Scale-Up Of Perovskite Oxides For Conversion Of Co2 To Co Through Reverse Water-Gas Shift Chemical Looping,
2023
University of South Florida
Scale-Up Of Perovskite Oxides For Conversion Of Co2 To Co Through Reverse Water-Gas Shift Chemical Looping, Hanzhong Shi
USF Tampa Graduate Theses and Dissertations
CO2 conversion to CO has the benefit of further conversion to hydrocarbon-based fuels and chemicals. Due to CO2 being an important greenhouse gas, its conversion to CO and an increase of the carbon cycling will help reduce the greenhouse effect. Reverse water-gas shift chemical looping (RWSG-CL) is a two-step process that can be employed for the conversion of CO2 to CO. The first step involves partial reduction of oxygen by hydrogen to form oxygen vacant oxide, and the second step is the conversion of CO2 to CO over these partially reduced materials to regain their original structures. The RWSG-CL process …
Application Of Pinch Analysis For Energy Saving And Reducing Gas Emissions Based On Mathematical Model In The Hydrocracking Unit,
2023
Department of Chemical Engineering, College of Engineering and Petroleum, Hadhramout University
Application Of Pinch Analysis For Energy Saving And Reducing Gas Emissions Based On Mathematical Model In The Hydrocracking Unit, Badiea S. Babaqi
Hadhramout University Journal of Natural & Applied Sciences
Pinch analysis approach of the heat exchanger network in the hydrocracking unit was carried out to save the energy consumption and reduce the gas emissions simultaneously. This method based on mathematical model of the hydrocracking unit for a heat exchanger network using LINGO program to achieve the minimization of environmental impacts and the reduction of energy cost. The presented energy demands for the heat exchanger network are 20.38 MMBtu/hr and 26.52 MMBtu/hr for heating and cooling loads, respectively. The current analysis shows a huge opportunity in order to decrease energy consumption of the hydrocracking process at a minimum temperature difference …
Magnetic Nanocomposites For The Remote Activation Of Sulfate Radicals For The Removal Of Rhodamine B,
2023
University of Kentucky
Magnetic Nanocomposites For The Remote Activation Of Sulfate Radicals For The Removal Of Rhodamine B, Pranto Paul, Marissa Nicholson, J. Zach Hilt
Chemical and Materials Engineering Faculty Publications
The widespread presence of numerous organic contaminants in water poses a threat to the ecological environment and human health. Magnetic nanocomposites exposed to an alternating magnetic field (AMF) have a unique ability for magnetically mediated energy delivery (MagMED) resulting from the embedded magnetic nanoparticles; this localized energy delivery and associated chemical and thermal effects are a potential method for removing contaminants from water. This work developed a novel magnetic nanocomposite—a polyacrylamide-based hydrogel loaded with iron oxide nanoparticles. For this magnetic nanocomposite, persulfate activation and the contamination removal in water were investigated. Magnetic nanocomposites were exposed to AMF with a model …
Synergistic Effect Of Temperature And Acid Catalyst To Enhance L-Ald,
2023
University of South Florida
Synergistic Effect Of Temperature And Acid Catalyst To Enhance L-Ald, Prabhsimran Singh
USF Tampa Graduate Theses and Dissertations
Liquid Atomic layer deposition (LALD) is an emergent technology used for depositing thin films. Extensive research has been done on this method, designing different techniques and modifications for the deposition of films. Wastage of alkoxide precursors, extra purging cycle, and extensive time for the reaction when added stoichiometrically are some of the drawbacks which shift the focus from metal alkoxide as precursors. In this thesis, modifications for the L-ALD method for the complete reaction of alkoxide precursors when added stoichiometrically were achieved. Temperature and catalyst’s synergistic effects were utilized for the modification. This modified method was applied for the doping …
A Data-Driven Multivariate Process Monitoring Platform For Knowledge Discovery And Model Building In Industrial Applications,
2023
Louisiana State University and Agricultural and Mechanical College
A Data-Driven Multivariate Process Monitoring Platform For Knowledge Discovery And Model Building In Industrial Applications, Estelle E. Seghers
LSU Master's Theses
In industrial chemical manufacturing processes, the amount of raw data generated can add complexity in the analysis and understanding of the process dynamics. Being able to properly interpret this data can help improve plant operation, especially regarding safety and profitability. This research has culminated in FastMan-JMP, a platform proposed for monitoring of industrial processes and optimization of the offline data-driven model-building process as part of the process monitoring workflow. FastMan-JMP is a tool developed in Python to apply various data mining and machine learning techniques quickly and easily to better understand valuable patterns and hidden trends in process data. One …
Control Education For Societal-Scale Challenges: A Community Roadmap,
2023
University of Sheffield
Control Education For Societal-Scale Challenges: A Community Roadmap, John Anthony Rossiter, Christos G. Cassandras, João Hespanha, Sebastian Dormido, Luis De La Torre, Gireeja Ranade, Antonio Visioli, John Hedengren, Richard M. Murray, Panos Antsaklis, Francoise Lamnabhi-Lagarrigue, Thomas Parisini
Faculty Publications
This article focuses on extending, disseminating and interpreting the findings of an IEEE Control Systems Society working group looking at the role of control theory and engineering in solving some of the many current and future societal challenges. The findings are interpreted in a manner designed to give focus and direction to both future education and research work in the general control theory and engineering arena, interpreted in the broadest sense. The paper is intended to promote discussion in the community and also provide a useful starting point for colleagues wishing to re-imagine the design and delivery of control-related topics …
Simulations Of Morphology Control Of Self-Assembled Amphiphilic Surfactants,
2023
Brigham Young University - Provo
Simulations Of Morphology Control Of Self-Assembled Amphiphilic Surfactants, Qinyu Zhu, Douglas R. Tree
Faculty Publications
One of the grand challenges of amphiphilic self-assembly is the design of ordered structures whose morphology or shape can be explicitly and dynamically controlled by adjusting the properties of the amphiphiles or their surroundings. Such a capacity would enable researchers to create synthetic systems with functionality that meets or exceeds biological cells, and provide a robust platform for a broad range of engineering applications such as artificial tissues, drug delivery, and separation membranes. Despite significant progress, important fundamental questions remain unanswered, due in part to the limited resolution and the restricted parameter spaces that are readily accessible in experiments. Computational …
Protocol To Engineer Nanofilms Embedded Lipid
Nanoparticles For Controlled And Targeted Drug Delivery
(Nectar),
2023
University of Nebraska-Lincoln
Protocol To Engineer Nanofilms Embedded Lipid Nanoparticles For Controlled And Targeted Drug Delivery (Nectar), Rashi Porwal, Stephen L. Hayward, Srivatsan Kidambi
Department of Chemical and Biomolecular Engineering: Faculty Publications
We present a protocol to engineer a substrate-mediated delivery platform comprising hyaluronic acid-coated lipid nanoparticles (HALNPs) embedded into polyelectrolyte multilayer (PEM) films. This platform allows controlled spatiotemporal release of lipid nanoparticles (LNP) by embedding them within the polyelectrolyte multilayer films matrix. HALNP conjugate with antibodies also adds the ability for targeted delivery. The use of LNP enables this platform to encapsulate both hydrophobic and hydrophilic drugs. This platform can easily be reproduced and utilized for various biomedical drug delivery applications. For complete details on the use and execution of this protocol, please refer to Hayward et al. (2015, 2016a, 2016b), …
Simulations Of Morphology Control Of Self-Assembled Amphiphilic Surfactants,
2023
Brigham Young University
Simulations Of Morphology Control Of Self-Assembled Amphiphilic Surfactants, Qinyu Zhu, Douglas R. Tree
Faculty Publications
One of the grand challenges of amphiphilic self-assembly is the design of ordered structures whose morphology or shape can be explicitly and dynamically controlled by adjusting the properties of the amphiphiles or their surroundings. Such a capacity would enable researchers to create synthetic systems with functionality that meets or exceeds biological cells, and provide a robust platform for a broad range of engineering applications such as artificial tissues, drug delivery, and separation membranes. Despite significant progress, important fundamental questions remain unanswered, due in part to the limited resolution and the restricted parameter spaces that are readily accessible in experiments. Computational …
Computational Discovery Of Active And Selective Metal-
Nitrogen-Graphene Catalysts For Electrooxidation Of Water
To H2O2,
2023
University of Nebraska - Lincoln
Computational Discovery Of Active And Selective Metal- Nitrogen-Graphene Catalysts For Electrooxidation Of Water To H2O2, Payal Chaudhary, Iman Evazzade, Rodion Belosludov,, Vitaly Alexandrov
Department of Chemical and Biomolecular Engineering: Faculty Publications
A direct electrosynthesis of H2O2 from either O2 or H2O is an attractive strategy to replace the energy-intensive industrial anthraquinone process. Two-electron water oxidation reaction (2e-WOR) offers several advantages over the oxygen reduction reaction such as better mass transfer due to the absence of gasphase reactants. However, 2e-WOR is a more challenging and less studied process with only a handful of metal oxides exhibiting reasonable activity/selectivity properties. Herein, we employ density-functional-theory calculations to screen a variety of metal-nitrogen-graphene structures for 2e-WOR. As a consequence of scaling between the adsorption energies of reaction intermediates, we …
Interfacial Tensions Of (Brine + H2 + Co2) Systems At Gas Geo-Storage Conditions,
2023
Edith Cowan University
Interfacial Tensions Of (Brine + H2 + Co2) Systems At Gas Geo-Storage Conditions, Zoha Dalal Isfehani, Ali Sheidaie, Mirhasan Hosseini, Jalal Fahimpour, Stefan Iglauer, Alireza Keshavarz
Research outputs 2022 to 2026
In hydrogen geological storage, cushion gas has vital role to retain adequate reservoir pressure to keep the hydrogen withdrawal stable. Presence of the cushion gas in the storage reservoir can affect the flow characteristics of hydrogen during injection and production cycles. One of the most crucial parameters that control the fluids flow in porous media is interfacial tension (IFT) between fluids. However, the literature data lacks in terms of IFT between cushion gas mixed with hydrogen and brine at geo-storage conditions. In this study, the pendant drop method was used to measure the IFT of (brine + H2 + …
Oh, My Darling Clementine: A Detailed History And Data Repository Of The Los Alamos Plutonium Fast Reactor,
2023
University of Nevada, Las Vegas
Oh, My Darling Clementine: A Detailed History And Data Repository Of The Los Alamos Plutonium Fast Reactor, Hannah K. Patenaude, Franz J. Freibert
College of Sciences Graduate Student Research
The Los Alamos Plutonium Fast Reactor, Clementine, provided the first fast neutron spectrum using a metallic plutonium fuel system and liquid mercury coolant. Clementine is often mentioned in the history of fast, metal-fueled, or metal-cooled designs, with little public information regarding the specifications or timeline. This paper contains a synopsis of each report regarding the development, operation, experimental results, failures, and subsequent disassembly of Clementine to explore this unique reactor within the context of modern advanced reactor development.
Molecular And Cellular Level Characterization Of Cytoskeletal Mechanics Using A Quartz Crystal Microbalance,
2023
University of Mississippi
Molecular And Cellular Level Characterization Of Cytoskeletal Mechanics Using A Quartz Crystal Microbalance, Emily M. Kerivan, Lyle Tobin, Mihir Basil, Dana N. Reinemann
Faculty and Student Publications
A quartz crystal microbalance (QCM) is an instrument that has the ability to measure nanogram-level changes in mass on a quartz sensor and is traditionally used to probe surface interactions and assembly kinetics of synthetic systems. The addition of dissipation monitoring (QCM-D) facilitates the study of viscoelastic systems, such as those relevant to molecular and cellular mechanics. Due to real-time recording of frequency and dissipation changes and single protein-level precision, the QCM-D is effective in interrogating the viscoelastic properties of cell surfaces and in vitro cellular components. However, few studies focus on the application of this instrument to cytoskeletal systems, …
Magnetic Nanocomposites For The Remote Activation Of Sulfate Radicals For The Removal Of Rhodamine B,
2023
University of Kentucky
Magnetic Nanocomposites For The Remote Activation Of Sulfate Radicals For The Removal Of Rhodamine B, Pranto Paul, Marissa Nicholson, J. Zach Hilt
UK CARES Faculty Publications
The widespread presence of numerous organic contaminants in water poses a threat to the ecological environment and human health. Magnetic nanocomposites exposed to an alternating magnetic field (AMF) have a unique ability for magnetically mediated energy delivery (MagMED) resulting from the embedded magnetic nanoparticles; this localized energy delivery and associated chemical and thermal effects are a potential method for removing contaminants from water. This work developed a novel magnetic nanocomposite—a polyacrylamide-based hydrogel loaded with iron oxide nanoparticles. For this magnetic nanocomposite, persulfate activation and the contamination removal in water were investigated. Magnetic nanocomposites were exposed to AMF with a model …
Engineering Oxygen Vacancy-Rich Ceox Overcoating Onto Ni/Al2o3 By Atomic Layer Deposition For Bi-Reforming Of Methane,
2023
Missouri University of Science and Technology
Engineering Oxygen Vacancy-Rich Ceox Overcoating Onto Ni/Al2o3 By Atomic Layer Deposition For Bi-Reforming Of Methane, Baitang Jin, Kaiying Wang, Han Yu, Xiaoqing He, Xinhua Liang
Chemical and Biochemical Engineering Faculty Research & Creative Works
Atomic Layer Deposition (ALD) Was Applied to Develop CeOx-Overcoated Ni/Al2O3 Catalyst for Bi-Reforming of Methane (BRM), as the Combination of Dry Reforming of Methane (DRM) and Steam Reforming of Methane (SRM). Non-Stoichiometric CeOx Thin Films Were Successfully Deposited on Ni/Al2O3 Particles by ALD, Which Constructed a Beneficial Ni-CeOx Interface and Modified the Catalyst Property. Ascribed to the Unique ALD Growth Mode, a High Amount of Ce(III) and Oxygen Vacancies Existed in the ALD-Deposited CeOx overcoating. a Reduction Process Before the BRM Reaction Contributed to the Further Reduction of Ce(IV) …
Dendrimer And Dendrimer Gel-Derived Drug Delivery Systems: Breaking Bottlenecks Of Topical Administration Of Glaucoma Medications,
2023
Missouri University of Science and Technology
Dendrimer And Dendrimer Gel-Derived Drug Delivery Systems: Breaking Bottlenecks Of Topical Administration Of Glaucoma Medications, Juan Wang, Boxuan Li, Uday B. Kompella, Hu Yang
Chemical and Biochemical Engineering Faculty Research & Creative Works
Due to high structural flexibility, multidrug carrying capability, and tunable size, dendrimers have been used as suitable carriers for ophthalmic drug delivery. Drug molecules can be either encapsulated or chemically coupled to dendrimers. the nanoscopic size, spheroidal shape, and cationic surface of Poly amidoamine (PAMAM) dendrimers promote their interaction with the cornea and result in prolonged precorneal retention. Dendrimers could be further cross-linked to produce three-dimensional hydrogel networks or dendrimer hydrogels (DH). the properties of the DH can be readily adjusted to maintain both fluidity and adhesiveness, making them suitable for developing topical ocular drug formulations. Micro-/nano- sized DHs, that …
Incoherency In Central American Hydroclimate Proxy Records Spanning The Last Millennium,
2023
Missouri University of Science and Technology
Incoherency In Central American Hydroclimate Proxy Records Spanning The Last Millennium, Jonathan Obrist-Farner, Byron A. Steinman, Nathan D. Stansell, Jeremy Maurer
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Continued Global Warming is Expected to Result in Reduced Precipitation and a Drier Climate in Central America. Projections of Future Changes Are Highly Uncertain, However, Due to the Spatial Resolution Limitations of Models and Insufficient Observational Data Coverage Across Space and Time. Paleoclimate Proxy Data Are Therefore Critical for Understanding Regional Climate Responses during Times of Global Climate Reorganization. Here We Present Two Lake-Sediment based Records of Precipitation Variability in Guatemala Along with a Synthesis of Central American Hydroclimate Records Spanning the Last Millennium (800–2000 CE). the Synthesis Reveals that Regional Climate Changes Have Been Strikingly Heterogeneous, even over Relatively …
Influence Of Adhesive Application Method And Thermocycling On The Bonding Performance Of Different Adhesive Systems To Dentin,
2023
Missouri University of Science and Technology
Influence Of Adhesive Application Method And Thermocycling On The Bonding Performance Of Different Adhesive Systems To Dentin, Lamiaa Mahmoud Moharam, Rasha Hassan Afifi
Chemical and Biochemical Engineering Faculty Research & Creative Works
Aim: To assess the effect of multiple layers application of different adhesive systems on the microshear bond strength (μSBS) of dentin with and without thermocycling. Materials and Methods: Two hundred forty sound human premolars had their enamel surfaces removed to expose even surfaces of dentin. The teeth were mounted in acrylic resin blocks and then assigned arbitrarily into four main groups (n = 60) representing the investigated adhesives (a self-etch [SE] adhesive, a total-etch [TE] adhesive, and a multimode [MM] adhesive used in TE and SE modes). Individually, the main groups were equally alienated into three subgroups (n = 20), …
Ferric Chloride-Induced Arterial Thrombosis And Sample Collection For 3d Electron Microscopy Analysis,
2023
University of Kentucky
Ferric Chloride-Induced Arterial Thrombosis And Sample Collection For 3d Electron Microscopy Analysis, Smita Joshi, Alexis N. Smith, Kanakanagavalli Shravani Prakhya, Hammodah Rawhi Hammodah Alfar, Joshua Lykins, Ming Zhang, Irina D. Pokrovskaya, Maria A. Aronova, Richard D. Leapman, Brian Storrie, Sidney W. Whiteheart
Saha Cardiovascular Research Center Faculty Publications
Cardiovascular diseases are a leading cause of mortality and morbidity worldwide. Aberrant thrombosis is a common feature of systemic conditions like diabetes and obesity, and chronic inflammatory diseases like atherosclerosis, cancer, and autoimmune diseases. Upon vascular injury, usually the coagulation system, platelets, and endothelium act in an orchestrated manner to prevent bleeding by forming a clot at the site of the injury. Abnormalities in this process lead to either excessive bleeding or uncontrolled thrombosis/insufficient antithrombotic activity, which translates into vessel occlusion and its sequelae. The FeCl3-induced carotid injury model is a valuable tool in probing how thrombosis initiates and progresses …
A Review Of Hydrogen/Rock/Brine Interaction: Implications For Hydrogen Geo-Storage,
2023
Edith Cowan University
A Review Of Hydrogen/Rock/Brine Interaction: Implications For Hydrogen Geo-Storage, Masoud Aslannezhad, Muhammad Ali, Azim Kalantariasl, Mohammad Sayyafzadeh, Zhenjiang You, Stefan Iglauer, Alireza Keshavarz
Research outputs 2022 to 2026
Hydrogen (H2) is currently considered a clean fuel to decrease anthropogenic greenhouse gas emissions and will play a vital role in climate change mitigation. Nevertheless, one of the primary challenges of achieving a complete H2 economy is the large-scale storage of H2, which is unsafe on the surface because H2 is highly compressible, volatile, and flammable. Hydrogen storage in geological formations could be a potential solution to this problem because of the abundance of such formations and their high storage capacities. Wettability plays a critical role in the displacement of formation water and determines …
