Condensed Matter Physics Commons^™

Mesoscopic Scaling Of Microwave Transmittance And Disorder-Induced Alignment, Israel Kurtz

Dissertations, Theses, and Capstone Projects

This thesis presents microwave measurements and numerical simulations of wave propagation and transmission through random mesoscopic waveguides. We analyze the scaling of mesoscopic microwave conductance, including departures from Ohm’s law near channel openings, which are frequencies at which new propagating modes enter the system, and the evolution of modal phase alignment within the medium, which leads to the observed diversity of transmission eigenvalues. We extend the transmission matrix formalism to all sample depths using the flux matrix, which relates the flux amplitude within the sample to the incident flux, and decompose the flux at each sample depth into forward- and …

Field-Like- And Self-Spin-Orbit Torques In Magnetic Multilayer Films, Kyle Jeffrey Peterson

Electronic Theses and Dissertations

Spin-orbit torques (SOTs) have been realized as an energy efficient mechanism to manipulate and drive magnetization dynamics in magnetic multilayer films. Their damping-like and field-like components provide distinct pathways for controlling the magnetization, enabling switching, sustaining magneto-oscillations, and driving domain-wall motion with potential applications in nonvolatile memory, spin-based logic, and microwave signal generation. However, the accurate quantification and interpretation of these torques remains complicated by experimental sensitivity, the co-symmetry of the Oersted field and the effective field due to the field-like torque, and assumptions regarding the material layers from which the torques originate. The body of work set forth in …

Synthesis And Characterization Of Carbon Quantum Dots And Gold Nanoparticles For Norovirus Biosensing Applications In Water Systems, Breanne Evans

Master's Theses

Rapid, reliable detection of viral pathogens remains a significant challenge across water-treatment and environmental monitoring systems, including drinking-water, wastewater, water reuse, and environmental surveillance applications. Waterborne viral contamination can pose substantial public-health risks, making early detection essential for protecting water quality and responding quickly to treatment failures or contamination events. Direct potable reuse (DPR) is one particularly demanding example because it requires continuous verification of treatment performance and the broader need for rapid virus monitoring extends across many water-treatment and environmental surveillance applications. Norovirus is a priority target because of its widespread occurrence in wastewater, environmental persistence, and exceptionally low …

Atomic-Scale Investigation Of Functional Molecular Systems And Graphene Nanoribbons Using Scanning Probe Microscopy, A.M. Shashika D. Wijerathna

Physics Theses & Dissertations

Emerging molecular electronics, molecular devices, and carbon-based nanotechnologies increasingly rely on the precise control of molecular structures and interfaces at the atomic scale. Advancing these systems requires experimental techniques capable of resolving atomic structures, quantifying molecular behavior, and revealing the mechanisms governing nanoscale assembly. Scanning probe microscopy uniquely provides these capabilities by combining atomic-resolution imaging with local spectroscopy and manipulation. This dissertation employs ultra-high-vacuum low-temperature scanning tunneling microscopy (UHV-LT-STM) and qPlus atomic force microscopy (qPlus AFM) to address three complementary challenges: (i) atomic-scale characterization of complex supramolecular architectures, (ii) quantitative investigation of mechanically induced conformational switching of individual molecules, and …

A Study On The Complex Doping Of Na2x2teo6 (X = Ni, Cu, Fe, Co, Zn), Omar Salas

Open Access Theses & Dissertations

Na2Ni2TeO6 is a layered honeycomb antiferromagnet in which Ni2+ ions form magnetic honeycomb planesseparated by sodium layers. In this work, four compositionally complex oxides derived from Na2Ni2TeO6 were synthesized to test whether the NNTO-type structure remains stable when 50% of the Ni sublattice is replaced by mixtures of Cu, Zn, Fe, and Co. Powder X-ray diffraction and neutron powder diffraction show that all four samples retain the hexagonal P 63/mcm average structure of the parent NNTO phase, demonstrating that the layered honeycomb framework is stable against substantial multiple-cation substitution. A small CoFe2O4 secondary phase is present in all four samples …

Establishing Ferromagnetism In Van Der Waals Antiferromagnets Mps3, Dinesh Upreti

Graduate Theses and Dissertations

Recent discoveries of magnetism in low dimensions not only have gained fundamental scientific interest but also holds significant potential in numerous technological applications, such as spintronics. This has led to a wide range of efforts in the synthesis of new layered materials or tuning their existing magnetic properties, which has been instrumental in understanding the novel physical concept and development of new technological frontiers. Transition metal thiophosphate, MPS3, is a class of layered antiferromagnet family. The rich magnetic/crystal structure with delicate choice of transition metal (M) together with intriguing optical, electronic, and ferroelectric properties have placed them as a model …

Fabrication Of Two-Dimensional Optoelectrical Devices, Holly Walworth

Honors Projects

Optoelectrical devices enable the exploration of interesting quantum states observed in two-dimensional (2D) condensed material systems. 2D materials, such as graphene and transition metal dichalcogenides, exhibit unique electronic properties, including the Fractional Quantum Anomalous Hall effect (FQAHE). The realization of the FQAHE offers a pathway toward topological quantum computing via non-Abelian anyons. Still, fabricating high-quality 2D optoelectrical devices remains a significant experimental challenge. Using mechanical exfoliation and stacking techniques within an inert argon environment, we attempted to fabricate optoelectrical devices using twisted molybdenum ditelluride (tMoTe2) and gallium telluride (GaTe). Three devices were successfully assembled; however, structural defects including hexagonal boron …

Momentum Space Algorithm For Electronic Structure Of Double-Incommensurate Trilayer Graphene, Kenneth Silver Beard

LSU Doctoral Dissertations

Numerical algorithms for computing the electronic structure of incommensurate 2D-materials using ab initio models are critical for predicting material properties and guiding experiments. For bilayers, momentum space and continuum models have been introduced to approximate observables of ab initio tight-binding models using a momentum description, despite the lack of periodicity in the tight-binding model required for Bloch theory. A similar structure has been introduced for double-incommensurate trilayers using a continuum model, where the three lattices are mutually incommensurate. However, this description leads to a four-dimensional lattice space, and numerical convergence of the density of states has been observed to be …

Designing Enhanced Nonlinearity In Plasmonic Devices With Epsilon-Near-Zero Films, Kevin Tran Le

Electrical Engineering and Computer Science (MS) Theses

The growing demand for energy-efficient optical information processing motivates compact nonlinear photonic devices that can operate at low power. Silicon photonics is a mature platform for linear optical functions, but nonlinear operation remains challenging because of its weak Kerr response, two-photon absorption at telecommunication wavelengths, and limited compatibility with deeply subwavelength plasmonic confinement. This thesis computationally investigates epsilon-near-zero thin films integrated into plasmonic waveguide architectures as a route toward stronger light–matter interaction in compact nonlinear devices.

Two waveguide geometries are examined: a hybrid metal-insulator-metal plasmonic slab waveguide incorporating an ultrathin indium tin oxide epsilon-near-zero layer (5–50 nm), and a dielectric-loaded …

Strain Engineering Of Excitonic And Vibrational Properties In Two-Dimensional Transition Metal Dichalcogenides, Sneha Minesh Patel

Graduate Theses and Dissertations

Mechanical strain represents a robust and non-invasive method for tuning the electronic and vibrational properties of two-dimensional transition-metal dichalcogenides (TMDs). This work examines homogeneous biaxial strain as a symmetry-preserving control parameter that governs excitonic and interlayer dynamics in atomically thin TMDs. In monolayer MoSe2, biaxial tensile strain is intrinsically generated during high-temperature physical vapor deposition due to thermal expansion mismatch with amorphous substrates. Optical spectroscopy demonstrates substantial and tunable excitonic energy shifts exceeding 100 meV per percent strain. Polarization-resolved second harmonic generation confirms the retention of lattice symmetry under biaxial deformation. The investigation is further extended to bilayer MoS2, where …

First-Principles Study Of Uranium Mononitride, Roy Noe Herrera Navarro

Open Access Theses & Dissertations

This thesis presents a first-principles investigation of uranium mononitride (UN), withemphasis on the connection between uranium 5f electron correlation and defect stability. Electronic-structure calculations were performed within density functional theory using the Vienna Ab initio Simulation Package. Exchange-correlation effects were treated within the generalized gradient approximation, and a Hubbard correction was applied to the uranium 5f manifold. The adopted Hubbard parameter was motivated by first-principles linear-response analysis and considered in the broader context of DFT+DMFT descriptions of correlated uranium systems, including recent interpretations of UN as a Hund-metal system. Bulk UN was studied in unit-cell and 2 x 2 x …

Structural Relaxation In Glass-Forming Liquids At Extreme Pressure: Photon-Correlation Spectroscopy And Constrained Thermodynamic Surface Modeling, Kevin Wayne Lyon

Graduate Theses and Dissertations

Structural relaxation in glass-forming liquids is strongly dependent on both temperature and pressure, yet direct measurement of structural α-relaxation under multi-gigapascal compression has remained experimentally challenging. This work extends depolarized photon correlation spectroscopy (DPCS) to pressures approaching 5 GPa in a diamond anvil cell, representing the highest-pressure implementation of this technique and enabling direct measurement of the structural α-relaxation in a pure liquid at extreme compression. This capability provides access to dynamical regimes previously unexplored by photon correlation spectroscopy and establishes a platform for probing glassy dynamics at high pressure. To describe these measurements, a constrained relaxation-time surface framework is …

Exactly Solving One-Dimensional Models For The Fractional Quantum Hall Effect, Joseph R. Cruise

Arts & Sciences Graduate Student Theses and Dissertations

Nearly fifty years after its experimental debut, the quantum hall effect has produced perhaps more unique descriptions than any other subject of condensed matter physics. From topological band theory to non-commutative geometry, topological and conformal field theories, random matrix models and more, each approach captures a subset of the essential features, and compliments the others to produce a beautiful mosaic description. In this thesis, we revisit the fractional quantum hall (FQH) effect from its oldest vantage point, that of the trial wavefunctions and the parent Hamiltonians which stabilize them. Laughlin's observation of the importance of the theory of holomorphic functions …

The Role Of Interactions In Moiré Quantum Materials, Liangtao Peng

Arts & Sciences Graduate Student Theses and Dissertations

Moiré quantum materials have emerged as a highly tunable platform for studying strongly interacting electrons in low dimensions. By twisting or lattice-mismatching atomically thin crystals, one can generate long-wavelength moiré superlattices that reconstruct the electronic bands, produce narrow bandwidths, and greatly enhance the importance of Coulomb interactions. As a result, these systems host a wide range of correlated phenomena, including symmetry breaking, magnetism, and superconductivity. This dissertation develops and applies Green's-function-based many-body methods to understand the role of interactions in moiré quantum materials. This dissertation consists of four chapters. The first chapter introduces moiré quantum materials and reviews the basic …

3Ω Thermal Transport In Atomically Thin Materials, Yiwei Le

Arts & Sciences Graduate Student Theses and Dissertations

Since the discovery of graphene, research on two-dimensional (2D) materials has become a central focus of condensed matter physics. While an enormous number and variety of investigations of their electrical, optical, and mechanical properties have been undertaken, their thermal properties remain comparatively underexplored, despite the importance for understanding low-energy excitations and phase transitions. Here, we introduce an extension of the 3ω method thermal measurement technique to the 2D limit of materials. We develop analytical models of thermal transport in the 3ω geometry with boundary conditions tailored for suspended 2D flakes. We then experimentally confirm the feasibility of this approach in …

Optimization Of Niobium Film For Particle Accelerators And Quantum Applications, Bektur Abdisatarov

Electrical & Computer Engineering Theses & Dissertations

Niobium (Nb) films play a central role in superconducting technologies used in particle accelerators and superconducting quantum circuits. Optimizing the physical properties of Nb films is therefore critical for improving both radiofrequency (RF) performance in superconducting radiofrequency (SRF) cavities and coherence in superconducting qubits. This thesis investigates the relationship between Nb film microstructure, impurity content, and electromagnetic response across these two application domains.

For particle accelerator applications, we studied Nb films deposited using high-power impulse magnetron sputtering (HiPIMS) with DC bias onto a 1.3 GHz elliptical SRF cavity. Nb film cavities exhibit a pronounced medium-field Q-slope, limiting their achievable accelerating …

Extension Of The Local Vibrational Mode Theory To Periodic Systems, Filippo Bodo

Chemistry Theses and Dissertations

Over the years, vibrational spectroscopy was used to gain a deeper understanding of the electronic structure and the chemical bond in both molecular and periodic systems. In this framework, the Local Vibrational Mode Theory (LVMT), as first introduced by Konkoli and Cremer in 1998, provides a unique tool to quantify the strength of a chemical bond, and better interpret the molecular vibrational spectra, thanks to the adiabatic force constants ($k^a$) and the composition of normal modes (CNM). While LVMT was originally developed for molecular systems, its application to periodic solids has remained limited. This thesis presents a complete and systematic …

Electronic Transport In Twisted Bilayer Tungsten Diselenides, Walid Zaher

Theses and Dissertations

This thesis investigates density waves (DWs) in twisted bilayer tungsten diselenide (tWSe₂) using a mean field approximation, with a focus on electron-electron interactions, and the system’s free energy at zero temperature. For the mean field approximation, the study initially employed same-spin nesting vectors, which were found insufficient to induce DWs formation. In contrast, when opposite-spin nesting vectors were used, DWs emerged, indicating that these vectors can support DWs formation. The plots were produced under perfect nesting conditions, where van Hove singularities (VHS) occur. At zero temperature, perfect nesting provides a complete picture of the upper limit of DWs formation, as …

Ultrafast Terahertz Spectroscopy And The Suppression Of Superconductivity In Strained Iron Selenide Below 1 Kelvin, Tracy Glen Hastings

ETDs from 2020-2029

We report on terahertz time-domain spectroscopy measurements of iron selenide thin films of various thicknesses grown on a magnesium oxide substrate, focusing on the frequency-dependent complex conductivity in the range of 0.25 - 7 THz. By an- alyzing films with and without an approximately 100 nm thick Se capping layer, we examined the role of oxidation in the suppression of superconductivity. X-ray photo- electron spectroscopy data confirmed that oxidation was effectively mitigated, yet the films exhibited insulating behavior down to 200 mK, a temperature range that has not been extensively studied in this system. Our results indicate that the suppression …

Magnetic Anisotropy Engineering In Rare-Earth-Free Iron-Based Magnetic Materials, Pramanand Joshi

Physics Dissertations - Archive

The development of high-performance, rare-earth-free hard magnetic materials is critical for next-generation energy, information, and spin-based technologies. This dissertation investigates structure-property relationships in iron-based magnetic systems, including iron carbides, Fe-Co-B boride alloys, hexaferrites, and FeCo nanostructures, synthesized via chemical and metallurgical routes. Through controlled synthesis and comprehensive structural and magnetic characterization, this work demonstrates that magnetic anisotropy, coercivity, and thermal stability can be systematically controlled through morphology design, compositional tuning, microstructural refinement, and interparticle interaction modulation.

Morphology-driven enhancement of magnetic properties, particularly coercivity and blocking temperature, is established in phase-pure Fe₅C₂ nanostructures. By precisely controlling particle geometry, …

Applications Of Doppler Broadening Spectroscopy For The Characterization Of The Surface And Near Surface Of Two-Dimensional Heterostructures, Hany M. Mahdy

Physics Dissertations

This dissertation describes experiments and the analysis of Doppler broadening spectroscopy applied to metal surfaces (Cu, Ag, Au), graphene/Cu heterostructures, and SiGe heterostructures, with particular emphasis on the development of new approaches for extracting quantitative information from annihilation spectra.

The first part establishes the capability of Doppler broadening spectroscopy, particularly coincidence Doppler broadening (CDB), as a surface-sensitive technique. Measurements on clean and adsorbate-covered Cu, Ag, and Au surfaces demonstrate that Doppler-broadened annihilation spectra retain element-specific signatures from the topmost atomic layer. New analysis methods based on ratio-curve modeling enable identification and quantification of sub-monolayer adsorbates, including sulfur, oxygen, selenium, and …

Ultrafast Vibrational Dynamics In Important Wide-Bandgap Semiconductors, Dielectrics And Energetic Materials, Dinusha Madushanka Senarathna

Open Access Dissertations

This dissertation applies time-resolved coherent anti-Stokes Raman scattering (tr-CARS), to measure ultrafast vibrational dynamics in technologically important solid-state and van der Waals molecular systems. The central goal is to use time-domain Raman methods to resolve mode-specific phonon and vibrational dephasing processes with high temporal precision, high spectral selectivity, and sufficient experimental flexibility to probe materials ranging from wide-bandgap semiconductors and oxide crystals to energetic molecular crystals. Across the work, I show that carefully designed tr-CARS measurements can access vibrational lifetimes from hundreds of femtoseconds to several picoseconds, enabling direct observation of decay pathways, relaxation mechanisms, and dispersion effects that shape …

Harnessing Coherent-Wave Control For Sensing Applications In Scattering Media, Pablo Xavier Jara Palacios

Doctoral Dissertations

"Diffuse electromagnetic waves are widely used for non-invasive sensing and imaging in complex scattering media such as biological tissues. A fundamental limitation of such techniques is the scarcity of detected photons: as the source-detector separation increases to access deeper regions of the medium, the signal strength decays rapidly, leading to poor signal-to-noise ratio and limited sensitivity. This dissertation addresses this challenge through a combination of theory and computation.

We show that coherent control of the incident optical wavefront can compensate for the scarcity of detected photons that limits conventional diffuse optical imaging, typically performed in the near-infrared spectral region. By …

Nanostructured Cathode Catalysts For Aem Electrolysis: From Catalyst Design To Degradation And Hydrogen Dynamics, Yamini Kumaran

Electronic Theses & Dissertations (2024 - present)

Anion exchange membrane water electrolysis (AEMWE) presents a promising pathway toward cost-effective and sustainable hydrogen production by integrating the chemical robustness of alkaline systems with the compact, zero-gap design of proton exchange membrane electrolyzers. However, the widespread implementation of AEMWE is limited by the availability of highly active and durable platinum-group-metal (PGM)-free catalysts and by an incomplete understanding of their degradation behavior under realistic operating conditions.

This dissertation focuses on the development, characterization, and mechanistic investigation of nanostructured MoNi₄–MoO₂-based electrodes for efficient and stable hydrogen generation under alkaline and membrane-integrated environments. MoNi₄–MoO₂ nanorods …

Growth And Dielectric Characterization Of Epitaxial Sr1-Xmgxtio3 Thin Films, Richard Badu

UNF Graduate Theses and Dissertations

Complex oxide materials with ferroelectric ground states remain promising candi dates for next-generation high-capacitance and nonlinear microelectronic applica tions. One of those materials is SrTiO3 (STO). However, STO is an incipient fer roelectric with anomalously high dielectric permittivity at low temperatures. STO crystals possess a highly polarizable lattice that is sensitive to even small amounts of impurities. Substituting Mg into the STO matrix is predicted to induce a corre lation between ferroelectric and relaxor behavior. In this thesis, we demonstrated the growth of a series of epitaxial STO and Sr1-xMgxTiO3 thin films using molec ular beam epitaxy. The surface evolution …

First-Principles Investigation Of Quasi-One-Dimensional Van Der Waals Magnets For Advancing Low-Dimensional Spintronics, Alyssa Horne

Dissertations, Master's Theses and Master's Reports

Van der Waals (vdW) magnets have been of great interest for advancing low- dimensional spintronics. A notable example is the quasi-one-dimensional (Q1D) vdW CrSbSe₃, as it is composed of individual one-dimensional units that are held together by the vdW forces. Finding other Q1D vdW magnets that exhibit non-metallic behavior together with long range ferromagnetic ordering is critical in developing next generation spintronics. Here in, using first-principles density functional theory (DFT), we investigate the compositional effects on electronic and magnetic behavior of Cr_1–xMn_xSbSe₃ (x = 0, 0.5, 1). When 50% of Cr is replaced …

Investigating The Effects Of Pressure On Fe And Co Intercalated 2h-Tas2 Through First-Principle Calculations, Ronald E. Putnam Jr.

UNF Graduate Theses and Dissertations

Using first-principles methods, we investigate the effects of applied isotropic pressure on the electronic and magnetic properties of intercalated Fe1/3TaS2 and Co1/3TaS2. Fe1/3TaS2 has been shown to be a ferromagnet that undergoes structural and magnetic phase transitions under applied pressure. The magnetic phase transitions are observed to be linked to the structural shift, and a mixture of magnetic phase states is present between 3 GPa and 6 GPa. Co1/3TaS2 was found to be antiferromagnetic, as confirmed by experimental work. One- and two-unit-cell systems of Co1/3TaS2 are analyzed, both showing band splitting that disappears under pressure. The application of pressure forces …

Investigating A Nanoparticle-Assisted Approach For Localized Strain Engineering In Two-Dimensional Materials, Skye Martichuski

Honors Theses and Capstones

This work investigated a fabrication strategy for inducing localized nanoscale deformation and strain in transferred MoS2 flakes using gold nanoparticle-coated substrates as a potential platform for strain engineering in two-dimensional materials. Substrate type, nanoparticle concentration, drying conditions, cleaning procedures, and flake transfer methods were investigated using optical microscopy and atomic force microscopy (AFM). Au-coated SiO2 substrates produced improved nanoparticle coverage compared to bare SiO2, while passive air drying yielded the most favorable nanoparticle distributions. Salt crystals introduced during passive drying were successfully removed with a gentle deionized water rinse, and a 50% diluted gold nanoparticle suspension provided improved particle spacing …

Charge Transport Modeling Of Multifunctional Molecular Transistors, Romena Akter

Graduate Studies Theses and Dissertations 2026

Distinguishing between the current–voltage characteristic curves associated with different transport mechanisms in a molecular electronic device and an artifact arising from device-level disorder is a central challenge in the study of molecular electronics. Characterizing these mechanisms and connecting them qualitatively to molecular-level orbital alignment, electrode coupling, voltage division, energetic disorder, and reorganization energy requires not only experimental data but also a rigorous theoretical framework for extracting physically meaningful parameters from measured transfer characteristics. This dissertation addresses this challenge in Chapters 2, 3, and 4 by developing and applying four complementary transport models —Simmons tunneling, single-level Landauer, Marcus hopping, and McConnell …

Investigation Of Exotic Phenomena In Topological Quantum Materials, Iftakhar Bin Elius

Graduate Studies Theses and Dissertations 2026

he First Quantum Revolution established quantum mechanics as the foundation of modern physics, enabling transformative technologies such as semiconductors, lasers, and transistors through prin-ciples of quantization, wave-particle duality, and uncertainty. The ongoing Second Quantum Rev-olution harnesses entanglement, superposition, and coherence to advance quantum computation, communication, simulation, and sensing. Central to this endeavor is the study of quantum mate-rials hosting novel electronic structures and emergent phases, including topological insulators and Dirac, Weyl, and nodal-line semimetals. In this thesis, using angle-resolved photoemission spec-troscopy (ARPES), transport measurements, and density functional theory (DFT) calculations, we investigate three classes of materials: (i) magnetic topological semimetals, …