Oceanography and Atmospheric Sciences and Meteorology Commons^™

Microplastic Composition And Exposure Pathways In Freshwater Systems: A Multi-Matrix Comparison Between Streams And Retention Ponds In Hamilton County, In, Mya Whaley

All-Inclusive List of Electronic Theses and Dissertations

Since the early 1900s, the use of plastics has increased exponentially. The breakdown of plastic materials has exposed all ecosystems to microplastics (small particles of plastic < 5 mm), which are now ubiquitous in natural settings. Microplastics have a relatively large surface area, and many chemicals adsorb to these small particles, impacting their fate and transport of pollution. While microplastics have been found in virtually every setting on Earth, research is necessary to understand their impact on freshwater ecosystems and biogeochemical cycles. The focus of this research was to investigate microplastic compositions in crayfish, sediments, and water samples collected in streams and retention ponds. We analyzed trends in microplastic counts across different land-cover classes, waterbody types, and species, and compared concentrations among matrices to improve our understanding of microplastic exposure pathways in freshwater ecosystems. As a secondary objective, lead and arsenic concentrations were analyzed from sediment samples to investigate metal burdens and compare them to microplastic concentrations. Our findings revealed that, in general, urban streams had the highest microplastic concentrations within land cover categories, and retention ponds had higher microplastic counts than streams. Crayfish, such as F. rusticus had higher microplastic concentrations than F. virilis and F. propinquus, although these results may be influenced by study design. The most common microplastic type was fibers, and most common color was transparent. There was no significant correlation between microplastic and metal concentrations in sediments. We found crayfish to be adequate bioindicators of microplastic pollution, because they were less impacted by environmental variability than sediment and water samples. This research presents the first evidence of microplastics in our study species, F. propinquus, F. rusticus, and F. virlis. This work presents new evidence of microplastic accumulation in crayfish, sediments, and water from freshwater systems in the Midwestern United States. Microplastics were found in every sample type—crayfish, water, and sediment—across urban, rural, and forested landscapes, highlighting their pervasive distribution. The findings provide foundational data for assessing emerging ecological and human-health risks and emphasize the importance of sustained monitoring and research on MP contamination in freshwater environments.

Aquatic Macrophytes As Nature-Based Solutions: Challenges And Opportunities Across Inland And Coastal Waters, Morgan Botrel, Roxane Maranger, Lindsay L. Trottier, Mathieu Cusson, Lars L. Iverson, Fanny Noisette, Christian Nozais, Katrine Turgeon, Andrea Bertolo, Thibaud André-Alphonse, Simon Bélanger, Arthur De Grandpré, Jean-Olivier Goyette, Sabine Hilt, Ladd Johnson, Valérie Langlois, Martin Laporte, Félix Lauzon, Brigitte Légaré, Anne Ola, Marie-Pomme Presne-Poissant, Matthieu Prugne, Caroline Susini, Richard Zimmerman

OES Faculty Publications

Macrophytes are foundation species whose use as nature-based solution (NbS) in aquatic ecosystems can help reduce climate change impacts while mitigating biodiversity loss. The discrepancy in research and application of macrophytes as NbS across inland and marine coastal ecosystems is an opportunity to expand the concept and learn from different approaches. We report on an initiative uniting marine and freshwater scientists that compared knowledge on macrophytes as NbS across realms, identified advances and gaps in their use, and synthesized challenges and opportunities for application. We conducted a bibliometric analysis and an expert participatory exercise around recent review papers. We reveal …

Understanding And Assessing Climate Change: Preparing For Nebraska’S Future, 2024 Climate Change Impact Assessment Report, Deborah J. Bathke, Eric Hunt, Heather Akin, Andrea D. Basche, Jesse E. Bell, Daniel R. Dileo, Ross Dixon, Martha Durr, Tonya Haigh, Francis John Hay, Kristina W. Kintziger, Nicholas A. Mcmillan, Hank Miller, Jerome Okojokwu-Idu, Crystal Powers, Tirthankar Roy, Zhenghong Tang, W. Ryan Wishart, Aaron R. Young, Sarah A. Sonsthagen, Jonathan J. Spurgeon

School of Natural Resources: Faculty Publications

Contents

Report Team

Acknowledgments

Executive Summary

Introduction

Climate Change Contexts: Global, National, and State

Observed Changes in Nebraska's Climate

Projections of Nebraska's Future Climate

Water Systems

Energy

Ecosystems

Agriculture

Human Health

Communities and the Built Environment

Indigenous Peoples

Climate Justice and Equity

The Response of Faith Communities

Nebraskans' Perceptions of Climate Change

Next Steps and Future Work

Supplemental Report: Adaptation, Risks, and Impacts

About the Authors

Faith-based Communities Survey

Evaluated Plans and Assessments

References

Common Era Time-Transgressive Forcing Of Caribbean Water Balance, Peter J. Van Hengstum, Shawna N. Little, Richard M. Sullivan, Jeffrey P. Donnelly, Tyler S. Winkler, Anne E. Tamalavage, Patricia A. Beddows, Patricia L. Fall, Jiabi Du, Kaustubh Thirumalai, Nancy A. Albury, Sloan Coats

OES Faculty Publications

Tropical North Atlantic sea surface temperatures and low-latitude rainfall covary, but prehistoric subtropical rainfall records are often misaligned. Here, a submarine groundwater discharge record from the northern Bahamas archives regional water balance in the northeastern Atlantic Warm Pool. We compare the reconstruction to the tropical North Atlantic seasonal temperature gradient, which can help inform how northeastern Caribbean rainy seasons are influenced by the Atlantic Warm Pool. A positive water balance in the northern Bahamas aligned with a ~0.9 °C seasonal temperature gradient from 0 to 950 CE, with both covarying on multi-decadal timescales. Aridity began at ~950 CE when a …

Swimming In Sh*T: Quantifying Lagoon Flushing Impacts On Fecal Indicator Bacteria In Surf Zones Of Three Beaches On The East End Of Long Island, Ny, Brody C. Eggert

Pomona Senior Theses

This thesis investigates how lagoon flushing influences fecal indicator bacteria (FIB) concentrations—specifically enterococcus bacteria—in the surf zones of East Hampton and Southampton, New York. Focusing on the coastal lagoons of Georgica Pond, Sagg Pond, and Mecox Bay, the study analyzes how episodic inlet openings and environmental conditions affect enterococcus levels at adjacent recreational beaches. Using over 700 observations from the Surfrider Foundation’s Blue Water Task Force (BWTF) database, I construct a series of statistical models ranging from ordinary least squares to mixed effects frameworks; this thesis shows my process in developing this model. My analysis reveals that open inlets between …

Managing Subsurface Water In Wa, Department Of Primary Industries And Regional Development, Western Australia

Natural resources factsheets

The Department of Primary Industries and Regional Development (DPIRD) recommends that subsurface water management is part of an integrated water and salinity program. An integrated program can help to lower water tables and alleviate problems with waterlogging, rising salinity, and infrastructure damage.

Submarine Groundwater Discharge As A Major Nutrient Source In River-Fed Vs. Tidally Dominated Estuaries, Stephanie J. Wilson, Joseph J. Tamborski, Bongkeun Song, Peter Bernhardt, Margaret R. Mulholland

OES Faculty Publications

The tidal tributaries of the lower Chesapeake Bay experience seasonally recurring harmful algal blooms and the significance of submarine groundwater discharge (SGD) as a nutrient vector is largely unknown. Here, we determined seasonal SGD nutrient loads in two tributaries with contrasting hydrodynamic conditions, river-fed (York River) vs. tidally dominated (Lafayette River). Radon surveys were performed in each river to quantify SGD at the embayment-scale during spring and fall 2021. Total SGD was determined from a ²²²Rn mass balance and Monte Carlo simulations. Submarine groundwater discharge rates differed by a factor of two during spring (Lafayette = 11 ± 17 cm …

Molecular Dynamics Simulation Data: Mw And Mlmw Water Model Ice Nucleation On A Hydrophilic Substrate With Negative Pressure, Will Cantrell, Tianshu Li, Issei Nakamura, Elise Rosky, Raymond Shaw

Michigan Tech Research Data

This dataset contains the data supporting Figures in the study by Rosky et al., "Molecular simulations reveal that heterogeneous ice nucleation occurs at higher temperatures in water under capillary tension", submitted for publication in Atmospheric Chemistry and Physics in February 2023. Input files for reproducing the molecular dynamics simulations are included.

The abstract from the paper reads: Using a molecular model of water freezing on a hydrophilic substrate, it is found that heterogeneous ice nucleation rates occur at higher temperatures in water that is under tension, in other words under negative pressure. For pressures ranging from from 1 atm to …

Future Colorado River Basin Drought And Surplus, Rama Bedri, Thomas Piechota

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Historical and future drought and surplus periods in the Colorado River basin are evaluated based on eight climate scenarios. Unimpaired streamflow from 17 stations in the Colorado River are evaluated based on U.S. Geological Survey, Bureau of Reclamation, and Coupled Modeled Intercomparison Projection 5 downscaled data from 1950–2099. Representative Concentration Pathway (RCP) 4.5 and 8.5 emission scenarios are considered for four climate models (HadGEM2-ES, CNRM-CM5, CanESM2, MI-ROC5). Drought (surplus) quantities, magnitudes, severities, and water year flows are compared for the historical and future periods. Results indicate that there is a significant difference between the historical record and future projections. The …

Comparing Past And Future Drought And Surplus Periods In The Colorado River Basin, Rama Bedri

Student Scholar Symposium Abstracts and Posters

The Colorado River Basin is crucial to the Western United States, providing water for seven states and Mexico. Historical and future periods of drought and surplus are analyzed in 17 Colorado River stations. Unimpaired streamflow data are evaluated from the U.S. Geological Survey, Bureau of Reclamation, and Coupled Modeled Intercomparison Projection 5 from 1950-2099. Future projections are based on eight climate scenarios. Four climate models (HadGEM2-ES, CNRM-CM5, CanESM2, MI-ROC5) are observed at Representative Concentration Pathways (RCP) 4.5 and 8.5 emission scenarios. Furthermore, the ensemble water year means of the four models are analyzed. The durations of drought or surplus, magnitudes, …

Aman Iman: Resilient Customs, Community Water Management, And Dry Futures In Anounizme, Morocco, Haley Kirtland

Independent Study Project (ISP) Collection

This project explores how Anounizme, a village in southeastern Morocco, interacts with water. I was particularly curious about how traditional community management systems operate in the context of drought. I argue that the customary management system exhibits resiliency like it has in the face of Arabization, colonization, exploitative industry, and land privatization. It is capable of adapting to drought because it is more than a management system; it is a part of culture engrained as custom. Customs have porous boundaries, allowing a space for old aspects of culture to interact with both emerging aspects of culture and external pressures. I …

Relative Energy Comparison For Various Water Clusters Using Mp2, Df-Mp2, And Ccsd(T):Mp2 Methods, Qihang Wang

Honors Theses

The study of water clusters is an important area of research in many disciplines, such as biology, physical chemistry, and environmental studies. However, due to the difficulty in studying larger water clusters, such as clathrate hydrates, it is beneficial to obtain accurate descriptions of smaller water clusters to use as models for larger systems via computational methods. By starting with small water clusters, such as (H2O)₆, and moving into larger systems it is possible to build up data on various water structures that can determine the energetics of the various geometries within a certain number of water molecules. …

Present And Future Thermal Regimes Of Intertidal Groundwater Springs In A Threatened Coastal Ecosystem, Jason J. Karrisallen, Aaron A. Mohammed, Joseph Tamborski, Rob C. Jamieson, Serban Danielescu, Barret L. Kurylyk

OES Faculty Publications

In inland settings, groundwater discharge thermally modulates receiving surface water bodies and provides localized thermal refuges; however, the thermal influence of intertidal springs on coastal waters and their thermal sensitivity to climate change are not well studied. We addressed this knowledge gap with a field- and model-based study of a threatened coastal lagoon ecosystem in southeastern Canada. We paired analyses of drone-based thermal imagery with in situ thermal and hydrologic monitoring to estimate discharge to the lagoon from intertidal springs and groundwater-dominated streams in summer 2020. Results, which were generally supported by independent radon-based groundwater discharge estimates, revealed that combined …

Phytoplankton Bloom Stages Estimated From Chlorophyll Pigment Proportions Suggest Delayed Summer Production In Low Sea Ice Years In The Northern Bering Sea, Clare B. Gaffey, Karen E. Frey, Lee W. Cooper, Jacqueline M. Grebmeier

Geography

Decreased sea ice cover in the northern Bering Sea has altered annual phytoplankton phenology owing to an expansion of open water duration and its impact on ocean stratification. Limitations of satellite remote sensing such as the inability to detect bloom activity throughout the water column, under ice, and in cloudy conditions dictate the need for shipboard based measurements to provide more information on bloom dynamics. In this study, we adapted remote sensing land cover classification techniques to provide a new means to determine bloom stage from shipboard samples. Specifically, we used multiyear satellite time series of chlorophyll a to determine …

California Drought Outlooks Based On Climate Change Models’ Effects On Water Availability, Lauren Lynam, Thomas Piechota

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Future streamflow in California is evaluated based on eight climate projections models and the effects on water availability. The unimpaired projected streamflow for eleven California rivers, collected from Cal-Adapt, are compared with unimpaired historical flows (1950–2015) using eight climate model projections (2020–2099) identified as representative as possible future scenarios; Warm Dry RCP 4.5, Average RCP 4.5, Cool Wet RCP 4.5, Other RCP 4.5, Warm Dry RCP 8.5, Average RCP 8.5, Cool Wet RCP 8.5, and Other RCP 8.5. Projected drought deficits (or magnitudes), durations, and intensities are statistically tested against historical values to determine significance of differences between past streamflow …

Adsorption Driven Regolith-Atmospheric Water Vapor Transfer On Mars: An Analysis Of Phoenix Tecp Data, Holly Nicole Farris

Graduate Theses and Dissertations

NASA’s Phoenix mission allowed for investigations of Martian diurnal water vapor cycles through the collection of temperature, relative humidity, and electric conductivity data by the Thermal and Electric Conductivity Probe (TECP) instrument. Using this data and previous experimental data, we propose a regolith-driven adsorption-desorption regime at the Phoenix landing site, where parameters intrinsic to the regolith are controlling localized relative humidity at the surface. To constrain these parameters, we model adsorption as a function of temperature and relative humidity across various Mars-relevant materials, defined by two layer-based adsorption theories: Langmuir (monolayer) and Brunauer-Emmett-Teller or BET (multilayer). Langmuir serves as an …

Carbon Dioxide Measurement In Irish Blanket Peatlands: An Assessment Of Pool-Soil Flux Variability, Mariya Radomski, Alan Gilmer, Vivienne Byers, Eugene Mcgovern

Articles

Peatlands have been recognised as having a significant role in the mediation of atmospheric carbon dioxide (CO2) levels with direct implications for global climate change. Longitudinal in situ measurement systems for CO2 concentrations in blanket peatland ecosystems are difficult to implement where the nature of terrestrial–aquatic connectivity and hydrodynamics have a significant effect on the carbon cycle. The need for greater data on CO2 concentrations and flux monitoring in these settings has been well recognised. However, applying the most appropriate monitoring approach presents a special challenge. This paper sets out the development of a direct method for field based longitudinal …

Delivering Sustained, Coordinated, And Integrated Observations Of The Southern Ocean For Global Impact, Louise Newman, Petra Heil, Rowan Tebilco, Katsuro Katsumata, Andrew Constable, Esmee Van Wijk, Karen Assmann, Joana Beja, Phillippa Bricher, Richard Coleman, Daniel Costa, Steve Diggs, Riccardo Farneti, Sarah Fawcett, Sarah T. Gille, Katharine R. Hendry, Sian Henly, Eileen Hofmann, Ted Maksym, Matthew Mazloff, Andrew Meijers, Michael M. Meredith, Sebastien Moreau, Burcu Ozsoy, Robin Robertson, Irene Schloss, Oscar Schofield, Jiuxin Shi, Elisabeth Sikes, Inga J. Smith, Sebastiaan Swart, Anna Wahlin, Guy Williams, Michael J. M. Williams, Laura Herraiz-Borreguero, Stefan Kern, Jan Lieser, Robert A. Massom, Jessica Melbourne-Thomas, Patricia Miloslavich, Gunnar Spreen

CCPO Publications

The Southern Ocean is disproportionately important in its effect on the Earth system, impacting climatic, biogeochemical, and ecological systems, which makes recent observed changes to this system cause for global concern. The enhanced understanding and improvements in predictive skill needed for understanding and projecting future states of the Southern Ocean require sustained observations. Over the last decade, the Southern Ocean Observing System (SOOS) has established networks for enhancing regional coordination and research community groups to advance development of observing system capabilities. These networks support delivery of the SOOS 20-year vision, which is to develop a circumpolar system that ensures time …

Spatial Patterns Of Particulate Organic Carbon Concentrations And Isotopic Signatures Across A Salinity Gradient In A River Dominated Estuary, Lauren E. Alvaro, John C. Lehrter, Mai Fung

Gulf and Caribbean Research

No abstract provided.

Enhanced Acidity Of Acetic And Pyruvic Acids On The Surface Of Water, Alexis J. Eugene, Elizabeth A. Pillar, Agustín J. Colussi, Marcelo I. Guzman

Chemistry Faculty Publications

Understanding the acid–base behavior of carboxylic acids on aqueous interfaces is a fundamental issue in nature. Surface processes involving carboxylic acids such as acetic and pyruvic acids play roles in (1) the transport of nutrients through cell membranes, (2) the cycling of metabolites relevant to the origin of life, and (3) the photooxidative processing of biogenic and anthropogenic emissions in aerosols and atmospheric waters. Here, we report that 50% of gaseous acetic acid and pyruvic acid molecules transfer a proton to the surface of water at pH 2.8 and 1.8 units lower than their respective acidity constants pK_{a …}

Analysis Of The Red And Green Optical Absorption Spectrum Of Gas Phase Ammonia, Nikolai F. Zobov, Phillip A. Coles, Roman I. Ovsyannikov, Aleksandra A. Kyuberis, Robert J. Hargreaves, Peter F. Bernath, Jonathan Tennyson, Sergei N. Yurchenko, Oleg L. Polyansky

Chemistry & Biochemistry Faculty Publications

Room temperature NH₃ absorption spectra recorded at the Kitt Peak National Solar Observatory in 1980 are analyzed. The spectra cover two regions in the visible: 15,200 - 15,700 cm^-1 and 17,950 - 18,250 cm^-1. These high overtone rotation-vibration spectra are analyzed using both combination differences and variational line lists. Two variational line lists were computed using the TROVE nuclear motion program: one is based on an ab initio potential energy surface (PES) while the other used a semi-empirical PES. Ab initio dipole moment surfaces are used in both cases. 95 energy levels with J = 1 …

Oxidation Of Substituted Catechols At The Air-Water Interface: Production Of Carboxylic Acids, Quinones, And Polyphenols, Elizabeth A. Pillar, Marcelo I. Guzman

Chemistry Faculty Publications

Anthropogenic activities contribute benzene, toluene, and anisole to the environment, which in the atmosphere are converted into the respective phenols, cresols, and methoxyphenols by fast gas-phase reaction with hydroxyl radicals (HO(•)). Further processing of the latter species by HO(•) decreases their vapor pressure as a second hydroxyl group is incorporated to accelerate their oxidative aging at interfaces and in aqueous particles. This work shows how catechol, pyrogallol, 3-methylcatechol, 4-methylcatechol, and 3-methoxycatechol (all proxies for oxygenated aromatics derived from benzene, toluene, and anisole) react at the air-water interface with increasing O3(g) during τc ≈ 1 μs contact time and contrasts their …

Hyperspectral Signatures And Worldview-3 Imagery Of Indian River Lagoon And Banana River Estuarine Water And Bottom Types, Charles R. Bostater Jr., Taylor S. Oney, Tyler Rotkiske, Samin Aziz, Charles Morrisette, Kelby Callahan, Devin Mcallister

Ocean Engineering and Marine Sciences Faculty Publications

Hyperspectral signatures and imagery collected during the spring and summer of 2017 and 2016 are presented. Ground sampling distances (GSD) and pixel sizes were sampled from just over a meter to less than 4.0 mm. A pushbroom hyperspectral imager was used to calculate bidirectional reflectance factor (BRF) signatures. Hyperspectral signatures of different water types and bottom habitats such as submerged seagrasses, drift algae and algal bloom waters were scanned using a high spectral and digital resolution solid state spectrograph. WorldView-3 satellite imagery with minimal water wave sun glint effects was used to demonstrate the ability to detect bottom features using …

Climate Change Adaptation For Southern California Groundwater Managers: A Case Study Of The Six Basins Aquifer, Frank Lyles

Pomona Senior Theses

Groundwater has been very important to the economic development of Southern California, and will continue to be a crucial resource in the 21st century. However, Climate Change threatens to disrupt many of the physical and economic processes that control the flow of water in and out of aquifers. One groundwater manager, the Six Basins Watermaster in eastern Los Angeles and western San Bernardino Counties, has developed a long-term planning document called the Strategic Plan that mostly fails to address the implications of Climate Change, especially for local water supplies. This thesis presents an in-depth analysis of the Six Basin Watermaster’s …

Agenda: Indigenous Water Justice Symposium, University Of Colorado Boulder. Getches-Wilkinson Center For Natural Resources, Energy, And The Environment

Indigenous Water Justice Symposium (June 6)

Indigenous peoples throughout the world face diverse and often formidable challenges of what might be termed “water justice.” On one hand, these challenges involve issues of distributional justice that concern Indigenous communities’ relative abilities to access and use water for self-determined purposes. On the other hand, issues of procedural justice are frequently associated with water allocation and management, encompassing fundamental matters like representation within governance entities and participation in decision-making processes. Yet another realm of water justice in which disputes are commonplace relates to the persistence of, and respect afforded to, Indigenous communities’ cultural traditions and values surrounding water—more specifically, …

Reducing Nutrient Runoff From Poultry Production Facilities Using Locally-Sourced Iron And Aluminum Byproducts, Sheri Lynn Herron

Graduate Theses and Dissertations

Phosphorus (P) inputs to fresh waters can accelerate the eutrophication process. Agricultural nutrient runoff has been shown to be a contributor of P and nitrogen (N). Broiler production areas were evaluated for their potential to contribute P and N to runoff. Broiler house dust (BHD) samples were analyzed and compared to broiler litter (BL), rainfall simulations were conducted on plots adjacent to broiler house fans to evaluate nutrient enrichment in runoff from deposited dust, and runoff was automatically sampled at two culverts draining the land around broiler houses. Following this, an on-farm byproduct containment and nutrient removal structure was designed …

Water In The 21st Century, Grayson Michael Shor

Social Sciences

The aim of this research project is to provide a comprehensive and global analysis of water use in order to provide the reader with a comprehensive grasp of current and impending issues. The included five (5) chapters discuss water distribution, conservation, purification, law, international development, economic debates, ethical consideration, as well as educated estimations of the effects water related issues may cause in the next one-hundred years.

Detection Of Seagrass Scars Using Sparse Coding And Morphological Filter, Ender Oguslu, Sertan Erkanli, Victoria J. Hill, W. Paul Bissett, Richard C. Zimmerman, Jiang Li, Charles R. Bostater Jr. (Ed.), Stelios P. Mertikas (Ed.), Xavier Neyt (Ed.)

OES Faculty Publications

We present a two-step algorithm for the detection of seafloor propeller seagrass scars in shallow water using panchromatic images. The first step is to classify image pixels into scar and non-scar categories based on a sparse coding algorithm. The first step produces an initial scar map in which false positive scar pixels may be present. In the second step, local orientation of each detected scar pixel is computed using the morphological directional profile, which is defined as outputs of a directional filter with a varying orientation parameter. The profile is then utilized to eliminate false positives and generate the final …

Slides: What Does Climate Change Mean For Cold Water Fisheries, Stan Bradshaw

Water, Climate and Uncertainty: Implications for Western Water Law, Policy, and Management (Summer Conference, June 11-13)

1 page "Abstract" and 8 slides

Slides: Is There A Dust Bowl In Our Future?: Projections For The Eastern Rockies And Central Great Plains, Dennis Ojima

Water, Climate and Uncertainty: Implications for Western Water Law, Policy, and Management (Summer Conference, June 11-13)

Presenter: Dennis Ojima, Senior Research Scientist, Natural Resource Ecology Laboratory, Colorado State University (NREL/CSU)

30 slides