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Articles 1 - 30 of 1579
Full-Text Articles in Nanoscience and Nanotechnology
Decoding Surface Chemistry Effects On Polystyrene Nanoplastic Fouling In Plasma-Grafted Pes Membranes With Distinct Functional Groups, Mohadeseh Najafi, Javad Farahbakhsh, Ebrahim Mahmoudi, Michael Johns, Masoumeh Zargar
Decoding Surface Chemistry Effects On Polystyrene Nanoplastic Fouling In Plasma-Grafted Pes Membranes With Distinct Functional Groups, Mohadeseh Najafi, Javad Farahbakhsh, Ebrahim Mahmoudi, Michael Johns, Masoumeh Zargar
Research outputs 2022 to 2026
Nanoplastic (NP) fouling remains a key challenge for ultrafiltration (UF) membranes, yet systematic, controlled comparisons of how membrane functional groups govern NP-membrane interactions are still limited. Here, the role of membrane surface chemistry was systematically investigated using a controlled comparative framework based on plasma-grafted polyethersulfone (PES) UF membranes tailored with structurally comparable methacrylate monomers bearing distinct terminal functionalities, including mono-2-(methacryloyloxy)ethyl succinate (MMES, -COOH), N-[3-(dimethylamino)propyl] methacrylamide (DMAPMA, -N(CH3)2), and [2-(methacryloyloxy)ethyl]dimethyl-(3-sulfopropyl)ammonium hydroxide (SBMA, zwitterionic). Comprehensive characterisations supported successful surface grafting while preserving the membrane substructure. Fouling and separation were assessed using polystyrene (PS) NPs having different surface chemistries, i.e., PS, PS-COOH and …
Nanoparticle-Enabled Superplasticity In Extruded Az91 Magnesium Alloy With Elongation Exceeding 600%, Bai Xin Dong, Hong Yu Yang, Xin Zhang, Feng Qiu, Qi Chuan Jiang, Lai Chang Zhang
Nanoparticle-Enabled Superplasticity In Extruded Az91 Magnesium Alloy With Elongation Exceeding 600%, Bai Xin Dong, Hong Yu Yang, Xin Zhang, Feng Qiu, Qi Chuan Jiang, Lai Chang Zhang
Research outputs 2022 to 2026
No abstract provided.
Harnessing Tio2-Based Nanofilaments: A Pathway To Enhanced Optoelectronic Performance In Dye-Sensitized And Perovskite Light Harvesters, Zahraa Ismail, Tarek A. Elmelegy, Hassan Nageh, Sameh Abdellatif
Harnessing Tio2-Based Nanofilaments: A Pathway To Enhanced Optoelectronic Performance In Dye-Sensitized And Perovskite Light Harvesters, Zahraa Ismail, Tarek A. Elmelegy, Hassan Nageh, Sameh Abdellatif
Mechanical Engineering
This study explores the integration of TiO2-based nanofilaments into dye-sensitized solar cells (DSSCs) and perovskite solar cells (PSCs) to enhance their optoelectronic performance. Despite the advancements in one-dimensional lepidocrocite TiO2 nanofilaments, there remains a significant gap in understanding their optical scattering mechanisms and dual applicability in both types of solar cells. We synthesized TiO2 nanofilaments and compared their performance to conventional P25 TiO2 in terms of morphology, electrical, and optical properties. The results indicate that the DSSC utilizing nanofilaments achieved a short-circuit current density of 8.2 mA/cm² and a power conversion efficiency (PCE) of 6.9%, compared to 7.1 mA/cm² and …
Interfacial Redox Mediation By Amine/Alkyne-Functionalized Silicon Nanoparticles: Surfactant-Free Gold Nanoparticle Synthesis, Amber L. Garcia, Brittany Griggs, Brian S. Mitchell, Mark J. Fink, Julie P. Vanegas
Interfacial Redox Mediation By Amine/Alkyne-Functionalized Silicon Nanoparticles: Surfactant-Free Gold Nanoparticle Synthesis, Amber L. Garcia, Brittany Griggs, Brian S. Mitchell, Mark J. Fink, Julie P. Vanegas
Physics & Astronomy Faculty Publications
We develop a surfactant-free synthesis method for gold nanoparticles (AuNPs) using 2-propynylamine-functionalized silicon nanoparticles as integrated redox-active supports. Surface-anchored amine groups act as built-in reducing sites for Au3+ precursors at the hexane–water interface under ambient conditions, enabling in situ AuNP nucleation and growth. Time-resolved UV-vis spectroscopy and dynamic light scattering track the emergence of plasmonic AuNPs, while quantitative morphology analysis reveals a final population dominated by spherical and near-spherical nanoparticles (∼74%), with faceted polyhedral structures (∼4%) and dendritic, hollow, irregular, and rod-like morphologies (∼22%) as minority species. The temporal evolution proceeds from early dendritic and irregular aggregates to a …
Enhanced Triboelectric Effect Using Functionalized Multiwalled Carbon Nanotube-Coated Fiber Mats For Biomechanical Energy Harvesting, Fernando Viesca, Diego De Leon, Kevin Alejandro, Rigobert Ybarra Jr., Md. Wasikur Rahman, Victoria Padilla, Horacio Vasquez, Karen Lozano, M. Jasim Uddin
Enhanced Triboelectric Effect Using Functionalized Multiwalled Carbon Nanotube-Coated Fiber Mats For Biomechanical Energy Harvesting, Fernando Viesca, Diego De Leon, Kevin Alejandro, Rigobert Ybarra Jr., Md. Wasikur Rahman, Victoria Padilla, Horacio Vasquez, Karen Lozano, M. Jasim Uddin
Mechanical Engineering Faculty Publications
Triboelectric nanogenerators (TENGs) have emerged as a cutting-edge technology for developing self-powered wearable electronic devices. In this study, TENGs were fabricated using two fiber mats: forcespun polytetrafluoroethylene (FS-PTFE) microfibers and electrospun polyvinyl alcohol (ES-PVA) nanofiber (NF) mats. The FS-PTFE mats were coated with functionalized multiwalled carbon nanotubes (MWCNTs). Functionalized MWCNTs were dispersed in water-based solutions containing three different surfactants—sodium dodecyl sulfate, sodium dodecylbenzene sulfonate, and Triton X-100 to enhance fiber interaction. The NF mats were subsequently immersed in aqueous systems. The surfactant facilitated the uniform deposition of COOH-MWCNTs onto the FS-PTFE fibers, serving as a negative layer, while ES-PVA mat …
Numerical Evaluation Of A Zero Poisson’S Ratio Structure In Μ-3d-Printed Self-Expanding Nitinol Stents, Farhana Yasmin, Ana Vafadar, Majid Tolouei-Rad
Numerical Evaluation Of A Zero Poisson’S Ratio Structure In Μ-3d-Printed Self-Expanding Nitinol Stents, Farhana Yasmin, Ana Vafadar, Majid Tolouei-Rad
Research outputs 2022 to 2026
Stenting is a minimally invasive treatment used in managing peripheral artery disease (PAD). However, clinical challenges persist, including in-stent thrombosis and restenosis, primarily driven by axial foreshortening or elongation and suboptimal balance between radial stiffness and flexibility inherent to conventional stent designs. This study proposes an innovative arrow-shaped geometry exhibiting zero Poisson’s ratio (ZPR) behaviour for 3D-printed self-expanding Nitinol stents. The complete stent deployment process was modelled using finite element analysis (FEA), including radial crimping and subsequent expansion to enable systematic parametric investigation while accounting for µ-3D printing constraints. Response surface methodology (RSM) rigorously evaluated mechanical performance, defining peak stress, …
From Thin Films To Energy Systems: A Perspective-Oriented Translational Framework For Deployable Functional Materials, Mohammad Nur-E-Alam
From Thin Films To Energy Systems: A Perspective-Oriented Translational Framework For Deployable Functional Materials, Mohammad Nur-E-Alam
Research outputs 2022 to 2026
The translation of high-performance thin-film materials from lab-scale development to field-deployable energy systems remains a significant holdup in sustainable technology development. The real-world impact of functional thin films, nanocomposites, and emerging photovoltaic architectures is often limited by issues with scalability, interfacial reliability, environmental stability, and system-level integration, despite their excellent optical and electronic performance at the device level. A translational framework that is deployment-oriented and systematically connects interface-centric device integration, application-context validation, system-level performance feedback, and process-aware thin-film engineering has been presented in this article. Common structure-property-deployment trade-offs are identified through a comparative analysis of representative case domains, such as …
Drilling Fluid Enhancement Via Addition Of Sustainably Synthesized Nanoparticles, Hasan A. Abbood, Sarmad Al-Anssari
Drilling Fluid Enhancement Via Addition Of Sustainably Synthesized Nanoparticles, Hasan A. Abbood, Sarmad Al-Anssari
Research outputs 2022 to 2026
The addition of nanoparticles to the drilling fluids for geological projects is a promising application for enhancing the stability, rheological properties, and overall performance of the mud. This study aims to thoroughly analyze and compare the effects of silica and alumina nanoparticles on the properties and effectiveness of polymer drilling mud. Silica and alpha-alumina nanoparticles were synthesized using the sol-gel process and characterized through several techniques, including X-ray diffraction, Fourier-transform infrared spectroscopy, field-emission scanning electron microscopy, and atomic force microscopy. The effects of silica and alumina nanoparticles on various properties of drilling mud were then measured using a permeable plugging …
Sonochemically Synthesized Al-Doped Zno Nanorods-Based Flexible Piezoelectric Nanogenerators For Durable Energy Harvesting, Tiham Fayaz, Ahmed Hasnain Jalal, Fahmida Alam
Sonochemically Synthesized Al-Doped Zno Nanorods-Based Flexible Piezoelectric Nanogenerators For Durable Energy Harvesting, Tiham Fayaz, Ahmed Hasnain Jalal, Fahmida Alam
Electrical and Computer Engineering Faculty Publications
This study presents a high-performance piezoelectric nanogenerator (PENG) based on aluminum-doped zinc oxide (Al:ZnO) nanorods synthesized via a novel sonochemical method. This rapid, cost-effective, and reproducible approach enables the synthesis of ZnO nanorods (ZnO NRs) under ambient conditions. The PENG, fabricated on a 177 µm flexible Indium Tin Oxide (ITO) coated polyethylene terephthalate (PET) substrate, benefits from optimized aluminum doping, enhancing the output voltage. Structural analyses conducted using atomic force microscopy (AFM), scanning electron microscopy (SEM), and X-ray diffraction (XRD) demonstrated that the synthesized ZnO nanorods possessed a high degree of crystallinity. The synthesis process was carefully fine-tuned to avoid …
Sensing Negative-Cone Rotational Diffusion Of Dipole-Like Emitters, Yuanxin Qiu, Kaizhi A. Nie, Matthew D. Lew
Sensing Negative-Cone Rotational Diffusion Of Dipole-Like Emitters, Yuanxin Qiu, Kaizhi A. Nie, Matthew D. Lew
Electrical & Systems Engineering Publications and Presentations
Fluorescence anisotropy and single-molecule orientation-localization microscopy (SMOLM) are powerful techniques that quantify the rotational diffusion of dipole-like emitters, which is important for sensing molecular interactions and chemical environments at the nanoscale. Numerous theoretical and experimental studies have thoroughly characterized single-molecule rotations even when those rotations are much faster than the detector integration time. Here, we extend the theory of measuring rotational diffusion to situations where a single dipole rotates uniformly everywhere outside of an isotropic cone of a certain size, termed a negative cone. This scenario corresponds to negative fluorescence anisotropy 𝑟 and has been observed in emitters exhibiting strong …
Emerging Design Paradigms And Microstructural Innovations In Refractory High-Entropy Alloys: A Critical Review, Deyu A. Jiang, Lai Chang Zhang, Kuaishe Wang, Mahmoud Ebrahimi, Wen Wang, Liqiang Wang, Weijie Lu, Di Zhang
Emerging Design Paradigms And Microstructural Innovations In Refractory High-Entropy Alloys: A Critical Review, Deyu A. Jiang, Lai Chang Zhang, Kuaishe Wang, Mahmoud Ebrahimi, Wen Wang, Liqiang Wang, Weijie Lu, Di Zhang
Research outputs 2022 to 2026
Refractory high-entropy alloys (RHEAs) are being developed to meet mechanical, thermal and chemical requirements that exceed what current super-alloys can withstand. This review explains how composition design, processing routes and the resulting microstructures now combine to realize that potential. We first link phase selection in BCC-, FCC- and dual-phase RHEAs to atomic-size mismatch, mixing enthalpy and valence-electron concentration, and compare manufacturing paths ranging from arc melting to powder metallurgy, additive manufacturing and vapor deposition, showing how each reshapes grain structure and defect chemistry to improve high-temperature strength, corrosion resistance and irradiation tolerance. Computation-led tools—density-functional theory, calculation of phase diagrams and …
Nanoscale Opportunities In Extracellular Matrix Mimicry, L. Andrew Lyon, Abbygail Caine, Elif Narbay, E. Daniel Cárdenas-Vásquez
Nanoscale Opportunities In Extracellular Matrix Mimicry, L. Andrew Lyon, Abbygail Caine, Elif Narbay, E. Daniel Cárdenas-Vásquez
Engineering Faculty Articles and Research
We present an overview of the composition, function, energetics, and dynamics of extracellular matrix and its relation to nanoscale structures and phenomena. These concepts are then related to the development of synthetic and biosynthetic materials that aim to mimic the extracellular matrix for regenerative medicine and tissue engineering technologies. Notable successes and advancements towards the goal of biomimicry are outlined, while remaining challenges and knowledge gaps towards that goal are highlighted. Finally, we frame the remaining challenges in the field in terms of nanoscience-related research opportunities that if solved, might prove to be transformative steps forward in the discipline.
Multidentate Surfactant-Dependent Synthesis Of Giant Iridium Superstructures, Ramjee Balasubramanian, Maeren E. Hill
Multidentate Surfactant-Dependent Synthesis Of Giant Iridium Superstructures, Ramjee Balasubramanian, Maeren E. Hill
Chemistry & Biochemistry Faculty Publications
Giant superstructures of iridium, comprised of smaller spherical and slightly larger anisotropic nanoparticles, were synthesized by reducing iridium chloride in the presence of resorcinarene, a class of tetrameric macrocyclic polyphenols, with sodium borohydride in ethanol in 30 min under mild conditions. These superstructures were characterized by a range of techniques including TEM, HRTEM, EDS and other spectroscopic methods. The impact of the macrocyclic surfactant, its features and reaction conditions in dictating the formation of giant iridium superstructures was evaluated. The packing density of nanoparticles in these giant iridium superstructures could be altered qualitatively by varying the duration of the reaction, …
Stiffening Of Soft Silicone Upon Deep Uv Treatment As Characterized Using Nanoindentation, Amanda Wilder, Zaria Booth, Caden Obermeyer, Saika Sharmin, Venkat Maruthamuthu
Stiffening Of Soft Silicone Upon Deep Uv Treatment As Characterized Using Nanoindentation, Amanda Wilder, Zaria Booth, Caden Obermeyer, Saika Sharmin, Venkat Maruthamuthu
Mechanical & Aerospace Engineering Faculty Publications
Silicones are elastomers that have a wide variety of uses, including biomedical applications such as the coating of biomedical devices and as implants. Soft silicones with mechanical properties similar to those of biological tissues have particularly gained use as substrates for cell culture in mechanobiology studies. In this context, it would be desirable to be able to alter their surface mechanical properties with a relatively simple physical treatment. While deep ultraviolet (deep UV) or ultraviolet C (UV-C) treatment has been previously used as a surface treatment method for stiffer silicones formulations, the effect of this treatment on soft silicones relevant …
Application Of A Hyaluronic Acid-Based Lotions Containing Hydroxyapatite Nano-Particles Approach For Treatment Of Initial Dental Caries, Zahra Gharavi, Zahra Namazi, Fatemehsadat Pishbin, Helia Givian, Maryam Torshabi, Farhood Najafi, Parisa Amdjadi
Application Of A Hyaluronic Acid-Based Lotions Containing Hydroxyapatite Nano-Particles Approach For Treatment Of Initial Dental Caries, Zahra Gharavi, Zahra Namazi, Fatemehsadat Pishbin, Helia Givian, Maryam Torshabi, Farhood Najafi, Parisa Amdjadi
Electrical & Computer Engineering Faculty Publications
This study evaluated the remineralization potential of a ceramic–polyelectrolyte system, based on a novel combination of hydroxyapatite nanoparticles (HAp NPs) and a hyaluronic acid (HY) matrix, for dental enamel, a tissue that remains challenging to repair in clinical dentistry. Nano-Hydroxyapatite (nanoHAp) powder was synthesized and characterized using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), field-emission scanning electron microscopy (FE-SEM), dynamic light scattering (DLS), and zeta potential analysis to confirm their crystalline structure, functional groups, morphology, particle size distribution, and colloidal stability. HY-based suspensions (remineralizing lotions) containing 5, 10, and 12 wt% of the synthesized nanoHAp particles were formulated via a …
Mobility Of Hydrophilic And Hydrophobic Nanoparticles In Carbonate Reservoirs: Application To Subsurface Projects, Zain Ul Abedin Arain, Sarmad Al-Anssari, Muhammad Ali, Faisal Ur Rahman Awan, Alireza Keshavarz, Jitendra Sangwai, Mohammad Sarmadivaleh, Stefan Iglauer
Mobility Of Hydrophilic And Hydrophobic Nanoparticles In Carbonate Reservoirs: Application To Subsurface Projects, Zain Ul Abedin Arain, Sarmad Al-Anssari, Muhammad Ali, Faisal Ur Rahman Awan, Alireza Keshavarz, Jitendra Sangwai, Mohammad Sarmadivaleh, Stefan Iglauer
Research outputs 2022 to 2026
Nanoparticles (NPs) have been suggested for subsurface projects, including enhanced oil recovery (EOR), carbon capture and storage (CCS), and hydrogen storage, due to their small size, high surface energy, controlled surface properties, and significant effects on the underground formation properties. Silica is an excellent NP that efficiently modifies the surface properties of subsurface formations for incremental oil recovery and to derisk carbon and hydrogen leaks. However, the retention of injected NPs in a narrow area near the injection inlet can limit a project’s feasibility. In the present study, hydrophobic (hybrid) NPs were produced via silanization of silica NPs, and the …
Effect Of Molybdenum Content On The Microstructure And Tribological Properties Of Ti-Nb-Cu Alloys Produced By Lpbf Additive Manufacturing, Lei Qin, Shengfeng Zhou, Jianbo Jin, Huan Yang, Kunmao Li, Cheng Deng, Yujie Yuan, Seyed Reza Elmi Hosseini, Laichang Zhang
Effect Of Molybdenum Content On The Microstructure And Tribological Properties Of Ti-Nb-Cu Alloys Produced By Lpbf Additive Manufacturing, Lei Qin, Shengfeng Zhou, Jianbo Jin, Huan Yang, Kunmao Li, Cheng Deng, Yujie Yuan, Seyed Reza Elmi Hosseini, Laichang Zhang
Research outputs 2022 to 2026
Obtaining excellent wear resistance is critical for titanium alloys used as orthopedic implants. In this study, the β-type Ti-35Nb-5Cu- x Mo alloys (Ti355 x , x = 0, 1, 2, and 4 wt%) were fabricated by the laser powder bed fusion (LPBF) method. In the meantime, the influence mechanism of Mo content on the microstructure and tribological properties was systematically investigated. The results show that all the LPBF-produced Ti355 x alloys exhibit a bimodal columnar-equiaxed grain structure, with Mo refining columnar grains and suppressing the α″ phase formation. Moreover, increasing the Mo content reduced the relative density, while enhancing the …
Machine-Learning-Guided Design Of A Biomedical High-Entropy Alloy For Additive Manufacturing: Cast-State Benchmark And Preliminary Lpbf Feasibility Assessment, Deyu Jiang, Lai Chang Zhang, Kuaishe Wang, Wen Wang, Chenyuan Zhu, Yuanfei Fu, Kai Wang, Wei Zhai, Ching Chiuan Yen, Weijie Lu, Di Zhang, Liqiang Wang
Machine-Learning-Guided Design Of A Biomedical High-Entropy Alloy For Additive Manufacturing: Cast-State Benchmark And Preliminary Lpbf Feasibility Assessment, Deyu Jiang, Lai Chang Zhang, Kuaishe Wang, Wen Wang, Chenyuan Zhu, Yuanfei Fu, Kai Wang, Wei Zhai, Ching Chiuan Yen, Weijie Lu, Di Zhang, Liqiang Wang
Research outputs 2022 to 2026
Additive manufacturing of biomedical high-entropy alloys (BioHEAs) demands a combination of low elastic modulus, high strength, and damage tolerance, yet composition discovery remains largely empirical. Here, we establish a machine-learning framework that couples virtual screening with physical prototyping to link composition, deformation mechanism, and properties. Ensemble models for strength, elongation, and modulus were applied to screen Ti–Zr–Nb–Ta–Mo-centered quinary-to-septenary spaces (∼15 million compositions), revealing discrete performance islands anchored by a Ti–Zr backbone. A Zr-rich BCC alloy (Zr₃₉.₃Ti₁₉.₅Nb₁₇.₉Ta₁₆.₈Mo₆.₅) was identified and validated. In the as-cast state, it delivers ∼1.0 GPa yield strength, 22.3% elongation, and an 88 GPa elastic modulus; ductility originates …
A Portable Potentiostat Integrated With A Pt/Zno/Lig Electrode For Non-Enzymatic Glucose Detection, Reagan Aviha, Gymama Slaughter
A Portable Potentiostat Integrated With A Pt/Zno/Lig Electrode For Non-Enzymatic Glucose Detection, Reagan Aviha, Gymama Slaughter
Center for Bioelectronics Publications
Continuous glucose monitoring is critical for effective diabetes management; however, conventional benchtop potentiostats are bulky, costly, and unsuitable for decentralized point-of-care (PoC) applications. To address these limitations, this work presents a miniaturized, low-cost electrochemical sensing platform integrating a non-enzymatic glucose sensor with a portable potentiostat. The sensing electrode is based on laser-induced graphene modified with zinc oxide and platinum nanostructures via electrodeposition to enable sensitive glucose detection under physiological conditions. A custom-designed portable potentiostat was developed to control electrode potentials and perform electrochemical measurements, and its performance was experimentally validated against a commercial Metrohm system. Glucose detection was evaluated using …
Advancing Sustainable Co2 Mitigation: Experimental And Computational Analysis Of Thermal Carbon Chitosan Sorbent For Automotive Exhaust Capture, Dalia A. Ali Dr., Amir Ahmed Elgamal Eng., Rania Rushdy Moussa Dr.
Advancing Sustainable Co2 Mitigation: Experimental And Computational Analysis Of Thermal Carbon Chitosan Sorbent For Automotive Exhaust Capture, Dalia A. Ali Dr., Amir Ahmed Elgamal Eng., Rania Rushdy Moussa Dr.
Chemical Engineering
This study investigated the efficiency of thermal carbon chitosan (TCCS) sorbent for CO2 capture from vehicle exhaust emissions within a designed adsorption system. TCCS was synthesized and meticulously characterized using a series of analytical techniques, including Brunauer-Emmett-Teller (BET) surface area analysis, Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), Ther- mogravimetric Analysis (TGA), Energy Dispersive X-ray Spectroscopy (EDX), and Differential Scanning Calo- rimetry (DSC). The TCCS adsorbent showed high thermal stability and a heating value (HHV) of 23.5 MJ/kg. Adsorption isotherm study demonstrated that the maximum capacity of CO2 adsorption is 0.084 kg.CO2/kg. TCCS, as well …
Nanotechnology Strategies For Endometrium Health: Are We On The Right Track?, Victoria Herrera, Dana Tarab-Ravski, Subhash Chauhan, Nikesh Narang, Mohammad Mirazul Islam, Dan Peer, Rajendra Prasad, Murali Yallapu
Nanotechnology Strategies For Endometrium Health: Are We On The Right Track?, Victoria Herrera, Dana Tarab-Ravski, Subhash Chauhan, Nikesh Narang, Mohammad Mirazul Islam, Dan Peer, Rajendra Prasad, Murali Yallapu
School of Medicine Publications
The endometrium is a vital mucosal tissue which undergoes cyclical regeneration, differentiation, and remodeling upon hormonal, cellular, and molecular signaling networks. Dysregulation of these processes can trigger a range of pathological conditions including chronic inflammatory disorders, hyperplastic lesions, malignancies, and infertility, necessitating the need for effective therapeutic interventions. Furthermore, we are still dependent on conventional treatment modalities which are often constrained by inefficient drug biodistribution, systemic toxicity, and emergence of therapeutic resistance. Recently, nanomedicines have gained tremendous attention in human healthcare, because they not only diagnose the disease but also deliver therapeutic agents to the targeted site without affecting healthy …
Melamine-Based Polymer Nanofibers For Supercapacitors, Samar A. Salim, Hani Nasser Abdelhamid
Melamine-Based Polymer Nanofibers For Supercapacitors, Samar A. Salim, Hani Nasser Abdelhamid
Nanotechnology Research Centre
This investigation describes the synthesis, electrospinning, and characterization of melamine-glutaraldehyde (MAGA) polymer composites with polymethyl methacrylate (PMMA) for supercapacitors applications. Electrospun fibers are generated by combining the MAGA polymer with PMMA at varying concentrations (2.5 %, 5 %, and 10 wt%). The synthesis of the polymer, its morphological attributes, and structural features are validated by characterization methods e.g., XRD, TEM, SEM, and FT-IR. In a three-electrode configuration, the electrochemical performances of the prepared electrodes are assessed using cyclic voltammetry (CV), galvanostatic charge-discharge (GCDC), and linear sweep voltammetry (LSV). The results suggest that the 5 % MAGA-PMMA composite has a specific …
Developing A Low-Temperature Pathway For The Synthesis Of Two-Dimensional Ws2 Nanosheets, Akhil Potdar
Developing A Low-Temperature Pathway For The Synthesis Of Two-Dimensional Ws2 Nanosheets, Akhil Potdar
Holster Scholar Projects
Since their discovery in 2004, two-dimensional (2D) materials have attracted great attention due to their unique mechanical, electrical, and chemical properties. However, their integration into devices is limited by the high temperatures required for crystalline growth, which prevents the use of flexible and biocompatible substrates like polymers for biomedical and next-generation electronic devices. This project aims to therefore develop a low-temperature synthesis process for two-dimensional tungsten disulfide (WS₂), a material particularly promising due to its tunable bandgap and biocompatibility. We propose that by first depositing an intermediate tungsten oxide film (WOx) via Hollow Cathode Plasma-Assisted Atomic Layer Deposition (HCP-ALD) and …
Eng- Semicon: Understanding Nanoscale Heat Transport In Wide- And Ultrawide Bandgap Semiconductors Using Novel Deep Ultraviolet Tools, Joshua Lee Knobloch
Eng- Semicon: Understanding Nanoscale Heat Transport In Wide- And Ultrawide Bandgap Semiconductors Using Novel Deep Ultraviolet Tools, Joshua Lee Knobloch
Funded Research Records
No abstract provided.
Click-Ready Gold Nanoparticles From Aqueous Mechanochemistry: 2-Propynylamine As A Reducing Agent And Surface Ligand, Amber L. Garcia, Brian S. Mitchell, Amanda Reusch, Mark J. Fink, Juan P. Hinestroza, Yelin Ko, Julie P. Vanegas
Click-Ready Gold Nanoparticles From Aqueous Mechanochemistry: 2-Propynylamine As A Reducing Agent And Surface Ligand, Amber L. Garcia, Brian S. Mitchell, Amanda Reusch, Mark J. Fink, Juan P. Hinestroza, Yelin Ko, Julie P. Vanegas
Physics & Astronomy Faculty Publications
We report a rapid aqueous method for synthesizing monodisperse gold nanoparticles (AuNPs), employing 2-propynylamine as both an intrinsic reducing agent and a surface-stabilizing ligand. This self-mediated process—achieved in a single step—yields spherical AuNPs with an average diameter of 4.0 ± 1.0 nm and a well-defined localized surface plasmon resonance band centered at 520 nm. Acting as a bifunctional molecule, 2-propynylamine simultaneously reduces HAuCl4·3H2O to elemental gold and passivates the nanoparticle surface through coordination via the amine group, while preserving a terminal alkyne (–C≡CH) functionality. This reactive moiety remains exposed and chemically accessible, enabling post-synthetic modification through Cu(I)-catalyzed azide–alkyne cycloaddition. Control …
Nanostructured Zinc Stannate Perovskite Films Synthesized Via Molten Salt Modified-Solvothermal Method For Enhanced Piezoelectric Properties, Christopher Munoz, Alyssah Fuentes, Christian Alaniz, Tarik Dickens, Mohammed Jasim Uddin
Nanostructured Zinc Stannate Perovskite Films Synthesized Via Molten Salt Modified-Solvothermal Method For Enhanced Piezoelectric Properties, Christopher Munoz, Alyssah Fuentes, Christian Alaniz, Tarik Dickens, Mohammed Jasim Uddin
School of Integrative Biological & Chemical Sciences Faculty Publications
Three dimensional (3D) piezoelectric zinc stannate (ZnSnO3) nanoweb arrays are synthesized using a molten salt modified solvothermal method and deposited in PDMS films for electrochemical analysis of its piezoelectric response. This work is a preliminary assessment of comparative piezoelectric efficacy influenced by changes in synthesis, effecting dimension and particle size. Advantages of hydrothermal, molten salt, and solvothermal synthesis methods were leveraged to facilitate several chemical and surface engineering techniques to enhance piezoelectric properties by increasing the surface area of zinc stannate nanoparticles. The combination of these treatments reduce the size of zinc stannate to approximately ∼40nm-80nm weblike networks. Scanning …
Single-Molecule Orientation And Localization Microscopy, Sophie Brasselet, Matthew D. Lew
Single-Molecule Orientation And Localization Microscopy, Sophie Brasselet, Matthew D. Lew
Electrical & Systems Engineering Publications and Presentations
Single-molecule localization microscopy (SMLM) offers enhanced spatial resolution in optical microscopy, providing detailed insights into the spatial organization of proteins in cells at the nanoscale. Over the past decade, SMLM has progressively incorporated the capability to retrieve the orientations of single molecules using their polarized dipolar emission pattern. Here we explore recent advancements in single-molecule orientation and localization microscopy (SMOLM), which yields super-resolved images of molecular three-dimensional (3D) orientations, wobble and 3D positions. This advancement opens possibilities to explore the nanoscale organization and conformation of biological molecules as well as to monitor and design local 3D optical fields in nanophotonics. …
Improved Triboelectric Nanogenerator By As-Prepared Lithium Niobate For Energy Harvesting And Sensing Applications, Jahid Inam Chowdhury, Md. Wasikur Rahman, Md Arafat Hossain, Nicholas Dimakis, Mohammed Jasim Uddin
Improved Triboelectric Nanogenerator By As-Prepared Lithium Niobate For Energy Harvesting And Sensing Applications, Jahid Inam Chowdhury, Md. Wasikur Rahman, Md Arafat Hossain, Nicholas Dimakis, Mohammed Jasim Uddin
School of Integrative Biological & Chemical Sciences Faculty Publications
Triboelectric nanogenerators (TENGs) have garnered significant research interest due to their ability to harvest mechanical energy efficiently. In this study, we report a TENG composed of polydimethylsiloxane (PDMS) and polyvinyl alcohol (PVA) as triboelectric layers. To enhance charge generation in the PDMS composite polymer, we incorporated lithium niobate (LiNbO3) nanoparticles, leveraging their piezoelectric and ferroelectric properties. The LiNbO3 nanoparticles were synthesized using a solid-state reaction method, resulting in two distinct phases: triclinic LiNbO3 and monoclinic LiNb3O8. Various weight percentages of LiNbO3 and LiNb3O8 nanoparticles were added to the PDMS matrix to optimize power generation. The maximum open-circuit voltage (VOC) and …
A Biocompatible Nitinol Based Triboelectric Stent Sensor For Prospective Cardiovascular Health Monitoring, Ulises Vidaurri Romero, Sk Shamim Hasan Abir, Najlah Karam, Mariana Torres, Shahria Ahmed, Md. Wasikur Rahman, Bahareh Azimi, Serena Danti, Jianzhi Li, M. Jasim Uddin
A Biocompatible Nitinol Based Triboelectric Stent Sensor For Prospective Cardiovascular Health Monitoring, Ulises Vidaurri Romero, Sk Shamim Hasan Abir, Najlah Karam, Mariana Torres, Shahria Ahmed, Md. Wasikur Rahman, Bahareh Azimi, Serena Danti, Jianzhi Li, M. Jasim Uddin
Mechanical Engineering Faculty Publications
Triboelectric nanogenerators (TENGs) have been considered as an effective approach for self-powered systems. Currently, coronary heart disease remains the leading cause of death in the United States. This can be easily resolved by balloon angioplasty or a specialized mesh tube called a stent. This study demonstrates a stent sensor made of nitinol, a nickel—titanium alloy used in the medical field for its pseudo-elasticity and strong corrosion resistance, poly(vinylidene fluoride) (PVDF) and polydimethylsiloxane (PDMS), which can measure several physiological parameters while placing it in the arteries. This nitinol health monitor sensor (NHMS) device thus integrates the TENG with a specific medical …
Methane Partial Oxidation With Ni-Mg-Al Hydrotalcites: Impact Of Magnesium On Catalyst Performance, Dalia A. Ali Dr.
Methane Partial Oxidation With Ni-Mg-Al Hydrotalcites: Impact Of Magnesium On Catalyst Performance, Dalia A. Ali Dr.
Chemical Engineering
The partial oxidation of methane (POM) is a promising route for hydrogen-rich syngas production with lower energy requirements compared to steam reforming. Herein, Ni-incorporated Mg-Al hydrotalcite- derived mixed oxide catalysts (5Ni-HT-x, x = 60, 65, 70, 75 wt.% Mg) were synthesized via co-precipitation and evaluated for CH₄ conversion and H₂ yield. Characterization techniques, including X-ray Diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), BET, H₂-TPR, TEM, FTIR, TGA, and Raman spectroscopy, were employed to investigate catalyst structure, active site stability, and carbon deposition. As a constituent of hydrotalcite-derived mixed oxides (HT), Ni2+ is strongly bound within the hydrotalcite- derived mixed oxides structure, …