Open Access. Powered by Scholars. Published by Universities.®

Nanoscience and Nanotechnology Commons™

Open Access. Powered by Scholars. Published by Universities.®

Discipline
Institution
Keyword
Publication Year
Publication
Publication Type
File Type

Articles 1741 - 1770 of 3535

Full-Text Articles in Nanoscience and Nanotechnology

Implementation Of New System For Oxygen Generation And Carbon Dioxide Removal, Angelo Peter Karavolos Jan 2016

Implementation Of New System For Oxygen Generation And Carbon Dioxide Removal, Angelo Peter Karavolos

Open Access Theses & Dissertations

This research effort develops an integrated system for CO2 removal and O2 production. A unique material, dodeca-tungsto-phosphoric acid (H3PO4W12O3; henceforth referred to as DTPA) is mixed with tetra-ethyl-ortho-silicate Si(OC2H5)4 or TEOS. This mixture exhibits unique properties of heat absorption and high electrical conductivity. In the system described herein, the DTPA resides within a cross linked arrangement of TEOS. The DTPA furnishes a source of O2, while the TEOS furnishes structural support for the large DTPA crystals. In addition, the large amount of H2O within the crystal also adsorbs CO2. It can also be cross-linked with other polymers such as polycarbonate, …

Go to article

In Situ Microscopy Of The Self-Assembly Of Branched Nanocrystals In Solution, Eli Sutter, Peter Sutter, Alexei V. Tkachenko, Roman Krahne, Joost De Graaf, Milena Arciniegas, Liberato Manna Jan 2016

In Situ Microscopy Of The Self-Assembly Of Branched Nanocrystals In Solution, Eli Sutter, Peter Sutter, Alexei V. Tkachenko, Roman Krahne, Joost De Graaf, Milena Arciniegas, Liberato Manna

Department of Mechanical and Materials Engineering: Faculty Publications

Solution-phase self-assembly of nanocrystals into mesoscale structures is a promising strategy for constructing functional materials from nanoscale components. Liquid environments are key to self-assembly since they allow suspended nanocrystals to diffuse and interact freely, but they also complicate experiments. Real-time observations with single-particle resolution could have transformative impact on our understanding of nanocrystal self-assembly. Here we use real-time in situ imaging by liquid-cell electron microscopy to elucidate the nucleation and growth mechanism and properties of linear chains of octapod-shaped nanocrystals in their native solution environment. Statistical mechanics modelling based on these observations and using the measured chain-length distribution clarifies the …

Go to article

Influence Of Shear Stress Magnitude And Direction On Atherosclerotic Plaque Composition, Ryan M. Pedrigi, Vikram V. Mehta, Sandra M. Bovens, Zahra Mohri, Christian Bo Poulsen, Willy Gsell, Jordi L. Tremoleda, Leila Towhidi, Ranil De Silva, Enrico Petretto, Rob Krams Jan 2016

Influence Of Shear Stress Magnitude And Direction On Atherosclerotic Plaque Composition, Ryan M. Pedrigi, Vikram V. Mehta, Sandra M. Bovens, Zahra Mohri, Christian Bo Poulsen, Willy Gsell, Jordi L. Tremoleda, Leila Towhidi, Ranil De Silva, Enrico Petretto, Rob Krams

Department of Mechanical and Materials Engineering: Faculty Publications

The precise flow characteristics that promote different atherosclerotic plaque types remain unclear. We previously developed a blood flow-modifying cuff for ApoE−/− mice that induces the development of advanced plaques with vulnerable and stable features upstream and downstream of the cuff, respectively. Herein, we sought to test the hypothesis that changes in flow magnitude promote formation of the upstream (vulnerable) plaque, whereas altered flow direction is important for development of the downstream (stable) plaque. We instrumented ApoE−/− mice (n=7) with a cuff around the left carotid artery and imaged them with micro-CT (39.6 μm resolution) eight to nine weeks …

Go to article

Substrate Effects And Dielectric Integration In 2d Electronics, Bhim Prasad Chamlagain Jan 2016

Substrate Effects And Dielectric Integration In 2d Electronics, Bhim Prasad Chamlagain

Wayne State University Dissertations

The ultra-thin body of monolayer (and few-layer) two dimensional (2D) semiconducting materials such as transitional metal dichalconiges (TMDs), black phosphorous (BP) has demonstrated tremendous beneficial physical, transport, and optical properties for a wide range of applications. Because of their ultrathin bodies, the properties of 2D materials are highly sensitive to environmental effects. Particularly, the performance of 2D semiconductor electronic devices is strongly dependent on the substrate/dielectric properties, extrinsic impurities and absorbates. In this work, we systematically studied the transport properties of mechanically exfoliated few layer TMD field-effect transistors (FETs) consistently fabricated on various substrates including SiO2,Parylene –C, Al2O3, SiO2 modified …

Go to article

Development Of Low-Temperature Atomic Layer Deposition Of Ultra-Thin Ruco Direct Plate Liners For Flexible Electronics Applications, Dillon Alexander Gregory Jan 2016

Development Of Low-Temperature Atomic Layer Deposition Of Ultra-Thin Ruco Direct Plate Liners For Flexible Electronics Applications, Dillon Alexander Gregory

Legacy Theses & Dissertations (2009 - 2024)

Low temperature plasma-assisted atomic layer deposition-grown metal nanocomposite layers based on mixtures of ruthenium and cobalt have been investigated as potential copper adhesion/barrier layers in flexible electronics applications. The success of adapting this process to flexible electronics depends on the candidate barriers meeting several necessary properties including sufficient electrical conductivity, compatibility with Cu electroplating, and ability to prevent Cu diffusion into the substrate. Preliminary testing has shown that atomic layer deposition (ALD) can be used as a technique for depositing alloyed metallic barrier layers at the lower thermal constraints dictated by the use of polymer substrates and still produce continuous …

Go to article

Texture And Microstructure Of Ipvd Copper Manganese Seed In 1 Μm & 70 Nm Wide Damascene Trenches, Robert Stuart Brown Jan 2016

Texture And Microstructure Of Ipvd Copper Manganese Seed In 1 Μm & 70 Nm Wide Damascene Trenches, Robert Stuart Brown

Legacy Theses & Dissertations (2009 - 2024)

This thesis describes the grain texture and microstructure of Ionized Physical Vapor Deposition (iPVD) Copper Manganese seed in 1 µm and 70 nm wide damascene trenches. Using Transmission Electron Microscopy (TEM) imaging and diffraction pattern analysis, the grain size and general orientation of the grains were determined. It was found that the 1 µm wide trenches contained larger grains and more texture than that of the 70 nm wide trenches. While this thesis builds upon previous work by Brendan O’Brien in the Dunn group, one significantly different finding will be presented regarding the structure on the sidewall of the trenches. …

Go to article

The Investigation Of Nanoscale Effects On Schottky Interfaces And The Scattering Rates Of High Resistivity Metals, Christopher Anthony Durcan Jan 2016

The Investigation Of Nanoscale Effects On Schottky Interfaces And The Scattering Rates Of High Resistivity Metals, Christopher Anthony Durcan

Legacy Theses & Dissertations (2009 - 2024)

Understanding the transport of electrons through materials and across interfaces is fundamental to modern day electronics. As electrons travel, interactions with defects within the crystal lattice induce scattering which gives rise to resistivity. At the interface between two materials, electrostatic barriers exist which can impede the flow of electrons. The work of this thesis is to further the understanding of electron transport by measuring the transport across metal-semiconductor interfaces at the nanoscale and measure scattering phenomena in metals. The measurement technique ballistic electron emission microscopy (BEEM) was used due to its ability to probe the scattering processes within a metal …

Go to article

Investigating The Size Dependent Material Properties Of Nanoceria, Bushra B. Alam Jan 2016

Investigating The Size Dependent Material Properties Of Nanoceria, Bushra B. Alam

Legacy Theses & Dissertations (2009 - 2024)

Nanoceria is widely being investigated for applications as support materials for fuel cell catalysts, free radical scavengers, and as chemical and mechanical abrasives due to its high antioxidant capacity and its oxygen buffering capacity. This antioxidant or oxygen buffering capacity has been reported to be highly size dependent and related to its redox properties. However, the quantification of this antioxidant capacity has not been well defined or understood and has been often been carried out using colorimetric assays which do not directly correlate to ceria nanoparticle properties. Fabrication rules for developing materials with optimal antioxidant/oxygen buffering capacities are not yet …

Go to article

Development Of Enhanced Window Layers For Cigs Photovoltaic Devices, James Nicholas Alexander Jan 2016

Development Of Enhanced Window Layers For Cigs Photovoltaic Devices, James Nicholas Alexander

Legacy Theses & Dissertations (2009 - 2024)

Photovoltaic devices are among the promising options for sustainable future energy generation. Thin film solar cells have demonstrated the ability to be a low-cost solution to clean renewable energy and are cost competitive with current silicon based photovoltaic devices. One of the most promising thin film devices right now is the Copper Indium Gallium Selenide (CIGS) solar cell with maximum reported power conversion efficiency of 22.3%. The Transparent Conducting Oxide (TCO) which is the top layer of the CIGS device also known as the window layer, is responsible for collecting the electrons generated in the CIGS device and conducting them …

Go to article

Degradation And Exciton Energy Transfer Studies In Single-Walled Carbon Nanotube Bundles, Abhishek Gottipati Jan 2016

Degradation And Exciton Energy Transfer Studies In Single-Walled Carbon Nanotube Bundles, Abhishek Gottipati

Legacy Theses & Dissertations (2009 - 2024)

Single walled carbon nanotubes (SWNTs) due to their unique optical behavior, large surface area, robust mechanical strength and electrical properties make them one of the ideal candidates for sensing and opto-electronic applications. In this work, we explore the energy transfer (exciton energy transfer-EET) phenomena occurring between nanotubes in bundles, using resonance Raman spectroscopy.

Go to article

Investigation Of The Optical And Sensing Characteristics Of Nanoparticle Arrays For High Temperature Applications, Gnanaprakash Dharmalingam Jan 2016

Investigation Of The Optical And Sensing Characteristics Of Nanoparticle Arrays For High Temperature Applications, Gnanaprakash Dharmalingam

Legacy Theses & Dissertations (2009 - 2024)

The monitoring of polluting gases such as CO and NOx emitted from gas turbines in power plants and aircraft is important in order to both reduce the effects of such gases on the environment as well as to optimize the performance of the respective power system. The need for emissions monitoring systems is further realized from increased regulatory requirements that are being instituted as a result of the environmental impact from increased air travel. Specifically, it is estimated that the contributions from aircraft emissions to total NOx emissions will increase from 4% to 17% between 2008 and 2020. Extensive fuel …

Go to article

Development Of Integrated Tio₂ On Carburized Si Nanowires As A Catalyst/Support Structure For Alkaline Fuel Cells, Adam Lemke Jan 2016

Development Of Integrated Tio₂ On Carburized Si Nanowires As A Catalyst/Support Structure For Alkaline Fuel Cells, Adam Lemke

Legacy Theses & Dissertations (2009 - 2024)

Due to a combination of environmental and economic motivations, there is a strong impetus to transition away from fossil fuels towards renewable sources of energy. Critical to achieving this goal will be technologies that allow for the storage and transmission of energy derived from renewable sources. Hydrogen fuel cells may play a significant role in making this a reality, allowing for the use of hydrogen as a non-carbon based fuel, in particular for vehicle applications. Hydrogen fuel cells directly convert chemical energy into electrical energy, with only water vapor and heat as waste products.

Go to article

Tailoring The Optical Properties Of Silicon With Ion Beam Created Nanostructures For Advanced Photonics Applications, Perveen Akhter Jan 2016

Tailoring The Optical Properties Of Silicon With Ion Beam Created Nanostructures For Advanced Photonics Applications, Perveen Akhter

Legacy Theses & Dissertations (2009 - 2024)

In today’s fast life, energy consumption has increased more than ever and with that the demand for a renewable and cleaner energy source as a substitute for the fossil fuels has also increased. Solar radiations are the ultimate source of energy but harvesting this energy in a cost effective way is a challenging task. Si is the dominating material for microelectronics and photovoltaics. But owing to its indirect band gap, Si is an inefficient light absorber, thus requiring a thickness of solar cells beyond tens of microns which increases the cost of solar energy. Therefore, techniques to increase light absorption …

Go to article

Strong Metal Support Interaction Of Pt On Tio₂ Grown By Atomic Layer Deposition And Physical Vapor Deposition For Fuel Cell Applications, Robin Paul Hansen Jan 2016

Strong Metal Support Interaction Of Pt On Tio₂ Grown By Atomic Layer Deposition And Physical Vapor Deposition For Fuel Cell Applications, Robin Paul Hansen

Legacy Theses & Dissertations (2009 - 2024)

Several roadblocks prevent the large-scale commercialization of hydrogen fuel cells, including the stability of the Pt catalysts and their substrates, as well as the high cost of Pt. This is particularly true for the cathode, which requires a higher Pt loading because of the slow kinetics of the oxygen reduction reaction (ORR). The problem with the stability of the substrate can be solved by replacing the traditional carbon support with a conductive metal oxide such as reduced TiO2, which will not easily corrode and should result in longer lasting fuel cells. In this study, Pt was deposited either by atomic …

Go to article

Magnetoresistance Of A Low-K Dielectric, Brian Thomas Mcgowan Jan 2016

Magnetoresistance Of A Low-K Dielectric, Brian Thomas Mcgowan

Legacy Theses & Dissertations (2009 - 2024)

Low-k dielectrics have been incorporated into advanced computer chip technologies as a part of the continuous effort to improve computer chip performance. One drawback associated with the implementation of low-k dielectrics is the large leakage current which conducts through the material, relative to silica. Another drawback is that the breakdown voltage of low-k dielectrics is low, relative to silica [1]. This low breakdown voltage makes accurate reliability assessment of the failure mode time dependent dielectric breakdown (TDDB) in low-k dielectrics critical for the successful implementation of these materials. The accuracy with which one can assess this reliability is currently a …

Go to article

Optical Metrology For Cigs Solar Cell Manufacturing And Its Cost Implications, Sravan Kumar Sunkoju Jan 2016

Optical Metrology For Cigs Solar Cell Manufacturing And Its Cost Implications, Sravan Kumar Sunkoju

Legacy Theses & Dissertations (2009 - 2024)

Solar energy is a promising source of renewable energy which can meet the demand for clean energy in near future with advances in research in the field of photovoltaics and cost reduction by commercialization. Availability of a non-contact, in-line, real time robust process control strategies can greatly aid in reducing the gap between cell and module efficiencies, thereby leading to cost-effective large-scale manufacturing of high efficiency CIGS solar cells. In order to achieve proper process monitoring and control for the deposition of the functional layers of CuIn1-xGaxSe2 (CIGS) based thin film solar cell, optical techniques such as spectroscopic reflectometry and …

Go to article

Nanotechnology & Human Stem Cells : Applications In Cardiogenesis And Neurogenesis, Martin Lyubomirov Tomov Jan 2016

Nanotechnology & Human Stem Cells : Applications In Cardiogenesis And Neurogenesis, Martin Lyubomirov Tomov

Legacy Theses & Dissertations (2009 - 2024)

Human stem cell research holds an unprecedented promise to revolutionize the way we approach medicine and healthcare in general, moving us from a position of mostly addressing the symptoms to a state where treatments can focus on removing the underlying causes of a condition. Stem cell research can shed light into normal developmental pathways, as we are beginning to replicate them in a petri dish and can also be used to model diseases and abnormal conditions. Direct applications can range from finding cures for single or multigene diseases to demonstrating that we can replace these genes with a normal copy. …

Go to article

The Gammaturc Nanomachine Mechanism And Future Applications, Timothy Riehlman Jan 2016

The Gammaturc Nanomachine Mechanism And Future Applications, Timothy Riehlman

Legacy Theses & Dissertations (2009 - 2024)

The complexity and precision of the eukaryotic cell’s cytoskeletal network is unrivaled by any man-made systems, perfected by billions of years of evolution, mastering elegant processes of self-assembly, error correction, and self-repair. Understanding the capabilities of these networks will have important and far reaching applications in human medicine by aiding our understanding of developmental processes, cellular division, and disease mechanisms, and through biomimicry will provide insights for biosynthetic manufacturing at the nanoscale and across scales. My research utilizes cross species techniques from Human to the model organism of Fission Yeast to investigate the structure and mechanisms of the g-tubulin ring …

Go to article

Single Particle-Inductively Coupled Plasma-Mass Spectrometry Technology Development For Metallic Nanoparticle Characterization In Complex Matrices, Yongbo Dan Jan 2016

Single Particle-Inductively Coupled Plasma-Mass Spectrometry Technology Development For Metallic Nanoparticle Characterization In Complex Matrices, Yongbo Dan

Doctoral Dissertations

"As the rapid growing of nanotechnology, the release of engineered nanoparticles (ENPs) into the environment is inevitable. After entering the real environment, ENPs tend to react with different components of the ecosystem (e.g. water, soil, air, plants) and make their characterization difficult. Analyzing ENPs in these complex matrices still remains as a grand challenge. ENPs characterization is normally the first step of risk assessment. Current analytical techniques have shown some limitations in revealing the unique characteristics of ENPs in complex matrices and reliable analytical techniques are in urgent need. Single particle inductively coupled plasma mass spectrometry (SP-ICP-MS) is an emerging …

Go to article

Synthesis And Photonic Sintering Of Bioresorbable Zinc Nanoparticle Ink For Transient Electronics Manufacturing, Bikram K. Mahajan Jan 2016

Synthesis And Photonic Sintering Of Bioresorbable Zinc Nanoparticle Ink For Transient Electronics Manufacturing, Bikram K. Mahajan

Masters Theses

"Zinc is an essential 'trace element' that supports immune systems, and is required for DNA synthesis, cell division, and protein synthesis. Zinc nanoparticles (Zn NP) has antibacterial properties and potential to be used in biodegradable printed electronics devices. The research presented here is about the synthesis of Zn NP and their potential use in transient electronics devices. In Paper 1, a technique of room temperature synthesis of Zn NP is reported using ball milling. Controlled amount of PVP was mixed in the solvent to stabilize the Zn particles and minimize cold welding during milling. The size of the produced Zn …

Go to article

Novel Design And Synthesis Of Transition Metal Hydroxides And Oxides For Energy Storage Device Applications, Peifeng Li Jan 2016

Novel Design And Synthesis Of Transition Metal Hydroxides And Oxides For Energy Storage Device Applications, Peifeng Li

Wayne State University Theses

Supercapacitors (SCs) and Li-ion batteries (LIBs) are two types of important electrical energy storage devices with high power density and high energy density respectively. However, to satisfy the increasing demand of high-performance energy storage devices, the energy density of SCs and power/energy densities of LIBs have to be further improved. The exploration, research, and development of electrode materials with high-performance for applications in SCs and LIBs are still needed to meet the ever-increasing demand on energy and power densities. Herein, the amorphous Ni-Co-Mo ternary hydroxides nanoflakes for SCs and oxides nanoflakes for LIBs with ultrathin stature, abundant open spaces, and …

Go to article

Targeted Delivery Of Nrf2 Sirna Using Modular Polymeric Micellar Nanodelivery System For Efficient Target Gene Knockdown In Hepatocellular Carcinoma, Shaimaa Mohamed Ibrahim Yousef Jan 2016

Targeted Delivery Of Nrf2 Sirna Using Modular Polymeric Micellar Nanodelivery System For Efficient Target Gene Knockdown In Hepatocellular Carcinoma, Shaimaa Mohamed Ibrahim Yousef

Wayne State University Theses

Tumor selective drug delivery as well as chemotherapy associated multi drug resistance (MDR) pose tremendous hurdles for effective cancer therapy. In this regard, designing multifunctional nanocarriers loaded with drug/gene payloads and engineered with tumor targeting ligands can serve as a modular platform for targeted drug/gene delivery. In this study we undertook the synthesis of a self-assembling block copolymer constructed using poly(styrene-co-maleic anhydride, partial iso-octyl ester) (SMAPIE) and branched polyethylenimine (PEI) as building blocks and evaluated its micelle forming ability, siRNA complexation and siRNA delivery potentials. In addition, we engineered galactosamine decorated nanomicelles using modular “click” chemistry based approaches for evaluating …

Go to article

Uv Light-Induced Aggregation Of Titania Submicron Particles, Can Zhou, Yashar Bashirzadeh, Timothy A. Bernadowsky Jr., Xiaoyu Zhang Jan 2016

Uv Light-Induced Aggregation Of Titania Submicron Particles, Can Zhou, Yashar Bashirzadeh, Timothy A. Bernadowsky Jr., Xiaoyu Zhang

Mechanical & Aerospace Engineering Faculty Publications

In this study, aggregation of TiO2 (rutile and anatase) submicron particles in deionized (DI) water under ultra-violet (UV) light irradiation was investigated. While no aggregation was observed in the dark, rutile and anatase submicron particles started aggregating upon application of UV light and ceased aggregation in about 2 and 8.4 h, respectively. It has been demonstrated that UV light directly mitigated the particle mobility of TiO2, resulting in a neutralization effect of the Zeta potential. It was also observed that rutile particles aggregated much faster than anatase particles under UV radiation, indicating that the Zeta potential of …

Go to article

Liquid-Phase Exfoliation Of Two-Dimensional Graphite For Ink-Jet Printing, Monica Michel Jan 2016

Liquid-Phase Exfoliation Of Two-Dimensional Graphite For Ink-Jet Printing, Monica Michel

Open Access Theses & Dissertations

Over the last decade, the study of two-dimensional (2D) materials has seen an incredible growth due to their unique thermal, mechanical and electronic properties. Solution phase manufacturing offers a way in which they can be produced at large scale by creating dispersions from the exfoliated material. Once created, different options for assembling devices exist. One technique for large scale manufacturing of materials in this form is ink-jet printing, which is a form of additive manufacturing that has proven to be attractive for the printed electronics industry. One challenge that ink-jet printing still faces is the shortage of inks with appropriate …

Go to article

Synthesis, Device Fabrication, And Characterization Of Two-Dimensional Molybdenum Disulfide, Gustavo Alberto Lara Saenz Jan 2016

Synthesis, Device Fabrication, And Characterization Of Two-Dimensional Molybdenum Disulfide, Gustavo Alberto Lara Saenz

Open Access Theses & Dissertations

The miniaturization of electronic devices according to Moore's Law has been propelled by the continuous demand for faster and smaller devices which continue to advance technology. One recent contribution to this trend was the isolation and characterization of one atom thick of graphite, known as graphene, which led to the Nobel Prize in physics in 2010 being awarded to Andre Geim and Konstantin Novoselov. Graphene and its related nanocarbon derivatives have exceptional mechanical, thermal, optical and electronic properties, making them a potential candidate for electronics and optoelectronics applications. However, this material has no intrinsic bandgap and complicated processes are required …

Go to article

Evolution Of Moiré Profiles From Van Der Waals Superstructures Of Boron Nitride Nanosheets, Yunlong Liao, Wei Cao, John W. Connell, Zhongfang Chen, Yi Lin Jan 2016

Evolution Of Moiré Profiles From Van Der Waals Superstructures Of Boron Nitride Nanosheets, Yunlong Liao, Wei Cao, John W. Connell, Zhongfang Chen, Yi Lin

Applied Research Center Publications

Two-dimensional (2D) van der Waals (vdW) superstructures, or vdW solids, are formed by the precise restacking of 2D nanosheet lattices, which can lead to unique physical and electronic properties that are not available in the parent nanosheets. Moiré patterns formed by the crystalline mismatch between adjacent nanosheets are the most direct features for vdW superstructures under microscopic imaging. In this article, transmission electron microscopy (TEM) observation of hexagonal Moiré patterns with unusually large micrometer-sized lateral areas (up to similar to 1μm2 and periodicities (up to similar to 50 nm) from restacking of liquid exfoliated hexagonal boron nitride nanosheets (BNNSs) …

Go to article

Nanosphere Lithography And Its Application In Rapid And Economic Fabrication Of Plasmonic Hydrogenated Amorphous Silicon Photovoltaic Devices, Chenlong Zhang Jan 2016

Nanosphere Lithography And Its Application In Rapid And Economic Fabrication Of Plasmonic Hydrogenated Amorphous Silicon Photovoltaic Devices, Chenlong Zhang

Dissertations, Master's Theses and Master's Reports

Solar photovoltaic (PV) devices harvest energy from solar radiation and convert it to electricity. PV technologies, as an alternative to traditional fossil fuels, use clean and renewable energy while minimizing pollution. For decades researchers have been developing thin film solar cells as an important alternatives to the relatively expensive bulk crystal solar cell technology. Among those, hydrogenated amorphous silicon (a-Si:H) solar cells prevails for good efficiency, non-toxic and materially abundant nature. However, a-Si:H thickness must be minimized to prevent light induced degradation, so optical enhancement is necessary. Light manipulation has to be applied and carefully engineered to trap light within …

Go to article

Characterization In 2d Sulfides And Graphene Composites For Sensing Applications, Alberto Delgado Jan 2016

Characterization In 2d Sulfides And Graphene Composites For Sensing Applications, Alberto Delgado

Open Access Theses & Dissertations

In this work, we have evaluated 2D layered material composites for opto-electro-mechanical sensing applications. In particular, we have focused on TMDCs and graphite and studied the effects of chemical liquid exfoliation on the structural characteristics of the 2D layered materials, through particle size, x-ray diffraction, Raman and surface area analysis. An approach was developed to combine the solution-processed dispersion with organic and inorganic matrix materials for forming the composites. From Raman Spectroscopy of the ultra-sonicated samples, the I2D/IG>2 for graphite, and for MoS2 the difference between the A1g and E2g peak was 22.85cm-1, consistent with few layer 2D MoS2. …

Go to article

Intrinsic And Metal-Doped Gallium Oxide Based High-Temperature Oxygen Sensors For Combustion Processes, Ernesto Javier Rubio Jan 2016

Intrinsic And Metal-Doped Gallium Oxide Based High-Temperature Oxygen Sensors For Combustion Processes, Ernesto Javier Rubio

Open Access Theses & Dissertations

Currently, there is enormous interest in research, development and optimization of the combustion processes for energy harvesting. Recent statistical and economic analyses estimated that by improving the coal-based firing/combustion processes in the power plants, savings up to ~$450-500 million yearly can be achieved. Advanced sensors and controls capable of withstanding extreme environments such as high temperatures, highly corrosive atmospheres, and high pressures are critical to such efficiency enhancement and cost savings. For instance, optimization of the combustion processes in power generation systems can be achieved by sensing, monitoring and control of oxygen, which is a measure of the completeness of …

Go to article

Structural, Dielectric, And Ferroelectric Characterization Of Lead-Free Calcium-Cerium Co-Doped Batio3 Ceramics, Juan Alberto Duran Jan 2016

Structural, Dielectric, And Ferroelectric Characterization Of Lead-Free Calcium-Cerium Co-Doped Batio3 Ceramics, Juan Alberto Duran

Open Access Theses & Dissertations

Structure, morphology, and regulation of the dielectric properties via close-composition intervals is demonstrated for variable-cerium, constant-calcium co-doped barium titanate (Ba0.80Ca0.20CeyTi1-yO3; y=0.0-0.25; referred to BCCT). The effect of variable Ce-content on the structure and dielectric properties of BCCT is investigated. X-ray diffraction spectra confirms the studied samples are mainly in BT tetragonal phase with a small secondary phase detected as CaTiO3 in BCCT for y = 0.20 and 0.25. However, the lattice parameter reduction was evident with increasing Ce-content. Composition-driven dielectric constant leap (4,000-5,500) was observed from intrinsic BCT to BCCT for (y = 0.0-0.04). The temperature dependent dielectric constant showed …

Go to article

First Prev Next Last