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Investigation Of Space Charge Effects On Co2 Electrocatalytic Reduction On Gd-Doped Ceria Via Scanning Kelvin Probe And Model-Based Bayesian Analysis, Alejandro Mejia 2024 West Virginia University

Investigation Of Space Charge Effects On Co2 Electrocatalytic Reduction On Gd-Doped Ceria Via Scanning Kelvin Probe And Model-Based Bayesian Analysis, Alejandro Mejia

Graduate Theses, Dissertations, and Problem Reports (ETD)

In studying novel energy conversion and storage systems, such as high-temperature electrolysis, numerous underlying fundamental physical processes remain unclear or inadequately understood. Among these, the modeling and comprehension of surface reaction mechanisms, coupled with the intricate effects of space‑charge interfaces, remains an unclear and challenging area of research.

The work of this dissertation involves the development of a 2D finite element analysis model, leveraging the robust MOOSE framework from INL. This model, featuring inhomogeneous defect thermodynamics for near-surface chemistry, formulated through Poisson‑Cahn variational theory, has been exploited for studying the electrocatalytic reduction of CO2 on gadolinia doped ceria. The …


Patterns Into Pathways For Improving Safety Culture: Refined Latent Class Analysis Informs Tailored Decision Support For South Carolina Dss Safety Culture Improvements, Michaela Voit 2024 University of Kentucky

Patterns Into Pathways For Improving Safety Culture: Refined Latent Class Analysis Informs Tailored Decision Support For South Carolina Dss Safety Culture Improvements, Michaela Voit

Theses and Dissertations--Public Health (M.P.H. & Dr.P.H.)

The rising prevalence of exposures to adverse childhood experiences (ACEs) demands a coordinated public health response, as a significant body of research details the cumulative impact of ACEs on chronic morbidities contributing to reduced life expectancy. Child welfare workers (CWW) are embedded in this public health effort, tasked with preventing and mitigating the impacts of ACEs through family and prevention services. The National Partnership for Child Safety (NPCS) may improve the wellbeing of CWWs and the effectiveness of Child Welfare (CW) services by improving the quality of safety culture within CW organizations. To inform NPCS quality improvement efforts, our project …


Imputation Strategies For Different Categories Of Missing Data, Karthik Chalumuri 2024 University of New Hampshire, Durham

Imputation Strategies For Different Categories Of Missing Data, Karthik Chalumuri

Honors Theses and Capstones

Addressing missing data in research is crucial for ensuring the reliability and validity of study findings, yet it remains a significant challenge. This study investigates the impact of missing data on research outcomes and explores the underutilization of existing tools for managing missingness, potentially leading to gaps in critical information with tangible implications for decision-making processes (Dziura et al.).

Focusing on the different categories of missing data—Missing Completely At Random (MCAR), Missing At Random (MAR), and Missing Not At Random (MNAR)—this research examines various imputation strategies tailored to each category. Specifically, we compare the efficacy of several model-based imputation methods, …


A Bayesian Inversion For Emissions And Export Productivity Across The End-Cretaceous Boundary, Alexander A. Cox 2024 Dartmouth College

A Bayesian Inversion For Emissions And Export Productivity Across The End-Cretaceous Boundary, Alexander A. Cox

Dartmouth College Master’s Theses

The end-Cretaceous mass extinction was marked by both the Chicxulub impact and the ongoing emplacement of the Deccan Traps flood basalt province. Both of these events perturbed the environment by the emission of climate-active volatiles, primarily CO2 and SO2. To understand the mechanism of extinction, we must disentangle the timing, duration, and intensity of volcanic and meteoritic environmental forcings. In this thesis, we used a parallel Markov chain Monte Carlo approach to invert for the aforementioned volatile emissions, export productivity, and remineralization from 67 to 65 million years ago using the LOSCAR (Long-term Ocean-atmosphere-Sediment CArbon cycle Reservoir) model. The parallel …


Difs And Bayescluster: Novel Methods For Single_Cell Rna Sequencing Analysis, Kun Liu 2024 University of Kentucky

Difs And Bayescluster: Novel Methods For Single_Cell Rna Sequencing Analysis, Kun Liu

Theses and Dissertations--Statistics

Single-cell RNA sequencing (scRNA-seq) has transformed our understanding of cellular heterogeneity and gene expression dynamics. Despite its potential, the inherent noise and sparsity of scRNA-seq data pose significant challenges in clustering cells into biologically meaningful groups. This dissertation addresses these challenges through two novel methodologies aimed at enhancing the accuracy and robustness of scRNA-seq data analysis.

First, we introduce the Differential Feature Selection (DIFS) framework, designed to improve the identification of differential features in scRNA-seq data. DIFS employs a two-stage marker identification process. In the first stage, a modified Dip Test is used to filter and identify genes with significant …


To Mean Or Not To Mean: An Investigation Of Regression To The Mean, Hunter Ellis 2024 The University of Akron

To Mean Or Not To Mean: An Investigation Of Regression To The Mean, Hunter Ellis

Williams Honors College, Honors Research Projects

Regression to the mean is a statistical phenomenon that can hide important characteristics of what is truly happening in a research study. Caused by statistical randomness, regression to the mean occurs when extreme values, high or low, are followed by less extreme values. To correctly deal with it, one must understand what it is and how to distinguish its effect on conclusions made from the data. This paper provides examples of regression to the mean in both a medical and academic performance study and explains simple identifiers one can observe. Those are then followed up by the introduction of the …


Ensemble Classification: An Analysis Of The Random Forest Model, Jarod Korn 2024 The University of Akron

Ensemble Classification: An Analysis Of The Random Forest Model, Jarod Korn

Williams Honors College, Honors Research Projects

The random forest model proposed by Dr. Leo Breiman in 2001 is an ensemble machine learning method for classification prediction and regression. In the following paper, we will conduct an analysis on the random forest model with a focus on how the model works, how it is applied in software, and how it performs on a set of data. To fully understand the model, we will introduce the concept of decision trees, give a summary of the CART model, explain in detail how the random forest model operates, discuss how the model is implemented in software, demonstrate the model by …


Statistical Modeling Of Bankruptcy Data, Andrew Elsfelder 2024 The University of Akron

Statistical Modeling Of Bankruptcy Data, Andrew Elsfelder

Williams Honors College, Honors Research Projects

My project uses a dataset of bankrupt and non-bankrupt companies in Taiwan from 1999 to 2009. This data was collected from the Taiwan Economic Journal. The statistical methods I used to model the data are CHAID, CART, and logistic regression. The models created are tools that can predict if a company is bankrupt, or not-bankrupt based on other data about the company. I created multiple models for each of the methods to find the best model for each method. I then analyzed the output from each method. Lastly, I determined which model was the best for this data based on …


Towards A More Engaged Democracy: Using Statistical Methods To Detect Election Fraud In The 2022 Philippine National Elections, Juan Miguel Cardaño, Bryan Patrick Mande, Seth William Tionko, Aldrich Ellis C. Asuncion, Jeric C. Briones 2024 Ateneo de Manila University

Towards A More Engaged Democracy: Using Statistical Methods To Detect Election Fraud In The 2022 Philippine National Elections, Juan Miguel Cardaño, Bryan Patrick Mande, Seth William Tionko, Aldrich Ellis C. Asuncion, Jeric C. Briones

Mathematics Faculty Publications

This paper aims to show how citizens can further participate in the elections, aside from just voting. Given the accusations of fraud, this study demonstrates how existing election fraud detection methods can be used in the 2022 Philippine National Elections (PNE) context. Specifically, histograms known as 2D vote turnout distributions were first utilized to model the frequency of the winner's percentage of votes based on the voter turnout in each electoral unit, with key parameters introduced to detect fraud. Vote turnout distributions were then simulated using parametric models involving the aforementioned fraud parameters, with the goal of replicating the actual …


Accounting For Variability Due To Resampling Using Bootstrapping, Dipendra Phuyal 2024 Georgia Southern University

Accounting For Variability Due To Resampling Using Bootstrapping, Dipendra Phuyal

College of Graduate Studies: Theses & Dissertations

Bradley Efron (1979) introduced bootrapping. Typically a researcher is interested in studying a process which generates individuals. The collection of individuals the process has(actual) or could have (conceptual) generated is the population. The collection of conceptual members of the population is an uncountable collection. Hence, the population is anuncountable collection of individuals. The collection of individuals the process has generated (actual individuals) is representative of what the process can generate and will bereferred to as the representative sample. The size of this sample is a nonnegative integervalued random variable N which may be a constant random variable such as in …


Investigating Flash Flood Occurrence Using Negative Binomial Models In Maryland, United States Of America, Zainab O. Akinsemoyin 2024 Georgia Southern University

Investigating Flash Flood Occurrence Using Negative Binomial Models In Maryland, United States Of America, Zainab O. Akinsemoyin

College of Graduate Studies: Theses & Dissertations

Globally, as extreme weather patterns intensify, flash floods have emerged as one of the most destructive and immediate environmental threats. In Maryland, flash floods are particularly concerning due to its diverse topography and increasing urban development, which exacerbates runoff and overwhelms drainage systems. The state has experienced significant flash flood events, highlighting the need for effective models to manage risks and inform mitigation strategies. While regression models such as the Negative Binomial (NB) and Zero-Inflated Negative Binomial (ZINB) are commonly used for count data analysis, their application to flash flood modeling in the USA, including regions like Maryland, remains limited …


Utility In Time Description In Priority Best-Worst Discrete Choice Models: An Empirical Evaluation Using Flynn's Data, Sasanka Adikari, Norou Diawara 2024 Old Dominion University

Utility In Time Description In Priority Best-Worst Discrete Choice Models: An Empirical Evaluation Using Flynn's Data, Sasanka Adikari, Norou Diawara

Mathematics & Statistics Faculty Publications

Discrete choice models (DCMs) are applied in many fields and in the statistical modelling of consumer behavior. This paper focuses on a form of choice experiment, best-worst scaling in discrete choice experiments (DCEs), and the transition probability of a choice of a consumer over time. The analysis was conducted by using simulated data (choice pairs) based on data from Flynn's (2007) 'Quality of Life Experiment'. Most of the traditional approaches assume the choice alternatives are mutually exclusive over time, which is a questionable assumption. We introduced a new copula-based model (CO-CUB) for the transition probability, which can handle the dependent …


Optimizing Sports Outcome Prediction Through Feature Engineering And Machine Learning, Vitor S. Freitas 2024 Missouri State University

Optimizing Sports Outcome Prediction Through Feature Engineering And Machine Learning, Vitor S. Freitas

Graduate Theses/Dissertations

The challenge of predicting the outcome of a team game lies in the high complexity and dynamics of the sports data. This thesis focuses on the aspect of using feature engineering and the genetic algorithm to predict the winner and the score of various sports events. Generally, it deals with how machine learning algorithms are combined with state-of-the-art feature engineering techniques in sports datasets derived from various sports disciplines. In this thesis, five different machine learning models have been applied, classification and regression trees (CART), random forest (RF), stochastic gradient boosting (SGB), eXtreme gradient boosting (XGBoost), and extreme learning machine …


Data-Driven Modeling Of Oxygen Kinetics In La0.6sr0.4co0.2fe0.8o3−Δ (Lscf) For High-Temperature Reduction Of Co2 In An Electrolysis Cell, Ferron Campbell 2024 West Virginia University

Data-Driven Modeling Of Oxygen Kinetics In La0.6sr0.4co0.2fe0.8o3−Δ (Lscf) For High-Temperature Reduction Of Co2 In An Electrolysis Cell, Ferron Campbell

Graduate Theses, Dissertations, and Problem Reports (ETD)

Electrolysis systems are critical to several societal applications, particularly energy storage and conversion. Developing these systems requires a detailed knowledge of the chemistry and thermodynamics of the materials used in the electrolysis cell. This work focuses on using embedded scientific machine learning as an efficient way to build an interpretable model for the reaction and transport kinetics in the LSCF electrode, whose performance directly influences the electrolysis system’s performance. The models developed in this study are trained using the publicly available machine learning package, FoKL-GP. This package incorporates a robust Gibbs sampler that employs a forward variable selection process to …


Simulation Of Wave Propagation In Granular Particles Using A Discrete Element Model, Syed Tahmid Hussan 2024 Georgia Southern University

Simulation Of Wave Propagation In Granular Particles Using A Discrete Element Model, Syed Tahmid Hussan

College of Graduate Studies: Theses & Dissertations

The understanding of Bender Element mechanism and utilization of Particle Flow Code (PFC) to simulate the seismic wave behavior is important to test the dynamic behavior of soil particles. Both discrete and finite element methods can be used to simulate wave behavior. However, Discrete Element Method (DEM) is mostly suitable, as the micro scaled soil particle cannot be fully considered as continuous specimen like a piece of rod or aluminum. Recently DEM has been widely used to study mechanical properties of soils at particle level considering the particles as balls. This study represents a comparative analysis of Voigt and Best …


Redesign, Evaluation, And Validation Of A Commercially Viable High-Resolution Melt Based Mixture Screening Tool, Chastyn Smith 2024 Virginia Commonwealth University

Redesign, Evaluation, And Validation Of A Commercially Viable High-Resolution Melt Based Mixture Screening Tool, Chastyn Smith

Theses and Dissertations

Analysis of evidentiary samples containing DNA from multiple contributors (“mixtures”) is a time intensive process for a forensic analyst and one where the contributor nature of a sample is not revealed until the end of the traditional forensic workflow. Often, at this stage, retesting or additional testing of mixture samples may not be possible, particularly if the DNA collection device did not preserve the DNA well enough; consequently leaving only trace amounts of a contributor’s DNA present. Thus, a new collection device that would allow for the increased preservation/integrity of evidentiary samples as well as a method that would allow …


The Genetic Architecture Of Cervical Change During Pregnancy: From Modeling To Mechanism — Does The Cervix Mediate Maternal Risk For Spontaneous Preterm Birth?, Hope M. Wolf 2024 Virginia Commonwealth University

The Genetic Architecture Of Cervical Change During Pregnancy: From Modeling To Mechanism — Does The Cervix Mediate Maternal Risk For Spontaneous Preterm Birth?, Hope M. Wolf

Theses and Dissertations

This project leverages clinical data and biospecimens from a prospective longitudinal cohort of pregnant women to study the genetic and phenotypic relationships between cervical shortening and the duration of pregnancy. Sonographic cervical length (CL) was measured throughout pregnancy in a cohort of 5,160 Black/African American women in Detroit, Michigan. Maternal DNA samples were sequenced with a next-generation low-pass whole genome platform. The heritability of cervical change during pregnancy and its genetic correlation with gestational age at delivery (GAD) were estimated using Genome-Wide Complex Trait Analysis. These estimates suggest that cervical change is heritable (h²CL = 51%) and highly polygenic trait. …


Self-Exciting Point Processes In Real Estate, Ian Fraser 2024 Wilfrid Laurier University

Self-Exciting Point Processes In Real Estate, Ian Fraser

Theses and Dissertations (Comprehensive)

This thesis introduces a novel approach to analyzing residential property sales through the lens of stochastic processes by employing point processes. Herein, property sales are treated as point patterns, using self-exciting point process models and a variety of statistical tools to uncover underlying patterns in the data. Key findings include the identification and explanation of clustering in both space and time, and the efficacy of a temporal Hawkes process with a sinusoidal background in predicting home sale occurrences. The temporal analysis starts by employing the state of art techniques for time series data like regression, autoregressive, and autoregressive integrated moving …


Last Passage Time And Excursion Theory For Solvable Diffusions With Applications In Mathematical Finance, Yaode Sui 2024 Wilfrid Laurier University

Last Passage Time And Excursion Theory For Solvable Diffusions With Applications In Mathematical Finance, Yaode Sui

Theses and Dissertations (Comprehensive)

In this dissertation, we investigate the properties of last passage times and excursion theory in one-dimensional solvable diffusions, emphasizing their applications in financial modeling, particularly in option pricing. We derive closed-form formulas for the marginal distribution of last passage times and their joint distribution with process values, including the maximum and minimum of the process value. The focus is on time-homogeneous diffusions with various boundaries and imposed killing. Employing spectral expansion theory, we derive explicit formulas for distributions of last passage times in common processes such as Drifted Brownian Motion (BM), Squared Bessel (SQB), Ornstein-Uhlenbeck (OU), and Cox-Ingersoll-Ross (CIR) models. …


Sparse Representation Learning For Temporal Networks, Maxwell McNeil 2024 University at Albany, State University of New York

Sparse Representation Learning For Temporal Networks, Maxwell Mcneil

Electronic Theses & Dissertations (2024 - present)

Temporal networks arise in many domains including activity of social network users, sensor network readings over time, and time course gene expression within the interaction network of a model organism. Data of this type contains a wealth of prior information such as the connectivity among nodes (e.g., a friendship graph), and prior knowledge of expected temporal patterns (e.g., periodicity). Modeling these temporal and network patterns jointly is essential for state-of-the-art performance in temporal network data analysis and mining. Sparse dictionary encoding is one modeling approach for such underlying patterns. However, most classical approaches consider only one dimension of the data …


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