Chemical Engineering Commons^™

Using Switchable Solvents For Enhanced Biodiesel Production, Eyad Abdel Rahman Sowan

Theses

This thesis presents a sustainable approach to biodiesel production using in-situ technology for direct conversion of microalgae-to-biodiesel. The proposed method operates on wet, untreated microalgae, thereby eliminating the cost/energy intensive drying and cell disruption steps. Owing to their favorable properties, the use of enzymes, specifically lipase, as a catalyst for the process was suggested over acid/base catalysts. However, the high cost of the enzyme necessitates its reuse at sustained activity for the process to be economically feasible. The use of non-toxic green solvents, such as switchable solvents, as an alternative to conventional organic solvents was a significant challenge for the …

Optimization Of Co2 Huff-N-Puff In Unconventional Reservoirs With A Focus On Pore Confinement Effects, Fluid Types, And Completion Parameters, Aaditya Khanal, Md Fahim Shahriar

Jasper Department of Chemical Engineering Faculty Publications and Presentations

The cyclic injection of CO2, referred to as the huff-n-puff (HnP) method, is an attractive option to improve oil recovery from unconventional reservoirs. This study evaluates the optimization of the CO2 HnP method and provides insight into the aspects of CO2 sequestration for unconventional reservoirs. Furthermore, this study also examines the impact of nanopore confinement, fluid composition, injection solvent, diffusivity parameters, and fracture properties on the long-term recovery factor. The results from over 500 independent simulations showed that the optimal recovery is obtained for the puff-to-huff ratio of around 2.73 with a soak period of fewer than 2.7 days. After …

Influence Of Magnetomechanical Properties Of Ferromagnetic Materials On The Sensitivity Of A Magnetoelastic Sensor, Sulton Amirov, Kamila Komilovna Jurayeva

Chemical Technology, Control and Management

The requirements of high operational reliability are most fully met by automated monitoring and control systems, the elements of which are magnetoelastic sensors. Such sensors, due to their metrological characteristics, have found application in electrified railway transport, in the metallurgical, metalworking, mining and other industries. The principle of operation of such sensors is based on the fact that in the process of influencing the magnetic core of the sensor by force, there is a change in the magnetic permeability of the material, a change in the magnetic resistance of the circuit, a change in the mutual inductance coefficient of the …

Model For Calculating The Static Characteristics Of Hydraulic Systems Of Hydro Technical Buildings, Mirkhalil Ismailov, Dong Zhang, Farkhod Kasimov

Chemical Technology, Control and Management

Hydraulic mechanisms that actuate flat gates, widely used in hydraulic structures, are studied as hydraulic actuators of the system. Their static mathematical models are developed using an integrated methodology with a hydraulic pump, inlet and suction pipes, and internal and external resistance factors. Unlike existing mathematical models, the model developed in this paper allows a detailed description of the characteristics of hydraulic drives due to the fact that pressure losses in the throttle, regulator, and power amplifier, as well as local resistances in hydraulic pipelines, are taken into account.

Algorithms For Multi-Factory Polynomial Modeling Of Technological Processes, Farrukh Do'stmirzayevich Jo'rayev, Murodjon Ashurqulovich Ochilov

Chemical Technology, Control and Management

The article reveals the meaning and essence of the modeling method in the study of complex technological processes based on the problematic aspects of building multifactorial relationships and the principles for their elimination. In the case of non-linearity of multifactorial connections of a complex system, the expediency of approximating such functions by polynomials is substantiated. The authors' ideas about the increasing importance of interpolation methods in practice against the background of the possibility of simplification based on the use of modern mathematical hardware and software for integration into the process of modeling and optimizing technological processes due to the complexity …

Synchronization Of The Training Of Specialists In The Automation Of Technological Processes In Accordance With The Dynamics Of The Taxonomy Of Learning Goals, Yusuf Shodievich Avazov, Kamola Abdullaeva

Chemical Technology, Control and Management

Changes in the characteristics of modern ones, reflecting them as the "digital generation", inevitably necessitate electronic interactive, mobile and mixed, machine learning, especially in the field of automation and control of technological processes and production. As a consequence of reflecting these realities, there have been parallel changes in the taxonomy of learning objectives - from the classical to the revised rethought and digital.

In order to study the problem of synchronizing the training of future specialists in the field of automation and control of technological processes and production and funny knowledge in accordance with the dynamics of the taxonomy of …

Analysis Of Vegetable Oil Refining Technology, Elyor Samadov

Chemical Technology, Control and Management

Innovative technologies for refining vegetable oils are presented, as well as the qualitative characteristics of raw vegetable oils obtained by extraction and mechanical methods. A general review of the chemical composition and impurities of vegetable oils resulting from the reaction between glycerol and fatty acids is carried out, and a brief review of the study to determine the effect of refining on biologically active components.

The analytical review is devoted to a comparative comparison of two types of refining - chemical and physical refining.

Research Of Three-Phases Current’S Transducers Of Filter-Compensation Devices For Control Reactive Power’S Consumption Of Asynchronous Motor, Ilkhomjon Khakimovich Siddikov, Dilyorbek Karimjonov Doniyorbek O'G'Li -, Abdumutal Abdikarimovich Abdigapirov

Chemical Technology, Control and Management

In the article given materials of developing of three-phase electromagnetic current transducers of reactive power, using with asynchronous motor, methods connecting of two sensing element, series, parallel and differential and loops suitable for each phase, dynamic characteristics of output signals of three-phase electromagnetic current transducers asynchronous motor.

On the basis of modern calculation and design complexes are of great importance in the research variable sizes of three-phase current electromagnetic transducers of filter-compensation devices of reactive power of asynchronous motors. Presented mathematical model of research of electrical, electromagnetic and magnetic elements of electromagnetic current transducers in the …

Advances And Challenges On Cathode Catalysts For Lithium-Oxygen Batteries, Bo Wen, Zhuo Zhu, Fu-Jun Li

Journal of Electrochemistry

Aprotic lithium-oxygen batteries (LOBs) with high theoretical energy density have received considerable attention over the past years. However, the oxygen reduction reaction (ORR)/oxygen evolution reaction (OER) at cathodes suffer from slow kinetics for large overvoltages in LOBs. Significant advances on catalysts have been achieved to accelerate cathode kinetics, but understanding on the formation/decomposition processes of Li₂O₂ is limited. Herein, this review highlights the fundamental understanding of the correlation between catalysts and formation/decomposition of Li₂O₂. Various types of cathode catalysts are discussed to reveal the mechanism of formation/decomposition of Li₂O₂, …

Recent Advances In Anode Materials Of Solid Oxide Electrolysis Cells, Geng Zou, Wei-Cheng Feng, Yue-Feng Song, Guo-Xiong Wang

Journal of Electrochemistry

Solid oxide electrolysis cell (SOEC) as an electrochemical energy conversion device has attracted increasing attention due to its large current density, high Faradaic efficiency and energy efficiency. Oxygen evolution reaction at the anode, a four-electron transfer process, is an important half-reaction for SOEC, which contributes to the main polarization resistance and consumes most electric energy during the electrolysis process. Hence, designing anode materials with high activity and stability is crucial for the performance improvement and practical application of SOEC. Recently, some advances have been made in the development of high-performance anode. In the current review, the mechanisms for CO_{2 …}

Anodic Electrocatalysis Of Glycerol Oxidation For Hybrid Alkali/Acid Electrolytic Hydrogen Generation, Xin Feng, Bo-Wen Liu, Ke-Xin Guo, Lin-Feng Fan, Gen-Xiang Wang, Su-Qin Ci, Zhen-Hai Wen

Journal of Electrochemistry

Electrolytic hydrogen production is heavily restricted by high-energy consumption majorly due to the relatively high potential of anodic oxygen evolution reaction (OER). Development of OER-alternative reaction at the anode has been recently proposed as a promising pathway to address the associated issues. In this work, we report a hybrid acid/alkali dual-electrolyte electrolyzer by coupling acidic hydrogen evolution reaction (HER) using commercial Pt/C cathode with alkaline Electrocatalytic glycerol oxidation (GOR) which is implemented by developing a nickel foam (NF) supporting Co₃O₄ nanosheets anode that shows low overpotential and high selectivity toward GOR for formate production. The hybrid acid/alkali …

Extraction And Characterization Of Collagen From Cattle Horns For Potential Wound Healing, Yeriko Halson

Tanzania Journal of Engineering and Technology (TJET)

The need for bandages and gauze for wound dressing and healing is inevitable due to the high increase in accidents. Most of the material used for the production of bandages and gauzes for wound healing are from non-renewable synthetic material. The sustainability of non renewable resources is at jeopardy due to the health and associated environmental impact. Consequently, the use of naturally occurring and biodegradable material is a promising solution to the sustainability challenges of synthetic material. In this paper, the extraction of collagen films from cattle horns for potential wound healing is reported. Collagen was extracted from cattle horns …

Current And Future Trends Of Construction Project Performance Models: A Review, Method Mtana

Tanzania Journal of Engineering and Technology (TJET)

The construction industry (CI) has experienced outstanding growth and contributed to economic growth for many countries, with enormous foreign investments that require quality projects. High pressure to reduce the construction cost and time commonly put the industry at risk of lower quality and safety of the construction facilities. Like many other developing countries, Tanzania needs more stringent quality control measures in the construction sector to contribute positively to sustainable growth. This study thus reviews current and future trends in construction industry performance in Tanzania. The literature review on construction projects (CPs) performance is based on information on time overruns from …

Towards The Development Of A Framework For Assessing Organizational Governance Maturity For Technical Audit Of Public Works, George Haule

Tanzania Journal of Engineering and Technology (TJET)

The quality of the audit work and its products is often associated with the organizational maturity of the audit function. The absence of a well-defined organizational maturity for an audit function leads to poor quality of audit work or products and ineffective audit function. The lack of a framework for measuring governance maturity was identified as a major deterrent factor to the attainment of quality audit work. Measuring the governance maturity of the technical audit of public works is challenging due to the absence of a maturity framework that fits its needs. The noted shortcomings include: (a) existing maturity frameworks …

Dynamic Multi-Dimensional Numerical Transport Study Of Lithium-Ion Battery Active Material Microstructures For Automotive Applications, Joseph S. Lopata, Taylor R. Garrick, Fengkun Wang, Han Zhang, Yangbing Zeng, Sirivatch Shimpalee

Faculty Publications

In support of GM’s traction battery efforts, we derived and implemented a method to describe the electrochemical performance of a battery cell considering the nuances of the electrode microstructure at the anode and the cathode and the corresponding impact on the electrochemical transport in the solid and liquid phases. To assess the capability of the method, we compared model results from the microstructure framework with the commonly used continuum-level porous electrode model, commonly referred to as the pseudo-2-dimensional model, or the Newman Model. The microstructure modeling framework was applied to simulate the electrochemical and transport processes within the battery cell …

Exploring Current And Future Research Trends On Safety Climate In Construction Projects, Kamugisha Joseph Kajumulo

Tanzania Journal of Engineering and Technology (TJET)

Clients, consultants, and contractors in the construction industry can benefit from a safety climate by obtaining knowledge of attitudes and perceptions for better safety outcomes. However, the current and future research trends for safety climate in construction projects have not yet been fully examined. In order to solve this problem, a systematic review of previous research findings using a social network approach must be conducted, and future trends for the safety climate in building projects must be identified. Sixty-three peer reviewed articles were gathered to study the literature on safety climate in construction projects. A social network approach was employed …

The Fourth Industrial Revolution: Opportunities And Challenges To The Future Of Mechanical Engineering, Ulingeta O.L. Mbamba

Tanzania Journal of Engineering and Technology (TJET)

This paper provides a conceptual overview of the developments of the Fourth Industrial Revolution (4IR) and derives challenges and opportunities for the future of the mechanical engineering profession. The paper broadly defines 4IR as the fusion of technologies and interaction across physical, digital and biological aspects, while defining mechanical engineering as "a multi-faceted discipline that encompasses the teaching, practice and guidance of others in the development and application of scientific principles to mechanical systems". The paper looks specifically at developments in the Internet of Things (IoT), blockchain technology, robotics, Big Data analytics, biotechnology, nanotechnology, 3D printing and artificial intelligence and …

Cellulose-Keratin Supramolecular Composite: Conformation By Combined Fourier Transform Spectroscopy And Partial Least Square Regression Coefficient, Ngesa Ezekiel Mushi Dr

Tanzania Journal of Engineering and Technology (TJET)

Keratin and cellulose are important nano components with excellent mechanical and biological properties. However, the preparation route through dissolution in organic solvents to make manmade materials is challenging because of their intensive bonding interaction characteristics. Structural modification of the natural attributes is difficult to maintain after polymer regeneration. A new technique by a green route was devised to dissolve keratin from wool, hair, and feather with cellulose in situ using 1-Butyl-3-methylimidazolium chloride [BMIm] + Cl- ionic liquid as a solvent. The mixture of keratin and cellulose homogeneously and synergistically resulted in a supramolecular composite film through non-derivatized mechanochemical interactions. The …

Designing And Manufacturing Of Vegetable Slicing Machine, Juma Nuhu Msuya

Tanzania Journal of Engineering and Technology (TJET)

Agro-processing industry is faced with a challenge of slicing of vegetables for immediate consumption. This stems from the fact that the traditional slicing methods use bare hands, and knives. This method is faced with shortcomings of inefficiency, poor hygiene, and significant dangers to injury. If vegetables are not sliced, their drying takes longer, may possibly be spoiled, and cannot be stored for future uses. Therefore, this paper strives to design a vegetable slicing machine to increase the efficiency of the drying process as a post-processing step. The study employed a Pugh’s design model to design the machine and manufacture it. …

Method For Solving The Kinematics Inverse Problem For Moving Along A Trajectory Objects (As An Example Of Assembly Industrial Robots), Oripjon Olimovich Zaripov, Dildora Usmonovna Sevinova

Chemical Technology, Control and Management

The task of performing a technological operation in kinematic calculation of industrial robots and determining various kinematic parameters describing the efficiency of robots is solved. Among them, one of the urgent problems based on the analysis of the entire kinematics of the assembly industrial robot is the problem of solving the inverse problem of the kinematics of the manipulator positions, that is, the problem of determining the relative parameters that change the coordinates of the gripper according to the given position. The article presents a scheme that allows solving the inverse kinematics problem of an industrial robot manipulator moving in …