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Articles 1 - 30 of 54
Full-Text Articles in Nanoscience and Nanotechnology
Interfacial Redox Mediation By Amine/Alkyne-Functionalized Silicon Nanoparticles: Surfactant-Free Gold Nanoparticle Synthesis, Amber L. Garcia, Brittany Griggs, Brian S. Mitchell, Mark J. Fink, Julie P. Vanegas
Interfacial Redox Mediation By Amine/Alkyne-Functionalized Silicon Nanoparticles: Surfactant-Free Gold Nanoparticle Synthesis, Amber L. Garcia, Brittany Griggs, Brian S. Mitchell, Mark J. Fink, Julie P. Vanegas
Physics & Astronomy Faculty Publications
We develop a surfactant-free synthesis method for gold nanoparticles (AuNPs) using 2-propynylamine-functionalized silicon nanoparticles as integrated redox-active supports. Surface-anchored amine groups act as built-in reducing sites for Au3+ precursors at the hexane–water interface under ambient conditions, enabling in situ AuNP nucleation and growth. Time-resolved UV-vis spectroscopy and dynamic light scattering track the emergence of plasmonic AuNPs, while quantitative morphology analysis reveals a final population dominated by spherical and near-spherical nanoparticles (∼74%), with faceted polyhedral structures (∼4%) and dendritic, hollow, irregular, and rod-like morphologies (∼22%) as minority species. The temporal evolution proceeds from early dendritic and irregular aggregates to a …
Enhanced Triboelectric Effect Using Functionalized Multiwalled Carbon Nanotube-Coated Fiber Mats For Biomechanical Energy Harvesting, Fernando Viesca, Diego De Leon, Kevin Alejandro, Rigobert Ybarra Jr., Md. Wasikur Rahman, Victoria Padilla, Horacio Vasquez, Karen Lozano, M. Jasim Uddin
Enhanced Triboelectric Effect Using Functionalized Multiwalled Carbon Nanotube-Coated Fiber Mats For Biomechanical Energy Harvesting, Fernando Viesca, Diego De Leon, Kevin Alejandro, Rigobert Ybarra Jr., Md. Wasikur Rahman, Victoria Padilla, Horacio Vasquez, Karen Lozano, M. Jasim Uddin
Mechanical Engineering Faculty Publications
Triboelectric nanogenerators (TENGs) have emerged as a cutting-edge technology for developing self-powered wearable electronic devices. In this study, TENGs were fabricated using two fiber mats: forcespun polytetrafluoroethylene (FS-PTFE) microfibers and electrospun polyvinyl alcohol (ES-PVA) nanofiber (NF) mats. The FS-PTFE mats were coated with functionalized multiwalled carbon nanotubes (MWCNTs). Functionalized MWCNTs were dispersed in water-based solutions containing three different surfactants—sodium dodecyl sulfate, sodium dodecylbenzene sulfonate, and Triton X-100 to enhance fiber interaction. The NF mats were subsequently immersed in aqueous systems. The surfactant facilitated the uniform deposition of COOH-MWCNTs onto the FS-PTFE fibers, serving as a negative layer, while ES-PVA mat …
Sonochemically Synthesized Al-Doped Zno Nanorods-Based Flexible Piezoelectric Nanogenerators For Durable Energy Harvesting, Tiham Fayaz, Ahmed Hasnain Jalal, Fahmida Alam
Sonochemically Synthesized Al-Doped Zno Nanorods-Based Flexible Piezoelectric Nanogenerators For Durable Energy Harvesting, Tiham Fayaz, Ahmed Hasnain Jalal, Fahmida Alam
Electrical and Computer Engineering Faculty Publications
This study presents a high-performance piezoelectric nanogenerator (PENG) based on aluminum-doped zinc oxide (Al:ZnO) nanorods synthesized via a novel sonochemical method. This rapid, cost-effective, and reproducible approach enables the synthesis of ZnO nanorods (ZnO NRs) under ambient conditions. The PENG, fabricated on a 177 µm flexible Indium Tin Oxide (ITO) coated polyethylene terephthalate (PET) substrate, benefits from optimized aluminum doping, enhancing the output voltage. Structural analyses conducted using atomic force microscopy (AFM), scanning electron microscopy (SEM), and X-ray diffraction (XRD) demonstrated that the synthesized ZnO nanorods possessed a high degree of crystallinity. The synthesis process was carefully fine-tuned to avoid …
Nanotechnology Strategies For Endometrium Health: Are We On The Right Track?, Victoria Herrera, Dana Tarab-Ravski, Subhash Chauhan, Nikesh Narang, Mohammad Mirazul Islam, Dan Peer, Rajendra Prasad, Murali Yallapu
Nanotechnology Strategies For Endometrium Health: Are We On The Right Track?, Victoria Herrera, Dana Tarab-Ravski, Subhash Chauhan, Nikesh Narang, Mohammad Mirazul Islam, Dan Peer, Rajendra Prasad, Murali Yallapu
School of Medicine Publications
The endometrium is a vital mucosal tissue which undergoes cyclical regeneration, differentiation, and remodeling upon hormonal, cellular, and molecular signaling networks. Dysregulation of these processes can trigger a range of pathological conditions including chronic inflammatory disorders, hyperplastic lesions, malignancies, and infertility, necessitating the need for effective therapeutic interventions. Furthermore, we are still dependent on conventional treatment modalities which are often constrained by inefficient drug biodistribution, systemic toxicity, and emergence of therapeutic resistance. Recently, nanomedicines have gained tremendous attention in human healthcare, because they not only diagnose the disease but also deliver therapeutic agents to the targeted site without affecting healthy …
Click-Ready Gold Nanoparticles From Aqueous Mechanochemistry: 2-Propynylamine As A Reducing Agent And Surface Ligand, Amber L. Garcia, Brian S. Mitchell, Amanda Reusch, Mark J. Fink, Juan P. Hinestroza, Yelin Ko, Julie P. Vanegas
Click-Ready Gold Nanoparticles From Aqueous Mechanochemistry: 2-Propynylamine As A Reducing Agent And Surface Ligand, Amber L. Garcia, Brian S. Mitchell, Amanda Reusch, Mark J. Fink, Juan P. Hinestroza, Yelin Ko, Julie P. Vanegas
Physics & Astronomy Faculty Publications
We report a rapid aqueous method for synthesizing monodisperse gold nanoparticles (AuNPs), employing 2-propynylamine as both an intrinsic reducing agent and a surface-stabilizing ligand. This self-mediated process—achieved in a single step—yields spherical AuNPs with an average diameter of 4.0 ± 1.0 nm and a well-defined localized surface plasmon resonance band centered at 520 nm. Acting as a bifunctional molecule, 2-propynylamine simultaneously reduces HAuCl4·3H2O to elemental gold and passivates the nanoparticle surface through coordination via the amine group, while preserving a terminal alkyne (–C≡CH) functionality. This reactive moiety remains exposed and chemically accessible, enabling post-synthetic modification through Cu(I)-catalyzed azide–alkyne cycloaddition. Control …
Nanostructured Zinc Stannate Perovskite Films Synthesized Via Molten Salt Modified-Solvothermal Method For Enhanced Piezoelectric Properties, Christopher Munoz, Alyssah Fuentes, Christian Alaniz, Tarik Dickens, Mohammed Jasim Uddin
Nanostructured Zinc Stannate Perovskite Films Synthesized Via Molten Salt Modified-Solvothermal Method For Enhanced Piezoelectric Properties, Christopher Munoz, Alyssah Fuentes, Christian Alaniz, Tarik Dickens, Mohammed Jasim Uddin
School of Integrative Biological & Chemical Sciences Faculty Publications
Three dimensional (3D) piezoelectric zinc stannate (ZnSnO3) nanoweb arrays are synthesized using a molten salt modified solvothermal method and deposited in PDMS films for electrochemical analysis of its piezoelectric response. This work is a preliminary assessment of comparative piezoelectric efficacy influenced by changes in synthesis, effecting dimension and particle size. Advantages of hydrothermal, molten salt, and solvothermal synthesis methods were leveraged to facilitate several chemical and surface engineering techniques to enhance piezoelectric properties by increasing the surface area of zinc stannate nanoparticles. The combination of these treatments reduce the size of zinc stannate to approximately ∼40nm-80nm weblike networks. Scanning …
Improved Triboelectric Nanogenerator By As-Prepared Lithium Niobate For Energy Harvesting And Sensing Applications, Jahid Inam Chowdhury, Md. Wasikur Rahman, Md Arafat Hossain, Nicholas Dimakis, Mohammed Jasim Uddin
Improved Triboelectric Nanogenerator By As-Prepared Lithium Niobate For Energy Harvesting And Sensing Applications, Jahid Inam Chowdhury, Md. Wasikur Rahman, Md Arafat Hossain, Nicholas Dimakis, Mohammed Jasim Uddin
School of Integrative Biological & Chemical Sciences Faculty Publications
Triboelectric nanogenerators (TENGs) have garnered significant research interest due to their ability to harvest mechanical energy efficiently. In this study, we report a TENG composed of polydimethylsiloxane (PDMS) and polyvinyl alcohol (PVA) as triboelectric layers. To enhance charge generation in the PDMS composite polymer, we incorporated lithium niobate (LiNbO3) nanoparticles, leveraging their piezoelectric and ferroelectric properties. The LiNbO3 nanoparticles were synthesized using a solid-state reaction method, resulting in two distinct phases: triclinic LiNbO3 and monoclinic LiNb3O8. Various weight percentages of LiNbO3 and LiNb3O8 nanoparticles were added to the PDMS matrix to optimize power generation. The maximum open-circuit voltage (VOC) and …
A Biocompatible Nitinol Based Triboelectric Stent Sensor For Prospective Cardiovascular Health Monitoring, Ulises Vidaurri Romero, Sk Shamim Hasan Abir, Najlah Karam, Mariana Torres, Shahria Ahmed, Md. Wasikur Rahman, Bahareh Azimi, Serena Danti, Jianzhi Li, M. Jasim Uddin
A Biocompatible Nitinol Based Triboelectric Stent Sensor For Prospective Cardiovascular Health Monitoring, Ulises Vidaurri Romero, Sk Shamim Hasan Abir, Najlah Karam, Mariana Torres, Shahria Ahmed, Md. Wasikur Rahman, Bahareh Azimi, Serena Danti, Jianzhi Li, M. Jasim Uddin
Mechanical Engineering Faculty Publications
Triboelectric nanogenerators (TENGs) have been considered as an effective approach for self-powered systems. Currently, coronary heart disease remains the leading cause of death in the United States. This can be easily resolved by balloon angioplasty or a specialized mesh tube called a stent. This study demonstrates a stent sensor made of nitinol, a nickel—titanium alloy used in the medical field for its pseudo-elasticity and strong corrosion resistance, poly(vinylidene fluoride) (PVDF) and polydimethylsiloxane (PDMS), which can measure several physiological parameters while placing it in the arteries. This nitinol health monitor sensor (NHMS) device thus integrates the TENG with a specific medical …
Tailoring Gel Polymer Electrolytes For Advancing Quasi-Solid-State Batteries, Linrui Duan, Juchen Zhang, Mataz Alcoutlabi, Hongtao Sun
Tailoring Gel Polymer Electrolytes For Advancing Quasi-Solid-State Batteries, Linrui Duan, Juchen Zhang, Mataz Alcoutlabi, Hongtao Sun
Mechanical Engineering Faculty Publications
Gel polymer electrolytes (GPEs) have attracted considerable attention due to their advantageous properties, such as uniform lithium deposition, stable solid electrolyte interphase (SEI) formation, nontoxicity, nonflammability, and leak-proof characteristics. In this study, a polyvinylidene fluoride hexafluoropropylene copolymer (PVDF-HFP)-based gel polymer electrolyte is synthesized via photo-polymerization, with a focus on examining the effects of curing time on electrolyte performance. The findings reveal that UV irradiation conditions significantly influence key material and electrochemical properties of the GPEs, including lithium-ion transference number, ionic conductivity, crystallinity, morphology, and liquid electrolyte uptake. Notably, the GPE cured for 120 s exhibited optimized performance, achieving an ionic …
Neodymium Doped Zinc Oxide Based Advanced Flexible Piezoelectric Energy Harvester And Self-Powered Biomotion Sensor, Muhtasim Ul Karim Sadaf, Abu Musa Abdullah, Haimanti Majumder, Sk Shamim Hasan Abir, Mariana Torres, Karen Lozano, Md. Wasikur Rahman, M. Jasim Uddin
Neodymium Doped Zinc Oxide Based Advanced Flexible Piezoelectric Energy Harvester And Self-Powered Biomotion Sensor, Muhtasim Ul Karim Sadaf, Abu Musa Abdullah, Haimanti Majumder, Sk Shamim Hasan Abir, Mariana Torres, Karen Lozano, Md. Wasikur Rahman, M. Jasim Uddin
Mechanical Engineering Faculty Publications
Flexible piezoelectric devices have garnered a lot of attention for their potential as energy harvesters and transducers. In this work, Neodymium (Nd) doped Zinc Oxide (ZnO) based flexible piezoelectric energy harvester and sensory device has been developed. Nd-doped ZnO has been synthesized using wet chemical co-precipitation and incorporated in Polyvinylidene Difluoride (PVDF) polymer matrix along with Multiwalled Carbon Nanotubes (MWCNT) to produce flexible piezoelectric films. The piezoelectric output of the device is tested at variable tapping frequency (60 to 240 BPM) and pressure (10 to 40 psi). The device has also been tested with conventional electronics like bridge rectifiers, capacitors, …
Fabrication And Charcaterization Of Pullulan-Collagen Nanofibers Via Forcespinning, Valeria Leon Leal
Fabrication And Charcaterization Of Pullulan-Collagen Nanofibers Via Forcespinning, Valeria Leon Leal
Theses and Dissertations
Extensive research on collagen has spurred advancements in tissue engineering and biomaterial development, given collagen´s pivotal role in regulating various tissue structures across diverse organisms. This study delves into fabricating nanocomposites utilizing collagen, along with silver nanoparticles, chondroitin sulfate and pullulan, for potential applications in antibacterial medical devices, and cell regeneration. Collagen, abundant in the extracellular matrix, provides essential structural support, while silver nanoparticles and chondroitin confer antimicrobial properties, crucial for combating infections. Pullulan, a polysaccharide polymer, serves as a biocompatible carrier for silver nanoparticles whilst being the starting nanofiber forming material. Utilizing Forcespinning® technology, composite nanofibers were successfully synthesized. …
Validation, Optimization, And Experimentation Of Electro-Centrifugal Spinning, Carlos Alberto Delgado
Validation, Optimization, And Experimentation Of Electro-Centrifugal Spinning, Carlos Alberto Delgado
Theses and Dissertations
The aim of this study is to understand the behavior of polymeric solutions, when exposed to both electric fields and centrifugal forces through the electro-centrifugal fiber creation method, observing both effects of various parameter variations on the resulting nanofibers. The elemental deposition on electrospun fibers through in-situ processes is studied and optimized. The morphology, crystallinity, thermal properties, and elemental composition of the nanofibers were characterized. The purpose of these nanofibers is for future applications such as energy harvesting, filtration, and biomedical applications.
Attachment Of 2d Nanomaterials Onto 1d Nanofibers For Separation And Sensing Applications, Elmmer A. Vera Alvarado
Attachment Of 2d Nanomaterials Onto 1d Nanofibers For Separation And Sensing Applications, Elmmer A. Vera Alvarado
Theses and Dissertations
Advancing materials for water desalination and sensing is essential for tackling global issues related to clean water and efficient energy systems. This thesis explores the application of 2D nanomaterials, specifically graphene, integrated onto 1D poly(vinylidene fluoride) (PVDF) nanofibers to enhance their effectiveness in these areas. Utilizing innovative techniques such as Forcespinning® and plasma treatment, PVDF nanofibers were strengthened with graphene and conductive polymers like poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT: PSS). The research involved thorough assessments using direct contact membrane distillation (DCMD) systems, oil-water separation tests, and various mechanical and electromechanical evaluations. Heat-pressed membranes consistently delivered a flux of 0.33 kg/m²/hr and …
Enhancement Of Polytetrafluoroethylene-Polyvinyl Alcohol Nanofibers Triboelectric Effect With Carboxylic Functionalized Multiwalled Carbon Nanotubes Coating, Fernando Viesca
Theses and Dissertations
In this study, we fabricated a TENG using Forcespinning® (FS) Polytetrafluoroethylene microfibers (FS-PTFE-MFs) and Electrospun (ES) Polyvinyl alcohol nanofibers (ES-PVA-NFs). The FS-PTFE-MFs were physically linked with functionalized carboxylic multiwall carbon nanotubes (MWCNTs-COOH) employing water dispersions. MWCNTs-COOH were dispersed using three different surfactants: Sodium Dodecyl Sulfate (SDS), Sodium dodecylbenzenesulfonate (SDBS), and Triton X-100 (TX-100). Coated FS-PTFE-MFs were then characterized using a field emission scanning electron microscope (FESEM) with an energy dispersive X-ray spectroscopy (EDS) attachment and Fourier-transform infrared spectroscopy (FTIR). While no significant difference in performance was observed with different surfactants, electrical results of the TENG recorded a notable enhancement of …
Oral Administration Of Ph-Responsive Polymeric Nanoparticles Based On Zein And Their Therapeutic Potential On Cancer., Bruno Alejandro Valades-Aguilar, José Raúl Rangel-López, Jennifer Citlally Leos-Rivera, Moisés Armides Franco-Molina, María Cristina Rodríguez-Padilla, Diana Ginette Zárate-Triviño
Oral Administration Of Ph-Responsive Polymeric Nanoparticles Based On Zein And Their Therapeutic Potential On Cancer., Bruno Alejandro Valades-Aguilar, José Raúl Rangel-López, Jennifer Citlally Leos-Rivera, Moisés Armides Franco-Molina, María Cristina Rodríguez-Padilla, Diana Ginette Zárate-Triviño
Research Symposium
Background: Zein is a water-insoluble protein extracted from the endosperm of corn seeds, this polymer is an attractive matrix to encapsulate hydrophilic compounds because of its high proportion of hydrophobic amino acids, making it a potential smart delivery material for several treatments in the biopharmaceutical industry. nanoparticles have been used as drug delivery systems for the improvement of oral bioavailability; however, the strategies of nanoparticle obtention need the addition of stabilizers. in this study, a modified method to obtain zein nanoparticles was developed.
Methods: Zein nanoparticles (ZNps) were made by a thermal treatment and precipitated into ovalbumin at a ratio …
La1-Xsrxcoo3 Perovskite Nanomaterial: Synthesis, Characterization, And Its Biomedical Application, Adhira Tippur, Anyet Shohag, Luke Franco, Ahmed Touhami, Swati Mohan, Mohammed Uddin
La1-Xsrxcoo3 Perovskite Nanomaterial: Synthesis, Characterization, And Its Biomedical Application, Adhira Tippur, Anyet Shohag, Luke Franco, Ahmed Touhami, Swati Mohan, Mohammed Uddin
Research Symposium
Early cancer detection is paramount for effective treatment and potential cures. This research explores the application of perovskite materials, specifically Sr2+-doped Lanthanum Cobaltite (La1-xSrxCoO3) nanomaterials, in cancer detection, with a focus on rats as an experimental model. The ferroelectric nature of these materials, synthesized through a combination of sol-gel and molten-salt processes, was examined at varying Sr2+ doping levels (1-20 wt%). Rigorous characterization, employing X-ray diffraction and scanning electron microscopy, confirmed the uniform morphology of nano cubes, laying the foundation for subsequent investigations. The magnetic properties of the perovskite nanoparticles were probed, suggesting their potential as a diagnostic tool for …
Engineered Exosomes For The Multimodal Imaging Directed Photo-Immunotherapy Of Colorectal Cancer, Deepak S. Chauhan, Meena Jaggi, Subhash C. Chauhan, Murali M. Yallapu
Engineered Exosomes For The Multimodal Imaging Directed Photo-Immunotherapy Of Colorectal Cancer, Deepak S. Chauhan, Meena Jaggi, Subhash C. Chauhan, Murali M. Yallapu
Research Symposium
Background: Rio Grande Valley experience severe cancer health disparity. A novel therapeutic modality may serve as better therapeutic option. Nanohybrids endowed with multifunctionality, longer circulation time, large surface area have emerged as an active preference for cancer research. However, rising concern of nanomaterials toxicity and scalability issues has slowed their translation to clinics. Exosomes (Exo) are endogenous endocytic origin 40-100 nm vesicles found in various body fluids, which in comparison to synthetic nanoparticles, are biodegradable, highly biocompatible as well as immunocompatible in nature. Although bulk isolation of exosomes from human body fluids is still a problem and engineering of exosomes …
Biocidal Properties Of Hybrid Nanonanomaterial, Chandrasekaran Karthikeyan, Kokkarachedu Varaprasad
Biocidal Properties Of Hybrid Nanonanomaterial, Chandrasekaran Karthikeyan, Kokkarachedu Varaprasad
Research Symposium
Background: Cancer is one of the essential unpredictable diseases worldwide; simultaneously, complicated issues created are by the human health system. Especially, breast cancer is the most commonly occurring cancer in women and is increasing remarkably in developing countries. It is a leading cause of cancer death in women, and breast cancer incidence rates are growing globally. To diagnose and treat cancer cells, different methods such as Radiation Therapy, Surgery, and Chemotherapy. These methods are high risk, more side effects, and high costs. The advanced healthcare material was developed to overcome this problem, inexpensive tools, and diagnosis of less-toxic drugs with …
L(D)-Tyrosine-Mediated One-Step Chiral Graphene Production For Chirality-Dependent Sensing, Fnu Pranav, Ali Ashraf, Meena Jaggi, Subhash C. Chauhan, Murali M. Yallapu
L(D)-Tyrosine-Mediated One-Step Chiral Graphene Production For Chirality-Dependent Sensing, Fnu Pranav, Ali Ashraf, Meena Jaggi, Subhash C. Chauhan, Murali M. Yallapu
Research Symposium
Background: Chirality has been the most iconic phenomenon that occurred in nature. The idea of mirror-image asymmetry associated with the biological entity is still unsolved The emergence of 2D layered nanomaterials which have already shown amazing properties and a wide range of applications, especially in the areas of sensing.Amino acids enantiomers have similar physical and chemical properties however their physiological responses get changed based on the enantiomers. For example, L from amino acids helps body in protein formation, and generation of biological signals etc. whereas the D-form may cause toxic effects. We have developed a novel and facile synthesis method …
Two-Dimensional Nanomaterials And Nanocomposites For Sensing, Separation, And Energy Applications, Md Ashiqur Rahman
Two-Dimensional Nanomaterials And Nanocomposites For Sensing, Separation, And Energy Applications, Md Ashiqur Rahman
Theses and Dissertations
Two-dimension (2D) nanomaterials have gained popularity for the last few decades due to their excellent mechanical, electrical and thermal properties. These unique properties of 2D nanomaterials can be exploited in various applications specially in sensor, energy, and separation devices. In this study, the sensing and energy generation performance of PVDF/PAni fiber mat systems made by the forcespinning method with and without graphene coating. The graphene-coated nanocomposites show an average output voltage of 75 mV (peak-to-peak) which is 300% higher compared to bare fiber mats and an output current of 24 mA (peak-to-peak) by gentle finger pressing. Moreover, the graphene-coated PVDF/PAni …
Reducing Leakage Current And Enhancing Polarization In Multiferroic 3d Super-Nanocomposites By Microstructure Engineering, Erik Enriquez, Ping Lu, Leigang Li, Bruce Zhang, Haiyan Wang, Quanxi Jia, Aiping Chen
Reducing Leakage Current And Enhancing Polarization In Multiferroic 3d Super-Nanocomposites By Microstructure Engineering, Erik Enriquez, Ping Lu, Leigang Li, Bruce Zhang, Haiyan Wang, Quanxi Jia, Aiping Chen
Physics & Astronomy Faculty Publications
Multiferroic materials have generated great interest due to their potential as functional device materials. Nanocomposites have been increasingly used to design and generate new functionalities by pairing dissimilar ferroic materials, though the combination often introduces new complexity and challenges unforeseeable in single-phase counterparts. The recently developed approaches to fabricate 3D super-nanocomposites (3D‐sNC) open new avenues to control and enhance functional properties. In this work, we develop a new 3D‐sNC with CoFe2O4 (CFO) short nanopillar arrays embedded in BaTiO3 (BTO) film matrix via microstructure engineering by alternatively depositing BTO:CFO vertically-aligned nanocomposite layers and single-phase BTO layers. This microstructure engineering method allows …
Twisted Laminar Superconducting Composite: Mgb2 Embedded Carbon Nanotube Yarns, Ujjal Lamichhane, Gamage C. Dannangoda, Mkhitar Hobosyan, R. A. Shohan, A. Zakhidov, Karen S. Martirosyan
Twisted Laminar Superconducting Composite: Mgb2 Embedded Carbon Nanotube Yarns, Ujjal Lamichhane, Gamage C. Dannangoda, Mkhitar Hobosyan, R. A. Shohan, A. Zakhidov, Karen S. Martirosyan
Physics & Astronomy Faculty Publications
Twisted laminar superconducting composite structures based on multi-wall carbon nanotube (MWCNT) yarns were crafted by integrating magnesium and boron homogeneous mixture into the carbon nanotube (CNT) aerogel sheets. After the ignition of the Mg–B–MWCNT system, under the controlled argon environment, the high exothermic reaction between magnesium (Mg) and boron (B) with stoichiometric ratio produced the MgB2@MWCNT superconducting composite yarns. The process was conducted under the controlled argon environment and uniform heating rate in the differential scanning calorimetry and thermogravimetric analyzer. The XRD analysis confirmed that the produced composite yarns contain nano and microscale inclusions of superconducting phase of MgB2. The …
Modeling And Simulation Of Janus-Like Nanoparticles Formation By Solid-Gas Exothermic Reactions, A. A. Markov, Karen S. Martirosyan
Modeling And Simulation Of Janus-Like Nanoparticles Formation By Solid-Gas Exothermic Reactions, A. A. Markov, Karen S. Martirosyan
Physics & Astronomy Faculty Publications
Theoretical model for the simulation of synthesis of Janus-like particles (JP) consisting two different phases using the Carbon Combustion Synthesis of Oxides (CCSO) is presented. The model includes the variation of sample initial porosity, carbon concentration and oxygen flow rate used to predict the formation of JP features. The two temperature (2T) combustion model of chemically active submicron-dispersed mixture of two phases including ferroelectric and ferromagnetic was implemented and assessed by using the experimentally estimated activation energy of 112±3.3 kJ/mol and combustion temperature. The experimental values allowed to account the thermal and concentration expansion effect along with the dispersion by …
Exploration Of Antimicrobial And Cell Proliferation Properties Of Nanofibers Incorporating Nopal (O. Cochenillifera) Extract, Cristobal Rodriguez
Exploration Of Antimicrobial And Cell Proliferation Properties Of Nanofibers Incorporating Nopal (O. Cochenillifera) Extract, Cristobal Rodriguez
Theses and Dissertations
This study focused on the fabrication of Forcespinning® nanofibers composed of Opuntia cochenillifera, ‘nopal’, mucilage (N) extract, chitosan (CH), and pullulan (PL) (N/CH/PL) were developed with an optimum fiber average diameter of 406±127 nm, and studied for their ability to sustain adhesion and proliferation of mouse embryonic fibroblast (NIH 3T3) cells. After a 6-day incubation period, N/CH/PL nanofibers displayed robust cell proliferation, while also exhibiting inhibitory properties through an N extract dip-coating process against gram-negative bacteria Escherichia coli in a 24 h bacterial growth study. A demonstration of integrated natural bioactive compounds with combined biodegradable polymers, provide an enhanced …
Fabrication Of Forcespinning® Nanofibers Incorporating Nopal Extract, Cristobal Rodriguez, Victoria Padilla, Karen Lozano, J. Andrew Mcdonald, Luis Materon, Alejandra Chapa, Fariha Ahmad, Carlos Trevino De Leon, Robert Gilkerson
Fabrication Of Forcespinning® Nanofibers Incorporating Nopal Extract, Cristobal Rodriguez, Victoria Padilla, Karen Lozano, J. Andrew Mcdonald, Luis Materon, Alejandra Chapa, Fariha Ahmad, Carlos Trevino De Leon, Robert Gilkerson
School of Integrative Biological & Chemical Sciences (Formerly Dept. of Biology)
In this study, nanofibers composed of Opuntia cochenillifera nopal mucilage (N) extract combined with chitosan (CH) and pullulan (PL) (N/CH/PL) were produced via Forcespinning®. The developed nonwoven composite membranes are comprised of long, continuous, and homogenous fibers with fiber average diameter varying between 251±77 nm and 406±127 nm depending on the concentration of N. After crosslinking, the developed membranes were highly stable in water. The water absorption capacity of the N/CH/PL composite nanofiber membranes was shown to be 65% higher when compared to the CH/PL nanofiber membranes. Nopal dipcoated membranes show inhibition of gram-negative Escherichia coli, indicating antibacterial properties. These …
Piezo-Tribo Dual Effect Hybrid Nanogenerators For Health Monitoring, Sk Md Ali Zaker Shawon, Andrew Xu Sun, Valeria Suarez Vega, Brishty Deb Chowdhury, Phong Tran, Zaida D. Carballo, Jim Aica Tolentino, Jianzhi Li, Muhammad Sufian Rafaqut, Mohammed Jasim Uddin
Piezo-Tribo Dual Effect Hybrid Nanogenerators For Health Monitoring, Sk Md Ali Zaker Shawon, Andrew Xu Sun, Valeria Suarez Vega, Brishty Deb Chowdhury, Phong Tran, Zaida D. Carballo, Jim Aica Tolentino, Jianzhi Li, Muhammad Sufian Rafaqut, Mohammed Jasim Uddin
Electrical and Computer Engineering Faculty Publications
Over the years, nanogenerators for health monitoring have become more and more attractive as they provide a cost-effective and continuous way to successfully measure vital signs, physiological status, and environmental changes in/around a person. Using such sensors can positively affect the way healthcare workers diagnose and prevent life-threatening conditions. Recently, the dual piezo-tribological effect of hybrid nanogenerators (HBNGs) have become a subject of investigation, as they can provide a substantial amount of data, which is significant for healthcare. However, real-life exploitation of these HBNGs in health monitoring is still marginal. This review covers piezo-tribo dual-effect HBNGs that are used as …
Polymer Based Triboelectric Nanogenerator For Cost‐Effective Green Energy Generation And Implementation Of Surface‐Charge Engineering, Diana Lopez, Aminur Rashid Chowdhury, Abu Masa Abdullah, Muhtasim Ul Karim Sadaf, Isaac Martinez, Brishty Deb Chowdhury, Serena Danti, Christopher J. Ellison, Karen Lozano, Mohammed Jasim Uddin
Polymer Based Triboelectric Nanogenerator For Cost‐Effective Green Energy Generation And Implementation Of Surface‐Charge Engineering, Diana Lopez, Aminur Rashid Chowdhury, Abu Masa Abdullah, Muhtasim Ul Karim Sadaf, Isaac Martinez, Brishty Deb Chowdhury, Serena Danti, Christopher J. Ellison, Karen Lozano, Mohammed Jasim Uddin
School of Integrative Biological & Chemical Sciences (Formerly Dept. of Chemistry)
Performance of triboelectric nanogenerators for harvesting mechanical energy from the ambient environment has been limited by structural complexity, cost-effectiveness, and mechanical weakness of materials. Herein, a cost-effective vertical contact separation mode triboelectric nanogenerator using polyethylene (PE) and polycarbonate (PC) in a regular digital versatile disc is reported. This cost-effective nanogenerator with simplified structures is able to generate an open-circuit voltage of 215.3 V and short-circuit current of 80 μA. The effects of the distance of impact and the air gap between the triboelectric layers have also been tested from 3 to 9 cm, and 0.25 to 1 cm, respectively. It …
Editorial: Carbon- And Inorganic-Based Nanostructures For Energy Applications, Federico Cesano, M. Jasim Uddin, Yuanbing Mao, Muhammad N. Huda
Editorial: Carbon- And Inorganic-Based Nanostructures For Energy Applications, Federico Cesano, M. Jasim Uddin, Yuanbing Mao, Muhammad N. Huda
School of Integrative Biological & Chemical Sciences (Formerly Dept. of Chemistry)
No abstract provided.
Novel Silica Filled Deep Eutectic Solvent Based Nanofluids For Energy Transportation, Changhui Liu, Hui Fang, Xinjian Liu, Ben Xu, Zhonghao Rao
Novel Silica Filled Deep Eutectic Solvent Based Nanofluids For Energy Transportation, Changhui Liu, Hui Fang, Xinjian Liu, Ben Xu, Zhonghao Rao
School of Integrative Biological & Chemical Sciences (Formerly Dept. of Chemistry)
Liquid range of nanofluids is a crucial parameter as it intensively determines their application temperature scope. Meanwhile, improved thermal conductivity and stability are of great significances and comprise the main fundamental research topics of nanofluids. In this work, 2- butoxy-3,4-dihydropyran (DP), produced from a convenient one-pot three-component reaction in water, was employed as dual lipophilic brusher and metal nanoparticle anchor. It was found that DP was able to enhance the dispersing ability and thermal conductivity of SiO2 nanoparticle filled deep eutectic solvent (DES) based nanofluids simultaneously. The key to the success of this protocol mainly relies on the electrophilic property …
Novel Silica Filled Deep Eutectic Solvent Based Nanofluids For Energy Transportation, Changhui Liu, Hui Fang, Xinjian Liu, Ben Xu, Zhonghao Rao
Novel Silica Filled Deep Eutectic Solvent Based Nanofluids For Energy Transportation, Changhui Liu, Hui Fang, Xinjian Liu, Ben Xu, Zhonghao Rao
Mechanical Engineering Faculty Publications
Liquid range of nanofluids is a crucial parameter as it intensively determines their application temperature scope. Meanwhile, improved thermal conductivity and stability are of great significances and comprise the main fundamental research topics of nanofluids. In this work, 2-butoxy-3,4-dihydropyran (DP), produced from a convenient one-pot three-component reaction in water, was employed as dual lipophilic brusher and metal nanoparticle anchor. It was found that DP was able to enhance the dispersing ability and thermal conductivity of SiO2 nanoparticle filled deep eutectic solvent (DES) based nanofluids simultaneously. The key to the success of this protocol mainly relies on the electrophilic property and …