Engineering Commons^™

Effects Of Perforations On Internal Cathodic Protection And Recruitment Of Marine Organisms To Steel Pipes, Alexander John Paluzzi

Theses and Dissertations

Steel monopile support structures for offshore wind turbines require protection from corrosion on their external and internal surfaces. Cathodic protection (CP) works effectively to protect the external surfaces of monopiles, but internally, byproducts from aluminum sacrificial anode CP (SACP) and impressed current CP (ICCP) induce acidification that accelerates steel corrosion. This project investigated the effects of perforations on the performance of aluminum SACP and ICCP when used inside of steel pipes. Additionally, marine growth on the external and internal surfaces of the pipes was assessed to determine if CP byproducts affect marine organism development.

Two sealed and two perforated steel …

Ti-6al-4v Β Phase Selective Dissolution: In Vitro Mechanism And Prediction, Michael A Kurtz

All Dissertations

Retrieval studies document Ti-6Al-4V β phase dissolution within total hip replacement systems. A gap persists in our mechanistic understanding and existing standards fail to reproduce this damage. This thesis aims to (1) elucidate the Ti-6Al-4V selective dissolution mechanism as functions of solution chemistry, electrode potential and temperature; (2) investigate the effects of adverse electrochemical conditions on additively manufactured (AM) titanium alloys and (3) apply machine learning to predict the Ti-6Al-4V dissolution state. We hypothesized that (1) cathodic activation and inflammatory species (H₂O₂) would degrade the Ti-6Al-4V oxide, promoting dissolution; (2) AM Ti-6Al-4V selective dissolution would occur …

Mechanisms Contributing To Hydrogen-Influenced Early Failure Of Bridge Tendons, David Dukeman

USF Tampa Graduate Theses and Dissertations

Failures in post-tensioned tendons have occurred without warning due to fractures in the high-strength steel strands. These strands are cold-drawn to increase their strength while still retaining the preferential ductile mode of fracture. Recently, a tendon failure that occurred in an upper deviation block of the I-526 James B. Edwards bridge crossing the Wando river showed signs of corrosion and potentially another method of failure, hydrogen embrittlement. One proposed source of hydrogen is through galvanic coupling that may exist between the galvanized steel duct and the steel strands. This coupling, if substantial, can promote hydrogen evolution at the steel strand's …

Corrosion Of Oil Pipeline: A Case Study On The Niger Delta Region Of Nigeria., Victor U. Okoro

Corrosion Research

Corrosion of oil pipelines in Nigeria, particularly in the Niger Delta region, has extensive and detrimental environmental and societal impacts. This issue results in substantial financial losses and reputational damage for oil companies operating in the area. Local communities suffer economically, affecting agriculture and food security. Furthermore, corrosion-related oil spills lead to air quality degradation by releasing volatile organic compounds and greenhouse gases, contributing to respiratory issues and worsening climate change.

These oil spill cleanups are costly and time-consuming, with estimated expenses reaching billions of dollars. Using the Nembe Creek Trunk Line (NCTL) case study, it is evident that addressing …

Evaluation Of Residual Flexural Behavior Of Corroded Fiber-Reinforced Super Workable Concrete Beams, Jingjie Wei, Nima Farzadnia, Alfred Addai-Nimoh, Kamal Khayat

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

This Study Investigates the Effect of Macro Synthetic Fiber (MSF) Volume and Crack Widths on Corrosion of the Reinforcing Bars and Residual Flexural Behavior of Fiber-Reinforced Super-Workable Concrete (FR-SWC) Beams Exposed to Accelerated Corrosion. FR-SWC Beams Prepared with 0, 0.33%, and 0.66% MSF Were Pre-Cracked at 0.2-, 0.4-, and 0.75-Mm Widths Before Corrosion Testing. the Controlled Crack Width Was Initiated in One Set of Beams that Were Then Unloaded. the Crack Width Was Maintained for Another Set of Beams during Corrosion Testing by Inserting a Shim. Test Results Showed that the Use of 0.33% and 0.66% MSF Reduced Crack Development …

Corrosion Related To The Nuclear Waste Containers, Ali Ebrahimzadeh Pilehrood

Corrosion Research

The disposal of nuclear waste is a demanding topic, and the existing methods, whether it is temporary storage in spent fuel pools or storage in geological repositories, both face the risk of corrosion-related problems. Any failure in these storage methods can potentially lead to the release of radioactive materials into the environment. To avert such catastrophic scenarios, people in the nuclear industry consistently monitor and maintain these storage facilities endlessly and attempt to improve the plans designed to store nuclear waste. Here, I will examine the nuclear waste management organization (NWMO) plan in Canada. Choosing an appropriate location for the …

Corrosion Case Study On Pipeline, Kangze Ren

Corrosion Research

The Kashagan pipeline leaks were likely caused by sulfur stress corrosion cracking, a combined corrosion mechanism developed by the presence of high pressure, the high level of hydrogen sulfide(the main "ingredient" of sour gas), and poor metallurgical choice. Improper welding and poor metallurgical examination were blamed for causing the leaking issue. The purpose of the current review is to raise the alarm about the inappropriate corrosion management of Kashagan oil production and its societal and environmental consequences.

Application Of Wavelet Analysis And Random Field In Integrity Management Of Pipelines Containing Dents And Corrosions, Junxiong Lin

Electronic Thesis and Dissertation Repository

Metal loss corrosions and dents are two major threats to the integrity of oil and natural gas pipelines. In the pipeline industry, the Fitness-For-Service (FFS) assessment is commonly employed for pipelines containing these defects. However, FFS assessment usually assumes that a defect has a simple shape, and such a simplification may significantly affect the accuracy of the assessment. Therefore, retaining the actual shapes of defects and incorporating them into the FFS assessment can improve assessment accuracy. The main objective of the present thesis is to extract key information about the sizes, directions, and shapes of corrosions and dents from the …

Predicting Corrosion Damage In The Human Body Using Artificial Intelligence: In Vitro Progress And Future Applications Applications, Michael A. Kurtz, Ruoyu Yang, Mohan S. R. Elapolu, Audrey C. Wessinger, William Nelson, Kazzandra Alaniz, Rahul Rai, Jeremy L. Gilbert

Publications

Artificial intelligence (AI) is used in the clinic to improve patient care. While the successes illustrate the impact AI can have, few studies have led to improved clinical outcomes. A gap in translational studies, beginning at the basic science level, exists. In this review, we focus on how AI models implemented in non-orthopedic fields of corrosion science may apply to the study of orthopedic alloys. We first define and introduce fundamental AI concepts and models, as well as physiologically relevant corrosion damage modes. We then systematically review the corrosion/AI literature. Finally, we identify several AI models that may be Preprint …

Extending The Service-Life Of Bridges Using Sustainable And Resilient Abutment Systems: An Experimental Approach To Electrochemical Characterization Of Lightweight Mechanically Stabilized Earth, Fariborz M. Tehrani, Kenneth L. Fishman, Farmehr M. Dehkordi

Mineta Transportation Institute Publications

Bridges are critical components of transportation infrastructure. This research addresses the need to extend the service life of bridges by improving the safety and reliability of bridge abutments and reducing their life-cycle cost and footprints. Mechanically stabilized earth (MSE) is a known strategy to enhance the economy and performance of bridge abutments. In addition, the application of rotary-kiln-manufactured lightweight aggregate backfills improves the performance of MSE bridge abutments with a leaner structural system. Such improvements include a reduction of structural demands due to a lower density, free drainage of granular materials, a high internal friction angle, less settlement with no …

The Influence Of Bio-Inhibitor On The Corrosion Resistance Of Reinforced Concrete Beams Containing Mswi-Ba As A Partial Sand Replacement, Jamal Khatib, Israa Amer, Ghanem Hassan, Adel Elkordi

BAU Journal - Science and Technology

In this paper, the corrosion behavior of reinforced concrete beams containing municipal solid waste incineration bottom ash (MSWI-BA) as a partial sand replacement and Ceratonia siliqua extract as a green corrosion inhibitor was investigated. Four mixes were prepared: (0 and 20% replacement of sand by MSWI-BA with and without Ceratonia siliqua extract). Tests conducted were UPV, compressive strength, split tensile strength, and elastic modulus. RC beams were prepared for determining the flexural performance. Eight beams were casted. Four beams were exposed to accelerated corrosion test and four beams were kept at room temperature. It was found that the compressive strength, …

Coating Condition Detection And Assessment On The Steel Girder Of A Bridge Through Hyperspectral Imaging, Pengfei Ma, Jiaoli Li, Ying Zhuo, Pu Jiao, Genda Chen

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The organic coating of bridge steel girders is subjected to physical scratches, corrosion, and aging in natural weathering. The breakdown of the coating may cause serviceability and safety problems if left unnoticed. Conventional coating inspection is time-consuming and lacks information about the coating's chemical integrity. A hyperspectral imaging method is proposed to detect the condition of steel coatings based on coating-responsive features in reflectance spectra. A field test was conducted on the real-world bridge, which shows obvious signs of degradation. The hyperspectral signature enables an assessment of the coating's health and defect severity. The results indicated that the coating scratch …

Hydrothermal Liquefaction (Htl) Of Lignocellulosic Biomass For Biocrude Production: Reaction Kinetics And Corrosion-Resistance Performance Of Candidate Alloys For Reactors, Haoyu Wang

Electronic Thesis and Dissertation Repository

In recent years, the rapid increase in the demand for clean energy and green chemicals as well as concerns over the supply and environmental impacts associated with fossil. resources have stimulated intensive research on conversion of bioresources, such as lignocellulosic biomass and biowaste, into energy, fuels, chemicals, and materials.

Hydrothermal liquefaction (HTL) is a unique thermochemical conversion process, particularly applicable for the conversion of wet biomass and biowaste feedstocks. Most of the biomass HTL studies are conducted in batch reactor and focus on the effects of catalysts, reaction temperature and time on production efficiency and chemical properties of the products. …

Analysis Of Ternary Chloride Salt Corrosion In High Nickel Alloys, Dimitri Madden, Gowtham Mohan

Mechanical Engineering ETDs

The United States Department of Energy seeks to improve the efficiency of concentrating solar power technologies by employing thermal energy storage with operating temperatures above 700°C. To meet these goals, the National Solar Thermal Test Facility at Sandia National Laboratories has considered the use of a ternary molten chloride salt for sensible heat storage systems. While favored for low cost, good heat transfer properties, and stability at high temperature, ternary chloride salt also exhibits high corrosive attack. Components of a chloride salt storage system would include piping, valves, tanks, pumps, receivers, and heat exchangers, which would be exposed to high …

Self-Assembly Of Exfoliated Graphene Flakes As Anticorrosive Coatings For Additive Manufactured Steels, Kaleb Hood, Wen Qian, Yi Xia, Savannah Krupa, Annie Dao, Sarah Ahmed, Samuel Olson, Nam Nguyen, Joseph A. Turner, Jun Jiao

Department of Mechanical and Materials Engineering: Faculty Publications

This study demonstrates the feasibility of using liquid exfoliation of expandable graphite into multilayer exfoliated graphene flakes (EGFs) to form a self-assembled thin film on an air–water interface. The film can coat the surface of additive manufactured (AM) steel substrates to enhance surface properties, specifically AM 316 stainless-steel (AM316), AM 8620 steel (AM8620), and samples of the same alloys made by conventional manufacturing (CM) processes. Liquid exfoliation offers a high yield route for an EGF coating that can cover up to 95% of the sample surface with a single application. The thin, flexible EGFs can coat a rough AM metal …

Estimating Remaining Life And Fitness-For-Services Evaluation Of Fuel Piping Systems, Sekar Putri Purwidyasari, Ahmad Isni Kurniawan, Deni Ferdian

Journal of Materials Exploration and Findings (JMEF)

Assets life extension are required to predict the design life expiry based on condition and effects of deterioration. The remaining life assessment will answer the questions about timing of the component or equipment will lead to failure and shall be evaluated by inspection and maintenance monitoring. This study elaborates process calculation and analysis by using remaining life assessment and fitness for services method according to API 579-1/ASME FFS-1 for process piping area. The result of remaining useful life estimation and estimated life has been proposed. There are 11 piping systems based on the condition monitoring with thickness measurements. The result …

The Study Of Corrosion On Additive-Manufactured Metals., Braydan Daniels

Electronic Theses and Dissertations

The purpose of this study was to investigate and compare the corrosion mechanisms between wrought and additive-manufactured (3D-printed) copper and stainless steel. The experimental procedure consisted of measuring the open circuit potential, electrochemical impedance spectroscopy, linear sweep voltammetry, Tafel analysis, surface topology, and scanning electron microscopy for each metal within salt water, tap water, sulfuric acid, and synthetic body fluid (excluding copper in synthetic body fluid).

Overall, printed stainless steel was more corrosion-resistant than wrought stainless steel in tap water and synthetic body fluid based on OCP, LSV, and surface topology results. Additionally, printed copper was more corrosion-resistant than wrought …

Surface Corrosion Response Of Al Alloys A383 And Aural 2 With Ce Additions In Aqueous Nacl And Salt-Fog Environments, Michael James Thompson

Masters Theses

Copper is commonly used in aluminum alloys to increase its strength by solid solution and precipitation strengthening, however, the corrosion resistance is inversely related to the amount of copper in the alloy. Over 70 percent of material used to produce aluminum alloys in the US come from recycled (secondary) alloys, many of which have a copper content of more than one percent by weight. Alloys with tightly controlled tolerances, where copper is seen as an impurity, are unable to utilize many of the recycling feedstock without adding newly processed (primary) aluminum to dilute impurities to within specifications. Primary aluminum is …

Corrosion Case Study On Automobile, Grace Ajayi, Xinran Pan, Geethu Sasikala, Marshall S. Yang

Chemistry Publications

No abstract provided.

Mineralogical Evidence Of Alkaline Corrosion Of Montmorillonite In Gmz Bentonite, Yan-Mei Tong, Hu-Yuan Zhang, Guang-Ping Zhou, Xiao-Ya Li

Rock and Soil Mechanics

During the operation of underground repository of high-level radioactive waste, the highly alkaline solution generated by groundwater corroding lining concrete will diffuse into the bentonite buffer barrier, resulting in the degradation of barrier property. The KOH solution with different pH values was used to simulate the alkaline solution, and a one-year contact diffusion test at room temperature was conducted. Then, X-ray fluorescence spectroscopy (XRF), X-ray diffraction (XRD), scanning electron microscope (SEM) and energy dispersive spectrometry (EDS) were performed to investigate the effect of slow diffusion on the mineralogy of bentonite. The XRF test results show that when the pH of …

Development Of Battery Materials To Function As Corrosion Protection On Car Body Plates, Tubagus Noor Rohmannudin, Sulistijono Sulistijono, Noval Adrinanda, Faridz Wira Dharma, Samuel Areliano

Journal of Materials Exploration and Findings (JMEF)

Most car bodies made for mass production are made from steel or aluminum. Both are strong metals, but steel is cheaper than aluminum and is more commonly used in lower-end cars for a broader consumer range. The weakness of steel compared to aluminum is that it is susceptible to corrosion under certain conditions, and thus it may deteriorate over time without proper care. To prevent corrosion, modern cars are coated with paint to prevent direct contact with the environment. As a second line of protection, a car battery can be connected to the body to create an impressed current cathodic …

Revised Load Rating Procedures For Deteriorated Prestressed Concrete Beams, Alex Stripsky, Sergio F. Brena, Jessica Boakye, Scott A. Civjan, Simos Gerasimidis

Structural Engineering and Mechanics Research Reports

The first prestressed concrete bridge in the United States was built in the early 1950s. Since then, several typical sections have been developed for use in bridge construction including I-beams, deck slabs, box beams, double tees, etc. In bridges under aggressive environments, corrosion deterioration of prestressing strands and stirrups has occurred creating challenges associated with determining the strength of deteriorated existing bridge sections. The MassDOT LRFD Bridge Manual includes provisions to estimate strength of corrosion deteriorated prestressed concrete box beams allowing engineers to calculate the load rating of these types of bridges. The provisions are based on the observed condition …

Investigation Of Oxidation And Corrosion Resistance Of Ni-Based Alloys And Stainless Steels Under Co2 Environments At Elevated Temperatures, Spencer Roy Fultineer

Graduate Theses, Dissertations, and Problem Reports

High mechanical strength integrity, high robustness towards oxidation, and high resistance to carburization under CO2 environments at elevated temperatures are usually required for metallic systems that are employed for power generation. INCONEL 625 is a nickel-based superalloy that started development in the 1950s. This material was designed with the distinct purpose of use in high-temperature and high-pressure systems. While various materials possess the physical properties to handle these conditions, the creation of IN625 addresses the need for a material to withstand the highly corrosive properties of these kinds of environments. In order to evaluate the oxidation and corrosion resistance of …

Corrosion Behavior And Mechanism Of Laser Powder Bed Fusion Produced Cocrw In An Acidic Nacl Solution, P. Qin, L. Y. Chen, Y. J. Liu, C. H. Zhao, Hongqi Sun, Laichang Zhang

Research outputs 2022 to 2026

The corrosion behavior and mechanism of the laser powder bed fusion (L-PBF) produced CoCrW were investigated in 0.9 wt% NaCl solution with a pH of 2. The corrosion resistance of the alloy increases after 28 days of immersion because of the formed oxide film, which results in the increased corrosion potential and the decreased passivation current density on the potentiodynamic polarization test. The corrosion mechanism of the L-PBF-produced CoCrW could be explained by the melt pool formed from the laser melting process, that the melt pools were “shrinking” by the formation and dissolution of the oxide film.

Intergranular And Pitting Corrosion Mechanisms Of Sensitized Aluminum Alloy Aa5083, Clayton Egleston

Williams Honors College, Honors Research Projects

The motivation and objectives of this project is to examine the mechanisms of intergranular corrosion (IGC) and pitting corrosion of sensitized AA5083. In this regard, different characterization techniques were used, including optical analysis of microstructure, cyclic potentiodynamic polarization with Tafel fitting, electrochemical impedance spectroscopy with electrical equivalent circuit (EEC) fitting, and potentiostatic current transient monitoring. The transition from IGC to pitting corrosion occurs when the grain boundaries become saturated with the β-phase (Mg₂Al₃). It was found that AA5083 becomes more vulnerable to pitting corrosion as the degree of sensitization increases.

Corrosion Behavior And Mechanisms Of The Heat-Treated Ti5cu Produced By Laser Powder Bed Fusion, Xin Wang, Peng Qin, L. Y. Chen, Hongqi Sun, Laichang Zhang

Research outputs 2022 to 2026

This work investigated the corrosion behavior of laser powder bed fusion produced (LPBFed) Ti5Cu and its heat-treated counterparts at 740 and 900 °C (named as HT-740 and HT-900 respectively) in Hank’s solution. The results indicated that the presence of acicular a'-Ti phase in LPBFed Ti5Cu was beneficial to corrosion, but the corrosion resistance of HT-740 and HT-900 were increased owing to the dual-phase microstructure (a'/a-Ti + Ti2Cu) or the increased content of Ti2Cu phase in the microstructure. The Ti2Cu phase could provide an ‘envelope’ protection to the a'/a-Ti phase and slow down the micro-galvanic reaction between a'/a-Ti phase and Ti2Cu …

Near-Ir Laser Ablation Of Simulated Radiologically Contaminated Oxides On Carbon Steel Feeder Pipes, Thao Viet Do

Electronic Thesis and Dissertation Repository

As nuclear power plants age and retire from service, many countries face significant challenges concerning the safe long-term storage and disposal of large volumes of low and intermediate level radioactive wastes (L&ILW). The volumes of metallic waste are of particular concern, as when metal corrodes it produces hydrogen that could lead to pressure build-up in interim storage and disposal. In Canada, a significant fraction of the metallic wastes for Canada Deuterium Uranium (CANDU) nuclear reactors are out-of-core reactor components, such as carbon steel (CS) feeder pipes. The radioactive contamination is expected to be largely confined to the surface oxide layers …

Seismic Performance Of Ductile Corrosion-Free Reinforced Concrete Frames, Mohamed Meshaly, Maged A. Youssef, Ahmed Elansary

Civil and Environmental Engineering Publications

Corrosion of steel bars is the main cause of the deterioration of reinforced concrete (RC) structures. To avoid this problem, steel rebars can be replaced with glass-fiber-reinforced-polymer (GFRP). However, the brittle behaviour of GFRP RC elements has limited their use in many applications. The use of shape memory alloy (SMA) and/or stainless steel (SS) rebars can solve this problem, because of their ductile behaviour and corrosion resistance. However, their high price is a major obstacle. To address issues of ductility, corrosion, and cost, this paper examines the hybrid use of GFRP, SS, and SMA in RC frames. The use of …

Understanding Charge Effects On Marked Ball Wear Rates – A Corrosion Study, John Bailey Fletcher

Masters Theses

"To measure the wear rates of grinding balls within a ball mill, marked ball wear tests (MBWTs) have been used extensively. Using the wear rates from a MBWT, operators select the most cost-effective media for their grinding application. One factor that a MBWT does not account for is the possible interaction between different media materials which could affect their corrosion rates. Galvanic coupling between dissimilar metals can cause significant changes in their corrosion rates. While galvanic interactions between minerals and grinding media have been studied, the interaction between dissimilar media has not. Corrosion rates and potentials of modern high carbon …

Joining Of Candidate Materials For Lead-Cooled Fast Reactors, Brandon M. Bohanon

Nuclear Engineering ETDs

The lead-cooled fast reactor (LFR) is a fourth-generation reactor design characterized by high temperatures, neutron dosage, and highly corrosive and erosive environment due to high flow velocities. Therefore, materials testing must be performed to find structural and system components that withstand this harsh environment. These candidate alloys must have high-temperature creep strength, resistance to damage from fast-spectrum neutrons, and must grow protective oxide layers. FeCrAl alloys have been identified as possessing all these qualities, however, there are limitations due to erosion and the joining of these materials. In this work, mechanical and microstructural properties of base and conventionally joined FeCrAl-based …