Other Chemical Engineering Commons^™

Comparison Of Biomass To Bio-Oils Reactor Systems: Direct Conversion Vs. Companion Coal Gasification, Alexandra Eicher

Honors Theses and Capstones

It is well known that the United States’ dependence on crude-oil negatively affects its economy, safety, and environment. To alleviate these negative consequences, a more economical and environmentally-friendly source of fuel, such as biomass, should be explored. The conversion of biomass to bio-oils involves the pyrolysis of biomass at about 500°C, thus requiring a great deal of heat. This heat source could be the excess waste heat from a coal gasifier.

As such, this report specifies the design of an industrial plant that produces bio-oils from biomass by using the waste heat from a coal gasifier. It is designed to …

Married Coal Gasification And Biomass Pyrolysis, Michael Balch

Honors Theses and Capstones

This project is a proposal to marry a coal gasification process to a biomass pyrolysis. Coal is pyrolized to produce syngas and a large amount of heat. The syngas is treated and fed to a Fischer-Tropsch process. The excess heat produces steam that is used to pyrolize biomass. The biomass produces char, gas, and vapor. The char and gas are recovered, and the vapor is condensed to produce bio-oil.

The proposed plant has a capacity of 1100 tons of biomass (550 dry tons) per day. I assumed an operating factor of 0.9 The plant could be operational within five years, …

Study Of An Alternative Process For Oxidizing Vapor Grown Carbon Nanofibers Using Electron Beam Accelerators, Maria Cecília Evora, Donald A. Klosterman, Khalid Lafdi, Lingchuan Li, L.G.A. Silva

Chemical and Materials Engineering Faculty Publications

The use of a high-energy electron beam was explored in this study as an alternative technique for oxidizing vapor grown carbon nanofiber surfaces. The radiation exposures were carried out at three different electron beam facilities with beam energies of 1.5, 3.0 and 4.5 MeV and radiation doses ranging from 1000 to 3500 kGy. XPS analysis showed that oxygen was readily incorporated on the surface: the ratio O1s/C1s increased approximately by a factor of 4 when the carbon nanofibers were irradiated at 3500 kGy. The oxidized nanofibers exhibited better dispersion in a water/methanol solution (50% v/v) than as-received nanofibers. Raman spectroscopy …

Note: A Simple Thermal Gradient Annealing Unit For The Treatment Of Thin Films, C. J. Metting, Johnathan K. Bunn, Ellen A. Underwood, Yihao Zhu, G. Koley, T. Crawford, Jason R. Hattrick-Simpers

Faculty Publications

A gradient annealing cell has been developed for the high-throughput study of thermalannealing effects on thin-film libraries in different environments. The inexpensive gradientannealing unit permits temperature gradients as large as 28 °C/mm and can accommodate samples ranging in length from 13 mm to 51 mm. The system was validated by investigating the effects of annealing temperature on the crystallinity, resistivity, and transparency of tin-doped indium oxide deposited on a glass substrate by magnetron sputtering. The unit developed in this work will permit the rapid optimization of materials properties such as crystallinity, homogeneity, and conductivity across a variety of applications.

Modeling Of Biorefinery Supply Chain Economic Performance With Discrete Event Simulation, Joseph S. Amundson

Theses and Dissertations--Manufacturing Systems Engineering

As competition for fossil fuels accelerates, alternative sources of chemicals, fuels, and energy production become more appealing to researchers and the layman. Among the candidates to fill this growing niche is lignocellulosic biomass. Many researchers have examined supply chain design and optimization for biofuel and bioenergy production throughout the years. However, these models often fail to capture the variability and uncertainty inherent to the biomass supply chain. Multiple factors with high degrees of stochasticity can have major impacts on the performance of a biorefinery: weather, biomass quality, feedstock availability, and market demand for products are just a few. To begin …

Infrared Optical Properties Of Amorphous And Nanocrystalline Ta2o5 Thin Films, Trevor J. Bright, J. I. Watjen, Zhuomin Zhang, Christopher Muratore, Andrey A. Voevodin, D. I. Koukis, David B. Tanner, Daniel J. Arenas

Chemical and Materials Engineering Faculty Publications

The optical constants of tantalum pentoxide (Ta 2O5) are determined in a broad spectral region from the visible to the far infrared. Ta 2O5 films of various thicknesses from approximately 170 to 1600 nm aredeposited using reactive magnetron sputtering on Si substrates. X-ray diffraction shows that the as-deposited films are amorphous, and annealing in air at 800 °C results in the formation of nanocrystallineTa 2O5. Ellipsometry is used to obtain the dispersion in the visible and near-infrared. Two Fourier-transform infrared spectrometers are used to measure the transmittance and reflectance at wavelengths from 1 to 1000 μm. The surface topography and …

Cross-Plane Thermal Properties Of Transition Metal Dichalcogenides, Christopher Muratore, Vikas Varshney, Jaime J. Gengler, Jianjun Hu, John E. Bultman, Timothy M. Smith, Patrick J. Shamberger, Bo Qiu, Xiulin Ruan, Ajit K. Roy, Andrey A. Voevodin

Chemical and Materials Engineering Faculty Publications

In this work, we explore the thermal properties of hexagonal transition metal dichalcogenide compounds with different average atomic masses but equivalent microstructures. Thermal conductivity values of sputtered thin films were compared to bulk crystals. The comparison revealed a >10 fold reduction in thin film thermal conductivity. Structural analysis of the films revealed a turbostratic structure with domain sizes on the order of 5–10 nm. Estimates of phonon scattering lengths at domain boundaries based on computationally derived group velocities were consistent with the observed film microstructure, and accounted for the reduction in thermal conductivity compared to values for bulk crystals.

Tannic Acid Coated Gold Nanorods Demonstrate A Distinctive Form Of Endosomal Uptake And Unique Distribution Within Cells, Emily A. Untener, Kristen K. Comfort, Elizabeth I. Maurer, Christin M. Grabinski, Donald A. Comfort, Saber M. Hussain

Chemical and Materials Engineering Faculty Publications

One of the primary challenges associated with nanoparticle-dependent biological applications is that endosomal entrapment in a physiological environment severely limits the desired targeting and functionality of the nanoconstructs. This study sought to overcome that challenge through a systematic approach of gold nanorod (GNR) functionalization: evaluating the influence of both aspect ratio and surface chemistry on targeted cellular internalization rates and preservation of particle integrity. Owing to their unique spectral properties and enhanced surface area, GNRs possess great potential for the advancement of nanobased delivery and imaging applications. However, their ability for efficient intracellular delivery while maintaining their specific physiochemical parameters …

Applications Of High Throughput (Combinatorial) Methodologies To Electronic, Magnetic, Optical, And Energy-Related Materials, Martin L. Green, Ichiro Takeuchi, Jason R. Hattrick-Simpers

Faculty Publications

High throughput (combinatorial) materials science methodology is a relatively new research paradigm that offers the promise of rapid and efficient materials screening, optimization, and discovery. The paradigm started in the pharmaceutical industry but was rapidly adopted to accelerate materials research in a wide variety of areas. High throughput experiments are characterized by synthesis of a “library” sample that contains the materials variation of interest (typically composition), and rapid and localized measurement schemes that result in massive data sets. Because the data are collected at the same time on the same “library” sample, they can be highly uniform with respect to …

Capacity Fade Model For Spinel Limn2O4 Electrode, Yiling Dai, Long Cai, Ralph E. White

Faculty Publications

A mathematical model for the capacity fade of a LiMn₂O₄ (LMO) electrode is developed in this paper by including the acid attack on the active material and the solid electrolyte interphase (SEI) film formation on the LMO particle surface. The acid generated by the LiPF₆ and the solvent decompositions are coupled to the manganese (Mn) dissolution. The decrease of the Li ion diffusion coefficient is involved as another contribution to the capacity fade, which is caused by the passive film formation on the active material surface. The effects of cell practical operation/fabrication conditions and kinetics of …

Characterization Of And Controlling Morphology Of Ultra-Thin Nanocomposites, Guy C. Laine

Theses and Dissertations--Chemical and Materials Engineering

Ultrathin film nanocomposites are becoming increasingly important for specialized performance of commercial coatings. Critical challenges for ultrathin film nanocomposites include their synthesis and characterization as well as their performance properties, including surface roughness, optical properties (haze, refractive index as examples), and mechanical properties. The objective of this work is to control the surface roughness of ultrathin film nanocomposites by changing the average particle size and the particle volume fraction (loading) of monomodal particle size distributions. This work evaluated one-layer and two-layer films for their surface properties. Monodispersed colloidal silica nanoparticles were incorporated into an acrylate-based monomer system as the model …

Energy Analysis Of Bio-Ethanol Dehydration Using Pervaporative Processes, Michel Elia Kahwaji Janho

Undergraduate Research Posters 2012

Environmental effects and health hazards posed by fossil-fuel based technologies complemented by changes in the global economy have increased the demand for “cleaner” and more efficient technologies. Developments in technologies that rely on renewable or synthetic resources have therefore become more relevant in today’s economy and current industrial outlook. This study focuses on a critical assessment of pervaporation as a dehydration technique in the production of ethanol from sugar-cane. Energy demands of various separation schemes using this technique are evaluated.

Fabrication And Characterization Of Thermomechanically Processed Sulfur And Boron Doped Amorphous Carbon Films, Lonnie Carlson

Department of Chemical and Biomolecular Engineering: Dissertations, Theses, and Student Research

Small scale, high power density, reliable, and long-life power supplies would be useful or even critical for space missions or the growing number of microdetectors, microsensors, and miniature vehicles. Alpha or beta particle voltaic devices could satisfy these requirements but have been shown to degrade quickly due to radiation damage. Amorphous carbon (a-C) PN junctions or PIN devices could provide radiation hardness and sufficiently high efficiency. As the range of alpha and beta particles in a-C is ~20-120μm, much thicker films than are typical are needed to maximize collection of the particle energy.

In this work, the fabrication of thermomechanically …

Cloning And Characterization Of Sas0754, A Hypothetical Protein From Community Associated Staphylococcus Aureus, Unknown Unknown

Symposium 2012

Community associated Staphylococcus aureus (strain MSSA476) is a gram positive cocci capable of infecting many different parts of the body and known to cause serious infections that can be fatal, such as bacterial arthritis and acute endocarditis. To find effective ways of fighting against CA-MRSA strains we must learn more about their ability to infect. The focus of this study was cloning and characterization of a protein referred to as SAS0754. The size of SAS0754 is 340 amino acids and the gene sequence is 1023 nucleotides. The hypothetical function of this protein is that it is an extracellular matrix binding …

A Convenient Synthesis Of 2,6-Dichlorohomonicotinic Acid, Chase Buchanan, Richard W. Fitch

Symposium 2012

In our synthetic efforts toward the alkaloid phantasmidine, we required a convenient source of the title compound. Herein, we describe a short synthesis of 2,6-dichlorohomonicotinic acid by direct allylation of 2,6-dichloropyridine with LDA/allyl chloride, followed by permanganate oxidation of the side chain [figure1]. Yields for the allylation are high, while permanganate oxidation required more adjustment. Successful conditions require the modest acidification of the mixture with acetic acid and cleanup by acid base workup. No chromatography is needed.

Convenient Parallel Synthesis Of Alkyl- And Aryl-S-Tert-Butyl Thiothers, Rebecca Norcross, Jessica Stanfield, Richard W. Fitch

Symposium 2012

While preparing novel cysteine derivatives as oxidation catalysts, we needed S-tert-butylcysteine. We also examined acid-promoted tert-butylation of thiols using tert-butanol as reagent and solvent. While cysteine and aminoethanethiol work well using tBuOH in 4M HCl, other thiols fail in the aqueous environment and aerobic conditions. We examined a variety of aliphatic and aromatic thiols in tBuOH with H2SO4 catalysis and found that argon sparging and the use of 1 eq of acid led to good yields in a parallel format.

Plasmonic Nanogel: Structure, Rheology, And Optical Properties, Georo Zhou

Renée Crown University Honors Thesis Projects - All

The invention of plasmonic nanogels (PNG) opens up the field of nanotechnology to a wide variety of applications such as, enhanced light trapping in solar cells, design of smart glasses, chemical detection, and optofluidic devices. In this work, it was determined that, the synthesis of a nanoparticle-micelle network in a fluid state is performed with the ability to suspend metal nanoparticles in a gel-like solution in a stable fashion. Furthermore, the stable suspension of the nanoparticles in the fluidic system allows the user to easily tune the PNG’s optical and rheological properties by controlling the concentration of the nanoparticles and …

Biomedical Properties And Preparation Of Iron Oxide-Dextran Nanostructures By Maple Technique, Carmen Steluta Ciobanu, Simona Liliana Iconaru, Eniko Gyorgy, Mihaela Radu, Marieta Costache, Anca Dinischiotu, Philippe Le Coustumer, Khalid Lafdi, Daniela Predoi

Chemical and Materials Engineering Faculty Publications

Background: In this work the chemical structure of dextran-iron oxide thin films was reported. The films were obtained by MAPLE technique from composite targets containing 10 wt. % dextran with 1 and 5 wt.% iron oxide nanoparticles (IONPs). The IONPs were synthesized by co-precipitation method. A KrF* excimer laser source (λ = 248 nm, τFWHM≅25 ns, ν = 10 Hz) was used for the growth of the hybrid, iron oxide NPs-dextran thin films.

Results: Dextran coated iron oxide nanoparticles thin films were indexed into the spinel cubic lattice with a lattice parameter of 8.36 Å. The particle sized calculated was …

Carbon Nanotubes Grown On Glass Fiber As A Strain Sensor For Real Time Structural Health Monitoring, Matthew Boehle, Qiong Jiang, Lingchuan Li, Alexandre Lagounov, Khalid Lafdi

Chemical and Materials Engineering Faculty Publications

In order to more effectively monitor the health of composite structures, a fuzzy fiber sensor has been developed. The fuzzy fiber is a bundle of glass fibers with carbon nanotubes or nanofibers (CNTs or CNFs) grown on the surface. The nanotube coating makes the fiber bundle conductive while the small conductive path increases sensitivity. The fuzzy fiber sensor can replace conventional metal foil strain gauges in composite applications. The electrical response of the sensor is monitored in real time to measure strain, vibration, cracking and delamination. Continuous monitoring provides instant notification of any problems. Implementation of this sensor network in …

Limited Thermal Conductance Of Metal-Carbon Interfaces, Jaime J. Gengler, Sergei V. Shenogin, John E. Bultman, Ajit K. Roy, Andrey A. Voevodin, Christopher Muratore

Chemical and Materials Engineering Faculty Publications

The thermal conductance for a series of metal-graphite interfaces has been experimentally measured with time-domain thermoreflectance (TDTR). For metals with Debye temperatures up to ∼400 K, a linear relationship exists with the thermal conductance values. For metals with Debye temperatures in excess of ∼400 K, the measured metal-graphite thermal conductance values remain constant near 60 MW m−2 K−1. Titanium showed slightly higher conductance than aluminum, despite the closeness of atomic mass and Debye temperature for the two metals. Surface analysis was used to identify the presence of titaniumcarbide at the interface in contrast to the aluminum and gold-carbon interfaces (with …