Deep Euteceic Solvents-Assisted Synthesis Of Novel Network Nanostructures For Accelerating Formic Acid Electrooxidation,
2023
Key Laboratory of Magnetic Molecules & Magnetic Information Materials Ministry of Education, The School of Chemical and Material Science, Shanxi Normal University, Taiyuan 030031, Shanxi, China; Guangxi Key Laboratory of Low Carbon Energy Materials, College of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guangxi, Guilin, 541004, China; Kunshan Superior Silk Screen Printing Material Co., LTD, Kunshan, 215300, Jiangsu, China
Deep Euteceic Solvents-Assisted Synthesis Of Novel Network Nanostructures For Accelerating Formic Acid Electrooxidation, Jun-Ming Zhang, Xiao-Jie Zhang, Yao Chen, Ying-Jian Fan, You-Jun Fan, Jian-Feng Jia
Journal of Electrochemistry
Deep eutectic solvents (DESs) have been reported as a type of solvent for the controllable synthesis of metal nanostructures. Interestingly, flower-like palladium (Pd) nanoparticles composed of staggered nanosheets and nanospheres are spontaneously transformed into three-dimensional (3D) network nanostructures in choline chloride-urea DESs using ascorbic acid as a reducing agent. Systematic studies have been carried out to explore the formation mechanism, in which DESs itself acts as a solvent and soft template for the formation of 3D flower-like network nanostructures (FNNs). The amounts of hexadecyl trimethyl ammonium bromide and sodium hydroxide also play a crucial role in the anisotropic growth and …
Fe Nanoparticles Encapsulated In N-Doped Porous Carbon For Efficient Oxygen Reduction In Alkaline Media,
2023
Key Laboratory of General Chemistry of the National Ethnic Affairs Commission, School of Chemistry and Environment, Southwest Minzu University, Sichuan, Chengdu 610041, China
Fe Nanoparticles Encapsulated In N-Doped Porous Carbon For Efficient Oxygen Reduction In Alkaline Media, Chun-Yan Li, Rui Zhang, Xiao-Jie Ba, Xiao-Le Jiang, Yao-Yue Yang
Journal of Electrochemistry
Rational design and synthesis of non-precious-metal catalyst plays an important role in improving the activity and stability for oxygen reduction reaction (ORR) but remains a major challenge. In this work, we used a facile approach to synthesize iron nanoparticles encapsulated in nitrogen-doped porous carbon materials (Fe@N-C) from functionalized metal-organic frameworks (MOFs, MET-6). Embedding Fe nanoparticles into the carbon skeleton increases the graphitization degree and the proportion of graphitic N as well as promotes the formation of mesopores in the catalyst. The Fe@N-C-30 catalyst showed the excellent ORR activity in alkaline solutions (E0 = 0.97 V vs. RHE, E1/2 …
Design And Performance Of A Laboratory Scale Pressurized Oxy-Coal Reactor,
2023
Brigham Young University - Provo
Design And Performance Of A Laboratory Scale Pressurized Oxy-Coal Reactor, Scott Gardner, Cody Carpenter, Jacob Tuia, Aaron Skousen, Dustin Badger, Sandra Thomas, Bradley R. Adams, Dale R. Tree, Andrew R. Fry
Faculty Publications
A pressurized oxy-coal (POC) reactor has been designed, built and tested to investigate key technologies related to oxy-coal combustion including a dry coal feed system, an oxy-coal burner, and a slagging ash management system. The coal feed system utilized a fluidized bed to convey pulverized coal with CO2 from a coal bed into the reactor. The reactor has diagnostic capabilities including optical access, embedded thermocouples, fuel and gas flow rates, exhaust gas analysis (CO2, CO, NO, O2) and heat flux. At 13.6 atm and a firing rate of 89 kWth a mean feed rate of 12.5 kg/h was …
Threshold Microsecond Pulsed Electric Field Exposures For Change In Spinach Quality,
2023
Rowan University
Threshold Microsecond Pulsed Electric Field Exposures For Change In Spinach Quality, Zachary Rosensweig, Abigail Martin, Colin Hackett, Jerrick Garcia, Gary L. Thompson Iii
Henry M. Rowan College of Engineering Departmental Research
Pulsed electric fields (PEFs) are often used to pretreat foods to enhance subsequent processes, such as drying, where maintaining food product quality is important for consumer satisfaction. This study aims to establish a threshold PEF exposure to determine the doses at which electroporation is viable for use on spinach leaves, wherein integrity is maintained postexposure. Three numbers of consecutive pulses (1, 5, 50) and two pulse durations (10 and 100 μs) have been examined herein at a constant pulse repetition of 10 Hz and 1.4 kV/cm field strength. The data indicate that pore formation in itself is not a cause …
Vitreoscilla Globin Promoter Cloning And Testing In Escherichia Coli,
2023
Rose-Hulman Institute of Technology
Vitreoscilla Globin Promoter Cloning And Testing In Escherichia Coli, Lauren J. Coffey
Rose-Hulman Undergraduate Research Publications
No abstract provided.
The Biological Activity Of Dual-Responsive Glycopolymers For Intracellular Codelivery Of Antigen And Lipophilic Adjuvant,
2023
University of Mississippi
The Biological Activity Of Dual-Responsive Glycopolymers For Intracellular Codelivery Of Antigen And Lipophilic Adjuvant, Micaela Shields
Honors Theses
Subunit vaccines present themselves as an attractive alternative to traditional approaches to vaccines, which utilizes whole organisms to trigger an immune response. While these traditional approaches have proven themselves reliable within the history of vaccinations, they generally deliver subpar robust cellular-mediated immunity and pose many safety risks. Composed of proteins and /or peptides, subunit vaccines are safer and more precise alternatives to traditional approaches. However, the pharmacokinetic properties of the macromolecules that make up these vaccines hinder the subunit vaccine’s level of immunogenicity [d1] Examples of this hindrance include but are not limited to aggregation at the injection site and …
Antimicrobial Activity And Mechanism Of Amyloid Proteins And Synthetic Conjugated Polyelectrolytes,
2023
University of New Mexico - Main Campus
Antimicrobial Activity And Mechanism Of Amyloid Proteins And Synthetic Conjugated Polyelectrolytes, Fahimeh Maghsoodi
Nanoscience and Microsystems ETDs
Although the exact cause of Alzheimer’s disease (AD) is still unknown, it is widely considered that the accumulation of amyloid plaques composed of the amyloid-β (Aβ) peptide in the brain is linked to neurodegeneration. Co-localization of viral DNA with Aβ plaques, the association of brain infection and AD, and research indicating the protective effect of Aβ against bacteria and fungi in mice and human cells have led to the hypothesis that Aβ expression and deposition may be central to its function as an antimicrobial peptide (AMP). In my thesis research, we seek to elucidate how Aβ functions as an AMP …
An Analysis Of The Production Of Pharmaceutical-Grade Acetone Via The Dehydrogenation Of Isopropanol (Ipa),
2023
University of Mississippi
An Analysis Of The Production Of Pharmaceutical-Grade Acetone Via The Dehydrogenation Of Isopropanol (Ipa), Jordan Desplas
Honors Theses
The production of 99.9 wt% acetone from isopropanol in Unit 1100 is designed to start up in 2025 and operate for 12 years after startup. The engineering team was tasked with designing the process, creating an economic model, and optimizing the net present value (NPV). The process was simulated in AVEVA PRO/II Simulation for the design process, and the economic analysis was estimated in Microsoft Excel. Parametric and topological optimization was performed linearly on the unit operations in the process. The NPV was improved by $14M from a base case of $122M to an optimized case of $136M. The project …
Optimization Of A Fluidized Bed Reactor For The Production Of Acetone From Isopropyl Alcohol,
2023
University of Mississippi
Optimization Of A Fluidized Bed Reactor For The Production Of Acetone From Isopropyl Alcohol, Andrew Rawls Wasson
Honors Theses
For the optimization of the isopropyl alcohol to acetone process, Unit 1100, the Net Present Value (NPV) was used as the objective function to observe the economic impact of each of the optimization factors being tested. During the optimization process, it is not only important to optimize the process’s profitability but also to ensure that the process operates efficiently and meets product specifications. The goal of this optimization was to alter variables from the base case calculations of Unit 1100 to maximize the NPV of the unit. AVEVA ProII software was used to simulate the process and make changes to …
Development Of Novel Sensor Coating Methodology To Enable Understanding Of Fouling Mechanisms On Ion Exchange Membranes,
2023
University of Mississippi
Development Of Novel Sensor Coating Methodology To Enable Understanding Of Fouling Mechanisms On Ion Exchange Membranes, Andrew Ulmer
Honors Theses
As populations expand and natural water resources are depleted, severe droughts and limited access to clean water have become an increased threat to areas across the world. Effective and economic water treatment methods such as electrodialysis (ED) are vital for combating these threats, especially in developing nations and secluded locations. Organic foulant adsorption on the surface of ion exchange membranes severely limits the capabilities of water desalination systems such as ED along with significantly increasing maintenance costs. Understanding characteristics such as the total amount and rate at which these foulants at specific concentrations adsorb and desorb to the membranes is …
Effects Of Alternative Jet Fuels On Aerospace-Grade Composites: Experimental And Modeling Studies,
2023
Mississippi State University
Effects Of Alternative Jet Fuels On Aerospace-Grade Composites: Experimental And Modeling Studies, Naoufal Harich
Theses and Dissertations
The aviation industry aims to reduce its environmental impact through innovation and research. The usage of composite materials for multiple primary structures represents one such measure. Several alternative fuels were approved and used along with the Federal Aviation Administration (FAA). These alternative fuels are produced from wastes and biomasses. Some alternative fuels were initially only approved as drop-in fuels, meaning they must be blended with conventional fuels to operate. Fuel tanks are usually embedded into the wing structure, which is mainly made of composite materials. These composites tend to absorb fluids it encounters through their matrix phase. The absorption behavior …
Monitoring Pm2.5 Pollution In The North End Of Hartford, Ct,
2023
University of Connecticut
Monitoring Pm2.5 Pollution In The North End Of Hartford, Ct, Jocelyn Phung, Kristina Wagstrom
Honors Scholar Theses
Particulate matter (PM) or particle pollution is one of the six criteria air pollutants that can cause harm to human health and the environment; yet, there is a lack of data in many areas of the United States. Particulate matter is a mixture of solid particles and liquid droplets suspended in the air (EPA). Exposure to PM2.5 has been linked to respiratory and cardiovascular conditions. People who live in urban areas are more likely to be exposed to particulate matter as many urban areas are known to have poor air quality. Our goal is to determine how particulate matter levels …
The Design Estimate Of A Warehouse Refrigeration System,
2023
University of Mississippi
The Design Estimate Of A Warehouse Refrigeration System, Jackson Dear
Honors Theses
The intention of this project was to provide a design and cost estimate for the refrigeration systems within an industrial cold storage distribution center for Magnolia Country Frozen Foods, Inc. in East Rutherford, NJ. The facility includes eighteen 300,000 ft3 units (200 ft x 100 ft x 15 ft). These units require 200 tons of refrigeration at a maintained temperature of 0oF. This project's scope included choosing an optimal refrigeration system, selecting a refrigerant for use within the system, and providing a cost estimate for the purchase of the refrigeration system equipment and for the yearly cost associated with running …
Microwave Regeneration And Thermal And Oxidative Stability Of Imidazolium Cyanopyrrolide Ionic Liquid For Direct Air Capture Of Carbon Dioxide,
2023
Case Western Reserve University
Microwave Regeneration And Thermal And Oxidative Stability Of Imidazolium Cyanopyrrolide Ionic Liquid For Direct Air Capture Of Carbon Dioxide, Yun-Yang Lee, Eda Cagli, Aidan Klemm, Ruth Dikki
Faculty Scholarship
Understanding the oxidative and thermal degradation of CO2 sorbents is essential for assessing long-term sorbent stability in direct air capture (DAC). The potential degradation pathway of imidazolium cyanopyrrolide, an ionic liquid (IL) functionalized for superior CO2 capacity and selectivity, is evaluated under accelerated degradation conditions to elucidate the secondary reactions that can occur during repetitive absorption-desorption thermal-swing cycles. The combined analysis from various spectroscopic, chromatographic, and thermal gravimetric measurements indicated that radical and SN2 mechanisms in degradation are encouraged by the nucleophilicity of the anion. Thickening of the liquid and gas evolution are accompanied by 50 % reduction in CO2 …
Exploring Methods For Recycling Filament Waste In 3d Printing,
2023
CUNY, New York City College of Technology
Exploring Methods For Recycling Filament Waste In 3d Printing, Max Rios Carballo
Publications and Research
The goal of the current study is to investigate cutting-edge techniques for recycling filament waste from 3D printing procedures. Appropriate waste management techniques are required to reduce this trash's harmful environmental consequences. The goal of the project is to look at new methods for recycling filament waste in order to minimize disposal and encourage reuse. To acquire data from pertinent papers and research, a thorough literature review methodology was used. The findings show that this issue may be resolved utilizing a variety of recycling techniques, including shredding, melting, and re-extrusion. The type of filament waste and the intended goal will …
Enhancing Compatibility And Mechanical Properties Of Natural Rubber Composites,
2023
University of Indonesia
Enhancing Compatibility And Mechanical Properties Of Natural Rubber Composites, Krisma Yessi Sianturi, Adam Febriyanto Nugraha, Belle Kristaura, Mochamad Chalid
Journal of Materials Exploration and Findings
Pure natural rubber (NR) exhibits low mechanical properties, necessitating the incorporation of additives like vulcanizing agents and fillers. Carbon black and silica, conventional fillers, are relatively expensive and not environmentally friendly. This study explores using Oil Palm Empty Fruit Bunch (OPEFB) fiber as an affordable, abundant, and biodegradable alternative filler for NR. However, compatibility issues arise between the nonpolar NR and the polar OPEFB fiber. A latex-starch hybrid coupling agent (CA (NR-St)) was added to the composite formulation to address this. NR, OPEFB fiber, and the coupling agent were mixed using an open roll mill with a 10 phr OPEFB …
Characterizing The Influence Of The Moc Support For The Pt Single Atom Catalyst For The Water Gas Shift Reaction,
2023
Clemson University
Characterizing The Influence Of The Moc Support For The Pt Single Atom Catalyst For The Water Gas Shift Reaction, Kathryn Mcgee
Honors College Theses
In this report, we looked at characterizing the effect of the support (MoC) for the water gas shift (WGS) environment. The single-atom catalyst analyzed was platinum supported in molybdenum carbide. The primary focus of this report was CO* because of the strong interest in using the WGS reaction to convert CO* contamination. All calculations were performed using the density functional theory (DFT) method. We analyzed the binding energies for the different adsorbates, with a special emphasis on CO and charges of the support. We compared our results to Pt/Al2O3 support. We observed that the support, specifically MoC …
Autonomous Raman Hyperspectral Imaging And Analysis; Advances Towards Mapping Crystalline Character In Biologically Important Polymers,
2023
Cleveland State University
Autonomous Raman Hyperspectral Imaging And Analysis; Advances Towards Mapping Crystalline Character In Biologically Important Polymers, Sadeq H. Alkhalifa
ETD Archive
Poly-l-lactic acid has been of a great interest to the medical profession in recent years because of its biodegradability and biocompatibility. The biodegradation rate can be controlled by its crystallinity content. One method to modify its crystallinity content is by cold drawing. Raman spectroscopy is utilized to distinguish between the different crystalline content on the sample. However, a chemical imaging method is needed to characterize the polymer on the macro level. Chemical imaging using Raman spectroscopy is an important method of characterization that is non-invasive and non-destructive. The emphasis of my research has been to develop a method to characterize …
Elucidating The Mechanical And Transport Properties Of Lignin-Based Hydrogel Composites,
2023
Clemson University
Elucidating The Mechanical And Transport Properties Of Lignin-Based Hydrogel Composites, Nicholas Gregorich
All Dissertations
The use of lignin in the fabrication of soft composites has become an emerging area of research in polymer science and polymer chemistry. These lignin-based materials present numerous benefits, notably, a reduction in the use of petroleum-based precursor, improved structural benefits to otherwise soft host polymers, as well as the inherent antimicrobial and antioxidant properties of lignin, making it suitable for biomaterials. Herein, we present two chemical reaction pathways of incorporating lignin that was fractionated and cleaned using the Aqueous Lignin Purification with Hot Agents (ALPHA) process into poly(vinyl alcohol) (PVA) hydrogel composites for aqueous-based separations. By leveraging the ALPHA …
Bridging The Gap Between Phase Behavior And Processing For Renewable And Refinable Carbonaceous Precursors,
2023
Clemson University
Bridging The Gap Between Phase Behavior And Processing For Renewable And Refinable Carbonaceous Precursors, Graham Tindall
All Dissertations
As a category of materials, engineered carbons, specifically carbon fibers, are first-in-class for properties such as modulus, specific strength, and thermal resilience; however, the inability to directly process atomic carbon necessitates the development and optimization of carbonaceous precursors. Because the structure and properties of carbon are highly dependent on the precursors and requisite processing, numerous materials have been investigated as feedstocks for large-scale production. Although cellulose and rayon were among the first investigated, polyacrylonitrile (PAN) is the current hegemon of carbon fiber precursors. PAN feeds 90% of this market, but it is neither inexpensive nor renewable. Because a significant fraction …
