Condensed Matter Physics Commons^™

Adsorption Of Tcnqh-Functionalized Quinonoid Zwitterions On Gold And Graphene: Evidence For Dominant Intermolecular Interactions+, Lingmei Kong, Lucie Routaboul, Pierre Braunstein, Hong-Gi Park, Jaewu Choi, John P. Colon Cordova, E Vega, Luis G. Rosa, Bernard Doudin, Peter A. Dowben

Peter Dowben Publications

We experimentally investigate the electronic structure of the strongly dipolar, quinonoid-type molecule obtained by TCNQH-functionalization (TCNQH = (NC)₂CC₆H₄CH(CN)₂) of (6Z)-4-(butylamino)-6-(butyliminio)- 3-oxocyclohexa-1,4-dien-1-olate C₆H₂(...NHR)₂(...O)₂ (where R = n-C₄H₉) to be very similar after deposition from solution on either graphene or gold substrates. These zwitterion adsorbate thin films form structures that are distinct from those formed by related quinonoid molecules previously studied. We argue that adsorbate–adsorbate interactions dominate and lead to a Stranski–Krastanov ‘island growth’ mechanism.

Comment On "Density And Physical Current Density Functional Theory", Xiao-Yin Pan, Viraht Sahni

Publications and Research

In this letter to the editor, the authors comment on an earlier article they had published, "Density and Physical Current Density Functional Theory" (Pan, X.-Y. and Sahni, V. (2010), Density and physical current density functional theory. Int. J. Quantum Chem., 110: 2833–2843. doi: 10.1002/qua.22862).

Voltage Modulated Infrared Reflectance Study Of Soluble Organic Semiconductors In Thin Film Transistors, Emily Geraldine Bittle

Theses and Dissertations--Physics and Astronomy

Soluble organic semiconductors have attracted interest due to their potential in making flexible and cheap electronics. Though their use is being implemented in electronics today, the conduction mechanism is still under investigation. In order to study the charge transport, this study examines the position, voltage, and frequency dependence of charge induced changes in far infrared absorption in soluble organic semiconductors in thin-film transistor structures. Measurements are compared to a simple model of a one-dimensional conductor which gives insight into the charge distribution and timing in devices. Main results of the study are dynamic measurements of charge taken by varying the …

Spin Dependent Transport In Novel Magnetic Heterostructures, Priyanga Buddhika Jayathilaka

USF Tampa Graduate Theses and Dissertations

Magnetic oxides have become of interest source for spin transport devices due to their high spin polarization. But the real applications of these oxides remains unsatisfactory up to date, mostly due to the change of properties as a result of nano structuring. Magnetite (Fe₃O₄) is one such a material. High Curie temperature and the half metallicity of Fe₃O₄ make it a good potential candidate for spin transport devices. Studies have shown that the nano structuring Fe₃O₄ changes most of it's important properties. This includes high saturation magnetization and drop of …

Non-Equilibrium Melting And Sublimation Of Graphene Simulated With Two Interatomic Potentials, Brad Steele

USF Tampa Graduate Theses and Dissertations

The mechanisms of the sublimation of graphene at zero pressure and the condensation of carbon vapor is investigated by molecular dynamics (MD) simulations. The interatomic interactions are described by the Reactive Empirical Bond Order potential (REBO). It is found that graphene sublimates at a temperature of 5,200 K. At the onset of sublimation, defects that contain several pentagons and heptagons are formed, that are shown to evolve from double vacancies and stone wales defects. These defects consisting of pentagons and heptagons act as nucleation sites for the gaseous phase. The influence of the interatomic interactions on the sublimation process are …

Synthesis And Properties Of Polymer Nanocomposites With Tunable Electromagnetic Response, Kristen Lee Stojak

USF Tampa Graduate Theses and Dissertations

Multifunctional polymer nanocomposites (PNCs) are attractive for the design of tunable RF and microwave components such as flexible electronics, attenuators, and antennas due to cost-effectiveness and durability of polymeric matrices. In this work, three separate PNCs were synthesized. Magnetite (Fe3O4) and cobalt ferrite (CFO) nanoparticles, synthesized by thermal decomposition, were used as PNC fillers. Polymers used in this work were a commercial polymer provided by the Rogers Corporation (RP) and polyvinylidene fluoride (PVDF). PNCs in this thesis consist of Fe3O4 in RP, CFO in RP, and Fe3O4 in PVDF. Characterization techniques for determining morphology of the nanoparticles, and their resulting …

Magnetism In Complex Oxides Probed By Magnetocaloric Effect And Transverse Susceptibility, Nicholas Steven Bingham

USF Tampa Graduate Theses and Dissertations

Magnetic oxides exhibit rich complexity in their fundamental physical properties determined by the intricate interplay between structural, electronic and magnetic degrees of freedom. The common themes that are often present in these systems are the phase coexistence, strong magnetostructural coupling, and possible spin frustration induced by lattice geometry. While a complete understanding of the ground state magnetic properties and cooperative phenomena in this class of compounds is key to manipulating their functionality for applications, it remains among the most challenging problems facing condensed-matter physics today. To address these outstanding issues, it is essential to employ experimental methods that allow for …

Magnetization Dynamics And Related Phenomena In Nanostructures, Sayan Chandra

USF Tampa Graduate Theses and Dissertations

Collective magnetic behavior in nanostructures is a phenomenon commonly observed in various magnetic systems. It arises due to competing inter/intra–particle interactions and size distribution and can manifest in phenomena like magnetic freezing, magnetic aging, and exchange bias (EB) effect. In order to probe these rather complex phenomena, conventional DC and AC magnetic measurements have been performed along with radio–frequency transverse susceptibility (TS) measurements. We also demonstrate the magnetic entropy change as a parameter sensitive to subtle changes in the magnetization dynamics of nanostructures. The focus of this dissertation is to study the collective magnetic behavior in core-shell nanostructures of Fe/γ–Fe …

Development Of Improved Models For Gas Sorption Simulation, Keith Mclaughlin

USF Tampa Graduate Theses and Dissertations

Computational chemistry offers one the ability to develop a better understanding of the complex physical and chemical interactions that are fundamental to macro- and mesoscopic processes that are seen in laboratory experiments, industrial processes, and ordinary, everyday life. For many systems, the physics of interest occur at the molecular or atomistic levels, and in these cases, computational modeling and two well refined simulation techniques become invaluable: Monte Carlo (MC) and molecular dynamics (MD). In this work, two well established problems were tackled. First, models and potentials for various gas molecules were produced and refined from first principles. These models, although …

Ultrasound For Improved Crystallisation In Food Processing, N. Misra, Navneet Deora, Brijesh Tiwari, Patrick J. Cullen

Articles

Within the food industry, controlling crystallisation is a key factor governing food structure, texture and consumer appeal, with some foods requiring the promotion of crystallisation in a controlled manner (e.g. chocolate) and others a check (e.g. in honey). Sonocrystallisation is the application of ultrasound energy to control the nucleation of a crystallisation process. The use of power ultrasound provides a non-invasive approach to producing crystals with desired properties. Sonocrystallisation facilitates process control, primarily by modulating crystal size distribution and morphology. This paper details the governing mechanisms of sonocrystallisation. Proven and potential applications of the process in foods, including chocolates, honey, …

Ferroelectric Instability Under Screened Coulomb Interactions, Yong Wang, Xiaohui Liu, John D. Burton, Sitaram S. Jaswal, Evgeny Y. Tsymbal

Evgeny Tsymbal Publications

We explore the effect of charge carrier doping on ferroelectricity using density functional calculations and phenomenological modeling. By considering a prototypical ferroelectric material, BaTiO₃, we demonstrate that ferroelectric displacements are sustained up to the critical concentration of 0.11 electron per unit cell volume. This result is consistent with experimental observations and reveals that the ferroelectric phase and conductivity can coexist. Our investigations show that the ferroelectric instability requires only a short-range portion of the Coulomb force with an interaction range of the order of the lattice constant. These results provide a new insight into the origin of ferroelectricity …

Pulse Sharpening Effects Of Thin Film Ferroelectric Transmission Lines, Robert J. Sleezer

Graduate Theses and Dissertations

Advances in material science have resulted in the development of electrically nonlinear high dielectric thin film ferroelectrics, which have led to new opportunities for the creation of novel devices. This dissertation investigated one such device: a low voltage nonlinear transmission line (NLTL). A finite element simulation of ferroelectric transmission lines showed that NLTLs are capable of creating shockwaves. Additionally, if the losses are kept sufficiently low, it was shown that voltage gain should be possible. Furthermore, a method of accounting for material dispersion was developed. Results from simulations including material dispersion showed that temporal solitons might be possible from a …

Electron–Phonon Coupling And Structural Phase Transitions On Au/Mo(112), Keisuke Fukutani

Department of Physics and Astronomy: Dissertations, Theses, and Student Research

The electronic structures, many-body interactions and Fermi surface topologies of Au/Mo(112) were investigated in detail and were found to play important roles in the newly discovered order-disorder structural phase transition of the system. First, the high-resolution angle-resolved photoemission spectroscopy was utilized to characterize the electronic band structure of Mo(112) in far greater details than before. This elucidated the existence of several surface-derived states and their dispersion relations in high precisions near the Fermi level, as well as the symmetries of the bulk and surface electronic states, which are in good quantitative agreement with the ab-initio calculations. Such thorough understanding of …

Hohenberg-Kohn Theorem Including Electron Spin, Xiao-Yin Pan, Viraht Sahni

Publications and Research

The Hohenberg-Kohn theorem is generalized to the case of a finite system of N electrons in external electrostatic epsilon(r) = -del nu(r) and magnetostatic B(r) = del x A(r) fields in which the interaction of the latter with both the orbital and spin angular momentum is considered. For a nondegenerate ground state a bijective relationship is proved between the gauge invariant density rho(r) and physical current density j(r) and the potentials {nu(r), A(r)}. The possible many-to-one relationship between the potentials {v(r), A(r)} and the wave function is explicitly accounted for in the proof. With the knowledge that the basic variables …

Equilibrium Magnetic States In Individual Hemispherical Permalloy Caps, Robert Streubel, Volodymyr P. Kravchuk, Denis D. Sheka, Denys Makarov, Florian Kronast, Oliver G. Schmidt, Yuri Gaididei

Robert Streubel Papers

The magnetization distributions in individual soft magnetic permalloy caps on non-magnetic spherical particles with sizes ranging from 50 to 800nm are investigated. We experimentally visualize the magnetic structures at the resolution limit of the x-ray magnetic circular dichroism photoelectron emission microscopy (XMCD-PEEM). By analyzing the so-called tail contrast in XMCD-PEEM, the spatial resolution is significantly enhanced, which allowed us to explore magnetic vortices and their displacement on curved surfaces. Furthermore, cap nanostructures are modeled as extruded hemispheres to determine theoretically the phase diagram of equilibrium magnetic states. The calculated phase diagram agrees well with the experimental observations. © 2012 American …

Nanomechanical Resonator Coupled Linearly Via Its Momentum To A Quantum Point Contact, Latchezar L. Benatov, Miles P. Blencowe

Dartmouth Scholarship

We use a Born-Markov approximated master equation approach to study the symmetrized-in-frequency current noise spectrum and the oscillator steady state of a nanoelectromechanical system where a nanoscale resonator is coupled linearly via its momentum to a quantum point contact (QPC). Our current noise spectra exhibit clear signatures of the quantum correlations between the QPC current and the back-action force on the oscillator at a value of the relative tunneling phase (η=−π/2) where such correlations are expected to be maximized. We also show that the steady state of the oscillator obeys a classical Fokker-Planck equation, but can experience thermomechanical noise squeezing …

High Frequency Study Of Magnetic Nanostructures, Abhishek Srivastava

LSU New Orleans Theses and Dissertations

The work in this thesis is divided in three parts. In part one we developed electrodeposition method of Nickel Nanowire in commercial AAO template in constant current (Galvanostatic) mode, further we tried to estimate the growth rate from theory, from saturation magnetization and direct measurement from SEM image.

In part two we focused on using the Vector Network Analyzer (VNA) to measure the Ferromagnetic Resonance (FMR))of various magnetic Nanowire arrays. We employed different measurement geometries using microstripline and coplanar waveguide as microwave transmission lines.

In part three our aim was to study the magnetic properties of complex ferromagnetic system, especially …

Ii-Vi Core-Shell Nanowires: Synthesis, Characterizations And Photovoltaic Applications, Kai Wang

LSU New Orleans Theses and Dissertations

The emergence of semiconducting nanowires as the new building blocks for photovoltaic (PV) devices has drawn considerable attention because of the great potential of achieving high efficiency and low cost. In special, nanowires with a coaxial structure, namely, core-shell structures have demonstrated significant advantages over other device configurations in terms of radial charge collection and cost reduction. In this dissertation, several core-shell nanowire structures, including ZnO/ZnSe, ZnO/ZnS, and CdSe/ZnTe, have been synthesized and the photovoltaic devices processed from a ZnO/ZnS core-shell nanowire array and a single CdSe/ZnTe core-shell nanowire have been demonstrated.

By combining the chemical vapor deposition and pulsed …

Electronic Transport In Thermoelectric Bismuth Telluride, Westly Nolting

LSU New Orleans Theses and Dissertations

An experimental investigation of the electronic transport properties of bismuth telluride nanocomposite materials is presented. The primary transport measurements are electrical conductivity, Seebeck coefficient and Hall effect. An experimental apparatus for measuring Hall effect and electrical conductivity was designed, constructed and tested. Seebeck coefficient measurements were performed on a commercial instrument. The Hall effect and Seebeck coefficient measurements are two of the most important tools for characterizing thermoelectric materials and are widely used in the semiconductor industry for determining carrier types, carrier concentration and mobility. Further, these transport parameters are used to determine the thermal to electrical conversion efficiency of …

Characterization Of Magnetic Nanostructured Materials By First Order Reversal Curve Method, Denny R. Lenormand

LSU New Orleans Theses and Dissertations

The Interactions and magnetization reversal of Ni nanowire arrays and synthetic anit-ferromagnetic coupled thin film trilayers have been investigated through first order reversal curve (FORC) method. By using a quantitative analysis of the local interaction field profile distributions obtained from FORC, it has proven to be a powerful characterization tool that can reveal subtle features of magnetic interactions.