Nonlinear Dynamic Analysis And Control Of Chemical Processes Using Dynamic Operability,
2023
West Virginia University
Nonlinear Dynamic Analysis And Control Of Chemical Processes Using Dynamic Operability, San Quan Dinh
Graduate Theses, Dissertations, and Problem Reports (ETD)
Nonlinear dynamic analysis serves an increasingly important role in process systems engineering research. Understanding the nonlinear dynamics from the mathematical model of a process helps to find the boundaries of all achievable process conditions and identify the system instabilities. The information on such boundaries is beneficial for optimizing the design and formulating a control structure. However, a systematic approach to analyzing nonlinear dynamics of chemical processes considering such boundaries in a quantifiable and adaptable way is yet to exist in the literature. The primary aim of this work is to formulate theoretical concepts for dynamic operability, as well as develop …
Evaluating Electrification Of Fossil Fuel-Fired Boilers For Decarbonization Using Discrete Event Simulation,
2023
West Virginia University
Evaluating Electrification Of Fossil Fuel-Fired Boilers For Decarbonization Using Discrete Event Simulation, Nahian Ismail Chowdhury
Graduate Theses, Dissertations, and Problem Reports (ETD)
Decarbonizing fossil fuel usage is crucial in mitigating the impacts of climate change. CO2, which comprises the major portion of greenhouse gas, is emitted from burning fossil fuels. One of the significant sources of fossil fuel user is industrial process heating, and most of the heating in industrial processes is achieved through boilers. Electrification is a promising solution for decarbonizing these boilers, as it enables renewable energy sources to generate electricity, which can then be used to power the electric boilers. The electrification of boilers can reduce greenhouse gas emissions, improve air quality, and increase energy efficiency. However, it requires …
Beeswax Wraps As An Alternative To Single-Use Plastics,
2023
The University of Akron
Beeswax Wraps As An Alternative To Single-Use Plastics, Sarah Skiver
Williams Honors College, Honors Research Projects
The project goal was to compare the food storage efficacy of sustainable beeswax wraps verses the single-use plastic methods of resealable plastic sandwich bags and plastic cling wrap. The goal was also to test the reusability of the beeswax wraps, as it is a key advantage of beeswax wraps that is advertised. The project purpose was to explore sustainable and eco-friendly alternatives to single use plastics, which are harmful to the environment in both their production and their disposal. Food spoilage was compared in beeswax wrap, plastic sandwich bags, and plastic cling wrap, and spoilage was also observed in a …
Teflon Replacement In Pans,
2023
The University of Akron
Teflon Replacement In Pans, Teodora Neamtu
Williams Honors College, Honors Research Projects
The purpose of the project is to determine an optimal prepping method of common cooking oils for pans that will be as effective as Teflon non-stick pans. The reason for this is to replace Teflon coating in pans, which can be very toxic for humans and the environment. Teflon has been a common coating for non-stick surfaces that is useful when cooking things such as eggs. To determine an optimal cooking method, three different oils were used: olive oil, vegetable oil, and shortening. The oils were tested on an aluminum pan by cooking egg whites at various temperatures, cooking times, …
Studies On Non-Transition Metal Substitution To Ab2 Metal Hydride Alloys For Battery Application,
2023
Wayne State University
Studies On Non-Transition Metal Substitution To Ab2 Metal Hydride Alloys For Battery Application, Shiuan Chang
Wayne State University Dissertations
Nowadays, multiphase transition metal-based AB2 metal hydride alloys and the rare-earth metal-based AB5 alloys (currently used in consumer NiMH batteries) are used as negative electrodes in NiMH batteries. It is of great interest to explore the possibility of significantly improving NiMH battery performance to compete with Li-ion batteries. In this area, the effect of dopant elements from Group-IA, -IIA, -IIIA non-transition metal family has not been thoroughly studied. In this study, lithium, magnesium, and boron (a metalloid considered metal in this study) were chosen as modifiers in the C14-phase predominant AB2 alloy by different dopant concentrations and synthesis methods, doping …
Optical Diagnostics Of Hydrocarbon Fuel Autoignition Using The Corrected Filtered Natural Emission Of Species Technique,
2023
Wayne State University
Optical Diagnostics Of Hydrocarbon Fuel Autoignition Using The Corrected Filtered Natural Emission Of Species Technique, Maysam Molana
Wayne State University Dissertations
The gas temperature and concentration of carbon monoxide and carbon dioxide of a hydrocarbon fuel mixture were measured using a rapid compression machine by applying a modern optical diagnostics methodology called the corrected filtered natural emission of species (C-FNES) technique. This technique uses a correction factor that includes all of the experimental and simulation errors and uncertainties into the measurements. To ensure the robustness of the proposed technique, the effect of temperature and pressure on the measured data was investigated extensively. To this end, a pentane inert mixture was tested in a wide range of operation conditions: six compressed gas …
Oil Recovery Performance And Asphaltene Deposition Evaluation Of Miscible And Immiscible Carbon Dioxide Or Nitrogen Huff-N-Puff Processes In Shale Reservoirs,
2023
Missouri University of Science and Technology
Oil Recovery Performance And Asphaltene Deposition Evaluation Of Miscible And Immiscible Carbon Dioxide Or Nitrogen Huff-N-Puff Processes In Shale Reservoirs, Mukhtar Elturki, Abdulmohsin Imqam, Shari Dunn-Norman, Hasan Shaglouf, Ahmed Kablan
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
The utilization of gas enhanced oil recovery to extract oil from unconventional reservoirs has become a widely discussed topic, as it has proven to be effective in significantly boosting oil recovery rates. Among various enhanced oil recovery methods, Gas Enhanced Oil Recovery (GEOR) is a frequently implemented approach. However, a significant challenge encountered during the process of injecting Carbon Dioxide (CO2) or Nitrogen (N2) to displace oil is the occurrence of asphaltene precipitation and deposition, which can impede production. This work is an experimental study to examine the effects of cyclic (huff-n-puff) CO2 or N …
The Success Story Of First Ever Polymer Flood Field Pilot To Enhance The Recovery Of Heavy Oils On Alaska's North Slope,
2023
Missouri University of Science and Technology
The Success Story Of First Ever Polymer Flood Field Pilot To Enhance The Recovery Of Heavy Oils On Alaska's North Slope, Abhijit Dandekar, Baojun Bai, John Barnes, Dave Cercone, Reid Edwards, Samson Ning, Randy Seright, Brent Sheets, Dongmei Wang, Yin Zhang
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
The primary goal of the first ever polymer flood field pilot at Milne Point is to validate the use of polymers for heavy oil Enhanced Oil Recovery (EOR) on Alaska North Slope (ANS). The specific objectives are systematic evaluation of advanced technology that integrates polymer flooding, low salinity water flooding, horizontal wells, and numerical simulation based on polymer flood performance data. Accordingly, under the co-sponsorship of the US Department of Energy and Hilcorp Alaska LLC the first ever polymer field pilot commenced on August 28, 2018 in the Schrader Bluff heavy oil reservoir at the Milne Point Unit (MPU) on …
Descriptive Systematics Of Upper Palaeocene–Lower Eocene Pollen And Spores From The Northern Niger Delta, South-Eastern Nigeria,
2023
Missouri University of Science and Technology
Descriptive Systematics Of Upper Palaeocene–Lower Eocene Pollen And Spores From The Northern Niger Delta, South-Eastern Nigeria, Luke Mander, Carlos Jaramillo, Francisca Oboh-Ikuenobe
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Fossil pollen and spores are a vital source of information on the geological history of tropical vegetation including reconstructions of vegetation diversity and composition. However, such work relies on a sound taxonomic framework, and this is challenging to achieve because of the large number of pollen and spore morphotypes that are encountered in palynological preparations from tropical sediments. In tropical West Africa, for example, extensive taxonomic work on Cretaceous–Paleogene pollen and spores was undertaken in the later part of the twentieth century, but more recent palynological work has focused on stratigraphy and basin evolution, and there is a need for …
Experimental Study: Investigating The Anions And Cations' Effects On The Elasticity Of The Anionic And Cationic High Viscosity Friction Reducers,
2023
Missouri University of Science and Technology
Experimental Study: Investigating The Anions And Cations' Effects On The Elasticity Of The Anionic And Cationic High Viscosity Friction Reducers, Xiaojing Ge, Ghith Biheri, Abdulmohsin Imqam, Baojun Bai, Yuwei Zhang
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
High viscosity friction reducers (HVFRs) are widely used as friction-reducing agents and proppant carriers during hydraulic fracturing. The reuse of produced water has gained popularity due to environmental and economic benefits. Currently, the field's most commonly used friction reducers are anionic and cationic HVFRs. Anionic HVFRs are typically pumped with freshwater, while cationic HVFRs are used with high Total Dissolved Solids (TDS) produced water. Cationic friction reducers are believed to have better TDS tolerance, friction reduction performance, and proppant transport capabilities compared to anionic friction reducers under high TDS conditions due to their superior viscoelastic properties. In addition, the impact …
Kinetic Experimental And Modeling Evaluations Of Asphaltene Morphology And Growth Rate Under Varying Temperature And Brine Conditions,
2023
Missouri University of Science and Technology
Kinetic Experimental And Modeling Evaluations Of Asphaltene Morphology And Growth Rate Under Varying Temperature And Brine Conditions, Kwamena Ato Quainoo, Abdulmohsin Imqam, Cornelius Borecho Bavoh
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
The utilization of predictive mechanisms to resolve asphaltene precipitation during oil production is a cleaner and less expensive means than the mechanical/chemical remediation techniques currently employed. Existing models lack predictive success due to opposing views on temperature-asphaltene precipitation interactions. In this study, the effect of varying temperatures (40, 50, 60, 70 80 and 90 °C) and brine concentrations (0 – 5 wt.%) on the long-time kinetics of asphaltene precipitations was evaluated. A series of experiments were conducted using the filtration technique and the confocal microscopy to study asphaltene precipitation on a model oil system consisting of asphaltenes, a precipitant, and …
Risk As A Process: A History Informed Hazard Planning Approach Applied To The 2018 Post-Fire Debris Flows, Montecito, California,
2023
Missouri University of Scienec and Technology
Risk As A Process: A History Informed Hazard Planning Approach Applied To The 2018 Post-Fire Debris Flows, Montecito, California, Anna Serra-Llobet, John Radke, G. Mathias Kondolf, Larry Gurrola, J. David Rogers, Sarah Lindbergh, Johnny Douvinet
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Historical information about floods is not commonly used in the US to inform land use planning decisions. Rather, the current approach to managing floods is based on static maps derived from computer simulations of the area inundated by floods of specified return intervals. These maps provide some information about flood hazard, but they do not reflect the underlying processes involved in creating a flood disaster, which typically include increased exposure due to building on flood-prone land, nor do they account for the greater hazard resulting from wildfire. We developed and applied an approach to analyze how exposure has evolved in …
Magnetic Inversion Approach For Modeling Data Acquired Across Faults: Various Environmental Cases Studies,
2023
Missouri University of Science and Technology
Magnetic Inversion Approach For Modeling Data Acquired Across Faults: Various Environmental Cases Studies, Khalid S. Essa, Eid R. Abo-Ezz, Neil Lennart Anderson, Omar A. Gomaa, Mahmoud Elhussein
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
An effective extension to the particle swarm optimizer scheme has been developed to visualize and modelize robustly magnetic data acquired across vertical or dipping faults. This method can be applied to magnetic data sets that support various investigations, including mining, fault hazards assessment, and hydrocarbon exploration. The inversion algorithm is established depending on the second horizontal derivative technique and the particle swarm optimizer algorithm and was utilized for multi-source models. Herein, the inversion method is applied to three synthetic models (a dipping fault model contaminated without and with different Gaussian noises levels, a dipping fault model affected by regional anomaly, …
Impact Of Hvfr Loading Concentrations On Its Viscoelastic Properties And Proppant Transport Performance,
2023
Missouri University of Science and Technology
Impact Of Hvfr Loading Concentrations On Its Viscoelastic Properties And Proppant Transport Performance, Ghith Biheri, Shari Dunn Norman, Abdulmohsin Imqam
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
In unconventional reservoirs, increasing the low formation conductivities through hydraulic fracturing may substantially increase oil production from wells. This work of improving the fracture conductivity could be conducted by distributing and transporting proppant within the fracture lengths using high fracture fluid concentrations. This research focused on three areas. First, it assessed the fluid rheology including the viscosity and elasticity of a high viscosity friction reducer (HVFR) and linear guar using deionized (DI) water at different fluid concentrations (i.e., 2, 4, and 8 gpt for the HVFR and 15, 25, and 35 ppt for linear guar), and measured the impact of …
Comparative Study Of Proppant Transport In The Vertical Fracture For High Viscosity Friction Reducers And Slickwater Fracturing With High-Tds Marcellus Shale Formation Water,
2023
Missouri University of Science and Technology
Comparative Study Of Proppant Transport In The Vertical Fracture For High Viscosity Friction Reducers And Slickwater Fracturing With High-Tds Marcellus Shale Formation Water, Xiaojing Ge, Abdulmohsin Imqam, Baojun Bai
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
High viscosity friction reducers (HVFRs) have been gaining more attention and increasing in use as proppant carriers. Reusing of produced water has also been driven by both environmental and economic benefits. However, high total dissolved solids (TDS) of produced water and high reservoir temperature significantly decrease the viscoelastic properties of HVFRs even for the cationic ones, which further reduce their proppant transport capabilities. Increasing loadings of HVFRs also has very limited effects on improving their proppant transport performances under high-TDS and high-Temperature conditions. The ultimate objective of this experimental study is to investigate the injection rate effects on the proppant …
Study Of Legionella Pneumophila Treatment With Copper In Drinking Water By Single Cell-Icp-Ms,
2023
Missouri University of Science and Technology
Study Of Legionella Pneumophila Treatment With Copper In Drinking Water By Single Cell-Icp-Ms, Lei Xu, Austin Sigler, Anna Chernatynskaya, Lindsey Rasmussen, Jingrang Lu, Endalkachew Sahle-Demessie, David J. Westenberg, Hu Yang, Honglan Shi
Biological Sciences Faculty Research & Creative Works
Legionella pneumophila is a persistent opportunistic pathogen that poses a significant threat to domestic water systems. Previous studies suggest that copper (Cu) is an effective antimicrobial in water systems. A rapid and sensitive quantification method is desired to optimize the conditions of L. pneumophila treatment by Cu and to better understand the interaction mechanisms between Cu and cells. In this study, we developed a highly sensitive single cell (SC)-ICP-MS method to monitor L. pneumophila cell concentration and track their uptake of Cu. The SC-ICP-MS method showed excellent sensitivity (with a cell concentration detection limit of 1000 cells/mL), accuracy (good agreement …
Influence Of Interfering Ions And Adsorption Temperature On Radioactive Iodine Removal Efficiency And Stability Of Ni-Mof-74 And Zr-Uio-66,
2023
Missouri University of Science and Technology
Influence Of Interfering Ions And Adsorption Temperature On Radioactive Iodine Removal Efficiency And Stability Of Ni-Mof-74 And Zr-Uio-66, Turki Alghamdi, Peter O. Aina, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
Metal-organic frameworks (MOFs) often exhibit an exceptional adsorption-based separation performance for a variety of gases, ions, and liquids. While most radioactive iodine removal studies focus on the capture of radioactive iodine from off-gas streams, few studies have systematically investigated the effect of structure-property relationships of MOFs on iodine removal performance in the presence of interfering ions in liquid solutions. Herein, we investigated the iodide ion (I-) adsorption performance of two model MOFs (e.g., Ni-MOF-74 and Zr-UiO-66) in liquid phase as a function of iodine concentration (e.g., 0.125 to 0.25 and 0.50 mmol/L) and adsorption temperature (e.g., 25 to …
A Comprehensive Review Of The Influence Of Heat Exchange Tubes On Hydrodynamic, Heat, And Mass Transfer In Bubble And Slurry Bubble Columns,
2023
Missouri University of Science and Technology
A Comprehensive Review Of The Influence Of Heat Exchange Tubes On Hydrodynamic, Heat, And Mass Transfer In Bubble And Slurry Bubble Columns, Dalia S. Makki, Hasan Sh Majdi, Amer A. Abdulrahman, Abbas J. Sultan, Zahraa W. Hasan, Laith S. Sabri, Bashar J. Kadhim, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
Bubble and slurry bubble column reactors (BCRs/SBCRs) are used for various chemical, biochemical, and petrochemical applications. They have several operational and maintenance advantages, including excellent heat and mass transfer rates, simplicity, and low operating and maintenance cost. Typically, a catalyst is present in addition to biochemical processes where microorganisms are used to produce industrially valuable bio-products. Since most applications involve complicated gas-liquid, gas-liquid-solid, and exothermic processes, the BCR/SBCR must be equipped with heat-exchanging tubes to dissipate heat and control the reactor's overall performance. In this review, past and very recent experimental and numerical investigations on such systems are critically discussed. …
Simulation And Optimization Of Waste Heat To Electricity Through Organic Rankine Cycles (Orcs): A Case Study In An Oil Refinery,
2023
Missouri University of Science and Technology
Simulation And Optimization Of Waste Heat To Electricity Through Organic Rankine Cycles (Orcs): A Case Study In An Oil Refinery, Mohamed A. Sadek, Mamdouh A. Gadalla, Noran Shedid, Dina Ahmed, Hany A. Elazab
Chemical and Biochemical Engineering Faculty Research & Creative Works
Energy efficiency has become a global problem that is detrimental to the chemical industries technically, economically and to the environment. Organic Rankine Cycle (ORC) is a promising technology that can solve this problem by recovering heat from low-grade waste heat sources by using organic working fluids. The heat source for the ORC system used in this article is air leaving air coolers in an oil refinery with a temperature of 140o C. The heat exchanger data for this refinery was used in the simulation of a basic cycle and a regenerative cycle using ASPEN HYSYS V.10. These ORC systems were …
Demonstration Of High Detoxification Efficiency Of Glassy Polymer-Metal Hydroxide Composites Toward Chemical Warfare Agent Simulants,
2023
Missouri University of Science and Technology
Demonstration Of High Detoxification Efficiency Of Glassy Polymer-Metal Hydroxide Composites Toward Chemical Warfare Agent Simulants, Peter O. Aina, Sukanta K. Mondal, Joshua Costain, Ali A. Rownaghi, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
The design and development of polymeric composites that can effectively capture and destruct toxic chemicals with a fast detoxification rate is of high importance for protecting the military, first responders, and civilians. Here we report the synthesis and assessment of zirconium hydroxide (Zr (OH)4)-incorporated Ultem, Matrimid, and PIM-1 composites for detoxification of dimethyl 4-nitrophenylphosphonate (DMNP), as a type G toxic nerve agent simulant. Maintaining homogeneity, three different loadings (8, 20, 30 wt %) of Zr (OH)4 were incorporated into the polymers, and the thin films of composite materials were developed for subsequent hydrolysis tests. Our results indicated that increasing the …
