Oceanography and Atmospheric Sciences and Meteorology Commons^™

Spectroscopic Characterization Of Oceanic Dissolved Organic Matter Isolated By Reverse Osmosis Coupled With Electrodialysis, John R. Helms, Jingdong Mao, Hongmei Chen, E. Michael Perdue, Nelson W. Green, Patrick G. Hatcher, Kenneth Mopper, Aron Stubbins

Chemistry & Biochemistry Faculty Publications

Oceanic dissolved organic matter (DOM) is one of the largest pools of reduced carbon on Earth, yet DOM remains poorly chemically characterized. Studies to determine the chemical nature of oceanic DOM have been impeded by the lack of efficient and non-fractioning methods to recover oceanic DOM. Here, a DOM fraction (~40 to 86% recovery) was isolated using reverse osmosis/electrodialysis (RO/ED) and analyzed by solid-state ¹³C nuclear magnetic resonance (NMR) spectroscopy. Samples were obtained from biogeochemically distinct environments: photobleached surface gyre, productive coastal upwelling zone, oxygen minimum, North Atlantic Deep Water, and North Pacific Deep Water. A ubiquitous ‘background’ refractory …

Characterization And Photodegradation Of Dissolved Organic Matter (Dom) From A Tropical Lake And Its Dominant Primary Producer, The Cyanobacteria Microcystis Aeruginosa, Thais B. Bittar, Aron Stubbins, Armando A. H. Vieira, Kenneth Mopper

Chemistry & Biochemistry Faculty Publications

This study investigates optical and high-resolution molecular signatures and photochemical degradation of DOM from the Barra Bonita Reservoir (BB-DOM), a tropical eutrophic lake, as well as from its dominant phytoplankton species, the cyanobacteria Microcystis aeruginosa (Microcystis-DOM). Consistent with a predominantly autotrophic source, BB-DOM and Microcystis-DOM exhibited high protein-like fluorescence and contained a large number of aliphatics. Microcystis-DOM was enriched in peptide-like formulae, while BB-DOM had higher chromophoric and fluorescent DOM(CDOM and FDOM) and was enriched in moderately unsaturated formulae, indicating additions of terrigenous DOM and/or in situ processing of autochthonous material in the lake. Consistent with …

Relative Drifts And Biases Between Six Ozone Limb Satellite Measurements From The Last Decade, N. Rahpoe, M. Weber, A. V. Rozanov, K. Weigel, H. Bovensmann, J. P. Burrows, A. Laeng, G. Stiller, T. Von Clarmann, E. Kyrölä, V. F. Sofieva, J. Tamminen, K. Walker, D. Degenstein, A. E. Bourassa, R. Hargreaves, P. Bernath, J. Urban, D. P. Murtagh

Chemistry & Biochemistry Faculty Publications

As part of European Space Agency's (ESA) climate change initiative, high vertical resolution ozone profiles from three instruments all aboard ESA's Envisat (GOMOS, MIPAS, SCIAMACHY) and ESA's third party missions (OSIRIS, SMR, ACE-FTS) are to be combined in order to create an essential climate variable data record for the last decade. A prerequisite before combining data is the examination of differences and drifts between the data sets. In this paper, we present a detailed analysis of ozone profile differences based on pairwise collocated measurements, including the evolution of the differences with time. Such a diagnosis is helpful to identify strengths …

Retrieval And Validation Of Carbon Dioxide, Methane, And Water Vapor For The Canary Islands Ir-Laser Occultation Experiment, V. Proschek, G. Kirchengast, S. Schweitzer, J.S. A. Brooke, P. F. Bernath, C. B. Thomas, J. G. Wang, K. A. Tereszchuk, G. González Abad, R. J. Hargreaves, C. A. Beale, J. J. Harrison, P. A. Martin, V. L. Kasyutich, C. Gerbig, O. Kolle, A. Loescher

Chemistry & Biochemistry Faculty Publications

The first ground-based experiment to prove the concept of a novel space-based observation technique for microwave and infrared-laser occultation between low-Earthorbit satellites was performed in the Canary Islands between La Palma and Tenerife. For two nights from 21 to 22 July 2011 the experiment delivered the infrared-laser differential transmission principle for the measurement of greenhouse gases (GHGs) in the free atmosphere. Such global and long-term stable measurements of GHGs, accompanied also by measurements of thermodynamic parameters and line-of-sight wind in a self-calibrating way, have become very important for climate change monitoring. The experiment delivered promising initial data for demonstrating the …

Decrease Of Carbon Tetrachloride (Ccl⁴) Over 2004-2013 As Inferred From Global Occultation Measurements With Ace-Fts, E. Mahieu, Peter F. Bernath, Christopher D. Boone, Kaley A. Walker

Chemistry & Biochemistry Faculty Publications

In this contribution, we use infrared solar occultation measurements performed by the ACE-FTS (Atmospheric Chemistry Experiment – Fourier Transform Spectrometer) instrument onboard the SCISAT-1 Canadian satellite (Bernath et al., 2005). Since its launch in August 2003, this spectrometer has been in continuous operation with no significant degradation of its performance, and global measurements are available from late February 2004 onwards, spanning now more than a decade.

Global Ozone Chemistry And Related Trace Gas Data Records For The Stratosphere (Gozcards): Methodology And Sample Results With A Focus On Hcl, H20, And 03, L. Froidevaux, J. Anderson, H. J. Wang, R. A. Fuller, M. J. Schwartz, M. L. Santee, N. J. Livesey, H. C. Pumphrey, P. F. Bernath, J. M. Russell Iii, M. P. Mccormick

Chemistry & Biochemistry Faculty Publications

We describe the publicly available data from the Global OZone Chemistry And Related trace gas Data records for the Stratosphere (GOZCARDS) project and provide some results, with a focus on hydrogen chloride (HCl), water vapor (H₂O), and ozone (O₃). This data set is a global long-term stratospheric Earth system data record, consisting of monthly zonal mean time series starting as early as 1979. The data records are based on high-quality measurements from several NASA satellite instruments and the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) on SCISAT. We examine consistency aspects between the various data sets. …

Recent Increase Of Ethane Detected In The Remote Atmosphere Of The Northern Hemisphere, Bruno Franco, Whitney Bader, Benoît Bovy, Emmanuel Mahieu, Emily V. Fischer, Kimberly Strong, Stephanie Conway, James W. Hannigan, Eric Nussbaumer, Peter F. Bernath, Chris D. Boone, Kaley A. Walker

Chemistry & Biochemistry Faculty Publications

Ethane (C₂H₆) has a large impact on tropospheric composition and air quality because of its involvement in the global VOC (volatile organic compound) – HO_x – NO_x chemistry responsible for generating and destroying tropospheric ozone. By acting as a major sink for tropospheric OH radicals, the abundance of C₂H₆ influences the atmospheric content of carbon monoxide and impacts the lifetime of methane. Moreover, it is an important source of PAN, a thermally unstable reservoir for NOx radicals.

On a global scale, the main sources of C₂H₆ are leakage from the production, transport of natural gas loss, biofuel consumption …

Assessment Of Water Vapor Isotopologue Measurements By Ace-Fts And Odin-Smr, Ralf Bauer, Patrick Sheese, Kaley Walker, Joachim Urban, Donal Murtagh, Chris Boone, Peter Bernath, Gloria Manney

Chemistry & Biochemistry Faculty Publications

[Introduction] Knowing the isotopic composition of trace gases can improve our understanding of processes in the Earth's atmosphere causing isotopic fractionation. In many studies, isotopologue (molecules of identical chemical but different isotopic composition) amounts are primarily discussed as δ values, which are defined relative to a standard, e.g.:

Ace-Fts And Haloe Observations Of Hydrogen Fluoride (Hf) And Their Comparison With Slimcat Chemical Transport Model Calculations, Jeremy Harrison, Martyn Chipperfield, Chris Boone, Peter Bernath, Lucien Froidevaux, John Anderson, James Russell Iii

Chemistry & Biochemistry Faculty Publications

The majority of fluorine in the atmosphere has resulted from the anthropogenic emission of chlorofluorocarbons (CFCs), hydrochlorofluorocarbons (HCFCs), and hydrofluorocarbons (HFCs). Most tropospheric fluorine is present in its emitted 'organic' form due to the molecules having long lifetimes (up to a decade or longer). Thus they are able to reach the stratosphere where they are broken down, liberating fluorine. The principal degradation products are carbonyl fluoride (COF2), carbonyl chloride fluoride (COClF), and hydrogen fluoride (HF); of these HF is the most abundant. In fact at the top of the stratosphere most of the fluorine is present as HF, which, due …

New Atlas Features Corn Belt Farmers' Perspectives On Agriculture And Climate, John Tyndall, J. Gordon Arbuckle, Tonya Haigh, Cody L. Knutson, Lois Wright Morton, Linda Stalker Prokopy, Melissa Widhalm

National Drought Mitigation Center: Faculty Publications

The Farmer Perspectives on Agriculture and Weather Variability in the Corn Belt: A Statistical Atlas is a new publication available online at . The atlas includes maps and tables that make it easy for readers to gauge farmer perspectives within the US Corn Belt. Topics covered include farmer beliefs about climate change, attitudes toward actions in response to increased weather variability, risk perceptions, and experiences with weather extremes. This region-specific information on farmers' climate change and risk beliefs is designed to help Extension personnel tailor the climate adaptation and education programming they offer in their region.

The Implications Of Climate Change For Nebraska: Summary Report Of Sector-Based Roundtable Discussions (September-October 2015), Donald A. Wilhite, Kimberly Morrow

National Drought Mitigation Center: Faculty Publications

Introduction ... iv

Roundtable Reports: Overview ... iv

Rural Nebraskans Poll: Summary of Key Outcomes on Climate Change ... vi

Summary of Roundtable Discussions ... 1

Addressing the Impacts of Climate Change on Ecosystems and Wildlife in Nebraska ... 1

Implications of Climate Change on Human Health in Nebraska ... 11

Implications of Climate Change on Nebraska’s Forests and Fire ... 21

Implications of Climate Change on Nebraska’s Agriculture, Food and Water ... 27

Implications of Climate Change on Energy Availability, Use and Management in Nebraska ... 31

Climate Change in Nebraska: What Does it Mean for our Faith Communities? …

Aerosol Physical And Chemical Properties Over Tropical Atlantic Ocean, Elsa Castillo

Open Access Theses & Dissertations

The atmospheric aerosol mass size distributions, modal characteristics, and a comparative analysis of the characteristic of PM2.5 versus trace gases: CO, O3, and SO2 over tropical Atlantic Ocean have been evaluated for Nov-Dec 2013. This study took place during the IX AEROSE expedition while the National Oceanic and Atmospheric Administration (NOAA) research vessel Ronald H. Brown traveled south along 23°W between 3°N and 5°S.

Aerosol mass size distributions were measured directly with a California Instruments Model PC-2H Quartz Crystal Microbalance (QCM). The corresponding values of average mass for accumulation, nuclei and coarse mode obtained were: 0.00124±0.00077, 0.00506±0.00254, and 0.00176±0.00114 μg/m …

What Do Experienced Water Managers Think Of Water Resources Of Our Nation And Its Management Infrastructure?, Faisal Hossain, Jeffrey R. Arnold, Edward Beighley, Casey M. Brown, Steven J. Burian, Ji Chen, Anindita Mitra, Dev Dutta S Niyogi, Roger A. Pielke, Vincent C. Tidwell, Dave Wegner

Department of Earth, Atmospheric, and Planetary Sciences Faculty Publications

This article represents the second report by an ASCE Task Committee "Infrastructure Impacts of Landscape-driven Weather Change" under the ASCE Watershed Management Technical Committee and the ASCE Hydroclimate Technical Committee. Herein, the 'infrastructure impacts" are referred to as infrastructure-sensitive changes in weather and climate patterns (extremes and non-extremes) that are modulated, among other factors, by changes in landscape, land use and land cover change. In this first report, the article argued for explicitly considering the well-established feedbacks triggered by infrastructure systems to the land-atmosphere system via landscape change. In this report by the ASCE Task Committee (TC), we present the …

Correlation Between Leader Speed And Peak Current In Natural Lightning, Juan G. Alonso Guzman

Summer Community of Scholars Posters (RCEU and HCR Combined Programs)

No abstract provided.

Aerosol Optical Properties Over Mount Song, A Rural Site In Central China, Lunche Wang, Wei Gong, Ramesh P. Singh, Xiangao Xia, Huizheng Che, Ming Zhang, Hong Lin

Mathematics, Physics, and Computer Science Faculty Articles and Research

Seasonal variations of aerosol optical depth (AOD), Ångström exponent (α), single scattering albedo (SSA), water vapor content (WVC), aerosol size distribution and refractive index at Mount Song, a rural site in Central China are analyzed using ground-based sunphotometer data for the period April 2012 to May 2014 for the first time. The results show that the area is highly polluted even the major anthropogenic emission sources are far away. Seasonal mean AOD is high (0.72 ± 0.52) during summer (June–August) season and low (0.51 ± 0.38) during autumn (September–November) season. The monthly mean α is very low (0.81 ± 0.30) …

Regional-Scale Simulations Of Fungal Spore Aerosols Using An Emission Parameterization Adapted To Local Measurements Of Fluorescent Biological Aerosol Particles, Matthias Hummel, Corinna Hoose, M. Gallagher, D. A. Healy, J. Alex Huffman, D. O'Connor, U. Pöschl, C. Pöhlker, N. H. Robinson, M. Schnaiter, J. R. Sodeau, M. Stengel, E. Toprak, H. Vogel

Chemistry and Biochemistry: Faculty Scholarship

Fungal spores as a prominent type of primary biological aerosol particles (PBAP) have been incorporated into the COSMO-ART (Consortium for Small-scale Modelling- Aerosols and Reactive Trace gases) regional atmospheric model. Two literature-based emission rates for fungal spores derived from fungal spore colony counts and chemical tracer measurements were used as a parameterization baseline for this study. A third, new emission parameterization for fluorescent biological aerosol particles (FBAP) was adapted to field measurements from four locations across Europe. FBAP concentrations can be regarded as a lower estimate of total PBAP concentrations. Size distributions of FBAP often show a distinct mode at …

The Micro-Orifice Uniform Deposit Impactor–Droplet Freezing Technique (Moudi-Dft) For Measuring Concentrations Of Ice Nucleating Particles As A Function Of Size: Improvements And Initial Validation, R. H. Mason, C. Chou, C. S. Mccluskey, E. J. T. Levin, C. L. Schiller, T. C. J. Hill, J. Alex Huffman, P. J. Demott, A. K. Bertram

Chemistry and Biochemistry: Faculty Scholarship

The micro-orifice uniform deposit impactor– droplet freezing technique (MOUDI-DFT) combines particle collection by inertial impaction (via the MOUDI) and a microscope-based immersion freezing apparatus (the DFT) to measure atmospheric concentrations of ice nucleating particles (INPs) as a function of size and temperature. In the first part of this study we improved upon this recently introduced technique. Using optical microscopy, we investigated the non-uniformity of MOUDI aerosol deposits at spatial resolutions of 1, 0.25 mm, and for some stages when necessary 0.10 mm. The results from these measurements show that at a spatial resolution of 1mm and less, the concentration of …

Analysis Of No2 And Hcho Vertical Column Densities In The Great Lakes Region Using The Ozone Monitoring Instrument, David J. Faber

Dissertations, Master's Theses and Master's Reports

Nitrogen oxides (NOx) and volatile organic compounds (VOC) are major contributors to air quality, especially for their direct involvement in ozone (O3) production. Retrievals of nitrogen dioxide (NO2) and formaldehyde (HCHO) mixing ratios can be used to represent NOx and VOCs respectively and the formaldehyde-to-NO2 ratio (FNR) can be used to analyze the O3 production chemistry in a region. Since the current monitoring network in the Great Lakes region for NO2 and HCHO is limited, the Ozone Monitoring Instrument (OMI) can be used to retrieve vertical column densities for NO2 and HCHO in rural areas away from ground-based sensors. OMI …

Relativistic Electron Avalanches As A Thunderstorm Discharge Competing With Lightning, Nicole A. Kelley, David M. Smith, Joseph R. Dwyer, Michael Splitt, Steven Lazarus, Forest Martinez-Mckinney, Bryna Hazelton, Brian Grefenstette, Alexander Lowell, Hamid K. Rassoul

Ocean Engineering and Marine Sciences Faculty Publications

Gamma-ray ‘glows’ are long duration (seconds to tens of minutes) X-ray and gamma-ray emission coming from thunderclouds. Measurements suggest the presence of relativistic runaway electron avalanches (RREA), the same process underlying terrestrial gamma-ray flashes. Here we demonstrate that glows are relatively a common phenomena near the tops of thunderstorms, when compared with events such as terrestrial gamma-ray flashes. Examining the strongest glow measured by the airborne detector for energetic emissions, we show that this glow is measured near the end of a downward RREA, consistent with occurring between the upper positive charge layer and the negative screening layer above it. …

Is Shallow Water A Suitable Surrogate For Assessing Efforts To Address Pallid Sturgeon Population Declines?, T R. Gemeinhardt, N.J C. Gosch, D M. Morris, M L. Miller, T L. Welker, J L. Bonneau

United States Army Corps of Engineers, Omaha District

It is hypothesized that slow, shallow water habitats benefit larval pallid sturgeon Scaphirhynchus albus; however, testing this hypothesis is difficult, given the low number of larval pallid sturgeon present in large rivers. In contrast, relatively large numbers of age-0 shovelnose sturgeon Scaphirhynchus platorynchus have been sampled, providing a potentially useful baseline to assess the importance of slow, shallow water to age-0 sturgeon of both species (hereafter age-0 sturgeon) in the lower Missouri River. Thus, we investigated the potential relationships between the prevalence of shallow water <1.5m and the age-0 sturgeon catch rates at multiple scales. Age-0 sturgeon were usually sampled in water >1.5 m, and catch rates were usually highest in the upper half [i.e. river kilometer …

Nutrient Contributions From Alluvial Soils Associated With The Restoration Of Shallow Water Habitat In The Lower Missouri River, D C. Heimann, D M. Morris, T R. Gemeinhardt

United States Geological Survey: Staff Publications

The Missouri River has been extensively altered as the result of channelization, bank stabilization, and the construction of six main stem reservoirs. In response to the resultant habitat loss, the US Army Corps of Engineers was tasked with restoring approximately 8100 ha of shallow water habitat (SWH), in part, for the benefit of the endangered pallid sturgeon (Scaphirhynchus albus). Construction of off-channel habitats involves the removal and disposal of excavated alluvium either by direct discharge into the river or by secondary erosion, which raised concerns regarding the introduction of sediment and associated nutrients into the Missouri River. Soils from nine …

Drought Monitoring And Assessment: Remote Sensing And Modeling Approaches For The Famine Early Warning Systems Network, G B. Senay, N M. Velpuri, S Bohms, M Budde, C Young, J Rowland, J P. Verdin

United States Geological Survey: Staff Publications

Drought monitoring is an essential component of drought risk management. It is usually carried out using drought indices/indicators that are continuous functions of rainfall and other hydrometeorological variables. This chapter presents a few examples of how remote sensing and hydrologic modeling techniques are being used to generate a suite of drought monitoring indicators at dekadal (10-day), monthly, seasonal, and annual time scales for several selected regions around the world. Satellite-based rainfall estimates are being used to produce drought indicators such as standardized precipitation index, dryness indicators, and start of season analysis. The Normalized Difference Vegetation Index is being used to …

On Underestimation Of Global Vulnerability To Tree Mortality And Forest Die-Off From Hotter Drought In The Anthropocene, Craig D. Allen, David D. Breshears, Nate G. Mcdowell

United States Geological Survey: Staff Publications

Patterns, mechanisms, projections, and consequences of tree mortality and associated broadscale forest die-off due to drought accompanied by warmer temperatures—‘‘hotter drought’’, an emerging characteristic of the Anthropocene—are the focus of rapidly expanding literature. Despite recent observational, experimental, and modeling studies suggesting increased vulnerability of trees to hotter drought and associated pests and pathogens, substantial debate remains among research, management and policy-making communities regarding future tree mortality risks. We summarize key mortalityrelevant findings, differentiating between those implying lesser versus greater levels of vulnerability. Evidence suggesting lesser vulnerability includes forest benefits of elevated [CO2] and increased water-use efficiency; observed and modeled increases …

Possible Tsunami Deposits On The Caribbean Coast Of The Yucatán Peninsula, Charles Shaw, Larry Benson

United States Geological Survey: Staff Publications

The western Caribbean Basin is notable for its tectonic stability. It has experienced no historical earthquakes or the tsunami that sometimes accompany them. This paper describes a single, wedge-shaped, boulder-covered, coastal berm on the Yucatán coast of México that stretches unbroken for 50 km across a coastal segment characterized by rocky headlands that alternate with crescent beaches. The remainder of the 350 km of Yucatán coast consists mostly of mangrove that extends 1 to 30 km inland, often behind long, sandy beaches. On the headlands, the surface of the berm is densely paved with boulders—large boulders on its seaward face …

Developing A 30-M Grassland Productivity Estimation Map For Central Nebraska Using 250-M Modis And 30-M Landsat-8 Observations, Yingxin Gu, Bruce K. Wylie

United States Geological Survey: Staff Publications

Accurately estimating aboveground vegetation biomass productivity is essential for local ecosystem assessment and best land management practice. Satellite-derived growing season time-integrated Normalized Difference Vegetation Index (GSN) has been used as a proxy for vegetation biomass productivity. A 250-m grassland biomass productivity map for the Greater Platte River Basin had been developed based on the relationship between Moderate Resolution Imaging Spectroradiometer (MODIS) GSN and Soil Survey Geographic (SSURGO) annual grassland productivity. However, the 250-m MODIS grassland biomass productivity map does not capture detailed ecological features (or patterns) andmay result in only generalized estimation of the regional total productivity. Developing a high …

Radiocarbon Dating Of Late Quaternary Sediments Using Fossil Gastropod Shells, Jeffrey S. Pigati, John P. Mcgeehin, Daniel R. Muhs

United States Geological Survey: Staff Publications

Terrestrial gastropods are one of the most successful groups of organisms on Earth. Their distribution includes all continents except Antarctica, and they occupy exceptionally diverse habitats, from marshes and wet meadows to alpine forests and Arctic tundra. Their shells are also commonly preserved in Quaternary deposits and potentially could be used for ¹⁴C dating. However, terrestrial gastropods are known to ingest limestone and incorporate the old carbon in their shells, resulting in apparent ages that are often too old. Recent studies have shown that many small (<1 cm diameter) terrestrial gastropods avoid this “limestone problem” even when living in areas in which carbonate rocks are readily available. However, the shells must also behave as closed systems with respect to carbon if their ages are to be considered reliable. Our latest work has been aimed at testing if small gastropod shells do, in fact, remain closed systems in late Quaternary deposits over a wide array of climate conditions across North America. Our results demonstrate that ages derived from Succineidae shells are identical to wood and charcoal ages in loess in Alaska, glacial deposits in the upper Midwest, loess in the Great Plains, and paleowetlands in the desert southwest. Moreover, Succineidae shell ages routinely fall within permitted limits set by stratigraphic boundaries, require less interpretation than humic acid ages that are commonly used in loess studies, can provide additional stratigraphic coverage to previous dating efforts, and maintain stratigraphic order more often than luminescence ages from the same stratigraphic intervals. Thus, we conclude that fossil Succineidae shells, and shells of a few other small gastropods, can be used for ¹⁴C dating regardless of the local lithology, past climate, or environmental …

Late Quaternary Sea-Level History And The Antiquity Of Mammoths (Mammuthus Exilis And Mammuthus Columbi), Channel Islands National Park, California, Usa, Daniel R. Muhs, Kathleen R. Simmons, Lindsey T. Groves, John Mcgeehin, R. Randall Schumann, Larry D. Agenbroad

United States Geological Survey: Staff Publications

Fossils of Columbian mammoths (Mammuthus columbi) and pygmymammoths (Mammuthus exilis) have been reported from Channel Islands National Park, California. Most date to the last glacial period (Marine Isotope Stage [MIS] 2), but a tusk of M. exilis (or immature M. columbi) was found in the lowest marine terrace of Santa Rosa Island. Uranium-series dating of corals yielded ages from 83.8 ± 0.6 ka to 78.6 ± 0.5 ka, correlating the terrace withMIS 5.1, a time of relatively high sea level.Mammoths likely immigrated to the islands by swimming during the glacial periodsMIS 6 (~150 ka) orMIS 8 (~250 ka),when sea levelwas …

Sea Level, Paleogeography, And Archeology On California's Northern Channel Islands, Leslie Reeder- Myers, Jon Erlandson, Daniel R. Muhs, Torben Rick

United States Geological Survey: Staff Publications

Sea-level rise during the late Pleistocene and early Holocene inundated nearshore areas in many parts of the world, producing drastic changes in local ecosystems and obscuring significant portions of the archeological record. Although global forces are at play, the effects of sea-level rise are highly localized due to variability in glacial isostatic adjustment (GIA) effects. Interpretations of coastal paleoecology and archeology require reliable estimates of ancient shorelines that account for GIA effects. Here we build on previous models for California's Northern Channel Islands, producing more accurate late Pleistocene and Holocene paleogeographic reconstructions adjusted for regional GIA variability. This region has …

Corn Belt Soil Carbon And Macronutrient Budgets With Projected Sustainable Stover Harvest, Zhengxi Tan, Shuguang Liu

United States Geological Survey: Staff Publications

Corn (Zea mays L.) stover has been identified as a prime feedstock for biofuel production in the U.S. Corn Belt because of its perceived abundance and availability, but long-term stover harvest effects on regional nutrient budgets have not been evaluated. We defined the minimum stover requirement (MSR) to maintain current soil organic carbon levels and then estimated current and future soil carbon (C), nitrogen (N), phosphorus (P), and potassium (K) budgets for various stover harvest scenarios. Analyses for 2006 through 2010 across the entire Corn Belt indicated that currently, 28 Tg or 1.6 Mgha^-1 of stover could be sustainably …

The Distribution Of Selected Elements And Minerals In Soil Of The Conterminous United States, Laurel Woodruff, William F. Cannon, David B. Smith, Federico Solano

United States Geological Survey: Staff Publications

In 2007, the U.S. Geological Survey initiated a low-density (1 site per 1600 km², 4857 sites) geochemical andmineralogical survey of soil of the conterminous United States as part of the North American Soil Geochemical Landscapes Project. Three soil samples were collected, if possible, from each site; (1) a sample from a depth of 0 to 5 cm, (2) a composite of the soil A-horizon, and (3) a deeper sample from the soil C-horizon or, if the top of the C-horizon was at a depth greater than 100 cm, from a depth of approximately 80–100 cm. The <2 mm fraction of each sample was analysed for a suite of 45 major and trace elements following near-total multi-acid digestion. The major mineralogical components in samples from the soil A- and C-horizons were determined by a quantitative X-ray diffraction method using Rietveld refinement. Sampling ended in 2010 and chemical and mineralogical analyses were completed in May 2013.Maps of the conterminous United States showing predicted element and mineral concentrations were interpolated from actual soil data for each soil sample type by an inverse distance weighted (IDW) technique using ArcGIS software. Regional- and national-scale map patterns for selected elements and minerals apparent in interpolated maps are described here in the context of soil-forming factors and possible human inputs. These patterns can be related to (1) soil parent materials, for example, in the distribution of quartz, (2) climate impacts, for example, in the distribution of feldspar and kaolinite, (3) soil age, for example, in the distribution of carbonate in young glacial deposits, and (4) possible anthropogenic loading of phosphorus (P) and lead (Pb) to surface soil. This new geochemical and mineralogical data set for the conterminous United States represents a major step forward from prior national-scale soil geochemistry data and provides a robust soil data framework for the United States now and into the future.