Oceanography and Atmospheric Sciences and Meteorology Commons^™

Arsenic And Phosphorus Biogeochemistry In The Ocean: Arsenic Species As Proxies For P-Limitation, Oliver Wurl, Louise Zimmer, Gregory A. Cutter

OES Faculty Publications

Arsenic and phosphorus are biochemically very similar, and hence arsenate (As⁵⁺) is toxic by interfering with the energy metabolism, in particular during P limitation. However, many phytoplankton detoxify As by reducing arsenate to arsenite (As³⁺), and/or methylating it to mono and dimethyl As. Such As detoxification becomes operative in oligotrophic waters when phosphate concentrations are below those for As; therefore, we evaluated the potential use of these detoxification products as indicators of P-limitation by measuring As speciation during the US GEOTRACES North Atlantic transect. The distribution of As³⁺ concentrations in surface waters is similar to …

Intercalibraton In Chemical Oceanography-- Getting The Right Number, Gregory A. Cutter

OES Faculty Publications

Intercalibration has a strict metrological definition, but in brief, it's an open sharing of methods and results between laboratories to achieve the most accurate data with the fewest random and systematic errors. In the field of chemical oceanography where concentrations of many constituents can be in the nano- to picomolar range, the salt water matrix can be difficult to analyze, and knowing the exact concentrations, or even chemical forms, of biologically required elements is essential, intercalibration is a very relevant and needed tool. Implementing it is not simple because errors can occur at any step in the process of taking …

Phosphorus Cycling In The Sargasso Sea: Investigation Using The Oxygen Isotopic Composition Of Phosphate, Enzyme-Labeled Fluorescence, And Turnover Times, Karen Mclaughlin, Jill A. Sohm, Gregory A. Cutter, Michael W. Lomas, Adina Paytan

OES Faculty Publications

Dissolved inorganic phosphorus (DIP) concentrations in surface water of vast areas of the ocean are extremely low (<10 nM) and phosphorus (P) availability could limit primary productivity in these regions. We explore the use of oxygen isotopic signature of dissolved phosphate (δ¹⁸O_PO4) to investigate biogeochemical cycling of P in the Sargasso Sea, Atlantic Ocean. Additional techniques for studying P dynamics including ³³P-based DIP turnover time estimates and percent of cells expressing alkaline phosphatase (AP) activity as measured by enzyme-labeling fluorescence are also used. In surface waters, δ¹⁸O_PO4 values were lower than equilibrium by 3–6%, indicative of dissolved organic phosphorous (DOP) remineralization by extracellular enzymes. An isotope mass balance model using a variety of possible combinations of …

Using Ammonium Pore Water Profiles To Assess Stoichiometry Of Deep Remineralization Processes In Methanogenic Continental Margin Sediments, David J. Burdige, Tomoko Komada

OES Faculty Publications

In many continental margin Sediments, a deep reaction zone exists which is separated from remineralization processes near the sediment surface. Here, methane diffuses upward to a depth where it is oxidized by downwardly diffusing sulfate. However, the methane sources that drive this anaerobic oxidation of methane (AOM) in the sulfate-methane transition zone (SMT) may vary among sites. In particular, these sources can be thought of as either (i) "internal" sources from in situ methanogenesis (regardless of where it occurs in the sediment column) that are ultimately coupled to organic matter deposition and burial, or (ii) "external" sources such as hydrocarbon …

Surface Production Fuels Deep Heterotrophic Respiration In Northern Peatlands, J. Elizabeth Corbett, David J. Burdige, Malak M. Tfaily, Angela R. Dial, William T. Cooper, Paul H. Glaser, Jeffrey P. Chanton

OES Faculty Publications

Multiple analyses of dissolved organic carbon (DOC) from pore waters were conducted to define the processes that govern carbon balance in peatlands: (1) source, reactivity, and transport of DOC with respect to vegetation, peat, and age of carbon substrate, (2) reactivity of DOC with respect to molecular size, and (3) lability to photoxidation of surficial DOC. We found that surface organic production fuels heterotrophic respiration at depth in advection-dominated peatlands, especially in fens. Fen DOC was Δ¹⁴Cenriched relative to the surrounding fen peat, and fen respiration products were similar to this enriched DOC indicating that DOC was the …

Diatom Proteomics Reveals Unique Acclimation Strategies To Mitigate Fe Limitation, Brook L. Nunn, Jessica F. Faux, Anna A. Hippman, Maria T. Maldonado, H. Rodger Harvey, David R. Goodlett, Philip W. Boyd, Robert F. Strzepek

OES Faculty Publications

Phytoplankton growth rates are limited by the supply of iron (Fe) in approximately one third of the open ocean, with major implications for carbon dioxide sequestration and carbon (C) biogeochemistry. To date, understanding how alteration of Fe supply changes phytoplankton physiology has focused on traditional metrics such as growth rate, elemental composition, and biophysical measurements such as photosynthetic competence (Fv/Fm). Researchers have subsequently employed transcriptomics to probe relationships between changes in Fe supply and phytoplankton physiology. Recently, studies have investigated longer-term (i.e. following acclimation) responses of phytoplankton to various Fe conditions. In the present study, the coastal diatom, Thalassiosira pseudonana, …

Dinitrogen Fixation In Aphotic Oxygenated Marine Environments, Eyal Rahav, Edo Bar-Zeev, Sarah Ohayon, Hila Elifantz, Natalia Belkin, Barak Herut, Margaret R. Mulholland, Iiana Berman-Frank

OES Faculty Publications

We measured N₂ fixation rates from oceanic zones that have traditionally been ignored as sources of biological N₂fixation; the aphotic, fully oxygenated, nitrate (NO¯₃)-rich, waters of the oligotrophic Levantine Basin (LB) and the Gulf of Aqaba (GA). N₂ fixation rates measured from pelagic aphotic waters to depths up to 720 m, during the mixed and stratified periods, ranged from 0.01 nmol N L^-1 d^-1 to 0.38 nmol N L^-1 d^-1. N₂ fixation rates correlated significantly with bacterial productivity and heterotrophic diazotrophs were identified from aphotic as well as …

Effect Of Laser Ablation Depth In Otolith Life History Scans, Renée R. Hoover, Cynthia M. Jones

OES Faculty Publications

Life history scans of fish otoliths are bringing new insight into the structure, connectivity, and movement of fish populations. Data obtained from such scans, however, possess in-herent limitations that have not yet been fully addressed or understood. For example, several investigators have noted delays in otolith elemental uptake that do not appear to reflect habitat exposure. We hypothesized that the 3-dimensional structure of otoliths may produce sampling artifacts in the results obtained from laser ablation scans. To test this hypothesis, we sampled sagittal otoliths from juvenile Atlantic croaker Micropogonias undulatus with laser ablation inductively coupled plasma mass spectrometry to obtain …

Distributions Of Particulate Heme B In The Atlantic And Southern Oceans- Implications For Electron Transport In Phytoplankton, Martha Gledhill, Eric P. Achterberg, David J. Honey, Maria C. Nielsdottir, Micha J.A. Rijkenberg

OES Faculty Publications

Concentrations of heme b, the iron-containing component of b-type hemoproteins, ranged from b concentrations were enhanced in the photic zone and decreased with depth. Heme b concentrations correlated positively with chlorophyll a (chl a) in the TNA (r=0.41, pb did not correlate with chl a in the IB or SS. In the IB and SS, stations with high-chlorophyll and low-nutrient (Fe and/or Si) concentrations exhibited low heme bconcentrations relative to particulate organic carbon (< 0.1 μmolmol^-1, and high chl a:heme b ratios (> 500). High chl a:heme b ratios resulted from relative decreases in …

Combined Effects Of Co2 And Light On Large And Small Isolates Of The Unicellular N2-Fixing Cyanobacterium Crocosphaera Watsonii From The Western Tropical Atlantic Ocean, Nathan S. Garcia, Fei-Xue Fu, Cynthia L. Breene, Elizabeth K. Yu, Peter W. Bernhardt, Margaret R. Mulholland, David A. Hutchins

OES Faculty Publications

We examined the combined effects of light and pCO₂ on growth, CO₂-fixation and N₂-fixation rates by strains of the unicellular marine N₂-fixing cyanobacterium Crocosphaera watsonii with small (WH0401) and large (WH0402) cells that were isolated from the western tropical Atlantic Ocean. In low-pCO₂-acclimated cultures (190ppm) of WH0401, growth, CO₂-fixation and N₂-fixation rates were significantly lower than those in cultures acclimated to higher (present-day approximate to 385ppm, or future approximate to 750ppm) pCO² treatments. Growth rates were not significantly different, however, in low-pCO₂-acclimated cultures of …

Development And Deployment Of A Point-Source Digital Inline Holographic Microscope For The Study Of Plankton And Particles To A Depth Of 6000 M, Alexander B. Bochdansky, Manfred H. Jericho, Gerhard J. Herndl

OES Faculty Publications

Bochdansky, A. B., Jericho, M. H., & Herndl, G. J. (2013). Development and deployment of a point-source digital inline holographic microscope for the study of plankton and particles to a depth of 6000 m. Limnology and Oceanography: Methods, 11, 28-40. doi: 10.4319/lom.2013.11.28

Hci And Cio Profiles Inside The Antarctic Vortex As Observed By Smiles In November 2009: Comparisons With Mls And Ace-Fts Instruments, T. Sugita, Y. Kasai, Y. Terao, S. Hayashida, G. L. Manney, W. H. Daffer, H. Sagawa, M. Suzuki, M. Shiotani, K. A. Walker, C. D. Boone, P. F. Bernath

Chemistry & Biochemistry Faculty Publications

We present vertical profiles of hydrogen chloride (HCl) and chlorine monoxide (ClO) as observed by the Superconducting Submillimeter-Wave Limb-Emission Sounder (SMILES) on the International Space Station (ISS) inside the Antarctic vortex on 19-24 November 2009. The SMILES HCl value reveals 2.8-3.1 ppbv between 450K and 500K levels in potential temperature (PT). The high value of HCl is highlighted since it is suggested that HCl is a main component of the total inorganic chlorine Cl_y, defined as Cl_y similar or equal to HCl + ClO + chlorine nitrate ClONO₂, inside the Antarctic vortex in spring, owing …

Stratospheric Loss And Atmospheric Lifetimes Of Cfc-11 And Cfc-12 Derived From Satellite Observations, K. Minschwaner, L. Hoffmann, A. Brown, M. Riese, R. Müller, P. F. Bernath

Chemistry & Biochemistry Faculty Publications

The lifetimes of CFC-11 and CFC-12 have been evaluated using global observations of their stratospheric distributions from satellite-based instruments over the time period from 1992 to 2010. The chlorofluorocarbon (CFC) datasets are from the Cryogen Limb Array Etalon Spectrometer (CLAES), the Cryogenic Infrared Spectrometers and Telescopes for the Atmosphere (CRISTA-1 and CRISTA-2), the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS), and the Atmospheric Chemistry Experiment (ACE). Stratospheric loss rates were calculated using an ultraviolet radiative transfer code with updated cross section and solar irradiance data. Mean steady-state lifetimes based on these observations are 44.7 (36-58) yr for CFC-11 and 106.6 …

Observations Of Peroxyacetyl Nitrate (Pan) In The Upper Troposphere By The Atmospheric Chemistry Experiment-Fourier Transform Spectrometer (Ace-Fts), K. A. Tereszchuk, D. P. Moore, J. J. Harrison, C. D. Boone, M. Park, J. J. Remedios, W. J. Randel, P. F. Bernath

Chemistry & Biochemistry Faculty Publications

Peroxyacetyl nitrate (CH₃CO·O₂NO₂, abbreviated as PAN) is a trace molecular species present in the troposphere and lower stratosphere due primarily to pollution from fuel combustion and the pyrogenic outflows from biomass burning. In the lower troposphere, PAN has a relatively short lifetime and is principally destroyed within a few hours through thermolysis, but it can act as a reservoir and carrier of NO_x in the colder temperatures of the upper troposphere, where UV photolysis becomes the dominant loss mechanism. Pyroconvective updrafts from large biomass burning events can inject PAN into the upper troposphere …

Rose: Roadmaps Towards Sustainable Energy Futures And Climate Protection: A Synthesis Of Results From The Rose Project, Elmar Kriegler, Ioanna Mouratiadou, Gunnar Luderer, Nico Bauer, Katherine Calvin, Enrica Decian, Robert J. Brecha, Wenying Chen, Aleh Cherp, Jae Edmonds, Kejun Jiang, Shonali Pachauri, Fabio Sferra, Massimo Tavoni, Ottmar Edenhofer

Physics Faculty Publications

EXECUTIVE SUMMARY

Exploring energy demand and supply uncertainty: An exploration of uncertainty on drivers of energy demand and supply is indispensable for better understanding the prospects of long-tern climate stabilization. The RoSE study is the first of its kind to systematically explore the impact of economic growth, population and fossil fuel scarcity, in scenarios with and without climate policy, using a model ensemble. A feature of RoSE is the participation of five established integrated assessment modelling teams from three important regions in international climate policy negotiations: the EU, the USA and China.

Economic growth: Neither slow nor rapid economic growth …

Isotopic (Δ13c, Δ14c) Analysis Of Organic Acids In Marine Samples Using Wet Chemical Oxidation, Susan Q. Lang, G. L. Früh-Green, S. M. Bernasconi, L. Wacker

Faculty Publications

We present a method for the isolation and off-line isotope analysis of formate and acetate in marine samples. Organic acids are separated by high performance liquid chromatography and collected in glass Exetainer® screw-capped vials that have been prespiked with an oxidant and flushed with helium. The vials are subsequently heated to convert the organic compounds to CO₂ for radiocarbon and δ¹³C analysis. Small aliquots are sampled for measurement of δ¹³C by isotope ratio mass spectrometry, whereas the majority of the CO₂ is saved for radiocarbon analysis by accelerator mass spectrometry using a gas ion …

Extreme Wave Events In Ireland: 14 680 Bp–2012, Laura Cooke, John M. Dudley, Frédéric Dias

Articles

The island of Ireland is battered by waves from all sides, most ferociously on the west coast as the first port of call for waves travelling across the Atlantic Ocean. However, when discussing ocean events relevant to the nation of Ire- land, one must actually consider its significantly larger designated continental shelf, which is one of the largest seabed territories in Europe. With this expanded definition, it is not surprising that Ireland has been subject to many oceanic events which could be designated as “extreme”; in this paper we present what we believe to be the first catalogue of such …

Conservation Mooring Study, Urban Harbors Institute, University Of Massachusetts Boston

Urban Harbors Institute Publications

Most boaters who moor their vessels in Massachusetts waters have traditionally employed free swinging moorings that use heavy bottom chain. In important sensitive habitats such as eelgrass beds, these types of moorings often have negative impacts on the benthic habitat – from the circular movement of the chain around the anchor point, and/or from the anchor itself.

This document objectively describes the different characteristics of conventional moorings versus conservation moorings designed to minimize disruption to the benthic habitat. This report includes discussions on the following topics:

• Technologies available
• Ecological impacts
• Functional differences
• Economical differences
• Regulatory issues

These comparisons, along with …

Implementation And Model To Model Intercomparison Of 12 Heat Stress Metrics, Jonathan Robert Buzan

Open Access Theses

Earth system models simulate the dynamics of the most complex systems on our planet with some success. Despite the overwhelming sophistication of these models, which include dynamical interactions of ocean, atmosphere, vegetation, ice, and land-surface properties, they fail to include the most important element. People. Humans are also a complex physical-biological system and coupling of human physiology within an Earth Systems Modeling framework is challenging. This thesis presents results that tackle one particular component of human physiological climate interaction--a representation of heat stress on human physiology. Twelve different metrics were implemented and analyzed. These metrics represent a variety of philosophical …

The Influence Of The Tibetan Plateau Elevation On The Global And Asian Monsoons, Rene Paul Acosta

Open Access Theses

It has been long hypothesized that large-scale topographic changes, such as the surface uplift of the Tibetan Plateau, impacts the development of the South Asian and East Asian monsoons and influences other monsoon regions. However, recent modeling has shown that spatial distribution of the global monsoon, which includes the South Asian and East Asian monsoons is largely unaffected by the elevation of the plateau. In this study, we present results from a series of modern day simulations using CESM1.0 in a mixed-layer (slab ocean) configuration. The Tibetan Plateau height is varied from double that of the modern maximum plateau elevation …

Chemical Consequences Of Chicxulub Impact Ejecta Reentry, Devon Donald Parkos

Open Access Theses

The Chicxulub impact 66.0 million years ago initiated the second biggest extinction in the Phanerozoic Eon. The global reentry of material ejected by the impact generated a strong pulse of thermal radiation that wiped out much of the terrestrial biota. The cause of the marine extinction, however, has remained elusive. This report shows that reentering ejecta produces enough NOx to acidify the upper ocean and cause a massive marine extinction. Using non-equilibrium chemically reacting flow simulations coupled with atmospheric transport modeling, it is determined that enough NOx reached the stratosphere and precipitated to overpower the carbonate buffer and acidify the …

Rock Glaciers In The Eastern Cascades, Washington, Mark Weidenaar

Undergraduate Honors Theses

The eastern portion of Washington State's Cascade Range is a place not previously examined for rock glaciers, due to proximity to the Pacific Ocean and its associated marine-influenced climate. The objectives of this study were to determine spatial, activity, and genesis patterns, and paleoclimatic implications of Eastern Cascade rock glaciers. Using Google Earth, I found 103 rock glaciers in the study area. Rock glaciers are more common further east of the Cascade crest and more north in latitude, with the largest concentrations occurring east of Lake Chelan (22) and in the Pasayten Wilderness (28) in the North Cascades. None were …

Radio Signals From Electron Beams In Terrestrial Gamma Ray Flashes, Valerie Connaughton, Joseph R. Dwyer, Eric Cramer

Aerospace, Physics, and Space Science Faculty Publications

We show that the rate of association between terrestrial gamma ray flashes (TGFs) observed by the Fermi gamma ray burst monitor and VLF discharges detected by the World Wide Lightning Location Network (WWLLN) depends strongly on the duration of the TGF, with the shortest TGFs having associated WWLLN events over 50% of the time, and the longest TGFs showing a less than 10% match rate. This correlation is stronger if one excludes the WWLLN discharges that are not simultaneous (within 200 ms) with the TGF. We infer that the simultaneous VLF discharges are from the relativistic electron avalanches that are …

The Angular Distribution Of Energetic Electron And X-Ray Emissions From Triggered Lightning Leaders, M. M. Schaal, Joseph R. Dwyer, Hamid K. Rassoul, Jonathan David Hill, Douglas M. Jordan, Martin A. Uman

Aerospace, Physics, and Space Science Faculty Publications

We investigate individual X-ray bursts from lightning leaders to determine if energetic electrons at the source (and hence X-rays) are emitted isotropically or with some degree of anisotropy. This study was motivated by the work of Saleh et al. (2009), which found the falloff of X-rays in concentric radial annuli, covering all azimuthal directions in each annulus, from the lightning channel to be most consistent with an isotropic electron source. Here we perform a statistical analysis of angular and spatial distributions of X-rays measured by up to 21 NaI/PMT detectors at the International Center for Lightning Research and Testing site …

Analysis Of The Experiment On Registration Of X-Rays From The Stepped Leader Of A Cloud-To-Ground Lightning Discharge, Leonid P. Babich, Igor M. Kutsyk, Evgeni N. Donsko, Joseph R. Dwyer

Aerospace, Physics, and Space Science Faculty Publications

Using a Monte Carlo technique to simulate the transport of runaway electrons (REs) and X-rays in the atmosphere and through attenuators covering detectors, we have modeled the results of experiments to detect X-rays from triggered lightning and stepped leaders of a natural cloud-to-ground lightning. In the model, bremsstrahlung of high-energy runaway electrons (REs) generated at the leader front is assumed to be the origin of X-rays. Specific fluxes (per one RE) of photons and bremsstrahlung energy at the detectors were calculated. The analysis was executed with monoenergetic and exponential initial energy distributions of REs with different angular distributions. To reproduce …

Modeling Terrestrial Gamma Ray Flashes Produced By Relativistic Feedback Discharges, Ningyu Liu, Joseph R. Dwyer

Aerospace, Physics, and Space Science Faculty Publications

This paper reports a modeling study of terrestrial gamma ray flashes (TGFs) produced by relativistic feedback discharges. Terrestrial gamma ray flashes are intense energetic radiation originating from the Earth’s atmosphere that has been observed by spacecraft. They are produced by bremsstrahlung interactions of energetic electrons, known as runaway electrons, with air atoms. An efficient physical mechanism for producing large fluxes of the runaway electrons to make the TGFs is the relativistic feedback discharge, where seed runaway electrons are generated by positrons and X-rays, products of the discharge itself. Once the relativistic feedback discharge becomes self-sustaining, an exponentially increasing number of …

Radio Emissions From Terrestrial Gamma-Ray Flashes, Joseph R. Dwyer, Steven A. Cummer

Aerospace, Physics, and Space Science Faculty Publications

The theory of radio frequency (RF) emissions by terrestrial gamma-ray flashes (TGFs) is developed. These radio emissions, which are separate from the emission caused by lightning, are produced by the electric currents generated by runaway electrons and resulting low-energy electrons and ions. It is found from theory that the radio frequency pulses produced by TGFs are large enough to measure. Features of these signals depend strongly on certain aspects of the runaway acceleration process and so should provide additional information about the source mechanism(s) of this interesting atmospheric phenomenon. The RF emissions from several TGF models are calculated and compared …

Contribution Of The Pacific Decadal Oscillation To Global Mean Sea Level Trends, B. D. Hamlington, R. R. Leben, M. W. Strassburg, R. S. Nerem, K-Y. Kim

CCPO Publications

Understanding and explaining the trend in global mean sea level (GMSL) have important implications for future projections of sea level rise. While measurements from satellite altimetry have provided accurate estimates of GMSL, the modern altimetry record has only now reached 20 years in length, making it difficult to assess the contribution of decadal to multidecadal climate signals to the global trend. Here, we use a sea level reconstruction to study the 20 year trends in sea level since 1950. In particular, we show that the Pacific Decadal Oscillation (PDO) contributes significantly to the 20 year trends in GMSL. We estimate …

Intrusion Of Warm Surface Water Beneath The Mcmurdo Ice Shelf, Antarctica, A. A. Stern, M. S. Dinniman, V. Zagorodnov, S. W. Tyler, D. M. Holland

CCPO Publications

A 6 month temperature record collected below McMurdo Ice Shelf in 2011-2012 shows the temporal and spatial structure of the summertime warm water signal that penetrates beneath the ice shelf. The strength and duration of the warm water intrusion suggest an annual melt rate at Windless Bight of 0.71 m/yr. A Ross Sea numerical model demonstrates a seasonal warm water pathway leading from the west side of the Ross Sea Polynya (RSP) toward McMurdo Sound. The warm water enters McMurdo Sound, subducts beneath the ice shelf and causes accelerated summer melting. Temperature data were recorded using Distributed Temperature Sensing fiber …

An Analysis Of Surface Air Temperature Trends And Variability Along The Andes, Eric Franquist

Legacy Theses & Dissertations (2009 - 2024)

Climate change is difficult to study in mountainous regions such as the Andes since steep changes in elevation cannot always be resolved by climate models. However, it is important to examine temperature trends in this region as rises in surface air temperature are leading to the melting of tropical glaciers. Local communities rely on the glacier-fed streamflow to get their water for drinking, irrigation, and livestock. Moreover, communities also rely on the tourism of hikers who come to the region to view the glaciers. As the temperatures increase, these glaciers are no longer in equilibrium with their current climate and …