyanin, with potent antioxidant and anti-inflammatory properties. Despite its industrial significance, large-scale commercialization remains constrained by high cultivation costs and inefficient extraction methods. This study investigated the use of food-based industrial wastewater as an alternative nutrient medium for Spirulina cultivation, aiming to reduce production costs, enhance phycocyanin yield, and support sustainable wastewater remediation. Three types of food-based wastewater with different nutrient composition (WW1, WW2, WW3) was diluted with Kosaric medium (1:1) and used for Spirulina cultivation. The highest biomass concentration was achieved in WW2 (1.93 …

Advancing Activated Carbon Production: Utilizing Pine Pruning Biochar Via Induction Heating With Co2and Iron-Based Catalysts, Ahmet Erdem, Muthanna H. Al-Dahhan, Ahmed Jasim

Chemical and Biochemical Engineering Faculty Research & Creative Works

This study introduces an induction heating approach for producing activated carbon from biochar obtained by thermal degradation of pine pruning waste from timber-related industries, using CO₂ and iron-based catalysts as activation agents. Activation experiments were performed using a 10 kW high-frequency induction system (28–40 kHz) under continuous CO₂ flow (15 mL min⁻¹), with electric current intensities of 200, 300, 400, and 500 A (corresponding to 700–1100°C) and durations of 30, 60, and 90 min, employing 45 g of iron-based catalysts (Fe–Ni–Ti–C, 85:6:3:6 wt.%) per 3 g biochar (15:1 w/w). Mass loss increased from 13.7 % (200 A, …

Sustainable Pathways For Fish Waste Oil Valorization Into Biofuel: Process Synthesis And Case Study, Hany A. Elazab, Radhi H. Alazmi, Abdelrahman El-Bagalaty, Hossam Tammam, Mahmoud El-Sayed, Mohamed Omar, Fathi Shokry, Mamdouh A. Gadalla, Fatma H. Ashour, Thokozani Majozi

Chemical and Biochemical Engineering Faculty Research & Creative Works

Biodiesel is a promising, sustainable alternative to fossil fuels such as petrol and diesel. Currently, biodiesel can be produced from edible plant oils and non-edible sources and wastes. Notably, fish waste oil is a sustainable resource for transesterification reactions to produce biodiesel. This research proposes a general process design methodology to investigate the potential of biodiesel production from fish waste oil as a pathway for waste-to-energy. The methodology integrates Pinch Analysis principles and process simulation to optimize the energy efficiency of a process design. Real data are collected on fish waste from fish industries in Egypt, focusing on three regions …

The Effect Of Reduction Of Input-Parameters On Data-Driven Prediction Of Critical Heat Flux In Rod Bundles Using Extended Parameters For Reactor Thermal–Hydraulic Safety, Rehan Zubair Khalid, Atif Khan, Farooq Ahmad, Muthanna H. Al-Dahhan, Atta Ullah

Chemical and Biochemical Engineering Faculty Research & Creative Works

Accurate prediction of the critical heat flux (CHF) is a key pillar for ensuring both the safety and economic performance of nuclear reactors. While machine learning (ML)-based methodologies have demonstrated considerable success in predicting CHF, most existing studies have been confined to simplified geometries, such as single tubes. Conversely, limited attention has been devoted to CHF prediction in realistic reactor environments, particularly within rod bundle configurations, where complex multiphase flow and heat transfer phenomena prevail. In this work we develop different AI models based on large dataset operating conditions as well as the complex geometric features of rod bundles. The …

Magnetically Driven Engineering Of Magnetic Hydroxyapatite/Ca Ro Membranes: Enhancing Surface Physicochemical Properties For High-Performance Water Desalination, Fariba Oulad, Ali Akbar Zinatizadeh, Sirus Zinadini, Amir Razmjou, Sara Eavani

Research outputs 2022 to 2026

This research focuses on the development of innovative hydrophilic reverse osmosis (RO) hydroxyapatite/cellulose acetate (HAP/CA) and magnetic-hydroxyapatite (M-HAP)/CA membranes, utilizing a phase-inversion technique with varying nanoparticles (NPs) concentration. The positioning of magneto-responsive M-HAP NPs within the advanced M-HAP/CA membranes was adeptly controlled using magnetic guidance during immersion- precipitation process in a coagulation bath. This precise control enabled a densely organized arrangement of M-HAP NPs, shifting from the membrane's core to its upper separation layer. Consequently, the barrier properties, mechanical integrity, and surface characteristics of the advanced M-HAP/CA membranes saw significant enhancement due to the uniform distribution of hydrophilic porous NPs …