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Articles 1 - 9 of 9

Full-Text Articles in Engineering

Corrosion And Passivation Behavior Of Laser Powder Bed Fusion Produced Ti-6al-4v Under Various Prior Plastic Deformation Strains, P. Qin, L. Y. Chen, Y. J. Liu, S. X. Liang, H. Sun, L. C. Zhang Apr 2024

Corrosion And Passivation Behavior Of Laser Powder Bed Fusion Produced Ti-6al-4v Under Various Prior Plastic Deformation Strains, P. Qin, L. Y. Chen, Y. J. Liu, S. X. Liang, H. Sun, L. C. Zhang

Research outputs 2022 to 2026

This work investigated the corrosion behavior of LPBF-produced Ti-6Al-4V under varying compression strains in a 3.5 wt% NaCl solution. It identifies that increasing compression strain causes significant alterations in the acicular a'-Ti phase (coarsening, breakage, and further coarsening). Corrosion resistance decreases with higher strains due to deformed a'-Ti phases, leading to increased film growth kinetics (from 0.09× 10−10 cm2/s increase to 12.75 × 10−10 cm2/s). Samples under higher strains (e.g., 32%) exhibit fluctuations in corrosion behavior due to initiated cracks and subsequent crevice corrosion. These findings are vital for understanding LPBF-produced Ti-6Al-4V in applications requiring mechanical strength and corrosion resilience.


Corrosion Behavior And Mechanism Of Laser Powder Bed Fusion Produced Cocrw In An Acidic Nacl Solution, P. Qin, L. Y. Chen, Y. J. Liu, C. H. Zhao, Hongqi Sun, Laichang Zhang Jan 2023

Corrosion Behavior And Mechanism Of Laser Powder Bed Fusion Produced Cocrw In An Acidic Nacl Solution, P. Qin, L. Y. Chen, Y. J. Liu, C. H. Zhao, Hongqi Sun, Laichang Zhang

Research outputs 2022 to 2026

The corrosion behavior and mechanism of the laser powder bed fusion (L-PBF) produced CoCrW were investigated in 0.9 wt% NaCl solution with a pH of 2. The corrosion resistance of the alloy increases after 28 days of immersion because of the formed oxide film, which results in the increased corrosion potential and the decreased passivation current density on the potentiodynamic polarization test. The corrosion mechanism of the L-PBF-produced CoCrW could be explained by the melt pool formed from the laser melting process, that the melt pools were “shrinking” by the formation and dissolution of the oxide film.


Corrosion Behavior And Mechanisms Of The Heat-Treated Ti5cu Produced By Laser Powder Bed Fusion, Xin Wang, Peng Qin, L. Y. Chen, Hongqi Sun, Laichang Zhang Jan 2023

Corrosion Behavior And Mechanisms Of The Heat-Treated Ti5cu Produced By Laser Powder Bed Fusion, Xin Wang, Peng Qin, L. Y. Chen, Hongqi Sun, Laichang Zhang

Research outputs 2022 to 2026

This work investigated the corrosion behavior of laser powder bed fusion produced (LPBFed) Ti5Cu and its heat-treated counterparts at 740 and 900 °C (named as HT-740 and HT-900 respectively) in Hank’s solution. The results indicated that the presence of acicular a'-Ti phase in LPBFed Ti5Cu was beneficial to corrosion, but the corrosion resistance of HT-740 and HT-900 were increased owing to the dual-phase microstructure (a'/a-Ti + Ti2Cu) or the increased content of Ti2Cu phase in the microstructure. The Ti2Cu phase could provide an ‘envelope’ protection to the a'/a-Ti phase and slow down the micro-galvanic reaction between a'/a-Ti phase and Ti2Cu …


Design, Microstructure And Properties Of Metastable Beta-Type Biomedical Titanium Alloys, Syed Faraz Jawed Jan 2020

Design, Microstructure And Properties Of Metastable Beta-Type Biomedical Titanium Alloys, Syed Faraz Jawed

Theses: Doctorates and Masters

Many existing implant biomaterials including cobalt-chromium alloy, stainless steel, Ti-6Al-4V and commercially pure titanium have all been shown to demonstrate mechanical incompatibility, poor osseointegration and/or cause cytotoxic effects on the human body after some years of application, leading to revision surgery in most cases. Consequently, there is an immediate need for an enduring biomaterial that displays good mechanical properties and possesses biocompatibility and corrosion resistance, in order to reduce rates of revision surgeries. In this PhD work, based on the 𝐵𝑜̅̅̅̅-𝑀𝑑̅̅̅̅̅, 𝑒/𝑎̅̅̅̅̅-𝛥𝑟̅̅̅ and BF-d-electron superelastic theoretical relationships four new series of quaternary Ti-25Nb-8Zr-xCr, Ti-25Nb-xSn-yCr, Ti26Nb-xMn-yZr and Ti-25Nb-xMn-ySn alloys have been …


Particle Size-Dependent Microstructure, Hardness And Electrochemical Corrosion Behavior Of Atmospheric Plasma Sprayed Nicrbsi Coatings, Peng Sang, Liang-Yu Chen, Cuihua Zhao, Ze-Xin Wang, Haiyang Wang, Sheng Lu, Dongpo Song, Jia-Huan Xu, Lai-Chang Zhang Jan 2019

Particle Size-Dependent Microstructure, Hardness And Electrochemical Corrosion Behavior Of Atmospheric Plasma Sprayed Nicrbsi Coatings, Peng Sang, Liang-Yu Chen, Cuihua Zhao, Ze-Xin Wang, Haiyang Wang, Sheng Lu, Dongpo Song, Jia-Huan Xu, Lai-Chang Zhang

Research outputs 2014 to 2021

Particle size is a critical consideration for many powder coating-related industries since it significantly influences the properties of the produced materials. However, the effect of particle size on the characteristics of plasma sprayed NiCrBSi coatings is not well understood. This work investigates the microstructures, hardness and electrochemical corrosion behavior of plasma sprayed NiCrBSi coatings synthesized using different-sized powders. All coatings mainly consist of Ni, N3B, CrB, Cr7C3 and Cr3C2 phases. The coatings produced by small particles (50–75 μm) exhibit lower porosity (2.0 ± 0.8%). Such coatings show a higher fraction (15.5 vol.%) of the amorphous phase and lower hardness (700 …


Calculation Of Oxygen Diffusion Coefficients In Oxide Films Formed On Low-Temperature Annealed Zr Alloys And Their Related Corrosion Behavior, Lina Zhang, Liang-Yu Chen, Cuihua Zhao, Yujing Liu, Lai-Chang Zhang Jan 2019

Calculation Of Oxygen Diffusion Coefficients In Oxide Films Formed On Low-Temperature Annealed Zr Alloys And Their Related Corrosion Behavior, Lina Zhang, Liang-Yu Chen, Cuihua Zhao, Yujing Liu, Lai-Chang Zhang

Research outputs 2014 to 2021

The growth of oxide film, which results from the inward oxygen diffusion from a corrosive environment, is a critical consideration for the corrosion resistance of zirconium alloys. This work calculates the oxygen diffusion coefficients in the oxide films formed on zirconium alloys annealed at 400~500 °C and investigates the related corrosion behavior. The annealed samples have a close size for the second-phase particles but a distinctive hardness, indicating the difference in substrate conditions. The weight gain of all samples highly follows parabolic laws. The weight gain of the sample annealed at 400 °C has the fastest increase rate at the …


A Practical Anodic And Cathodic Curve Intersection Model To Understand Multiple Corrosion Potentials Of Fe-Based Glassy Alloys In Oh-Contained Solutions, Yingjie Li, Yonggang Wang, Bang An, Hui Xu, Yihua Liu, Laichang Zhang, Houyi Ma, Weimin Wang Jan 2016

A Practical Anodic And Cathodic Curve Intersection Model To Understand Multiple Corrosion Potentials Of Fe-Based Glassy Alloys In Oh-Contained Solutions, Yingjie Li, Yonggang Wang, Bang An, Hui Xu, Yihua Liu, Laichang Zhang, Houyi Ma, Weimin Wang

Research outputs 2014 to 2021

A practical anodic and cathodic curve intersection model, which consisted of an apparent anodic curve and an imaginary cathodic line, was proposed to explain multiple corrosion potentials occurred in potentiodynamic polarization curves of Fe-based glassy alloys in alkaline solution. The apparent anodic curve was selected from the measured anodic curves. The imaginary cathodic line was obtained by linearly fitting the differences of anodic curves and can be moved evenly or rotated to predict the number and value of corrosion potentials. © 2016 Li et al. This is an open access article distributed under the terms of the Creative Commons Attribution …


Distinction In Corrosion Resistance Of Selective Laser Melted Ti-6al-4v Alloy On Different Planes, Nianwei Dai, Laichang Zhang, Junxi Zhang, Xin Zhang, Qingzhao Ni, Yang Chen Jan 2016

Distinction In Corrosion Resistance Of Selective Laser Melted Ti-6al-4v Alloy On Different Planes, Nianwei Dai, Laichang Zhang, Junxi Zhang, Xin Zhang, Qingzhao Ni, Yang Chen

Research outputs 2014 to 2021

Electrochemical measurements and microstructural analysis were performed to study the corrosion resistance of different planes of Ti-6Al-4V alloy manufactured by selective laser melting (SLM). The electrochemical results suggest that its XY-plane possesses a better corrosion resistance compared to XZ-plane in 1 M HCl solution, in spite of slight difference in 3.5 wt.% NaCl solution, suggesting that the different planes exhibit more pronounced distinction in corrosion resistance in harsher solution system. The inferior corrosion resistance of XZ-plane is attributed to the presence of more α′ martensite and less β-Ti phase in microstructure for XZ-plane than for XY-plane of the SLM-produced Ti-6Al-4V …


Structure-Property-Performance Of Nanocomposite Cr-Si-N Films Synthesized By A Duplex Surface Treatment Technique, Daohui Lai, Jiang Xu, Zong-Han Xie, Paul R. Munroe Jan 2011

Structure-Property-Performance Of Nanocomposite Cr-Si-N Films Synthesized By A Duplex Surface Treatment Technique, Daohui Lai, Jiang Xu, Zong-Han Xie, Paul R. Munroe

Research outputs 2011

Nanocomposite Cr–Si–N films were prepared on to Ti–6Al–4V substrates by a novel duplex surface treatment technique. Coatings consisting of a Cr3Si surface layer were deposited using a double cathode glow plasma and subsequent surface plasma nitriding. The surface topography, chemical composition, and microstructure of these treated alloys were analyzed by a variety of surface characterization techniques. The resulting Cr–Si–N films consisted of nanocrystallite CrN grains embedded in amorphous SiNx phase. Nanoindentation tests showed that with increasing nitrogen partial pressure the hardness of the Cr–Si–N films increased and the elastic modulus decreased. Wear experiments showed that the Cr–Si–N films produced at …