Electrochemical Performance Of Sodium Difluoro(Oxalato)Borate As The Additive Of Non-Aqueous Electrolytes For Sodium-Ion Batteries, Ding Zhang, Qin Zhu, Ying Wang, Cheng-Long Zhao, Shi-Bin Liu, Shou-Dong Xu

Journal of Electrochemistry

Sodium ion battery has attracted worldwide and intensive attention recently, while the adoption of electrolyte additives has been considered as one effective strategy to promote the cell performance. Within this work sodium difluoro(oxalato)borate (NaDFOB) was prepared and adopted as an additive for the general non-aqueous electrolyte formula of 1 mol·L-1 NaClO4/EC/PC (Vol: Vol=1:1), and the effects of the additive concentration on ionic conductivity and oxidization decomposition voltage were investigated in detail. In addition, the cell performance evaluated by NaNi0.5Mn0.5O2 as the cathode was also studied. It reveals that the addition of NaDFOB into the NaClO4/EC/PC electrolyte resulted in the significantly …

Density Functional Investigation On Cathode/Electrolyte Interface In Solid-State Lithium Batteries, Xuelong Wang, Ruijuan Xiao, Yong Xiang, Hong Li, Liquan Chen

Journal of Electrochemistry

The rapidly expanding application of lithium ion batteries stimulates research interest on energy storage devices with higher energy density, better safety and faster charge/discharge speed. All-solid-state lithium batteries have been considered as promising candidates because of their fewer side reactions and better safety compared with conventional lithium-ion batteries with organic liquid electrolytes. Looking for well-matched electrode/electrolyte interfaces is one of the keys to ensuring good comprehensive performance of solid-state lithium batteries. In this report, with the aid of first-principles simulations, the local structure and lithium ions transportation properties of electrolyte surfaces and cathode/electrolyte interfaces are investigated. The β-Li₃PS …

A New Type Carbon Composited Molybdenum Doped Vanadium Oxide Nanowires As A Cathode Material For Sodium Ion Batteries, Guang-Rui Zhang, Li-Qiang Hu, Bao-Zhu Zhang

Journal of Electrochemistry

In recent years, the development of lithium ion batteries (LIBs) has been limited due to the insufficient lithium resource and increasing cost. As a promising candidate, sodium ion batteries (SIBs) with the similar electrochemical mechanism and lower cost than LIBs are developing rapidly. However, as a result of the larger radius of Na⁺ compared with Li⁺, the crystalline structures of the most electrode materials are damaged severely during the intercalation of Na⁺, which limits the electrochemical properties of SIBs. Thus, developing new types of electrode materials for SIBs is particularly important. Among the cathode materials, …

Effects Of Surface Modification Modes On Proton-Over-Vanadium Ion Selectivity Of Nafion®Membrane For Application In Vanadium Redox Flow Battery, Qing-Long Tan, Hai-Ning Wang, Shan-Fu Lu, Da-Wei Liang, Chun-Xiao Wu, Yan Xiang

Journal of Electrochemistry

The effect of surface modification modes on proton-over-vanadium ion selectivity was studied by spin-coating chitosan-Phosphotungstic Acid (PWA) as a single or double layer on Nafion membrane surface. To suppress the vanadium ions permeation through the Nafion? membrane in a vanadium redox flow battery (VRFB), the single surface-modified Nafion membrane (Nafion/chitosan-PWA)S and double surface-modified Nafion membrane (Nafion/chitosan-PWA)D demonstrated a 89.9% and 92.7% reduction of vanadium ion permeability in comparison with pristine Nafion, respectively. The (Nafion/chitosan-PWA)D exhibited betterhigher selectivity between proton and vanadium ions than the (Nafion/chitosan-PWA)S at the same layer thickness. Furthermore, the columbic efficiency for the VRFB single cell based …

Radcool: A Web-Enabled Simulation Tool For Radiative Cooling, Yu-Wen Lin, Evan L. Schlenker, Zhiguang Zhou, Peter Bermel

The Summer Undergraduate Research Fellowship (SURF) Symposium

Thermophotovoltaic (TPV) systems can generate electricity from high-temperature heat sources via thermal radiation. However, the intense heating of a photovoltaic (PV) cell can greatly reduce the overall efficiency of the system. Therefore, it is critical to develop techniques to keep the PV cells close to ambient temperature without consuming energy. Radiative cooling is a passive technique that dissipates heat into remote space via thermal radiation. A simulation tool to predict the performance of radiative cooling systems would be particularly helpful in designing new experiments. The current TPV model simulation tool, TPVexpt, can calculate the theoretical performance of the TPV system. …

Carbon Removal And Optoelectronic Property Tuning In Copper Arsenic Sulfide Thin Films Through Ligand Exchange And Alloying, Louis R. Schroeder, Scott Mcclary, Rakesh Agrawal

The Summer Undergraduate Research Fellowship (SURF) Symposium

Solution processed thin film solar cells are attractive alternatives to conventional energy sources due to low waste generation, flexibility in substrate choice, and scalability. The novel semiconductor Cu3AsS4 in the enargite phase has a near ideal band gap of 1.4 eV and has earth abundant constituent elements; yet single-junction solar cells have yielded low efficiencies due to a secondary carbonaceous phase present, among other issues. This carbonaceous phase may be eliminated by exchanging the carbonaceous ligands with molecular metal chalcogenides. To characterize the ligand exchanged particles, UV-Vis-NIR spectroscopy, Raman spectroscopy, X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy, and …

Thermal Characterization Of Magnetic Components, Jiazhou Zhong, Veda Samhitha Duppalli, Scott D. Sudhoff Professor

The Summer Undergraduate Research Fellowship (SURF) Symposium

Thermal limits are crucial constraints in the design of power magnetic components. As the power density of magnetic components continues to increase, cooling becomes more critical. Our research focuses on solving for the amount of cooling needed for a particular magnetic component. During the research process, a low-velocity wind tunnel designed and built from the ground up is used to form uniform and controlled conditions for the test components. Thermal Equivalent Circuit (TEC) and parameter identification techniques are used in conjunction to yield temperature distribution results. The expected result is temperature data on various areas of the component under different …

Realization Of A High Power Microgrid Based On Voltage Source Converters, Yusi Liu

Graduate Theses and Dissertations

Microgrid concepts are gradually becoming more popular because they are expected to interface with renewable energies, increase end users’ reliability and resiliency, and promote seamless integration of distributed generators (DG) and energy storage units [1]. Most units are connected through power electronics interfaces, such as ac-dc, dc-dc, and dc-ac converters. The converter design and control are critical to the stability and efficiency of a microgrid.

A microgrid may operate in either gird connected mode or islanded mode [1]. In terms of stability, the grid connected mode is less challenging compared to the islanded mode of operation due to the nearly …

A Low Temperature Co-Fired Ceramic (Ltcc) Interposer Based Three-Dimensional Stacked Wire Bondless Power Module, Atanu Dutta

Graduate Theses and Dissertations

The objective of this dissertation research is to develop a low temperature co-fired ceramic (LTCC) interposer-based module-level 3-D wire bondless stacked power module. As part of the dissertation work, the 3-D wire bondless stack is designed, simulated, fabricated and characterized. The 3-D wire bondless stack is realized with two stand-alone power modules in a half-bridge configuration. Each stand-alone power module consists of two 1200 V 25 A silicon insulated-gate bipolar transistor (IGBT) devices in parallel and two 1200 V 20 A Schottky barrier diodes (SBD) in an antiparallel configuration. A novel interconnection scheme with conductive clamps and a spring loaded …

Design & Evaluation Of A Hybrid Switched Capacitor Circuit With Wide-Bandgap Devices For Dc Grid Applications, Joshua L. Stewart

Electrical and Computer Engineering ETDs

ABSTRACT

As technologies advance, the rate at which renewable power sources, such as solar photovoltaic (PV) and wind, are being added to the power grid is increasing. Typically, PV power plants require large inverters for direct current to alternating current (DC-AC) power conversion, as well as large transformers to step up voltages to the grid voltage. Offshore wind farms and large PV power plants in remote locations often aggregate power on a DC bus in order to improve efficiency and reduce the cost of power conversion hardware within the energy complex. However, the power must still be converted to AC …

The Impact Of Power Curve Estimation On Commercial Wind Power Forecasts - An Empirical Analysis, Gianni Goretti, Aidan Duffy, Tek Tjing Lie

Conference papers

An increasing number of utilities participating in the energy market require short term (i.e. up to 48 hours) power forecasts for renewable generation in order to optimize technical and financial performances. As a result, a large number of forecast providers now operate in the marketplace, each using different methods and offering a wide range of services. This paper assesses five different day-ahead wind power forecasts generated by various service providers currently operating in the market, and compares their performance against the state-of-the-art of short-term wind power forecasting. The work focuses on how power curve estimations can introduce systematic errors that …

Impact Analysis Of Increased Dispatchable Resources On A Utility Feeder In Opendss, Crystal Eppinger

Dissertations and Theses

Oregon utilities are replacing their portfolios of traditional fossil fuel generation with renewable generating sources. Stepping away from carbon-producing energy will leave a deficit of on-demand power, resulting in decreased reliability. To overcome these technical challenges, utilities must maximize the use of their present dispatchable resources. One such resource is the Portland General Electric (PGE) Dispatchable Standby Generation Program (DSG), which is an aggregated 105 MWs of distributed generation (DG). These resources are brought on-line when there is a critical need for power. Resources are added to the program if a transfer trip scheme is in place or a modeling …

Energy From Chemical Reactions: Understanding The Combustion Engine, Tammy Guthrie, Kathy Prophet, Greg Herzig, Cassie Kautzer

Middle School Lesson Plans

Automobiles produce a large amount of heat generated by the burning of gasoline. Burning gasoline is a chemical reaction that causes a phase change. This is called combustible energy. During combustion fuel combines with oxygen to release energy (such as heat, light, sound) along with another product that is often considered waste. Most of the energy produced is not used to power the automobile, but is released as heat. 19.3 pounds of the greenhouse gas, carbon dioxide, is produced from the combustion of 1 gallon of U.S. gasoline according to the U.S. Energy Information Administration.

Anion Exchange Membrane Capacitive Deionization Cells, Ayokunle Omosebi, Xin Gao, Nicolas Holubowitch, Zhiao Li, James Landon, Kunlei Liu

Center for Applied Energy Research Faculty and Staff Publications

The electrochemical response of capacitive deionization (CDI) employing a single anion exchange membrane (AEM-CDI) is contrasted to conventional two-membrane CDI (MCDI) formed with complementary anion and cation exchange membranes. Pristine activated carbon cloth electrodes that possess native positive surface charge in solution were used as both anode (positive electrode) and cathode (negative electrode) in these cells. In a separate set of tests to investigate the impact of surface charge modification on deionization responses, the single and dual membrane cells were formed with asymmetric electrodes (AEM-aCDI and aMCDI) consisting of nitric acid oxidized electrodes that possess negative surface charge as the …

Solvent Degradation And Emissions From A 0.7mwe Pilot Co2 Capture System With Two-Stage Stripping, Jesse Thompson, Heather Nikolic, Megan Combs, Saloni Bhatnagar, Jonathan Pelgen, Keemia Abad, Kunlei Liu

Center for Applied Energy Research Faculty and Staff Publications

The UKy-CAER team successfully tested an advanced 0.7 MWe post-combustion CO₂ capture system on a coal-fired power plant using a heat integration process combined with two-stage stripping to enhance the CO₂ absorber performance. One of the unique feature of the UKy-CAER integrated process is a two-stage stripping unit for solvent regeneration. The secondary stripper is empowered by the heat rejection from a conventional steam-heated (primary) stripper. The secondary stripper outlet stream at the commercial scale can be used as boiler secondary combustion air, consequently enriching the flue gas with CO₂, resulting in less energy penalty required …

Size And Shape Distributions Of Primary Crystallites In Titania Aggregates, Eric A. Grulke, Kazuhiro Yamamoto, Kazuhiro Kumagai, Ines Häusler, Werner Österle, Erik Ortel, Vasile-Dan Hodoroaba, Scott C. Brown, Christopher Chan, Jiwen Zheng, Kenji Yamamoto, Kouji Yashiki, Nam Woong Song, Young Heon Kim, Aleksandr B Stefaniak, D. Schwegler-Berry, Victoria A. Coleman, Åsa K. Jämting, Jan Herrmann, Toru Arakawa, Woodrow W. Burchett, Joshua W. Lambert, Arnold J. Stromberg

Chemical and Materials Engineering Faculty Publications

The primary crystallite size of titania powder relates to its properties in a number of applications. Transmission electron microscopy was used in this interlaboratory comparison (ILC) to measure primary crystallite size and shape distributions for a commercial aggregated titania powder. Data of four size descriptors and two shape descriptors were evaluated across nine laboratories. Data repeatability and reproducibility was evaluated by analysis of variance. One-third of the laboratory pairs had similar size descriptor data, but 83% of the pairs had similar aspect ratio data. Scale descriptor distributions were generally unimodal and were well-described by lognormal reference models. Shape descriptor distributions …

Kinetic Energy Investigation, Mike Jackson

High School Lesson Plans

Students will build a mouse trap powered car that converts elastic potential energy contained in the trap’s spring to linear kinetic energy of the car. The release of this energy results in a net force which leads to linear acceleration. This acceleration can be measured with Vernier Logger Pro®, and using Newton’s Second Law of Motion, the net force can be calculated. Finally, using the concept of work, the final kinetic energy of the car can be calculated. Once students become familiar with the calculation of work and energy, the teacher will challenge the students to modify their cars to …

Design And Manufacture Of A Waste Compactor Prototype: A Step Towards Implementing A Non-Burn Health Care Waste Disposal In Developing Countries, Tito Mwinuka

Tanzania Journal of Engineering and Technology (TJET)

Non-burn technology is the only safe way of handling and disposing infectious healthcare waste. It involves steam treatment of infectious waste at temperatures higher than 121 o C for a minimum of 30 minutes before disposing them just like other municipal waste. Infectious healthcare waste is normally only about 10 25% of all healthcare waste. In this paper, design, manufacturing and testing of a waste compactor for reducing waste volume to facilitate its handling is discussed. Preliminary tests show that the waste volume can be reduced to less than 10% of its original volume using the developed compactor. Waste compactors …

Ionic Thermoelectric Paper, Fei Jiao, Ali Naderi, Dan Zhao, Joshua Schlueter, Maryam Shahi, Jonas Sundström, Hjalmar Granberg, Jesper Edberg, Ujwala Ail, Joseph W. Brill, Tom Lindström, Magnus Berggren, Xavier Crispin

Physics and Astronomy Faculty Publications

Ionic thermoelectric materials, for example, polyelectrolytes such as polystyrene sulfonate sodium (PSSNa), constitute a new class of materials which are attracting interest because of their large Seebeck coefficient and the possibility that they could be used in ionic thermoelectric SCs (ITESCs) and field effect transistors. However, pure polyelectrolyte membranes are not robust or flexible. In this paper, the preparation of ionic thermoelectric paper using a simple, scalable and cost-effective method is described. After a composite was fabricated with nanofibrillated cellulose (NFC), the resulting NFC–PSSNa paper is flexible and mechanically robust, which is desirable if it is to be used in …

Loss Model For Gallium Nitride Dc-Dc Buck Converter, Rushi P. Patel

Pursuit - The Journal of Undergraduate Research at The University of Tennessee

In recent years, more research has been done on Enhancement Mode Gallium Nitride (eGaN) converters, as the world is moving towards more power efficient converters. Power converters play a major role in efficiently controlling and converting electric energy used by machines, systems, and everyday products. The process to make converters more efficient was complicated and slow in the twentieth century. One of the important aspects in power electronics is to evaluate different losses and minimize losses to achieve high efficiency of the converter. With help of simulation tools such as MATLAB and LTspice, this process has become much faster and …