Power and Energy Commons^™

The Problem Of The Anode Electrolyte In H-Type Electrolytic Cell For Electrochemical Reduction Of Carbon Dioxide, Rui Zhang, Wei-Xin Lv, Li-Xu Lei

Journal of Electrochemistry

Electrochemical reduction of carbon dioxide (CO₂) was studied in the H-type electrolytic cell. It was found that the voltage between the cathode and the anode would increase during the long time electrolysis process, for this reason the electrolytic process would be unsustainable. After the experimental investigations carried out by constant potential electrolysis, constant current electrolysis, pH test and KHCO₃ concentration analysis of anode electrolyte before and after the electrolysis, the increase in cell voltage might be caused by the following process: H⁺, that was generated from the anodic oxygen evolution reaction, reacted with HCO_{3 …}

Effects Of Flame Retardant On The Rate Capability And Safety Performances Of The Soft-Package 5ah Lithium Ion Battery, Yan-Zhuo Lv, Xiao-He Wang, Yi-Ming Qin, Zhen-Bo Wang, Ke Ke

Journal of Electrochemistry

The 5 Ah soft packed lithium ion batteries with LiNi _0.4Co_0.2Mn_0.4 O₂ as the positive electrode material and the organic electrolytes with different amounts of fire retardants as the electrolyte solution were prepared. The effects of the fire retardant amount (5 %,10 %,20 %) of the fire retardants on the rate performances, short-circuit characteristics and overcharged behaviors of the 5 Ah soft packed lithium ion battery were investigated by electrochemical methods. The results indicated that the best rate performances were obtained by adding 5 vol.% of the fire retardants in the electrolyte solution when the …

Application Of Composite Ionic Liquid In Electro-Oxidation Activation Of A C-H Bond, Zi-Ying Chen, Qian-Qian Wu, Jian-Qing Zhang, Ying-Hong Zhu, Chun-An Ma

Journal of Electrochemistry

In this paper, the ionic liquid/carbon nanotube composite material was prepared through modifying the ionic liquid 1-ethyl-3-methylimidazolium acetate to multi-walled carbon nanotubes. The electro-oxidation properties of p-methoxy toluene (p-MT) were studied using the composite as an electrolyte. The effects of scanning speed, temperature and substrate concentration were studied by cyclic voltammetry and chronoamperometry. The electrochemical kinetics of p-MT in this system was also studied. The results showed that the electrochemical oxidation of p-MT in the composite electrolyte solution was irreversible. The process was mainly controlled by diffusion, and the diffusion coefficient (D) was 7.69×10-10 cm²·s^-1. Increasing …

Electrochemical Nucleation Of Invar Alloy On Glassy Carbon Electrode, Xian-Jie Huang, Hui Yan, Shuai-Shuai Huang, Fang-Zu Yang, Zhong-Qun Tian, Shao-Min Zhou

Journal of Electrochemistry

The linear sweep voltammetry, cyclic voltammetry and potential step methods were used to study the electrodeposition mechanism of Invar nickel-iron alloy (the mass fraction of nickel was 32~36%) on glassy carbon electrode surface in the weak acidic bath. The results demonstrate that the electrodeposition is was a diffusion controlled irreversible electrode process in this system. The Scharifker-Hill (SH) theory theoritic model (SH) were was used employed to fitting the experimental data and the result shows that the codeposition of Invar alloy on glassy carbon electrode surface conformed to the diffusion controlled three-dimensional instantaneous nucleation mechanism. The kinetic parameters were obtained …

Electrochemical Synthesis Of Porous Polyaniline Electrodes Using Hkust-1 As A Template And Their Electrochemical Supercapacitor Property, Qiong Luan, Chun-Feng Xue, Hong-Ye Zhu, Fu-Juan Yang, Xu-Li Ma, Xiao-Gang Hao

Journal of Electrochemistry

Excellent electrode plays vital important role in the performance of supercapacitors. Polyaniline (PANI) with good conductivity is often used to prepare electrode. However, its available surface is limited and results in a poor supercapacitance in many cases. It is desirable to fabricate an electrode containing electroactive PANI with high surface area deriving from its porous structure. Here, the metal-organic framework (MOF) material with high surface area was selected as a hard template for synthesizing porous PANI. Microporous PANI composite electrodes (Micro-PANI/CC) were fabricated by depositing aniline on to carbon cloth (CC) pre-coated with MOF material of HKUST-1 using a unipolar …

Sn-Doped Α-Fe2O3 Photocatalyst Containing Oxygen Vacancy For Water-Splitting, Zu-Hua Wang, Dong-Fang Niu, Hui-Cheng Li, Rong-Bin Du, Heng Xu, Xin-Sheng Zhang

Journal of Electrochemistry

The α-Fe₂O₃ nanoparticles containing oxygen vacancies were synthesized in atmospheric N₂ by dip-dropping method without a high vacuum employed before annealing. The influences of annealing atmosphere and Sn-doping on the photocatalytic performance of α-Fe₂O₃ nanoparticles were studied by annealing the photocatalyst in N₂ or air and adding SnCl₄ to the precursor directly. The results showed that the current density of Sn-doping α-Fe₂O₃ annealed in N₂ at 550 °C and 1.23 V (vs. RHE) was 35 times greater than that of pristine α-Fe₂O₃ annealed in …

Preparation And Electrochemical Properties Of Attapulgite-Supported Nitrogen-Doped Carbon@Nico2O4 Composites For Supercapacitors, Hui Wan, Zong-Rong Ying, Xin-Dong Liu, Jian-Jian Lu, Wen-Wen Zhang

Journal of Electrochemistry

In this work, the attapulgite-supported nitrogen-doped carbon (ANC) was prepared by in-situ chemically polymerizing polyaniline coating upon attapulgite, followed by high temperature heat treatment, and then NiCo₂O₄was reacted onto the surface of ANC by a combination of hydrothermal reaction and calcination to synthesize ANC@NiCo₂O₄ composites. The chemical composition and morphology of the samples were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and N₂ adsorption/desorption. The electrochemical properties were evaluated by means of constant current charge discharge (GCD) and cyclic voltammetry (CV). …

An Investigation In The Performance Of Lithium Sulfur Battery With A Tic Coated Separator, Jian-Hua Fang, Yong Cao, Mao-Ping Yang, Ming-Sen Zheng, Quan-Feng Dong

Journal of Electrochemistry

To improve the specific capacity and cycle stability of lithium-sulfur (Li-S) battery, a TiC/Celgard coating separator was developed and its performance in Li-S battery was investigated. The electrochemical test results confirmed that the TiC coating layer could significantly increase the capacity and cycle stability. At a high rate of 2C, it still delivered the capacity of 650 mAh·g^-1. At 0.5C, the specific capacity was maintained at 841.3 mAh·g^-1 after 100 cycles.

Direct Electrochemistry Of Glucose Oxidase Based On Ws2 Quantum Dots And Its Biosensing Application, Chen-Lu Li, Hua-Ping Peng, Zhong-Nan Huang, Yi-Lun Sheng, Pei-Wen Wu, Xin-Hua Lin

Journal of Electrochemistry

In this study, a novel electrochemical glucose biosensor has been developed by immobilizing glucose oxidase (GOx) on tungsten disulfide quantum dots (WS₂ QDs) on the surface of glassy carbon electrode (GCE). Transmission electron microscopy, UV-vis spectroscopy and cyclic voltammetry were employed to characterize the morphology, structure, and electrochemical behaviors of the as-prepared WS₂ QDs and the biofilm modified electrode. The results suggested that the WS₂ QDs could accelerate the electron transfer between the electrode and the immobilized enzyme, which enabled the direct electrochemistry of GOx without any electron mediator. Besides, the immobilized GOx in WS₂ QDsfilm …

Application Of Adamantane Schiff Base Nickel Complexes/Graphene Oxide/Glassy Carbon Modified Electrode In Detection Of Carmine, Peng Guo, Zheng Liu, Hai-Ying Li, Li-Ming Ma

Journal of Electrochemistry

The Schiff base nickel complexes/graphene oxide/glassy carbon electrodes were prepared by embedded method and electrodeposition on which were used to quantitatively detect the contents of carmine. Cyclic voltammetry, chronoamperometry, scanning electron microscopy (SEM) and other methods were employed to characterize properties and morphologies of the modified electrodes. The results show that the adamantane double Schiff base nickel complexes/graphene oxide/glassy carbon electrode had high electric catalytic activity toward carmine oxidation reaction, and might provide an easy and quick way to detect carmine content with good reproducibility.

Energy Management System Modeling Of Dc Data Center With Hybrid Energy Sources Using Neural Network, Khalid Althomali

Master's Theses

As data centers continue to grow rapidly, engineers will face the greater challenge in finding ways to minimize the cost of powering data centers while improving their reliability. The continuing growth of renewable energy sources such as photovoltaics (PV) system presents an opportunity to reduce the long-term energy cost of data centers and to enhance reliability when used with utility AC power and energy storage. However, the inter-temporal and the intermittency nature of solar energy makes it necessary for the proper coordination and management of these energy sources.

This thesis proposes an energy management system in DC data center using …

Stakeholder Outcomes In A Wind Turbine Investment; Is The Irish Energy Policy Effective In Reducing Ghg Emissions By Promoting Small-Scale Embedded Turbines In Sme's?, Tony Kealy

Articles

As a member state of the European Union (EU), Ireland has adopted an energy policy which includes promoting wind powered electricity generators as an economically viable, GHG-reducing, alternative to environmentally damaging fossil-fuel driven electrical generators. This longitudinal, inductive in-depth study investigates the outcomes for the government and other stakeholders involved in a wind turbine project investment by a Small-to-Medium-Enterprise (SME) based in rural Ireland. A case study research methodology is used to acquire and analyse quantitative numerical data from multiple sources including electrical power and energy meters, historical electricity bills and company sustainability reports. The study found that the installation …

2017 Spring Engr333 Project Assignment, Matthew K. Heun

ENGR 333

The Spring 2017 ENGR333 project focused on campus energy consumption.

I asked the students “Can you construct a fine-grained, bottom-up electricity demand model that predicts the annual electricity consumption for the dormitories (section A) and the PE complex (section B) for each year of the last decade with an accuracy of ±2%?”

Customer

The customer for this project was Jack Phillips, Assistant Director (Mechanical) at Calvin’s Physical Plant.

Coreless Multidisc Axial Flux Pm Machine With Carbon Nanotube Windings, Vandana Rallabandi, Narges Taran, Dan M. Ionel, John F. Eastham

Power and Energy Institute of Kentucky Faculty Publications

Coreless axial flux permanent magnet (AFPM) machines are attracting increasing attention due to their compact structure and high torque density. The torque to weight ratio can be further enhanced by the use of alternate conductor materials, such as carbon nanotube (CNT), or aluminum windings in place of the copper material coils. This paper proposes a coreless AFPM synchronous motor with CNT windings. Analytical equations are developed to allow a systematic comparison of machine designs with different conductor materials. The performance of machine designs with different coil materials, namely, copper, aluminum, and CNT, is evaluated and compared. The calculations are also …

Ocean Renewable Power Company, James Donegan

MARENER 2017

No abstract provided.

Lighting Standards For Ship And Alternative Solutions For Energy Efficiency, Efe Akyurek

MARENER 2017

Lighting has an important role amongst human life. In this respect, an adequate lighting on board gives moral, motivation also helps to improve safety and security for ships’ crew. This paper aims to both determine an adequate lighting for crew and bring energy efficiency with optimal lighting considering existing regulations on shipboard lighting. After a brief introduction, on the first part the preferred lighting tendencies to be discussed at maritime regulatory base including SOLAS, MLC with comparing ILO 92/133 Conventions. The second part initially defines optimal lighting for crew accommodation and working areas with demonstrating an example on a river …

Overcoming The Challenges To Maritime Energy Efficiciency In The Caribbean Region, Deniece Aiken

MARENER 2017

Maritime energy efficiency in the Caribbean appears to be predicated on two key requirements; regulatory controls over the vessels operating in the region and the availability and use of efficient technology. While many Caribbean territories have ratified MARPOL AnnexVI, implementation of the standards therein, presents challenges that are familiar to maritime administrators of the region. These challenges include insufficient resources and inadequate implementation of relevant standards. These issues have traditionally plagued the region. The paucity of data and monitoring in this part of the world also contributes to ineffective policy interventions. There is also a need to identify the gap …

The Law Of Conservation Of Energy Towards Defining Maritime Cluster Dynamics, Peter J. Stavroulakis, Stratos Papadimitriou, Ioannis Koliousis

MARENER 2017

Industrial clusters have for many decades been considered as the stepping stone for regional and national competitiveness, due to the fact that within these systems of economies, many propitious qualities seem to flourish. Competition and cooperation are witnessed to complement one another, firms can thrive through the marvels of knowledge creation and innovation, and positive externalities are seen to blossom into an interconnected system of collective prosperity. This system bears semblance to many occurrences in nature, and thus can guide the reflection of natural dynamics that may pave an industrial cluster’s threads. Maritime clusters in particular, are distinct vanguards of …

Costs And Benefits Of Lng Economic Development In The Baltic And Arctic Regions, Fabio Ballini, Lawrence Kuroshi

MARENER 2017

Global warming is becoming increasingly evident. However, rising temperatures also offer new economic opportunities, such as new maritime routes in previously ice-locked waters. Valuable minerals in the Arctic region are also becoming more accessible. Maritime stakeholders are therefore seeking to operate in this remote region safely and efficiently. Accommodating these developments from a regulatory standpoint, IMO has amended the International Convention for the Prevention of Pollution from Ships (MARPOL) to include Chapter 9 of Annex I, prohibiting the use of heavy-grade marine fuels as well as heavy-duty oils as cargo carriage in the seas beyond 60th parallel south. In addition, …

Energy Consumption Of Small Scale Fishing Vessel Operations In Indonesia: A Case Study In Palabuhanratu, Indonesia, Vita R. Kurniawati, Richard W. Birmingham, Alan J. Murphy

MARENER 2017

About 79% of the global fishing fleet is small motorized boats typically operating in coastal areas, supplying local markets, and contributing to human well-being through food supplies and economic development. For example, Indonesian fisheries which predominantly are artisanal fishing, have supported 54% of animal protein intake, accounted for 2% of employment level and increased the fishermen’s prosperity index by 2.44%. However, they cause significant environmental impacts including fish resource depletion and intensive energy use. Balancing the benefits and challenges, sustainably managing these fishing operations is an important yet complex task given the requirements to proportionally account for fish resources, fishing …