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Regulation Of Copper Surface Via Redox Reactions For Enhancing Carbon Dioxide Electroreduction, Bao-Hua Hang, Jin-Tao Zhang

Journal of Electrochemistry

A large-scale application of fossil fuels has led to excessive emission of carbon dioxide (CO₂), resulting in serious environmental issues. A promising path to reducing CO₂ emissions is recycling CO₂ into valuable chemicals and fuels through an electrochemical process. Herein, the redox reactions between copper (Cu) and ferric chloride (FeCl₃) have been utilized to regulate the Cu surface composition and structure, aimed to improve the electrocatalytic activity toward CO₂ reduction. Typically, a series of samples (named Cu-1h, Cu-2h, Cu-3h and Cu-4h) were prepared via the redox reactions for various time from 1 to …

Single-Layer Oxygen Deficiency Δ-Mno2 For Electrochemical Co2 Reduction, Yue-Feng Zhang, Jian-Jun Liu, Zeng-Xi Wei, Xin-Xin Tian, Jian-Min Ma

Journal of Electrochemistry

Manganese dioxide (MnO₂) has been widely used in catalysis. In addition, since the defect engineering can change the electronic properties of the catalyst, here we have systematically studied electrocatalytic carbon dioxide reduction reaction (CO₂RR) on δ-MnO₂ with and without oxygen deficiency, denoted as Ov-MnO₂ and MnO₂, respectively. We calculate the electronic properties and the intermediate of free energy for MnO₂ and Ov-MnO₂ with the help of spin-polarized density functional theory. By analyzing this result, we can find that the introduction of defects change the δ-MnO₂ from semiconducting properties to …

Statuses, Challenges And Strategies In The Development Of Low-Temperature Carbon Dioxide Electroreduction Technology, Xu-Rui Zhang, Xiao-Lin Shao, Jin Yi, Yu-Yu Liu, Jiu-Jun Zhang

Journal of Electrochemistry

Low-temperature carbon dioxide (CO₂) electrochemical reduction technology is a hotspot for research and development in recent years as a way to reduce the negative impact of CO₂ on the environment and to generate energy storage through converting electricity to low-carbon fuels. Although basic research on catalyst activity, product selectivity, and reaction mechanism has been widely reported, the design and practicality of catalytic stability and corresponding electrochemical reactor systems have not been given sufficient attention and systematic development.  In this paper, two important factors affecting the development of CO₂ electrochemical reduction technology in low temperature aqueous solution …

Copper-Based Compounds For Electrochemical Reduction Of Carbon Dioxide, Fan Yang, Pei-Lin Deng, You-Jia Han, Pan Jing, Bao-Yu Xia

Journal of Electrochemistry

The electrochemical reduction of carbon dioxide (CO₂) to useful chemicals and fuels has attracted enormous interest since the deteriorating global warming and energy shortage problems resulted from ever-increasing CO₂ emission. Designing efficient catalysts is of capital significance to realize the efficient and selective conversion of CO₂. Among various catalysts explored, copper-based compounds have promising potentials with acceptable efficiency for hydrocarbon production. Herein, recent advances on copper-based materials are summarized for electrochemical CO₂ conversion. We intend to include the dimensional structure, different forms (alloy, oxide) and molecular catalysts in copper-based catalysts. Moreover, the reaction mechanisms …

Recent Advances In Bismuth-Based Co2 Reduction Electrocatalysts, Rui Zhou, Na Han, Yan-Guang Li

Journal of Electrochemistry

Carbon dioxide (CO₂) is an economical, secure and sustainable carbon resource around us. Its effective capture and recycling have been the focus of our entire society. Using the electrochemical method, CO₂ can be reduced to different value-added chemicals or fuels. This approach not only would mitigate CO₂ accumulation in the atmosphere, but also would help alleviate our dependence on fossil fuel. In this article, the basic principle and process of electrochemical CO₂ reduction are first introduced. The recent development in bismuth-based catalysts for electrocatalytic CO₂ reduction is reviewed with an emphasis on their preparation, …

Electrocatalytic Reduction Of Carbon Dioxide To Carbon Monoxide Using Cobalt Nitride, Chen Ma, Peng-Fei Hou, Peng Kang

Journal of Electrochemistry

Electrocatalytic reduction of carbon dioxide (CO₂) is a promising method to alleviate global warming issues, although it still faces many challenges. Herein, we report cobalt nitride for electrocatalytic reduction of CO₂ to carbon monoxide (CO) in an aqueous electrolyte. A comparison of catalysts with different preparation temperatures and atmospheres suggests that nitrogen doping is critical to improve catalytic activity. For the most active catalyst of 700-Co_5.47N/C, the CO current density reached 9.78 mA·cm^-2 at potential of -0.7 V vs. RHE. In addition, the CO/H₂ ratio could be adjusted from 1:3 to 3:2 by …

Effect Of Morphology Of Fe-N Codoped Carbon Nanomaterial On Electrochemical Reduction Reactions, Er-Ling Li, Fa Yang, Ming-Bo Ruan, Ping Song, Wei-Lin Xu

Journal of Electrochemistry

Graphene nanosheets (GS) and carbon nanotubes have been considered as good catalysts candidates for applications in energy conversion and storage. However, hybrids of GS and carbon nanotubes are always formed in transition metal-based nitrogen-doped system, making the system quite complex for exploring the structure-activity relationship. To prepare the catalysts with desired species controllably, we try to adjust the outcomes with the effect of nitrogen on the growth of carbon nanotubes. In this work, a series of Fe-N co-doped carbon hybrid catalysts containing N-doped GS or hybrids of GS/bamboo carbon nanotubes (BCNTs) or BCNTs were obtained with one-step pyrolyzed method. To …

Electrochemical Detection Of 4-Nitrophenol Based On Glassy Carbon Electrode Modified By Tio2Nps/Rgo Composite, Lin-Na Jiu, Yong-Qiang Cheng

Journal of Electrochemistry

4-nitrophenol (4-NP) has become factitious pollution, and presented a serious threat to the nature and human health. It is necessary to develop a convenient and fast detection method. In this work, the glassy carbon electrode modified by titanium dioxide nanoparticles (TiO₂NPs)/reduced graphene oxide (RGO) composite as an electrochemical sensor was studied for the trace detection of 4-NP. The morphology of the composite was characterized by scanning electron microscopy (SEM). The homogeneous mixing of titanium dioxide nanoparticles and reduced graphene oxide increased the specific surface area of the composite, and facilitated the electrochemical reaction of 4-NP. The electrochemical characteristics …

Preparations And Electrocatalytic Properties Of Cu-Bipy-Btc-Derived Carbon-Based Catalyst For Oxygen Reduction Reaction, Li-Hua Zhang, Jun-Feng Chen, Wan-Tang Huang, Yong-You Hu, Jian-Hua Cheng, Yuan-Cai Chen

Journal of Electrochemistry

Efficient and low-cost oxygen reduction reaction (ORR) electrocatalyst plays a key role for fuel cells. In this paper, ORR active metal organic framework (MOF: Cu-bipy-BTC, bipy = 2,2?-bipyridine, BTC = 1,3,5-tricarboxylate) was prepared using hydrothermal method, and then carbon-based material MOF-800 was obtained from pyrolyzing Cu-bipy-BTC at 800 °C. Scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), nitrogen sorption isotherm and X-ray photolectron spectroscopy (XPS) were used to characterize the morphologies and structures of the catalysts. Linear sweep voltammetry (LSV) and current-time curve (i-t) were adopted to evaluate the electrocatalytic properties of the catalysts. The results …

Understanding Of The Ship Design Energy Efficiency And Its Implications In Practice, Haichao Yuan

Maritime Safety & Environment Management Dissertations (Dalian)

No abstract provided.

Machine Learning In Support Of Electric Distribution Asset Failure Prediction, Robert D. Flamenbaum, Thomas Pompo, Christopher Havenstein, Jade Thiemsuwan

SMU Data Science Review

In this paper, we present novel approaches to predicting as- set failure in the electric distribution system. Failures in overhead power lines and their associated equipment in particular, pose significant finan- cial and environmental threats to electric utilities. Electric device failure furthermore poses a burden on customers and can pose serious risk to life and livelihood. Working with asset data acquired from an electric utility in Southern California, and incorporating environmental and geospatial data from around the region, we applied a Random Forest methodology to predict which overhead distribution lines are most vulnerable to fail- ure. Our results provide evidence …

Visualizing United States Energy Production Data, Bruce P. Kimbark, Melissa Luzardo, Charles South, James Taber

SMU Data Science Review

Power plants production, load, financials and environmental impact from power plants in the United States is publicly available either from the Energy Information Administration, the Environmental Protection Agency or Lazard among others. The general public is interested in US energy production and its potential environmental impact but the available information is complex and difficult to properly understand and not shared in ways that are accessible. Our objective was to gather this data and create different interactive visualizations that make it consumable. Each of the five visualization was designed to explain a specific part of energy that together can provide a …

Design, Development And Implementation Of An Electrical Controller For A Solar-Electrical Collector, Sahar Mahboob, Razieh Pourdarbani, Bahman Behfar, Hossein Behfar

Emirates Journal for Engineering Research

Todays, maintaining atmospheric health is one of the most important prerequisites for sustainable global economic development, and the international community has no choice but to switch to renewable energies, including solar energy. The goal of the study was to provide a temperature of 60 ° C for drying summer fruits such as apricots therefore we investigated the effect of temperature control systems on the solar-electrical collector performance. Three LM35 temperature sensors were placed at 3 points of the collector (before the air inlet to the collector, after the air outlet from the collector and after heating elements) that were linked …

Design And Analysis Of Modular Axial Flux Switched Reluctance Motor, Rochak Shiwakoti

LSU New Orleans Theses and Dissertations

This thesis presents a new modular structure of the axial flux Switched Reluctance Motor (SRM). The design consists of four stator disks with each adjacent disk rotated 30 degrees apart and four rotor disks connected to a common shaft. The proposed design aims to reduce the unwanted radial force, mitigate the torque ripple, and improve the efficiency. The modular structure distributes the radial force and torque strokes along the axial length of the motor, potentially damping the torque pulsation. In addition, the modular structure would deliver the rating power at a lower current level, reducing the overall ohmic loss. Moreover, …

Modeling And Simulation Of A Utility-Scale Battery Energy Storage System, Oluwaseun M. Akeyo, Vandana Rallabandi, Nicholas Jewell, Dan M. Ionel

Power and Energy Institute of Kentucky Faculty Publications

This paper presents the modeling and simulation study of a utility-scale MW level Li-ion based battery energy storage system (BESS). A runtime equivalent circuit model, including the terminal voltage variation as a function of the state of charge and current, connected to a bidirectional power conversion system (PCS), was developed based on measurements from an operational utility-scale battery demonstrator. The accelerated response of the battery unit was verified by pulse discharging it from maximum to minimum SOC and its application for grid resiliency was demonstrated through an example droop control frequency response. For the purpose of validating the equivalent BESS …

Load Variation Reduction By Aggregation In A Community Of Rooftop Pv Residences, Huangjie Gong, Vandana Rallabandi, Dan M. Ionel

Power and Energy Institute of Kentucky Faculty Publications

This paper performs computational studies and develops control schemes for a virtual power plant (VPP) network formed by a community of homes with rooftop solar PV generation, and battery energy storage. Appropriate control and scheduling of the battery operations, and peer-peer power flow between the homes provide a possible solutions for reducing the higher costs and uncertainties brought to grid by high solar PV penetration. The residential community studied here includes twelve homes categorized into four types depending on whether they have energy storage or rooftop solar PV panels. The homes exchange power among themselves, and the real-time electricity rate …

Smart Charging Of Future Electric Vehicles Using Roadway Infrastructure, Sara Ahmed, Ethan Ahn, Mahmoud Reda Taha, Samer Dessouky, Moneeb Genedy, Daniel Fernandez, Ann Sebestian, Patience Raby

Data

Corresponding data set for Tran-SET Project No. 18ITSTSA03. Abstract of the final report is stated below for reference:

"Inspired by the fact that there is an immense amount of renewable energy sources available on the roadways such as mechanical pressure and frictional heat, this study presented the development and implementation of an innovative charging technique for future electric vehicles (EVs) by fully utilizing the existing roadways and the state-of-the-art nanotechnology and power electronics. The project introduced a novel wireless charging system, SIC (Smart Illuminative Charging), that uses LEDs powered by piezoelectric nanomaterials as the energy transmitter source and thin film …

Smart Charging Of Future Electric Vehicles Using Roadway Infrastructure, Sara Ahmed, Ethan Ahn, Mahmoud Reda Taha, Samer Dessouky, Moneeb Genedy, Daniel Fernandez, Ann Sebestian, Patience Raby

Publications

Inspired by the fact that there is an immense amount of renewable energy sources available on the roadways such as mechanical pressure and frictional heat, this study presented the development and implementation of an innovative charging technique for future electric vehicles (EVs) by fully utilizing the existing roadways and the state-of-the-art nanotechnology and power electronics. The project introduced a novel wireless charging system, SIC (Smart Illuminative Charging), that uses LEDs powered by piezoelectric nanomaterials as the energy transmitter source and thin film solar panels placed at the bottom of the EVs as the receiver, which is then poised to deliver …

Backstepping Control And Transformation Of Multi-Input Multi-Output Affine Nonlinear Systems Into A Strict Feedback Form, Khalid Salim D. Alharbi

Graduate Theses and Dissertations

This dissertation presents an improved method for controlling multi-input multi-output affine nonlinear systems. A method based on Lie derivatives of the system's outputs is proposed to transform the system into an equivalent strict feedback form. This enables using backstepping control approaches based on Lyapunov stability and integrator backstepping theory to be applied. The geometrical coordinate transformation of multi-input multi-output affine nonlinear systems into strict feedback form has not been detailed in previous publications. In this research, a new approach is presented that extends the transformation process of single-input single-output nonlinear. A general algorithm of the transformation process is formulated. The …

Five-Level Flying Capacitor Converter Used As A Static Compensator For Current Unbalances In Three-Phase Distribution Systems, Rafael Franceschi

Graduate Theses and Dissertations

This thesis presents and evaluates a solution for unbalanced current loading in three-phase distribution systems. The proposed solution uses the flying capacitor multilevel converter as its main topology for an application known as Unbalanced Current Static Compensator. The fundamental theory, controller design and prototype construction will be presented along with the experimental results. The Unbalanced Current Static Compensator main objective is the balancing of the up-stream currents from the installation point to eliminate the negative- and zero-sequence currents originated by unbalanced single-phase loads.

Three separate single-phase flying capacitor converters are controlled independently using a d-q rotating reference frame algorithm to …