A Safety Analysis On The Potential Risks Onboard Ships That Would Use Ammonia As Marine Fuel,
2022
World Maritime University
A Safety Analysis On The Potential Risks Onboard Ships That Would Use Ammonia As Marine Fuel, Praveen Raghavan Nair
World Maritime University Dissertations
No abstract provided.
Electrochemical Syntheses Of Nanomaterials And Small Molecules For Electrolytic Hydrogen Production,
2022
School of Materials Science and Engineering, Nanyang Technological University,50 Nanyang Avenue, Singapore, 639798, Singapore;
Electrochemical Syntheses Of Nanomaterials And Small Molecules For Electrolytic Hydrogen Production, Jia-Qi Wei, Xiao-Dong Chen, Shu-Zhou Li
Journal of Electrochemistry
Hydrogen is a clean, efficient, renewable energy resource and the most promising alternative to fossil fuels for future carbon-neutral energy supply. Therefore, sustainable hydrogen production is highly attractive and urgently demanded, especially via water electrolysis that has clean, abundant precursors and zero emission. However, current water electrolysis is hindered by the sluggish kinetics and low cost/energy efficiency of both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). In this regard, electrochemical synthesis offers prospects to raise the efficiency and benefit of water electrolysis by fabricating advanced electrocatalysts and providing more efficient/value-adding co-electrolysis alternatives. It is an eco-friendly and facile …
Alkaline Seawater Electrolysis At Industrial Level:Recent Progress And Perspective,
2022
1. School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link,Singapore 637371, Singapore;
Alkaline Seawater Electrolysis At Industrial Level:Recent Progress And Perspective, Tao Zhang, Yi-Pu Liu, Qi-Tong Ye, Hong-Jin Fan
Journal of Electrochemistry
Industrial hydrogen generation through water splitting, powered by renewable energy such as solar, wind and marine, paves a potential way for energy and environment sustainability. However, state-of-the-art electrolysis using high purity water as hydrogen source at an industrial level would bring about crisis of freshwater resource. Seawater splitting provides a practical path to solve potable water shortage, but still faces great challenges for large-scale industrial operation. Here we summarize recent developments in seawater splitting, covering general mechanisms, design criteria for electrodes, and industrial electrolyzer for direct seawater splitting. Multi-objective optimization methods to address the key challenges of active sites, reaction …
A Self-Supported Ru-Cu3P Catalyst Toward Alkaline Hydrogen Evolution,
2022
New Energy Research Institute, School of Environment and Energy, South China University of Technology, Higher Education Mega Center, Guangzhou 510006, Guangdong, China;
A Self-Supported Ru-Cu3P Catalyst Toward Alkaline Hydrogen Evolution, Zi-Xuan Wan, Chao-Hui Wang, Xiong-Wu Kang
Journal of Electrochemistry
Transition metal phosphide (TMP) is a kind of effective catalysts toward hydrogen evolution reaction (HER) in alkaline electrolytes. However, the performance of TMP catalysts is strongly limited by water splitting. In this work, we developed a method to prepare a copper foam (CF) supported Ru-doped Cu3P catalyst (Ru-Cu3P/CF) by a consecutive growth of Cu(OH)2 nanoarrays, soaking in RuCl3 solution and phosphorization. A large surface area was obtained by the self-supported catalysts with the appropriative Ru doping. As an excellent HER catalyst, it exhibited a low overpotential of 95.6 mV at a current density of …
Catalytic Effect Of Disordered Ru-O Configurations For Electrochemical Hydrogen Evolution,
2022
1. MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, Harbin Institute of Technology, Harbin, 150001, China;2. Chongqing Research Institute of HIT, Chongqing 401135, P. R. China;
Catalytic Effect Of Disordered Ru-O Configurations For Electrochemical Hydrogen Evolution, Xue Sun, Ya-Jie Song, Ren-Long Li, Jia-Jun Wang
Journal of Electrochemistry
Phase engineering is considered as an effective method for modulating the electronic structure and catalytic activity of catalysts. The disordered conformation of amorphous materials allows flexible reforming of the surface electronic structure, showing their attractiveness as catalysts for hydrogen evolution reaction (HER). Herein, we designed and developed an amorphous ruthenium dioxide (a-RuO2) catalyst with a disordered Ru-O configuration. The conformational relationship between Ru-O ordering and HER performance is established by combining advanced electron microscopic techniques with detailed electrochemical tests. Specifically, the disordered Ru-O coordination significantly enhanced the HER catalytic activity in both acidic and alkaline media, ultimately leading …
Alkaline Water Electrolysis For Efficient Hydrogen Production,
2022
State Key Laboratory of Chemical Resource Engineering, College of Chemistry,Beijing University of Chemical Technology, Beijing 100029, China;
Alkaline Water Electrolysis For Efficient Hydrogen Production, Wen-Fu Xie, Ming-Fei Shao
Journal of Electrochemistry
Hydrogen production from water electrolysis is a sustainable and environmentally benign strategy in comparison with fossil fuel-based hydrogen. However, this promising technique suffers from the high energy consumption and unsatisfactory cost due to the sluggish kinetics of both half reaction and inferior stability of electrocatalysts. To address this challenge, herein, we present a timely and comprehensive review on advances in alkaline water electrolysis that is already commercialized for large scale hydrogen production. The design principles and strategies with aiming to promote the performance of hydrogen generation are discussed from the view of electrocatalyst, electrode, reaction and system. The challenges and …
Agglomerative Hierarchical Clustering With Dynamic Time Warping For Household Load Curve Clustering,
2022
Western University
Agglomerative Hierarchical Clustering With Dynamic Time Warping For Household Load Curve Clustering, Fadi Almahamid, Katarina Grolinger
Electrical and Computer Engineering Publications
Energy companies often implement various demand response (DR) programs to better match electricity demand and supply by offering the consumers incentives to reduce their demand during critical periods. Classifying clients according to their consumption patterns enables targeting specific groups of consumers for DR. Traditional clustering algorithms use standard distance measurement to find the distance between two points. The results produced by clustering algorithms such as K-means, K-medoids, and Gaussian Mixture Models depend on the clustering parameters or initial clusters. In contrast, our methodology uses a shape-based approach that combines Agglomerative Hierarchical Clustering (AHC) with Dynamic Time Warping (DTW) to classify …
Digital Twin For Hvac Load And Energy Storage Based On A Hybrid Ml Model With Cta-2045 Controls Capability,
2022
University of Kentucky
Digital Twin For Hvac Load And Energy Storage Based On A Hybrid Ml Model With Cta-2045 Controls Capability, Rosemary E. Alden, Evan S. Jones, Huangjie Gong, Abdullah Al Hadi, Dan Ionel
Power and Energy Institute of Kentucky Faculty Publications
Building modeling, specifically heating, ventilation, and air conditioning (HVAC) load and equivalent energy storage calculations, represent a key focus for decarbonization of buildings and smart grid controls. Widely used white box models, due to their complexity, are too computationally intensive to be employed in high resolution distributed energy resources (DER) platforms without simulation time delays. In this paper, an ultra-fast one-minute resolution Hybrid Machine Learning Model (HMLM) is proposed as part of a novel procedure to replicate white box models as an alternative to widespread experimental big data collection. Synthetic output data from experimentally calibrated EnergyPlus models for three existing …
Study Of Stochastic Market Clearing Problems In Power Systems With High Renewable Integration,
2022
Southern Methodist University
Study Of Stochastic Market Clearing Problems In Power Systems With High Renewable Integration, Saumya Sakitha Sashrika Ariyarathne
Operations Research and Engineering Management Theses and Dissertations
Integrating large-scale renewable energy resources into the power grid poses several operational and economic problems due to their inherently stochastic nature. The lack of predictability of renewable outputs deteriorates the power grid’s reliability. The power system operators have recognized this need to account for uncertainty in making operational decisions and forming electricity pricing. In this regard, this dissertation studies three aspects that aid large-scale renewable integration into power systems. 1. We develop a nonparametric change point-based statistical model to generate scenarios that accurately capture the renewable generation stochastic processes; 2. We design new pricing mechanisms derived from alternative stochastic programming …
Preface To Special Issue On Water Electrolysis For Hydrogen Production,
2022
1. School of Chemistry and Chemical Engineering, Chongqing University, Chongqing, 400044;
Preface To Special Issue On Water Electrolysis For Hydrogen Production, Li Li, Jin-Song Hu, Zi-Dong Wei
Journal of Electrochemistry
No abstract provided.
Recent Development Of Low Iridium Electrocatalysts Toward Efficient Water Oxidation,
2022
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry,Jilin University, Changchun 130012, P. R. China;
Recent Development Of Low Iridium Electrocatalysts Toward Efficient Water Oxidation, Jing Ni, Zhao-Ping Shi, Xian Wang, Yi-Bo Wang, Hong-Xiang Wu, Chang-Peng Liu, Jun-Jie Ge, Wei Xing
Journal of Electrochemistry
Developing high-performance and low-cost electrocatalysts for oxygen evolution reaction (OER) is the key to implementing polymer electrolyte membrane water electrolyzer (PEMWE) for hydrogen production. To date, iridium (Ir) is the state-of-the-art OER catalyst, but still suffers from the insufficient activity and scarce earth abundance, which results in high cost both in stack and electricity. Design low-Ir catalysts with enhanced activity and stability that can match the requirements of high current and long-term operation in PEMWE is thus highly desired, which necessitate a deep understanding of acidic OER mechanisms, unique insights of material design strategies, and reliable performance evaluation norm, especially …
The Rapid Preparation Of Efficient Mofeco-Based Bifunctional Electrocatalysts Via Joule Heating For Overall Water Splitting,
2022
1. Fuel Cell System and Engineering Laboratory, Key Laboratory of Fuel Cells & Hybrid Power Sources, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;2. University of Chinese Academy of Sciences, Beijing, 100049, China;
The Rapid Preparation Of Efficient Mofeco-Based Bifunctional Electrocatalysts Via Joule Heating For Overall Water Splitting, Ao Zhou, Wei-Jian Guo, Yue-Qing Wang, Jin-Tao Zhang
Journal of Electrochemistry
Water electrolysis is an available way to obtain green hydrogen. The development of highly efficient electrocatalysts is a current research hotspot for water splitting, but it remains challenging. Herein, we demonstrate the synthesis of a robust bifunctional multi-metal electrocatalysts toward water splitting via the rapid Joule-heating conversion of metal precursors. The composition and morphology were well regulated via altering the ratio of metal precursors. In particular, the trimetal MoC/FeO/CoO/carbon cloth (CC) electrode revealed the outstanding bifunctional electrocatalytic performance due to the unique composition and large electrochemical active surface area. Typically, the MoC/FeO/CoO/CC catalyst needed low overpotentials of 121 and 268 …
Perovskite-Type Water Oxidation Electrocatalysts,
2022
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry,Jilin University, Changchun 130012, P. R. China;
Perovskite-Type Water Oxidation Electrocatalysts, Xiao Liang, Ke-Xin Zhang, Yu-Cheng Shen, Ke Sun, Lei Shi, Hui Chen, Ke-Yan Zheng, Xiao-Xin Zou
Journal of Electrochemistry
The development of energy conversion/storage technologies can achieve the reliable and stable renewable energy supply, and bring us a sustainable future. As the core half-reaction of many energy-related systems, water oxidation is the bottleneck due to its sluggish kinetics of the four-concerted proton-electron transfer (CPET) process. This necessitates the exploitation of low cost, highly active and stable water oxidation electrocatalysts. Perovskite-type oxides possess diverse crystal structures, flexible compositions and unique electronic properties, enabling them ideal material platform for the optimization of catalytic performance. In this review, we provide a comprehensive summary for the crystal structures, electronic structures and synthetic methods …
Surface Structure Engineering Of Feni-Based Pre-Catalyst For Oxygen Evolution Reaction: A Mini Review,
2022
1. State Key Laboratory of Electroanalytic Chemistry, Jilin Province Key Laboratory of Low Carbon Chemistry Power, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences,Changchun 130022, China;2. School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei 230026, China;
Surface Structure Engineering Of Feni-Based Pre-Catalyst For Oxygen Evolution Reaction: A Mini Review, Jia-Xin Li, Li-Gang Feng
Journal of Electrochemistry
Nitrite, a widespread raw material, is harmful to human health for long-term consumption. At present, the detection methods of nitrite mainly include chemical analysis, fluorescence, ultraviolet spectrophotometry and chromatography. These methods have ideal sensitivity and selectivity, but also have some characteristics: cumbersome operation, expensive equipment and professional personnel. Therefore, the development of a simple and sensitive nitrite assay is of great significance. In this paper, the Au/rGO/FeOOH composite materials, which revealed good synergistic catalytic performance among the three elements in the composite, were prepared by simple hydrothermal method and reduction method for the first time with large specific surface area …
A Co Porphyrin With Electron-Withdrawing And Hydrophilic Substituents For Improved Electrocatalytic Oxygen Reduction,
2022
Key Laboratory for Colloid and Interface Chemistry Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, Shandong, China;
A Co Porphyrin With Electron-Withdrawing And Hydrophilic Substituents For Improved Electrocatalytic Oxygen Reduction, Hong-Bo Guo, Ya-Ni Wang, Kai Guo, Hai-Tao Lei, Zuo-Zhong Liang, Xue-Peng Zhang, Rui Cao
Journal of Electrochemistry
Understanding factors that influence the catalyst activity for oxygen reduction reaction (ORR) is essential for the rational design of efficient ORR catalysts. Regulating catalyst electronic structure is commonly used to fine-tune electrocatalytic ORR activity. However, modifying the hydrophilicity of catalysts has been rarely reported to improve ORR, which happens at the liquid/gas/solid interface. Herein, we report on two Co porphyrins, namely, NO2-CoP (Co complex of 5,10,15,20-tetrakis(4-nitrophenyl)porphyrin) and 5F-CoP (Co complex of 5,10,15,20-tetrakis(pentafluorophenyl)porphyrin), and their electrocatalytic ORR features. By simultaneously controlling the electronic structure and hydrophilic property of the meso-substituents, the NO2-CoP showed higher electrocatalytic activity than …
Identifying Opportunities And Priorities For Energy Extension,
2022
University of Maryland
Identifying Opportunities And Priorities For Energy Extension, Drew F. Schiavone
Journal of Extension
An online survey was administered to all educators and specialists within the University of Maryland Extension to assess client-driven opportunities and priorities for energy-related programming, while in-service training evaluations were used to further assess programmatic needs. Results indicate the need for information related to energy conservation and clean energy technology for agricultural and residential clientele. Primary barriers were perceived as the insufficient understanding and high costs associated with clean energy, while experiential participation and firsthand observation were reported as preferred learning methods. These results provide an understanding of how energy-related programming can expand the role and relevancy of Extension.
Developing Positive Thermal Coefficient (Ptc) Heaters For Solar Electric Cooking,
2022
California Polytechnic State University, San Luis Obispo
Developing Positive Thermal Coefficient (Ptc) Heaters For Solar Electric Cooking, Katarina Ivana Brekalo, Andrew Shepherd
Physics
Positive Thermal Coefficients, PTCs, are materials that abruptly change in resistance in response to changes in temperature. The purpose of this experiment is to explore the viability of using the switching type ceramic PTC thermistor as a replacement for current resistive heaters. These types of PTCs have a nonlinear change in resistance with increases in temperature. This device will be used as a temperature-controlling heating element intended to power an Insulated Solar Electric Cooker (ISEC). The ISEC is designed to cook meals throughout the day for impacted communities as an alternative cooking method that doesn’t require biofuel as an energy …
How Will Heat Pumps Affect Electricity Load Profiles For Buildings In Ireland? Empirical Data Used To Model Possible Financial Impacts Facing Consumers,
2022
Technological University Dublin
How Will Heat Pumps Affect Electricity Load Profiles For Buildings In Ireland? Empirical Data Used To Model Possible Financial Impacts Facing Consumers, Michael Mcdonald
Conference papers
The current geopolitical situation is certainly challenging the colossal transition to Zero carbon Economy. In fact, in the coming years, the electricity sector will have to find new innovative ways to meet the ever increasing need for energy without the over reliance on fossil fuels and their country of origin. Over the next decade, oil and gas boilers will not be permitted in new buildings in Ireland, in line with the Irish Building Regulations, Technical Guidance Document L – Conservation of Fuel and Energy 2021. This is a major shift in traditional building services methodology and heat technology. …
Products Pricing And Return Strategies For The Dual Channel Retailers,
2022
Missouri University of Science and Technology
Products Pricing And Return Strategies For The Dual Channel Retailers, Jian Liu, Xinyue Sun, Yanyan Liu
Electrical and Computer Engineering Faculty Research & Creative Works
This paper analyzed how different return strategies and return rates affect dual-channel retailers' profits and channel pricings. Return can stimulate sales; however, the return has presented significant challenges to retailers. The return has long been studied to maximize profit and pricing; however, the different return strategies for dual-channel retailers affect channel both. This paper aimed to study whether or not dual-channel retailers should allow customers to return items in two channels and whether or not the retailer should contract with the manufacturers and pay extra fees to return products. This study indicated when the retailer should allow customers' returns to …
Quantitative Lithium Composite As 3d Lithium Foam Anode For Lithium Metal Battery,
2022
Key Laboratory of General Chemistry of the National Ethnic Affairs Commission, School of Chemistry and Environment, Southwest Minzu University, Chengdu 610225, China;
Quantitative Lithium Composite As 3d Lithium Foam Anode For Lithium Metal Battery, Hu-Dong Li, Wei-Shang Jia, Xin-Xiu Yan, Yao-Yue Yang
Journal of Electrochemistry
Lithium (Li) metal as an anode material for batteries has extremely high specific capacity and extremely low redox potential, which can significantly improve the energy density of the battery. However, the main problems faced by the use of Li metal anodes are Li dendrite growth, interfacial side reaction and volumetric change of electrode. Herein, a strategy to prepare the three-dimensional (3D) Li foam by combining 3D scaffold with quantitative Li was proposed to suppress Li dendrites growth and alleviate electrode volumetric change. The 3D Li foam facilitated the efficient utilization of Li metal by suppressing the Li dendrite growth, mitigating …
