Engineering Commons^™

Evaluation Of Residual Flexural Behavior Of Corroded Fiber-Reinforced Super Workable Concrete Beams, Jingjie Wei, Nima Farzadnia, Alfred Addai-Nimoh, Kamal Khayat

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

This Study Investigates the Effect of Macro Synthetic Fiber (MSF) Volume and Crack Widths on Corrosion of the Reinforcing Bars and Residual Flexural Behavior of Fiber-Reinforced Super-Workable Concrete (FR-SWC) Beams Exposed to Accelerated Corrosion. FR-SWC Beams Prepared with 0, 0.33%, and 0.66% MSF Were Pre-Cracked at 0.2-, 0.4-, and 0.75-Mm Widths Before Corrosion Testing. the Controlled Crack Width Was Initiated in One Set of Beams that Were Then Unloaded. the Crack Width Was Maintained for Another Set of Beams during Corrosion Testing by Inserting a Shim. Test Results Showed that the Use of 0.33% and 0.66% MSF Reduced Crack Development …

Coating Condition Detection And Assessment On The Steel Girder Of A Bridge Through Hyperspectral Imaging, Pengfei Ma, Jiaoli Li, Ying Zhuo, Pu Jiao, Genda Chen

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The organic coating of bridge steel girders is subjected to physical scratches, corrosion, and aging in natural weathering. The breakdown of the coating may cause serviceability and safety problems if left unnoticed. Conventional coating inspection is time-consuming and lacks information about the coating's chemical integrity. A hyperspectral imaging method is proposed to detect the condition of steel coatings based on coating-responsive features in reflectance spectra. A field test was conducted on the real-world bridge, which shows obvious signs of degradation. The hyperspectral signature enables an assessment of the coating's health and defect severity. The results indicated that the coating scratch …

Understanding Charge Effects On Marked Ball Wear Rates – A Corrosion Study, John Bailey Fletcher

Masters Theses

"To measure the wear rates of grinding balls within a ball mill, marked ball wear tests (MBWTs) have been used extensively. Using the wear rates from a MBWT, operators select the most cost-effective media for their grinding application. One factor that a MBWT does not account for is the possible interaction between different media materials which could affect their corrosion rates. Galvanic coupling between dissimilar metals can cause significant changes in their corrosion rates. While galvanic interactions between minerals and grinding media have been studied, the interaction between dissimilar media has not. Corrosion rates and potentials of modern high carbon …

Wavelet Power And Shannon Entropy Applied To Acoustic Emission Signals For Corrosion Detection And Evaluation Of Reinforced Concrete, Jinrui Zhang, Ziye Kang, Dongshuai Hou, Biqin Dong, Hongyan Ma

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Acoustic emission (AE) signals detected from corrosion test on a steel reinforced concrete beam subjected to the coupling effects of corrosive wet-dry cycles and static load are analyzed by power spectral density, wavelet transform, and Shannon entropy. The degradation process of the corroded reinforced concrete beam can be divided into four stages on the basis of the accumulated event number (AEN). Due to the difference of material properties, steel reinforcement and concrete matrix have distinguished AE features. The time-frequency characteristics of AE signals can reflect the microstructural degradation mechanism of steel corrosion and concrete cracking. The corrosion evaluation entails investigating …

Corrosion Protection Mechanisms Of Trivalent Chromium Based Passivations On Γ-Znni Coated Al6061-T6 Alloy, Kevin Foster

Doctoral Dissertations

“The role of cobalt in trivalent chromium passivations (TCPs) to improve corrosion resistance of γ-ZnNi coated steel and aluminum is based on its effect on hexavalent chromium content in the passive layer. Investigations of both a cobalt-containing and cobalt-free TCP on SAE 1008 steel indicated that both passivations protect well for up to 1000 hours in neutral salt spray exposure (SSE). A repetition on Al 6061-T6 alloy indicated that TCP performed much better than cobalt-free TCP implicating the underlying substrate. Optical and electron micrographs indicated physical changes such as crack thickness, crack density, passivation porosity, and passivation thickness existed between …

A Review On Alpha Case Formation And Modeling Of Mass Transfer During Investment Casting Of Titanium Alloys, R. Sharon Uwanyuze, Janos E. Kanyo, Sarah F. Myrick, Stefan Schafföner

Materials Science and Engineering Faculty Research & Creative Works

Titanium alloys have excellent corrosion resistance, high temperature strength, low density, and biocompatibility. Therefore, they are increasingly used for aerospace, biomedical, and chemical applications. Investment casting is a well-established process for manufacturing near-net-shape intricate parts for such applications. However, mass transfer arising from metal-mold reactions is still a major problem that drastically impairs the surface and properties of the castings. Although there have been astounding developments over the past 20 years, they remain scattered in various research papers and conference proceedings. This review summarizes the current status of the field, gaps in the scientific understanding, and the research needs for …

Prediction On Service Life Of Concrete Pipeline Buried In Chlorinated Environment Under Nonuniformly Distributed Earth Pressure, Lin Li, Weibing Gong, Jingpei Li

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

This paper proposes an analytical model to estimate the service life of concrete pipelines buried in chloride contaminated soils, which properly considers the effects of nonuniformly distributed earth pressures on both the internal tensile stress of concrete protective cover and the chloride diffusion coefficient through the nonhomogeneous coefficient of earth pressure. It is assumed that the underground concrete pipeline arrives at the service life end when cracking induced by expansion pressure due to the corrosion products occurs in the concrete protective cover. Hence, the whole service life of underground concrete pipeline is composed of chloride diffusion period and protective cover …

Bridge Resilience Assessment With Inspire Data, Iris Tien, Yijian Zhang

Project RR-1

This project proposed a methodology to assess the impact of corrosion on the performance of bridges. The combined analytical and numerical modeling of shear-critical and lap-spliced columns is detailed, and outcomes are verified with previous experimental test data. The impact of corrosion on risk is assessed through conducting fragility analyses. Results quantify the increase in failure probabilities of these structures, measured by increasing probabilities of exceeding defined damage states, with increasing levels of corrosion. Corrosion is found to have a larger impact on increasing probabilities of exceeding more severe damage states. Twenty percent mass loss of reinforcement increases the probability …

Microwave Detection Of Surface Breaking Cracks In Metallic Structures Under Heavy Corrosion And Paint, John Robert Gallion

Masters Theses

"We live in the world of "aging infrastructures". In this environment, critical and heavily utilized infrastructure, i.e. ships, planes, bridges, etc., are operating at or beyond their designed age. Replacement is no longer an option and "retirement for cause" is the current approach to maintenance and replacement. Consequently, there is an ever-increasing demand for efficient and robust nondestructive evaluation (NDE) methods that can determine the physical health of these structures. Large structures, which are primarily made of metals, either steel or aluminum, are susceptible to high-stress cracking and corrosion. Stress-induced cracks in heavily corroded steel, used in bridges, railroads, storage …

Spatial Delineation Of Corrosion Zones For Metal Culverts Based On Coastal Louisiana Soil Characteristics, Sanjay Tewari, Francis Manning

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Corrosion of metal pipes used as culverts is a problem that affect many agencies directly involved in designing and maintaining these culverts. The corrosive environment of soil types found in a region could vary in a significant way (mildly corrosive to extremely corrosive) based on soil characteristics. Environmental conditions such as high water table, acidity and presence of various salts could make a soil corrosive to metal pipes. In this article, authors have applied a methodology of processing readily available soil data such as spatial distribution of soil types and soil characteristics (e.g. pH and conductivity) in delineating spatial corrosion …

Corrosion Performance Of Zirconium-Based Passivations On Electroplated Zinc Nickel, Madison Morgan Reed

Masters Theses

“Performance requirements for Department of Defense (DoD) electrical components include corrosion and electrical contact resistance. Historically, electroplated cadmium with a chromate conversion coating (CrCC) has been used to meet corrosion and contact resistance standards. However, replacements are needed for these materials because they are toxic and carcinogenic. Electroplated γ-ZnNi has been identified as an acceptable alternative to Cd. This study evaluated commercially available Zr-based thin films and sealers as passivations for potential replacement of CrCCs. Ten different passivations were tested and compared with bare γ-ZnNi. X-Bond and Zircobond passivations were found to provide some improvement to the bare ZnNi corrosion …

Identifying Corrosion Zones In Coastal Regions For Metal Pipes -- A Gis Approach, Sanjay Tewari, Francis Manning

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Transportation agencies often allow metal pipes as an option for cross drains under/along roads and highways. Metal culverts can corrode over time at various rates based on their environmental conditions (e.g., corrosive nature of coastal soils, high water table and saltwater intrusion). This paper focuses on applying readily available soil data such as spatial distribution of soil types and soil characteristics (e.g., pH and conductivity) towards creating a geospatial information system (GIS) based approach to identifying corrosion zones in the coastal regions. A combination of data, obtained from field surveys provided by the Louisiana Transportation Research Center and Web Soil …

Corrosion Map For Metal Pipes In Coastal Louisiana, Sanjay Tewari

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Transportation agencies often allow metal pipes as an option for cross drains under/along roads and highways. Metal culverts can corrode over time at various rates based on their environmental conditions (e.g., corrosive nature of coastal soils, high water table, and saltwater intrusion).

This project was focused on applying available soil data, such as spatial distribution of soil types and soil characteristics (e.g., pH and conductivity), towards creating a Geographic Information System (GIS) based map to identify corrosion zones in coastal Louisiana. The effect of the soil characteristics (pH and conductivity) was incorporated in to the published corrosion models for calculating …

Evaluation Of Non-Chromate Passivations On Electroplated Γ-Phase Zinc Nickel, Steven Michael Volz

Masters Theses

"This research focused on the corrosion response and electrochemical behavior of electroplated low hydrogen embrittlement alkaline γ-phase zinc nickel with passivation layers. The motivation was the need to replace hexavalent chromium conversion coatings in military grade electrical systems with a more environment friendly alternative. The passivation layers were employed for the purpose of mitigating corrosion attack while maintaining low contact resistance. Trivalent chromium-based passivations and cerium-based passivations were compared against the currently used hexavalent chromium conversion coating. The coating systems were compared using electrochemical impedance spectroscopy, cyclic potentiodymanic scans, salt spray exposure testing, electrical resistance measurements, microstructure analysis, and compositional …

Weak Magnetic Field Accelerates Chromate Removal By Zero-Valent Iron, Pian Feng, Xiaohong Guan, Yuankui Sun, Wonyong Choi, Hejie Qin, Jianmin Wang, Junlian Qiao, Lina Li

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Weak magnetic field (WMF) was employed to improve the removal of Cr(VI) by zero-valent iron (ZVI) for the first time. The removal rate of Cr(VI) was elevated by a factor of 1.12-5.89 due to the application of a WMF, and the WMF-induced improvement was more remarkable at higher Cr(VI) concentration and higher pH. Fe2+ was not detected until Cr(VI) was exhausted, and there was a positive correlation between the WMF-induced promotion factor of Cr(VI) removal rate and that of Fe²⁺ release rate in the absence of Cr(VI) at pH 4.0-5.5. These phenomena imply that ZVI corrosion with Fe^{2+ …}

Phosphate-Doped Borosilicate Enamel Coating Used To Protect Reinforcing Steel From Corrosion, Xiaoming Cheng

Doctoral Dissertations

"Phosphate-doped sodium borosilicate glasses were developed for enamel coatings to provide corrosion protection for reinforcing steel in concrete. Phosphates have low solubilities in borosilicate glasses, generally less than about 4 mol%, and are incorporated mainly as isolated PO₄^3- and P₂O₇^4- anions, along with some borophosphate bonds. With the addition of P₂O₅, the silicate network is repolymerized and tetrahedral borates are converted to trigonal borates, because the phosphate anions scavenge sodium ions from the borosilicate network. The addition of Al₂O₃ significantly increases the solubility of P₂O …

Application Of Millimeter Wave, Eddy Current And Thermographic Methods For Detection Of Corrosion In Aluminum Substrate, Mohammad Tayeb Ahmad Ghasr, Adam C. Ryley, Sergey Kharkovsky, R. Zoughi, Gary Steffes

Electrical and Computer Engineering Faculty Research & Creative Works

Aluminum structures exposed to the elements are susceptible to corrosion. Corrosion may cause various mechanical and structural deficiencies such as material thinning. It is desirable to rapidly detect and evaluate the properties of an aluminum substrate early in the corrosion process to avoid costly maintenance actions later. There are several nondestructive testing methods for this purpose. To investigate capabilities of millimeter wave, conventional eddy current, and flash thermography techniques for detection of large corrosion areas in aluminum substrates, two corroded samples were inspected with and without dielectric coating (appliqué). This paper presents the results of the c-scan imaging of these …

Evaluation Of Microwave Reflection Properties Of Cyclically Soaked Mortar Based On A Semiempirical Electromagnetic Model, Shanup Peer, K. E. Kurtis, R. Zoughi

Electrical and Computer Engineering Faculty Research & Creative Works

Detection of chloride ingress and evaluation of its distribution and temporal movement in reinforced concrete structures is an important practical issue. Steel reinforcing bars embedded in good quality concrete are normally protected from corrosion. However, the presence of a sufficient concentration of free chloride ions in the region of the reinforcing steel can initiate the process of corrosion. Therefore, it is important to be able to detect ingress of chloride ions and their distribution in cement-based materials. Moreover, it is important to obtain this information nondestructively. In recent years, near-field microwave nondestructive evaluation methods, using open-ended rectangular waveguide probes, have …

Comparison Of Near-Field Millimeter-Wave Probes For Detecting Corrosion Precursor Pitting Under Paint, Mohammad Tayeb Ahmad Ghasr, Sergey Kharkovsky, R. Zoughi, Russell A. Austin

Electrical and Computer Engineering Faculty Research & Creative Works

Aircraft structural components such as wings and fuselages are constantly exposed to harsh environments, which make them susceptible to corrosion initiation and growth. To complicate matters, corrosion is normally hidden under paint and primer and cannot be visually detected until significant corrosion has occurred, causing the paint to blister. Corrosion of this type is usually preceded by the presence of corrosion precursor pitting. Hence, early detection of pitting is a critical issue in the maintenance of an aircraft and its structural components. Near-field microwave nondestructive testing techniques have been successfully used for detection of corrosion under paint, including very small …

Electromagnetic Modeling Of Saltwater Ingress In Mortar At Microwave Frequencies, Shanup Peer, R. Zoughi, K. E. Kurtis

Electrical and Computer Engineering Faculty Research & Creative Works

Corrosion of reinforcing steel is a major cause of damage and deterioration in reinforced concrete structures. Therefore, as the presence of a sufficient concentration of chloride ions can lead to the onset of corrosion in embedded steel, it is of utmost importance to be able to determine the free salt content and its distribution in these materials. Moreover, it is important to obtain this information nondestructively. Previous investigations have shown the capability of near-field microwave nondestructive evaluation methods, using open-ended rectangular waveguide probes, to evaluate many important properties of cement-based materials. In this Investigation, the temporal microwave reflection properties of …

Microwave Reflection And Dielectric Properties Of Mortar Subjected To Compression Force And Cyclically Exposed To Water And Sodium Chloride Solution, Shanup Peer, Joseph Toby Case, Eric Gallaher, K. E. Kurtis, R. Zoughi

Electrical and Computer Engineering Faculty Research & Creative Works

Corrosion of the reinforcing steel is a major cause of damage and deterioration in reinforced concrete structures such as concrete bridge decks and columns. Chloride intrusion into concrete can lead to depassivation of the steel and initiation of corrosion. Thus, it is very important to be able to nondestructively detect and evaluate the free chloride content in concrete. Near-field microwave nondestructive testing techniques, using open-ended rectangular waveguide probes, have shown great potential for evaluating various properties of concrete, including the successful detection of sodium chloride added to mortar mixing water. In this study, several mortar samples are cyclically soaked in …

The Anodic Dissolution Of Tungsten, James W. Johnson, Cheng-Hsiao Wu

Chemical and Biochemical Engineering Faculty Research & Creative Works

The anodic dissolution of tungsten was studied in H₂SO₄-K₂SO₄ solutions (pH = -2 to 2.5) and K₂SO₄-K₂CO₃-KOH solutions (pH = 11.5 to 14.5) at 25 C. Faradaic efficiency studies in basic solutions showed the metal to be oxidized to the +6 state. In acid solutions, a thick protective film of yellow WO₃ was formed. Polarization curves possessed linear Tafel regions (slope ~ 2.3 RT/F) at potentials slightly more positive than the rest potentials. An anodic dissolution mechanism is proposed which involves a surface film …