Chemical Engineering Commons^™

Dry Reforming Of Methane Over Substituted Lanthanum Zirconate Pyrochlore Catalysts, Srikar Bhattar

LSU Doctoral Dissertations

One of the potential methods for producing syngas from two greenhouse gases (CH₄ and CO₂) is dry reforming of methane (DRM), which has received a lot of attention. DRM could lower the net emission of these gases if the energy used to power it comes from sources other than hydrocarbons. Despite being highly active, many conventional Ni based metal/support catalyst systems rapidly lose their activity due to the sintering or deposition of coke on the metal clusters' surfaces. Thus, it is crucial that the DRM catalyst must be coke resistant and thermally stable to avoid sintering.

DRM …

Development Of Novel Biosensors For Direct Measurement Of Proteasome Activity In Intact Single Cells, Alireza Rahnama

LSU Doctoral Dissertations

Enzymes regulate nearly all cellular and biochemical processes governing cellular proliferation, metabolism, and migration. One example is the ubiquitin-proteasome system (UPS), a highly complex, tightly regulated pathway responsible for the recognition and degradation of misfolded or damaged proteins inside the cell. Protein degradation requires posttranslational addition of a polyubiquitin chain to target the protein to the proteasome for degradation which can be reversed by deubiquitinating enzymes (DUBs) which remove the chain. Dysregulation of the UPS is associated with many diseases including cancer which has resulted in the development of inhibitors, like Bortezomib and Carfilzomib, driving higher median patient survival rates …

Selection Of Natural Surfactants For Possible Use In Improving Oil Recovery Of Carbonate Oil Reservoirs, Hiba Hachem Limam

Thesis/ Dissertation Defenses

Middle East petroleum industry is currently searching for the most suitable enhanced oil technique to improve the oil recovery from local oil reservoirs. The biggest challenge for the application of enhanced oil recovery (EOR) in the Middle East is the harsh environment (high salinity and temperature). Surfactant (synthetic or natural) is one of the enhanced oil recovery (EOR) major players considered for application in the Middle East. However, synthetic surfactants have several drawbacks, such as being economically unattractive and their high levels of toxicity. This study investigated the possible use of natural surfactant extracted from the leaves of three types …

Carbonate Precipitation Behavior In Co2 Mea Electrolyzers With Cu Electrocatalyst, John C. Hendershot

LSU Master's Theses

Annually, over 35 billion metric tons of carbon dioxide (CO₂) are emitted into Earth’s atmosphere. The accumulated CO₂ emissions in the atmosphere over the last century drive climate change. CO₂ electroreduction (CO₂ER) is an emerging technology that aims to recycle carbon emissions from the industrial sector by using CO₂, H₂O, and electricity as a feedstock to produce ethylene (C₂H₄) at current densities as high as 1 A cm^-2 and Faradaic efficiencies (FE) of 60%. However, CO₂ electrolyzers currently demonstrate poor durability at industrially relevant …

Induction Heating Driven Heterogeneous Catalysis: Magnetically Induced Nanoparticle Catalysts, Cameron Lee Roman

LSU Doctoral Dissertations

Heterogeneous catalysis has been and continues to be highly studied due to being one of the cornerstones of the chemical industry. With an increasing demand for chemicals and rising costs, there is a growing need to adapt to changing feed stocks and increase production efficiency. Polymers, oxygenates, and other chemical intermediates are predicted to experience continued growth, corresponding to an increased need for olefines. Due to the abundance of shale gas, researchers and producers are interested in meeting this demand via the dehydrogenation of light alkanes.

While dehydrogenation catalysts are a valuable tool in olefin production, selectivity and deactivation remain …

A Consortium Of Microalgae And Wastewater Activated Sludge To Generate Biohydrogen, Muhammad Asad Javed

Thesis/ Dissertation Defenses

Hydrogen is a clean source and carbon-free source of energy that can be generated photobiologically using green microalgae with 122 kJ/g of energy output which is 2.75 times that of hydrocarbon-based fuels. However, challenges, such as presence of molecular oxygen (O2) within the cells, hinder their practical application. Molecular O2, emanating from the activity of photosynthesis, acts as a powerful and effective switch that turns off bioH2 production activity. The objective of this research is to develop an innovative approach to increase the yield and sustain bioH2 photoproduction. For this purpose, a consortium of microalgae and wastewater activated sludge (WWAS) …

Swelling Induced Buckling Of Photopatterned Hydrogel Beams, Chinar Yogesh Kokaje

USF Tampa Graduate Theses and Dissertations

The main goal of this study was to learn more about swelling induced buckling of surface-attached gel lines photo-patterned from thermally responsive polymers. A library of 10 different polymer compositions was synthesized using methacryloyloxybenzophenone (MABP) as the photo-cross-linking monomer. For each of the polymers, a series of beam-like patterns were prepared on polystyrene tissue culture dishes by first depositing a known amount of polymer into the tissue culture dish followed by pattern generation using a photo-lithography mask with line widths of 10, 20, 30, 50, and 80 μm. The target height of each polymer line was 100 μm. After development …

Comparative Evaluation Of Investigation Methods For Estimating The Load-Dependent State Of Charge And End Of Discharge Of A Multirotor Uav Battery, Hanna Dibbern, Morten Roßberg, Claudia Werner

Journal of Aviation Technology and Engineering

As the scope of multirotor unmanned aerial vehicle (UAV) applications increases, more attention is being paid to UAV energy requirements, which vary depending on the mission profile. To obtain accurate information about the UAV battery during flight, the idea of a digital twin including a battery state estimation model is promising. For battery state estimation, a Kalman filter combination is the preferred approach in the literature. Comparing different Kalman filters, the unscented Kalman filter has a more accurate estimation for nonlinear systems compared to the extended Kalman filter. In the application of UAV flight with load-dependent flight missions, the comparison …

Stereoscopic-Based Mass Properties Estimation For Warhead Fragments, Alessia Nocerino, Katharine Larsen, Riccardo Bevilacqua, Elisabetta L. Jerome

Student Works

FRAGMENTATION characteristics such as spatial distribution, number of fragments, fragment velocity, and fragment mass can be used to characterize the lethality of a fragmenting weapon or any metal cased explosive [1,2]. However, most warhead tests and evaluations are limited to static arena testing, where fragment characteristics must be collected by hand. Recently, stereoscopic imaging techniques have been added to static arena tests. Using this method, position tracks can be collected for each fragment, and then velocity information can be found. This paper proposes a method to estimate the mass and moment of inertia using data collected by a stereoscopic imaging …

Ambient Air Emission Profiles Of Polycyclic Aromatic Hydrocarbons Around A Typical University Power House In Nigeria, Oyetunji Okedere

Tanzania Journal of Engineering and Technology (TJET)

The level of electricity generation in Nigeria is presently grossly inadequate. Consequently, the productive sectors of the economy do not presently enjoy an uninterrupted supply of electrical energy from the country’s national grid and the downtime is in most cases too much. Using diesel-fueled electric power generators has become an attractive alternative to meet the shortfall in the energy supply gap. In this study, the levels of polycyclic aromatic hydrocarbons in the vicinity of the diesel-fueled electric power generators operated by Osun State University, Osogbo, Nigeria were investigated with a view to ascertain the priority levels and carcinogenic PAHs. Since …

Employment Of Intelligent Predictive Maintenance On Thermal Power Plant Component Parts Taking Condenser Vacuum As A Case Study, Titus Ajewole

Tanzania Journal of Engineering and Technology (TJET)

This work proposes deployment of machine learning in the maintenance of individual constituent parts of steam power plant assemblages. With the condenser vacuum of a steam turbine (in a six-turbine plant assemblage) taken as a case study, information on the past operating parameters of the selected plant component was used to forecast its future working condition. Based on Exponential Gaussian Process of Regression, a model was developed, trained using the diachronic operational data, and employed in determining the future. A quantitative evaluation was employed to provide the distribution of the test values of the data about the lines of regression, …

Computational Modeling Using A Novel Continuum Approach Coupled With Pathway-Informed Neural Networks To Optimize Dynein-Mediated Centrosome Positioning In Polarized Cells, Arkaprovo Ghosal, Padmanabhan Seshaiyar Dr., Adriana Dawes Dr., General Genomics Inc.

Annual Symposium on Biomathematics and Ecology Education and Research

No abstract provided.

New Dual Modality Technique Of Gamma-Ray Densitometry (Grd) And Optical Fiber Probe (Ofp) To Investigate Line-Averaged Diameter Profiles Of Gas, Liquid, And Solid Holdups Along The Height Of A Slurry Bubble Column, Omar Farid, Binbin Qi, Sebastián Uribe, Muthanna H. Al-Dahhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

A new hybrid measurement technique was developed and employed to study line-averaged three-phase holdup distribution in a Slurry Bubble Column Reactor (SBCR) using gamma-ray densitometry (GRD) and point optical fiber probe (OFP) techniques. The OFP technique was used to measure the local gas holdup at 45 nodes in the cross-section area of the SBCR at three different axial levels. Thus, the GRD technique measured the spectrum of the SBCR for two different orientations simultaneously with the OFP technique at the same operating conditions to determine the solid holdup distribution radially and axially. The line-averaged solid holdup for 25% solids loading …

A Multi-Organ Maize Metabolic Model Connects Temperature Stress With Energy Production And Reducing Power Generation, Niaz Bahar Chowdhury, Margaret Simons- Senftle, Berengere Decouard, Isabelle Quillere, Martine Rigault, Karuna Anna Sajeevan, Bibek Acharya, Ratul Chowdhury, Bertrand Hirel, Alia Dellagi, Costas Maranas, Rajib Saha

Department of Chemical and Biomolecular Engineering: Faculty Publications

Climate change has adversely affected maize productivity. Thereby, a holistic understanding of metabolic crosstalk among its organs is important to address this issue. Thus, we reconstructed the first multi-organ maize metabolicmodel, iZMA6517, and contextualized itwith heat and cold stress transcriptomics data using expression distributed reaction flux measurement (EXTREAM) algorithm. Furthermore, implementing metabolic bottleneck analysis on contextualized models revealed differences between these stresses. While both stresses had reducing power bottlenecks, heat stress had additional energy generation bottlenecks.We also performed thermodynamic driving force analysis, revealing thermodynamics-reducing power-energy generation axis dictating the nature of temperature stress responses. Thus, a temperaturetolerant maize ideotype can …

A Novel Application Of Spinning Disk Technology To Collect Plasma From Whole Blood Prior To Quantifying Plasma Rna, Naomi Rapier-Sharman, Mae-Lynn L. Hutchinson, Carlos M. Moreno, Abraham Quaye, Brian D. Poole, K. Scott Weber, William G. Pitt, Brett E. Pickett

Faculty Publications

The spinning disk technology has previously been utilized to isolate bacterial components from blood in hours instead of days. We hypothesized that this platform could be applied as an alternative approach to isolating plasma RNA from a whole blood sample. We consequently tested the efficacy of the spinning disk technology to extract plasma from whole blood upstream of RNA isolation and analysis. To do so, we collected plasma using either the spinning disk or the typical two-spin centrifuge method. We found that the spinning disk method results in significantly more hemolysis during collection than the conventional two-spin centrifuge method. However, …

Chain Conformation And Exciton Delocalization In A Push-Pull Conjugated Polymer, Yulong Zheng, Rahul Venkatesh, Connor P. Callaway, Campbell Viersen, Kehinde H. Fagbohungbe, Aaron L. Liu, Chad Risko, Elsa Reichmanis, Carlos Silva-AcuñA

UK CARES Faculty Publications

Linear and nonlinear optical line shapes reveal details of excitonic structure in polymer semiconductors. We implement absorption, photoluminescence, and transient absorption spectroscopies in DPP-DTT, an electron push−pull copolymer, to explore the relationship between their spectral line shapes and chain conformation, deduced from resonance Raman spectroscopy and from ab initio calculations. The viscosity of precursor polymer solutions before film casting displays a transition that suggests gel formation above a critical concentration. Upon crossing this viscosity deflection concentration, the line shape analysis of the absorption spectra within a photophysical aggregate model reveals a gradual increase in interchain excitonic coupling. We also observe …

Innovative Approaches To Poultry Processing Wastewater Treatment: The Stainless Steel Ultrafiltration Membrane As A Viable Option, Saubana Olorunrola Dada, Chidambaram Thamariselvan, Mahmood Jebur, Sumith Ranil Wickramasinghe

Chemical Engineering Faculty Publications and Presentations

In pursuit of sustainability, we explored replacing conventional dissolved air floatation (DAF) in poultry processing wastewater (PPW) treatment with a precisely tuned 0.02 µm stainless-steel ultrafiltration (SSUF) membrane. SSUF is a robust, homogenously porous membrane with strong chemical resistance, ease of cleaning, and exceptional resistance to organic fouling. Unlike polymeric membranes, it can be regenerated multiple times, making it a cost-effective choice due to its compatibility with harsh chemical cleaning. The PPW used for the study was untreated wastewater from all processing units and post-initial screening. Our study revealed the SSUF membrane’s exceptional efficiency at eliminating contaminants. It achieved an …

Biomimetic Approach To Elucidate The Role Of Microenvironment In Regulating Cell Communications In Liver Diseases, Youra Moeun

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

Liver is a complex organ but often underappreciated for its functions to remove toxins and fight infection in the body. Despite the ongoing prevalence of patients contracting chronic liver diseases, coupled with a global healthcare investment of approximately $70 billion, there is still no effective treatment for chronic liver diseases including alcoholic liver disease. The purpose of this dissertation was to understand the interactions of parenchymal and non-parenchymal liver cells in physiological and pathological like environments. This allowed us to recreate a healthy and the diseased microenvironments to observe the stages of the liver diseases development and apply appropriate treatments …

Selection Of Natural Surfactants For Possible Use In Improving Oil Recovery Of Carbonate Oil Reservoirs, Hiba Hachem Limam

Theses

Middle East petroleum industry is currently searching for the most suitable enhanced oil technique to improve the oil recovery from local oil reservoirs. The biggest challenge for the application of enhanced oil recovery (EOR) in the Middle East is the harsh environment (high salinity and temperature). Surfactant (synthetic or natural) is one of the EOR major players considered for application in the Middle East. However, synthetic surfactants have several drawbacks, such as economically unattractive and environmental impacts. This study investigated the possible use of natural surfactant extracted from the leaves of three types of plants, namely Aloe Vera, Tetraena qatarensis, …

Development Of Unsaturated Polyester Resin Mortar Utilizing Industrial Wastes, Fatema Ahmed Alahmed

Theses

In recent years, polymer mortar (PM) has played a crucial role in the modern construction industry. It is gaining recognition as an effective and quick repair material in construction applications because it has several benefits over traditional Portland cement concrete. Various types of polymer binders, such as unsaturated polyester resin (UPR), have been used in these materials owing to their low cost, excellent strength, high workability, and rapid curing. This study investigates the feasibility of reutilizing locally available waste in the production of UPR-based polymer mortar, which facilitates the development of mortars with less environmental impact. In this study, the …