Engineering Commons^™

Mechanisms Contributing To Hydrogen-Influenced Early Failure Of Bridge Tendons, David Dukeman

USF Tampa Graduate Theses and Dissertations

Failures in post-tensioned tendons have occurred without warning due to fractures in the high-strength steel strands. These strands are cold-drawn to increase their strength while still retaining the preferential ductile mode of fracture. Recently, a tendon failure that occurred in an upper deviation block of the I-526 James B. Edwards bridge crossing the Wando river showed signs of corrosion and potentially another method of failure, hydrogen embrittlement. One proposed source of hydrogen is through galvanic coupling that may exist between the galvanized steel duct and the steel strands. This coupling, if substantial, can promote hydrogen evolution at the steel strand's …

Impedance Analysis Of Anodized Aluminum And Structural Bridge Tendons, Justin Silnutzer

USF Tampa Graduate Theses and Dissertations

This is a two-part thesis with the overall investigation technique being electrochemical impedance spectroscopy (EIS). In the first part, EIS is used to estimate the layer thickness of anodized aluminum oxide. This required the development of an appropriate electrical circuit model; that with parameters that correspond to physical properties of the oxide. In this work, it was found that for thicker oxides of which the outer porous layer is greater than 12 microns, impedance may be used to estimate the outer layer thickness. However, further research is required to understand the role of outer porous layer structure on the impedance …

Rapid Cross-Section Imaging With Magnetic And Impedance Sensors For Grout Anomaly Detection In External Post-Tensioned Tendons, Hani Freij

USF Tampa Graduate Theses and Dissertations

Post-tensioned (PT) bridges have had severe corrosion issues with tendons that fail suddenly without prior notice. The corrosion of external post-tensioned tendons has been associated with grout deficiencies/anomalies from inadequate grouting. Deficiencies include voids, regions of chalky low strength grout, and regions where excessive water content or even free water is present. In those zones mechanical bonding of strand to the grout is degraded and, of more concern, the strand steel risks corrosion failure reducing the expected lifespan of the structure. As tendons are critical structural components, it is important to detect those deficiencies during inspection preferably by a cross …

Mechanism Of Cathodic Prevention Of Carbon Steel In Concrete, Krittin Rattakham

USF Tampa Graduate Theses and Dissertations

In this work, I aim to clarify the mechanism that allows steel to attain higher chloride threshold as it is cathodically polarized. Specifically, I seek to provide empirical information on whether an intrinsic (predominantly interfacial effects of polarization) or an extrinsic (predominantly concentration changes due to polarization) mechanism may be dominant in the beneficial effect of polarization. I carried out this experiment with 12 identical concrete specimens, each with a cast-in steel plate, constantly exposed them to high-chloride environment. The specimens were divided into 4 triplicates and polarized at 4 different level from OCP, -200, -300 to -400 mV_{SCE …}

Electrochemical Methods To Characterize Drilled Shaft Deficiencies, Sarah Jo Mobley

USF Tampa Graduate Theses and Dissertations

In recent years drilled shafts have become the preferred foundation method for marine bridges. Typically, the drilled shaft is selected over traditional driven piles due to soil strata encountered, construction economy, increased lateral stiffness requirements, and/or vibration control considerations. The most critical component in drilled shaft construction is borehole stabilization. Wall sloughing or groundwater inclusion can have devastating effects on the strength of the finished shaft however recent research has shown that the materials, more specifically the slurry, used to accomplish stabilization may be having a negative impact on the durability of the finished product. This thesis investigates the durability …

Feasibility Of Cathodic Protection In Grouted Post Tensioned Tendons - Exploratory Model Calculations, Jacob Dharma Bumgardner

USF Tampa Graduate Theses and Dissertations

Recent corrosion related failures of grouted post tensioned tendons, even after the introduction of improved grouts, have led to renewed interest in supplemental or backup means of corrosion control for these systems. A finite element model is presented to explore feasibility of impressed current cathodic protection of strand in grouted tendons. The model examines polarization evolution as function of service time and includes consideration of anode placement and size, grout porosity, pore water alkalinity, electrochemical species diffusivity and applied voltage on the polarization efficacy and durability of such a system. The exploratory model projections suggested that, within the context of …

Metallic Encapsulation For High Temperature (>500 °C) Thermal Energy Storage Applications, Abhinav Bhardwaj

USF Tampa Graduate Theses and Dissertations

Deployment of high temperature (>500 °C) thermal energy storage in solar power plants will make solar power more cost competitive and pave the way towards a sustainable future. In this research, a unique metallic encapsulation has been presented for thermal energy storage at high temperatures, capable of operation in aerobic conditions. This goal was achieved by employing low cost materials like carbon steel. The research work presents the unique encapsulation procedure adopted, as well as various coatings evaluated and optimized for corrosion protection. Experimental testing favored the use of 150 μm of nickel on carbon steel for corrosion protection …

Feasibility Of Application Of Cathodic Prevention To Cracked Reinforced Concrete In Marine Service, Kevin Williams

USF Tampa Graduate Theses and Dissertations

Corrosion can take place as chloride ions accumulate above a critical concentration (CT) at the surface of a reinforcing bar inside concrete in marine service. The initiation of corrosion can be delayed by polarizing the steel cathodically, which is known to increase the value of CT. That effect is the basis of the cathodic prevention (CPrev) method to control corrosion of reinforcing steel in concrete. However, concrete cracks are a common occurrence and at cracks, the buildup of chloride ions is accelerated to the extent that CPrev may be less effective. The findings from an ongoing investigation to determine the …

Kelvin Probe Electrode For Contactless Potential Measurement On Concrete-Properties And Applications, Michael Thomas Walsh

USF Tampa Graduate Theses and Dissertations

The practical feasibility of using a Kelvin Probe as a novel reference electrode in the measurement of both potential and polarization pulse response of reinforcing steel in concrete is demonstrated. Potential values measured using a KP reflect greater stability and repeatability than can typically be attained with conventional reference electrodes. Duplicate reinforced concrete beam test specimens with well-differentiated centrally corroding rebar segments were analyzed using both the Kelvin Probe (KP) and a conventional Saturated Calomel Electrode (SCE). Potential profile maps were developed using potential values recorded under static conditions with both the SCE and the KP. Nominal polarization resistance was …

Encapsulation Of High Temperature Phase Change Materials For Thermal Energy Storage, Rupa Nath

USF Tampa Graduate Theses and Dissertations

Thermal energy storage is a major contributor to bridge the gap between energy demand (consumption) and energy production (supply) by concentrating solar power. The utilization of high latent heat storage capability of phase change materials is one of the keys to an efficient way to store thermal energy. However, some of the limitations of the existing technology are the high volumetric expansion and low thermal conductivity of phase change materials (PCMs), low energy density, low operation temperatures and high cost. The present work deals with encapsulated PCM system, which operates at temperatures above 500°C and takes advantage of the heat …

Oxygen Diffusion Characterization Of Frp Composites Used In Concrete Repair And Rehabilitation, Chandra K. Khoe

USF Tampa Graduate Theses and Dissertations

Many independent studies have conclusively demonstrated that fiber reinforced polymers (FRP) slow down chloride-induced corrosion of steel in concrete. The mechanism for this slow down is not well understood but it has been hypothesized that FRP serves as a barrier to the ingress of chloride, moisture, and oxygen that sustain electrochemical corrosion of steel.

This dissertation presents results from an experimental study that determined the oxygen permeation rates of materials used in infrastructure repair. In the study, the oxygen permeation constants for epoxy, carbon and glass fiber laminates, concrete, epoxy-concrete and FRP-concrete systems were determined and a method developed to …