Novel Investigation Of Catalytic Hydrogenation And Oxidation Of 1,3-Butadiene,
2023
United Arab Emirates University
Novel Investigation Of Catalytic Hydrogenation And Oxidation Of 1,3-Butadiene, Ali M. Alabedkhalil
Theses
The hydrogenation of 1,3 Butadiene (BD) is an important industrial process that is generally used to generate butene, which is a key feedstock to produce a variety of chemicals such as polymers, plastic, and synthetic rubber. This process involves reacting BD with hydrogen using different metallic Ni-based catalysts. In this study, Ni/Al2O3 and Ni/Nb2O5 catalysts were used and investigated to perform the hydrogenation reaction because of their commercial availability, effective hydrogenation activity, and affordability compared to Platinum Group Metal (PGM) catalysts.
The catalytic reactions were conducted using a quartz tube reactor between a temperature range …
Dual Crosslinked Poly(Acrylamide-Co-N-Vinylpyrrolidone) Microspheres With Re-Crosslinking Ability For Fossil Energy Recovery,
2023
Missouri University of Science and Technology
Dual Crosslinked Poly(Acrylamide-Co-N-Vinylpyrrolidone) Microspheres With Re-Crosslinking Ability For Fossil Energy Recovery, Jingyang Pu, Baojun Bai, Jiaming Geng, Na Zhang, Thomas Schuman
Chemical and Biochemical Engineering Faculty Research & Creative Works
Microspheres have been proposed to be applied in controlling wastewater production for mature oilfields and migrating leakage for gas and nuclear waste storage. However, it remains challenging for stacked microspheres to maintain strong blocking ability in micron-sized small pores or fractures. in this study, a novel microsphere was developed with comprehensive properties including high deformability and long re-crosslinking time upon tunable swelling ratio for the applications. a dual covalent and physical crosslinking strategy was used to develop novel microspheres reinforced by a hydrogen bond (H-bond, between pyrrole ring and amide group) and coordination bond (between chromium acetate (CrAc) and carboxyl …
Dual Crosslinked Poly(Acrylamide-Co-N-Vinylpyrrolidone) Microspheres With Re-Crosslinking Ability For Fossil Energy Recovery,
2023
Missouri University of Science and Technology
Dual Crosslinked Poly(Acrylamide-Co-N-Vinylpyrrolidone) Microspheres With Re-Crosslinking Ability For Fossil Energy Recovery, Jingyang Pu, Baojun Bai, Jiaming Geng, Na Zhang, Thomas P. Schuman
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Microspheres have been proposed to be applied in controlling wastewater production for mature oilfields and migrating leakage for gas and nuclear waste storage. However, it remains challenging for stacked microspheres to maintain strong blocking ability in micron-sized small pores or fractures. In this study, a novel microsphere was developed with comprehensive properties including high deformability and long re-crosslinking time upon tunable swelling ratio for the applications. A dual covalent and physical crosslinking strategy was used to develop novel microspheres reinforced by a hydrogen bond (H-bond, between pyrrole ring and amide group) and coordination bond (between chromium acetate (CrAc) and carboxyl …
Estimating Aquifer System Storage Loss With Water Levels, Pumping And Insar Data In The Parowan Valley, Utah,
2023
Missouri University of Science and Technology
Estimating Aquifer System Storage Loss With Water Levels, Pumping And Insar Data In The Parowan Valley, Utah, Ryan G. Smith, Jiawei Li, Katherine R. Grote, Jim Butler
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
In the Parowan Valley of Utah, Groundwater Levels Have Declined by as Much as 30 M over the Past 50 Years with Accompanying Subsidence Rates of Up to 5 Cm/year. Traditional Methods to Estimate Groundwater Storage Change Use a Combination of Groundwater Level and Storativity Estimates, But There is Often Considerable Uncertainty in These. in This Study, We Demonstrate a New Method that Relies on a Combination of Geodetic Data from InSAR, as Well as Groundwater Level and Pumping Data, to Estimate Both the Total Groundwater Storage Loss and the Percentages of Storage Loss in Fine- and Coarse-Grained Layers within …
Organic Matter Assessment And Paleoenvironmental Changes Of The Middle Jurassic Main Source Rocks (Khatatba Formation) In The North Western Desert, Egypt: Palynofacies And Palynomorph Perspectives,
2023
Missouri University of Science and Technology
Organic Matter Assessment And Paleoenvironmental Changes Of The Middle Jurassic Main Source Rocks (Khatatba Formation) In The North Western Desert, Egypt: Palynofacies And Palynomorph Perspectives, Ahmed Mansour, Sameh S. Tahoun, Aya Raafat, Mohamed S. Ahmed, Francisca Oboh-Ikuenobe, Thomas Gentzis, Xiugen Fu
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
The Middle Jurassic in the north Western Desert, Egypt, was a time of complex tectonics and increased environmental perturbations attributed to the predominant sedimentation of organic carbon-rich fine siliciclastic and carbonate deposits of the Khatatba Formation. Although some studies have addressed the hydrocarbon potential and source rock characteristics of the Khatatba Formation, a regional-scale investigation of the prevalent paleoenvironmental conditions and organic matter characteristics is still necessary. In this study, the Khatatba Formation is investigated for detailed palynofacies analysis and palynomorph composition to assess organic matter kerogen types and reconstruct the depositional paleoenvironmental patterns on a regional scale. For this …
Biodegradable Preformed Particle Gel (Ppg) Made Of Natural Chitosan Material For Water Shut-Off Application,
2023
Missouri University of Science and Technology
Biodegradable Preformed Particle Gel (Ppg) Made Of Natural Chitosan Material For Water Shut-Off Application, Reem Elaf, Ahmed Ben Ali, Mohammed Saad, Ibnelwaleed A. Hussein, Hassan Nimir, Baojun Bai
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Oil and Gas Extraction Frequently Produces Substantial Volumes of Produced Water, Leading to Several Mechanical and Environmental Issues. Several Methods Have Been Applied over Decades, Including Chemical Processes Such as In-Situ Crosslinked Polymer Gel and Preformed Particle Gel, Which Are the Most Effective Nowadays. This Study Developed a Green and Biodegradable PPG Made of PAM and Chitosan as a Blocking Agent for Water Shutoff, Which Will Contribute to Combating the Toxicity of Several Commercially Used PPGs. the Applicability of Chitosan to Act as a Crosslinker Has Been Confirmed by FTIR Spectroscopy and Observed by Scanning Electron Microscopy. Extensive Swelling Capacity …
Laboratory Comparative Study Of Anionic And Cationic High-Viscosity Friction Reducers In Moderate To Extremely High Total Dissolved Solids Environments,
2023
Missouri University of Science and Technology
Laboratory Comparative Study Of Anionic And Cationic High-Viscosity Friction Reducers In Moderate To Extremely High Total Dissolved Solids Environments, Xiaojing Ge, Abdulmohsin Imqam
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
High-Viscosity Friction Reducers (HVFRs) Have Been Recently Gaining More Attention and Increasing in Use, Not Only as Friction-Reducing Agents But Also as Proppant Carriers. Reusing Produced Water Has Also Been Driven by Both Environmental and Economic Benefits. Currently, Most Friction Reducers on the Market Are Anionic Friction Reducers, Which Are Fully Compatible with Most Produced Water with Low to Medium Level of Total Dissolved Solids (TDS) But Show a Significant Drop at High TDS Conditions in Terms of their Friction Reduction Performance in Most Cases. on the Contrary, Cationic Friction Reducers Are Believed to Have Better TDS Tolerance and Friction …
Integrated Experimental And Dft Study Of Palladium And Nickel Metals Supported On Reducible Metallic Oxides For Selective Hydrogenation Of Alkynes And Dienes Bonds,
2023
United Arab Emirates University
Integrated Experimental And Dft Study Of Palladium And Nickel Metals Supported On Reducible Metallic Oxides For Selective Hydrogenation Of Alkynes And Dienes Bonds, Toyin Daniel Shittu
Dissertations
This dissertation investigates the capacity of ceria (CeO2) to serve as a stand-alone reactive catalyst, and to act as catalyst support for different catalyst configurations. Experimental and density functional theory (DFT) approach were used to critically predict and to design ceria-containing catalysts. Ceria owes the catalytic propensity to the ability to undergo switch in the oxidation state from the +4 to +3 states. Motivated by experimental studies involving CeO2 catalysts, defects CeO2 surface with an oxygen vacancy (CeO2(111)_Vo) was used to explore the decomposition chemistry of methanethiol based on DFT. The potential formation pathways revealed that …
Incoherency In Central American Hydroclimate Proxy Records Spanning The Last Millennium,
2023
Missouri University of Science and Technology
Incoherency In Central American Hydroclimate Proxy Records Spanning The Last Millennium, Jonathan Obrist-Farner, Byron A. Steinman, Nathan D. Stansell, Jeremy Maurer
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Continued Global Warming is Expected to Result in Reduced Precipitation and a Drier Climate in Central America. Projections of Future Changes Are Highly Uncertain, However, Due to the Spatial Resolution Limitations of Models and Insufficient Observational Data Coverage Across Space and Time. Paleoclimate Proxy Data Are Therefore Critical for Understanding Regional Climate Responses during Times of Global Climate Reorganization. Here We Present Two Lake-Sediment based Records of Precipitation Variability in Guatemala Along with a Synthesis of Central American Hydroclimate Records Spanning the Last Millennium (800–2000 CE). the Synthesis Reveals that Regional Climate Changes Have Been Strikingly Heterogeneous, even over Relatively …
Using Switchable Solvents For Enhanced Biodiesel Production,
2023
United Arab Emirates University
Using Switchable Solvents For Enhanced Biodiesel Production, Eyad Abdel Rahman Sowan
Theses
This thesis presents a sustainable approach to biodiesel production using in-situ technology for direct conversion of microalgae-to-biodiesel. The proposed method operates on wet, untreated microalgae, thereby eliminating the cost/energy intensive drying and cell disruption steps. Owing to their favorable properties, the use of enzymes, specifically lipase, as a catalyst for the process was suggested over acid/base catalysts. However, the high cost of the enzyme necessitates its reuse at sustained activity for the process to be economically feasible. The use of non-toxic green solvents, such as switchable solvents, as an alternative to conventional organic solvents was a significant challenge for the …
Design And Performance Analysis Of Dry Gas Fishbone Wells For Lower Carbon Footprint,
2023
University of North Dakota
Design And Performance Analysis Of Dry Gas Fishbone Wells For Lower Carbon Footprint, Habib Ouadi, Aimen Laalam, Amjed Hassan, Abderraouf Chemmakh, Vamegh Rasouli, Mohamed Mahmoud
Petroleum Engineering Student Publications
Multilateral well drilling technology has recently assisted the drilling industry in improving borehole contact area and reducing operation time, while maintaining a competitive cost. The most advanced multilateral well drilling method is Fishbone drilling (FbD). This method has been utilized in several hydrocarbon fields worldwide, resulting in high recovery enhancement and reduced carbon emissions from drilling. FbD involves drilling several branches from laterals and can be considered as an alternative method to hydraulic fracturing to increase the stimulated reservoir volume. However, the expected productivity of applying a Fishbone well from one field to another can vary due to various challenges …
Evaluation Of Liquid Loading In Gas Wells Using Machine Learning,
2023
University of North Dakota
Evaluation Of Liquid Loading In Gas Wells Using Machine Learning, Abderraouf Chemmakh, Olusegun Stanley Tomomewo, Kegang Ling, Ahmed Shammari
Petroleum Engineering Student Publications
The inevitable result that gas wells witness during their life production is the liquid loading problem. The liquids that come with gas block the production tubing if the gas velocity supplied by the reservoir pressure is not enough to carry them to surface. Researchers used different theories to solve the problem naming, droplet fallback theory, liquid film reversal theory, characteristic velocity, transient simulations, and others. While there is no definitive answer on what theory is the most valid or the one that performs the best in all cases. This paper comes to involve a different approach, a combination between physics-based …
Applications Of Underbalanced Fishbone Drilling For Improved Recovery And Reduced Carbon Footprint In Unconventional Plays,
2023
University of North Dakota
Applications Of Underbalanced Fishbone Drilling For Improved Recovery And Reduced Carbon Footprint In Unconventional Plays, Habib Ouadi, Siamak Mishani, Vamegh Rasouli
Petroleum Engineering Student Publications
Fishbone Drilling (FbD) consists of drilling several micro-holes in different directions from the main vertical or deviated wellbore. Similar to multilateral micro-hole drilling, FbD may be used to enhance hydrocarbon production in naturally fractured formations or in refracturing operations by interconnecting the existing natural fractures. When combined with underbalanced drilling using a coiled tubing rig, FbD enhances the production further by easing the natural flow of the hydrocarbon from the reservoir to the wellbore. The design aspects of the Fishbones include determining the number, length, distance between the branches, and the angle of sidetracking of the branches from the main …
A Systematic Design Approach For Bulk Gel Treatments Based On Gel Volume-Concentration Ratio In Field Projects,
2023
Missouri University of Science and Technology
A Systematic Design Approach For Bulk Gel Treatments Based On Gel Volume-Concentration Ratio In Field Projects, Munqith Aldhaheri, Mingzhen Wei, Baojun Bai
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Controlling excessive water production in mature oil fields has always been a desired objective of the oil and gas industry. This objective calls for planning of more effective water-control gel treatments with optimized designs to obtain more attractive outcomes. Unfortunately, planning such effective treatments remains a dilemma for reservoir engineers due to the lack of methodical design tools in the industry. This paper presents a novel systematic design approach for polyacrylamide-Based bulk gel treatments by classifying their field projects according to the gel volume-concentration ratio (VCR) into three design types. in terms of one another, the approach estimates either the …
A Systematic Design Approach For Bulk Gel Treatments Based On Gel Volume-Concentration Ratio In Field Projects,
2023
Missouri University of Science and Technology
A Systematic Design Approach For Bulk Gel Treatments Based On Gel Volume-Concentration Ratio In Field Projects, Munqith Aldhaheri, Mingzhen Wei, Baojun Bai
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Controlling excessive water production in mature oil fields has always been a desired objective of the oil and gas industry. This objective calls for planning of more effective water-control gel treatments with optimized designs to obtain more attractive outcomes. Unfortunately, planning such effective treatments remains a dilemma for reservoir engineers due to the lack of methodical design tools in the industry. This paper presents a novel systematic design approach for polyacrylamide-based bulk gel treatments by classifying their field projects according to the gel volume-concentration ratio (VCR) into three design types. In terms of one another, the approach estimates either the …
Seismic Azimuthal Anisotropy Beneath A Fast Moving Ancient Continent: Constraints From Shear Wave Splitting Analysis In Australia,
2023
Missouri University of Science and Technology
Seismic Azimuthal Anisotropy Beneath A Fast Moving Ancient Continent: Constraints From Shear Wave Splitting Analysis In Australia, Kailun Ba, Stephen S. Gao, Jianguo Song, Kelly H. Liu
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Seismic Azimuthal Anisotropy Beneath Australia is Investigated using Splitting of the Teleseismic PKS, SKKS, and SKS Phases to Delineate Asthenospheric Flow and Lithospheric Deformation Beneath One of the Oldest and Fast-Moving Continents on Earth. in Total 511 Pairs of High-Quality Splitting Parameters Were Observed at 116 Seismic Stations. Unlike Other Stable Continental Areas in Africa, East Asia, and North America, Where Spatially Consistent Splitting Parameters Dominate, the Fast Orientations and Splitting Times Observed in Australia Show a Complex Pattern, with a Slightly Smaller Than Normal Average Splitting Time of 0.85 ± 0.33 S. on the North Australian Craton, the Fast …
Coreflooding Evaluation Of Fiber-Assisted Recrosslinkable Preformed Particle Gel Using An Open Fracture Model,
2023
Missouri University of Science and Technology
Coreflooding Evaluation Of Fiber-Assisted Recrosslinkable Preformed Particle Gel Using An Open Fracture Model, Shuda Zhao, Ali Al Brahim, Junchen Liu, Baojun Bai, Thomas P. Schuman
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Recrosslinkable Preformed Particle Gels (RPPGs) Have Been Used to Treat the Problem of Void Space Conduits (VSC) and repair the "Short-Circuited" Waterflood in Alaska's West Sak Field. Field Results Showed a 23% Increase in Success Rates over Typical Preformed Particle Gel (PPG) Treatments. in This Paper, We Evaluated Whether Adding Fiber into RPPGs Can Increase the RPPG Plugging Efficiency and Thus Further Improve the Success Rate. We Designed Open Fracture Models to Represent vs.C and Investigated the Effect of Swelling Ratio (SR), Fracture Size, and Fiber Concentration on Gel Injection Pressure, Water Breakthrough Pressure, and Permeability Reduction. Results Show that …
Lysine Crosslinked Polyacrylamide─A Novel Green Polymer Gel For Preferential Flow Control,
2023
Missouri University of Science and Technology
Lysine Crosslinked Polyacrylamide─A Novel Green Polymer Gel For Preferential Flow Control, Tao Song, Baojun Bai, Yugandhara Eriyagama, Thomas P. Schuman
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Acrylamide-based polymer gels have been applied to control the preferential flow in the subsurface for decades. However, some commonly used crosslinkers, such as Cr (III) and phenol-formaldehyde, are highly toxic and are being phased out because of stringent environmental regulations. This work uses l-lysine as the green crosslinker to produce acrylamide-based polymer gels. This article systematically studied the effect of lysine and polymer concentration, salinity, pH, and temperature on gelation behavior and thermal stability. Besides, the gelation mechanism and crosslinking density were elucidated in this work. A high-permeability sandstone core was used to test the plugging efficiency of this novel …
Experimental Study: Investigating The Anions And Cations' Effects On The Elasticity Of The Anionic And Cationic High Viscosity Friction Reducers,
2023
Missouri University of Science and Technology
Experimental Study: Investigating The Anions And Cations' Effects On The Elasticity Of The Anionic And Cationic High Viscosity Friction Reducers, Xiaojing Ge, Ghith Biheri, Abdulmohsin Imqam, Baojun Bai, Yuwei Zhang
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
High viscosity friction reducers (HVFRs) are widely used as friction-reducing agents and proppant carriers during hydraulic fracturing. The reuse of produced water has gained popularity due to environmental and economic benefits. Currently, the field's most commonly used friction reducers are anionic and cationic HVFRs. Anionic HVFRs are typically pumped with freshwater, while cationic HVFRs are used with high Total Dissolved Solids (TDS) produced water. Cationic friction reducers are believed to have better TDS tolerance, friction reduction performance, and proppant transport capabilities compared to anionic friction reducers under high TDS conditions due to their superior viscoelastic properties. In addition, the impact …
Finite Line Relief Well System Design For Dams And Levees,
2023
Missouri University of Science and Technology
Finite Line Relief Well System Design For Dams And Levees, Andrew M. Keffer, Erich D. Guy, Katherine R. Grote
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
An Analytical Method is Commonly Used to Design Relief Well Systems by Assuming the Well Line Extends an Infinite Distance Parallel to the Dam or Levee. This Assumption May Be Met in Some Cases, But When a Well Line is of Finite Length, This Can Severely Underestimate Excess Heads. Although These Consequences Have Been Historically Recognized, a Practical Graph-Based Analytical Approach for Finite Well Line Design Has Not Been Developed. Finite Well Lines Exist and Continue to Be Installed at Many Locations, So This Study Developed a Practical Design Method for Such Systems. Analytical Solutions and Numerical Models Were Used …
