Condensed Matter Physics Commons^™

Strain-Mediated Elastic Coupling In Magnetoelectric Nickel/Barium-Titanate Heterostructures, Robert Streubel, Denny Köhler, Rudolf Schäfer, Lukas M. Eng

Robert Streubel Papers

Multiferroic nanomaterials bear the potential for assembling a manifold of novel and smart devices. For room temperature (RT) applications, however, only the BiFeO3 single-phase perovskites are potential candidates to date. Nevertheless, vertical heterostructures separating magnetic and ferroelectric functionality into different layers are now widely proposed to circumvent this lack in materials' availability. We show here that the second approach is very profitable as illustrated by the strain-mediated coupling between such two layers, i.e., a ferroelectric barium titanate single-crystal (BTO) and a magnetostrictive nickel (Ni) thin film. Applying an electric field across the BTO substrate forces the magnetic easy axis in …

Diffusion Of Degenerate Minority Carrier In A P-Type Semiconductor, Christopher P. Weber, Eric A. Kittlaus

Physics

We report ultrafast transient-grating experiments on heavily p-type InP at 15 K. Our measurement reveals the dynamics and diffusion of photoexcited electrons and holes as a function of their density n in the range 2  ×  10¹⁶ to 6  ×  10¹⁷ cm⁻³. After the first few picoseconds, the grating decays primarily due to ambipolar diffusion. While, at low density, we observe a regime in which the ambipolar diffusion is electron-dominated and increases rapidly with n, it appears to saturate at 34 cm²/s at high n. We present a simple calculation that reproduces the main …

Low Energy Positron Interactions With Biological Molecules, Indika Lasantha Wanniarachchi

Wayne State University Dissertations

Calculations of the positron density distribution which can be used for positrons bound to midsize and larger molecules have been tested for smaller molecules and subsequently applied to investigate the most likely e+e- annihilation sites for positrons interacting with biological molecules containing C, H, O, and N. In order to allow consideration of positrons bound to extended molecules with regions of different character and no particular symmetry, atom-centered positron basis sets of Gaussian-type functions were developed for positrons bound to molecules containing O, N, C, H, Li, Na, and Be. Testing shows that there is no need to scale the …

Adherent Cells Avoid Polarization Gradients On Periodically Poled Litao3 Ferroelectrics, Christof Christophis, Elisabetta Ada Cavalcanti-Adam, Maximilian Hanke, Kenji Kitamura, Alexei Gruverman, Michael Grunze, Peter A. Dowben, Axel Rosenhahn

Peter Dowben Publications

The response of fibroblast cells to periodically poled LiTaO₃ ferroelectric crystals has been studied. While fibroblast cells do not show morphological differences on the two polarization directions, they show a tendency to avoid the field gradients that occur between polarization domains of the ferroelectric. The response to the field gradients is fully established after one hour, a time at which fibroblasts form their first focal contacts. If suspension cells, with a lower tendency to establish strong surface contacts are used, no influence of the field gradients is observed.

Proton Transfer In Surface-Stabilized Chiral Motifs Of Croconic Acid, Donna A. Kunkel, James Hooper, Scott Simpson, Geoffrey Rojas, Stephen Ducharme, Timothy Usher, Eva Zurek, Axel Enders

Stephen Ducharme Publications

The structure and cooperative proton ordering of two-dimensional sheets of croconic acid were studied with scanning tunneling microscopy and first-principles calculations. Unlike in the crystalline form, which exhibits a pleated, densely packed polar sheet structure, the confinement of the molecules to the surface results in hydrogenbonded chiral clusters and networks. First-principles calculations suggest that the surface stabilizes networks of configurational isomers, which arise from direct hydrogen transfer between their constituent croconic acid monomers. Some of these configurations have a net polarization. It is demonstrated through constrained molecular dynamics simulations that simultaneous proton transfer between any two molecules can occur spontaneously. …

Infrared Phonon Modes In Multiferroic Single-Crystal Fete2o5br, K. H. Miller, X. S. Xu, H. Berger, V. Cracium, Xiaoxiang Xi, C. Martin, G. L. Carr, D. B. Tanner

Xiaoshan Xu Papers

Reflection and transmission as a function of temperature (7–300 K and 5–300 K respectively) have been measured on single crystals of the multiferroic compound FeTe₂O₅Br utilizing light spanning from the far infrared to the visible. The complex dielectric function and other optical properties were obtained via Kramers-Kronig analysis and by fits to a Drude-Lortentz model. Analysis of the anisotropic excitation spectra via Drude-Lorentz fitting and lattice dynamical calculations have led to the observation of 43 of the 53 modes predicted along the b axis of the monoclinic cell. The phonon response parallel to the a and …

Growth Diagram Of La0.7sr0.3mno3 Thin Films Using Pulsed Laser Deposition, Hangwen Guo, Dali Sun, Wenbin Wang, Zheng Gai, Ivan Kravchenko, Jian Shao, Lu Jiang, Thomas Z. Ward, Paul C. Snijders, Lifeng Yin, Jian Shao, Xiaoshan Xu

Xiaoshan Xu Papers

An experimental study was conducted on controlling the growth mode of La_0.7Sr_0.3MnO₃ thin films on SrTiO₃ substrates using pulsed laser deposition (PLD) by tuning growth temperature, pressure, and laser fluence. Different thin film morphology, crystallinity, and stoichiometry have been observed depending on growth parameters. To understand the microscopic origin, the adatom nucleation, step advance processes, and their relationship to film growth were theoretically analyzed and a growth diagram was constructed. Three boundaries between highly and poorly crystallized growth, 2D and 3D growth, stoichiometric and non-stoichiometric growth were identified in the growth diagram. A good …

Room-Temperature Multiferroic Hexagonal Lufeo3 Films, Wenbin Wang, Jun Zhao, Wenbo Wang, Zheng Gai, Nina Balke, Miaofang Chi, Ho Nyung Lee, Wei Tian, Leyi Zhu, Xuemei Cheng, David J. Keavney, Jieyu Yi, Thomas Z. Ward, Paul C. Snijders, Hans M. Christen, Weida Wu, Jian Shen, Xiaoshan Xu

Xiaoshan Xu Papers

The crystal and magnetic structures of single-crystalline hexagonal LuFeO₃ films have been studied using x-ray, electron, and neutron diffraction methods. The polar structure of these films are found to persist up to 1050 K; and the switchability of the polar behavior is observed at room temperature, indicating ferroelectricity. An antiferromagnetic order was shown to occur below 440 K, followed by a spin reorientation resulting in a weak ferromagnetic order below 130 K. This observation of coexisting multiple ferroic orders demonstrates that hexagonal LuFeO₃ films are room-temperature multiferroics.

Stacking Principle And Magic Sizes Of Transition Metal Nanoclusters Based On Generalized Wulff Construction, S. F. Li, X. J. Zhao, X. S. Xu, Y. F. Gao, Zhenyu Zhang

Xiaoshan Xu Papers

Nanoclusters with extra stability at certain cluster sizes are known as magic clusters with exotic properties. The classic Wulff construction principle, which stipulates that the preferred structure of a cluster should minimize its total surface energy, is often invoked in determining the cluster magicity, resulting in close-shelled Mackay icosahedronal clusters with odd-numbered magic sizes of 13, 55, 147, etc. Here we use transition metal clusters around size 55 as prototypical examples to demonstrate that, in the nanometer regime, the classic Wulff construction principle needs to be generalized to primarily emphasize the edge atom effect instead of the surface energy. Specifically, …

Proton Transfer In Surface-Stabilized Chiral Motifs Of Croconic Acid, Donna A. Kunkel, James Hooper, Scott Simpson, Geoffrey A. Rojas, Stephen Ducharme, Timothy Usher, Eva Zurek, Axel Enders

Physics Faculty Publications

The structure and cooperative proton ordering of two-dimensional sheets of croconic acid were studied with scanning tunneling microscopy and first-principles calculations. Unlike in the crystalline form, which exhibits a pleated, densely packed polar sheet structure, the confinement of the molecules to the surface results in hydrogen-bonded chiral clusters and networks. First-principles calculations suggest that the surface stabilizes networks of configurational isomers, which arise from direct hydrogen transfer between their constituent croconic acid monomers. Some of these configurations have a net polarization. It is demonstrated through constrained molecular dynamics simulations that simultaneous proton transfer between any two molecules can occur spontaneously. …

Infrared Dielectric Anisotropy And Phonon Modes Of Rutile Tio2, Rafal Korlacki, Stefan Schöche, Tino Hofmann, Tom E. Tiwald, Mathias Schubert

Department of Electrical and Computer Engineering: Faculty Publications

Spectroscopic ellipsometry in the mid-infrared and far-infrared spectral range and generalized ellipsometry in the mid-infrared spectral range are used to investigate the anisotropic dielectric response of rutile TiO₂. The ordinary and extraordinary dielectric function tensor components and all infrared active phonon mode parameters of single crystalline rutile TiO₂ are determined with high accuracy for wavelengths from 3 μm to 83 μm. The data were acquired from samples of (001), (100), and (111) surfaces cut from bulk single crystals. A factorized model dielectric function is employed in order to determine the frequencies and damping parameters of the transverse …

Diffusion Of Gold Nanoparticles In Synthetic And Biopolymer Solutions, Indermeet Kohli

Wayne State University Dissertations

Soft matter systems of colloidal particles, polymers, amphiphiles and liquid crystals are ubiquitous in our everyday life. Food, plastics, soap and even human body is comprised of soft materials. Research conducted to understand the behavior of these soft matter systems at molecular level is essential for many interdisciplinary fields of study as well as important for many technological applications.

We used gold nanoparticles (Au NPs) to investigate the length-scale dependent dynamics in semidilute poly(ethylene glycol) (PEG)-water, bovine serum albumin (BSA)-phosphate buffer, dextran and particulate solutions. In case of PEG-water solutions, fluctuation correlation spectroscopy was used to measure the diffusion coefficients …

Investigation Of Nbnx Thin Films And Nanoparticles Grown By Pulsed Laser Deposition And Thermal Diffusion, Ashraf Hassan Farha

Electrical & Computer Engineering Theses & Dissertations

Niobium nitride films (NbNx) were grown on Nb and Si (100) substrates using pulsed laser deposition (PLD), laser heating, and thermal diffusion methods. Niobium nitride films were deposited on Nb substrates using PLD with a Q-switched Nd: YAG laser (λ = 1064 nm, 40 ns pulse width, and 10 Hz repetition rate) at different laser fluences, different nitrogen background pressures and deposition temperatures. The effect of changing PLD parameters for films done by PLD was studied. The seen observations establish guidelines for adjusting the laser parameters to achieve the desired morphology and phase of the grown NbNx films.

When the …

Domain Wall Roughness And Creep In Nanoscale Crystalline Ferroelectric Polymers, Zhengguo Xiao, Shashi Poddar, Stephen Ducharme, X. Hong

Stephen Ducharme Publications

We report piezo-response force microscopy studies of the static and dynamic properties of domain walls (DWs) in 11 to 36 nm thick films of crystalline ferroelectric poly(vinylidene-fluoride-trifluorethylene). The DW roughness exponent ζ ranges from 0.39 to 0.48 and the DW creep exponent µ varies from 0.20 to 0.28, revealing an unexpected effective dimensionality of ~1.5 that is independent of film thickness. Our results suggest predominantly 2D ferroelectricity in the layered polymer and we attribute the fractal dimensionality to DW deroughening due to the correlations between the in-plane and out-of-plane polarization, an effect that can be exploited to achieve high lateral …

Origin Of The Low Frequency Radiation Emitted By Radiative Polaritons Excited By Infrared Radiation In Planar La2o3 Films, Anita J. Vincent-Johnson, Yosep Schwab, Harkirat S. Mann, Mathieu Francoeur, James S. Hammonds Jr., Giovanna Scarel

Department of Physics and Astronomy - Faculty Scholarship

Upon excitation in thin oxide films by infrared radiation, radiative polaritons are formed with complex angular frequency ω, according to the theory of Kliewer and Fuchs (1966 Phys. Rev. 150 573). We show that radiative polaritons leak radiation with frequency ωi to the space surrounding the oxide film. The frequency ωi is the imaginary part of ω. The effects of the presence of the radiation leaked out at frequency ωi are observed experimentally and numerically in the infrared spectra of La2O3 films on silicon upon excitation by infrared radiation of the 0TH type radiative polariton. The frequency ωi is found …

Scaling Of The Coercive Field In Ferroelectrics At The Nanoscale, R. V. Gaynutdinov, M. Minnekaev, S. Mitko, A. L. Tolstikhina, A. Zenkevich, Stephen Ducharme, Vladimir M. Fridkin

Stephen Ducharme Publications

The scaling of the coercive field in ferroelectric films at the nanoscale is investigated experimentally. The scaling in the films of copolymer vinylidene fluoride and BaTiO3 with thickness equal by the order of value to the critical domain nucleus size 1–10 nm reveals deviation from the well-known Kay–Dunn law. At this thickness region coercive field does not depend on thickness and coincides with Landau–Ginzburg–Devonshire value.

Rhodizonic Acid On Noble Metals: Surface Reactivity And Coordination Chemistry, Donna A. Kunkel, James Hooper, Scott Simpson, Sumit Beniwal, Katie L. Morrow, Douglas C. Smith, Kimberly Cousins, Stephen Ducharme, Eva Zurek, Axel Enders

Stephen Ducharme Publications

A study of the two-dimensional crystallization of rhodizonic acid on the crystalline surfaces of gold and copper is presented. Rhodizonic acid, a cyclic oxocarbon related to the ferroelectric croconic acid and the antiferroelectric squaric acid, has not been synthesized in bulk crystalline form yet. Capitalizing on surface-assisted molecular self-assembly, a two-dimensional analogue to the well-known solution-based coordination chemistry, two-dimensional structures of rhodizonic acid were stabilized under ultrahigh vacuum on Au(111) and Cu(111) surfaces. Scanning tunneling microscopy, coupled with first-principles calculations, reveals that on the less reactive Au surface, extended two-dimensional islands of rhodizonic acid are formed, in which the molecules …

Changing Molecular Band Offsets In Polymer Blends Of (P3ht/P(Vdf–Trfe)) Poly(3-Hexylthiophene) And Poly(Vinylidene Fluoride With Trifluoroethylene) Due To Ferroelectric Poling, Freddy Wong, Godohaldo Perez, Manuel Bonilla, Juan A. Colon-Santana, Xin Zhang, Pankaj Sharma, Alexei Gruverman, Peter A. Dowben, Luis G. Rosa

Peter Dowben Publications

Photoelectron emission and inverse photoemission spectroscopy studies of polymer blends of poly(vinylidene fluoride (70%) – trifluoroethylene (30%)) P(VDF–TrFE 70 : 30) and regio-regular poly(3- hexylthiophene) (P3HT) provide evidence of changes in the molecular band offsets as a result of changes in the ferroelectric polarization in P(VDF–TrFE). Investigation of the blends with higher concentrations of the semiconducting P3HT component revealed that the organic semiconductor component of the blend dominates the electronic structure in the vicinity of the chemical potential. Specifically, the states of P3HT at the conduction band minimum and valence band maximum fall within the HOMO–LUMO gap of the dielectric …

Induced Magneto-Electric Coupling In Ferroelectric/Ferromagnetic Heterostructures, Jeffery Carvell, Ruihua Cheng, Peter A. Dowben, Q Yang

Peter Dowben Publications

Using an external magnetic field, we have demonstrated room temperature control of the electric polarization of a ferroelectric polymer, polyvinylidene fluoride (PVDF), in an artificial multiferroic structure. For ferroelectric PVDF polymer thin films in an iron-PVDF-iron heterostructure, both the ferroelectric coercivity and polarization display a hysteresis dependence on the external magnetic field. We also find that the thickness of the PVDF layer has an effect on the magnetoelectric coupling in our samples. We observe a giant magnetoelectric coupling with values as large as 3700 V/cm Oe to 41700 V/cm Oe.

Magnetoelectric Coupling At The Euo/Batio3 Interface, Shi Cao, P Liu, Jinke Tang, Haidong Lu, C W. Bark, Sangjin Ryu, Chang-Beom Eom, Alexei Gruverman, Peter A. Dowben

Peter Dowben Publications

Magnetization modulation by ferroelectric polarization switching is reported for the ferromagnetic-ferroelectric EuO/BaTiO₃heterostructure. The value of the magnetization critical exponent β is consistent with the expected Heisenberg-like ferromagnetism of EuO and reported Curie temperature. The critical exponent is seen to decrease with increased magnetic coupling. The results are discussed in the context of data obtained earlier for epitaxial La_0.67Sr_0.33MnO₃/BaTiO₃ heterostructures, where magnetization increases and critical exponent b also declines with ferroelectric polarization pointing away from ferromagnetic layer. The observed similarity between two systems illustrates an importance of charge doping in magnetoelectric coupling, …