Synthesis Of Acetylene Diols In The Catalytic System Of Cu(Otf)2/Thf/Tbabr,
2025
Tashkent Institute of Chemical Technology, Tashkent, Uzbekistan
Synthesis Of Acetylene Diols In The Catalytic System Of Cu(Otf)2/Thf/Tbabr, Abduvakhаb Ikramov, Lochinbek Q. Ablakulov, Odiljon E. Ziyadullayev, Sardor M. Rakhmatov, Mirjalol E. Ziyadullayev
CHEMISTRY AND CHEMICAL ENGINEERING
The aim of the work was the synthesis of acetylenediols in the Cu(OTf)2/THF/TBABr catalytic system. The synthesis of acetylenic diols based on the alkynylation process of aliphatic and heterocyclic ketones containing two carbonyl groups in their molecules in the presence of alkyne hydrocarbons was studied for the first time using the Cu(OTf)2/THF/TBABr catalytic system. The effects of temperature, reaction time, nature of solvent and catalyst, and molar amount of starting materials on the synthesis of acetylenic alcohols in the selected system were studied, and based on the results obtained, alternative conditions for the process were found.
Synthesis And Study Of New Complex Compounds Of Copper(Ii) And (5-Methyl-1,3,4-Thiadiazole-2-Ylsulfanil)-Acetic Acid,
2025
National University of Uzbekistan, Tashkent, Uzbekistan
Synthesis And Study Of New Complex Compounds Of Copper(Ii) And (5-Methyl-1,3,4-Thiadiazole-2-Ylsulfanil)-Acetic Acid, Ekaterina V. Kinshakova, Aziz K. Atashov, Batirbay S. Torambetov, Shakhnoza A. Kadirova
CHEMISTRY AND CHEMICAL ENGINEERING
The purpose of this study is to synthesize new copper (II) coordination compounds with a heterocyclic polydentate ligand (5-methyl-1,3,4-thiadiazole-2-ylsulfanyl) -acetic acid and to study their structure. The structure of the complexes was established by the method of X-ray diffraction analysis (XRD) of single crystals, it was shown that the complexes have a polymer structure and a coordination polyhedron of the square pyramid type, however, one of them is mono-nuclear composition (C10H14CuN4O6S4*2H2O)n, and the second is bi-nuclear composition of cluster type (C20H20Cu2 …
Synthesis Of Acetylene-Based Hetarene Derivatives In The Presence Of Catalysts,
2025
Navoi State University of Mining and Technology, Navoi, Uzbekistan
Synthesis Of Acetylene-Based Hetarene Derivatives In The Presence Of Catalysts, Abdulla T. Umrzokov, Abduvaxаb Ikramov, Khusnitdin M. Vapoev, Yusuf K. Zhumanov, Sardor M. Kodirov
CHEMISTRY AND CHEMICAL ENGINEERING
The aim of the study is to synthesize hetaren derivatives of acetylene amination reactions using local natural raw materials as catalyst carriers. Various grades of Oltintag and Angren kaolins, various grades of Navbakhor bentonite, as well as the opaque rock of the Karmaninsky deposit were used as catalyst carriers. Thermal, acidic and hydrothermal treatment was carried out on the appropriate sorbents, with the production of catalysts of various modifications from sorbents and active components. The processes of catalytic condensation of acetylene with ammonia were studied using modified catalysts. The effect of the reaction temperature, the active components of the catalyst, …
The Role Of Chitosan In Increasing The Mechanical And Antibacterial Properties Of Paper,
2025
Tashkent State Technical University, Tashkent city, Republic of Uzbekistan, Basic Doctoral, https://orcid.org/0009-0000-9704-789X;
The Role Of Chitosan In Increasing The Mechanical And Antibacterial Properties Of Paper, Khurshid Khamidulla Ugli Khaydullaev, Jaloliddin Faxriddin Ugli Ungarov, Munavvar Umar Kizi Iskandarova, Yorqinjon Tulqin Ugli Ergashev, Guzal Yusupovna Akmalova, Elmurod Abduqodirovich Egamberdiev
Technical science and innovation
Chitosan is also widely used in the paper industry to improve paper production and paper properties. Indeed, the molecular structure of chitosan is similar to cellulose, which contributes to the formation of a strong compound. Due to the presence of chitin (-NHCOCH3) functional groups in chitosan (-NH2), these groups are insoluble in water, but soluble in a solution of chitosan acid with deacetylation levels above 60%. On the contrary, chitin does not dissolve. Chitin and chitosan are insoluble in alkaline and organic solutions under normal conditions. In general, a high percentage of the amine (NH2 …
Design Features Of Ion Exchange Plant For Wastewater Treatment,
2025
Tashkent State Technical University, Tashkent city, Republic of Uzbekistan, https://orcid.org/0000-0002-1688-9073
Design Features Of Ion Exchange Plant For Wastewater Treatment, Tatyana Vladimirovna Drabkova, Sadritdin Makhamatdinovich Turabdzhanov, Fayzulla Nigmatullaevich Rakhmatullaev, Ulughukha Nusratullaevich Rakhmatov, Aziza Alimdzhanovna Shokhakimova
Technical science and innovation
This study presents an ion exchange unit designed for selective and comprehensive wastewater treatment. The unit includes all technological processes: solution filtration, ion exchanger loosening, sorbent regeneration and washing, which is a significant advantage of the proposed technology and eliminates the need for additional devices. This significantly increases the overall efficiency of the cleaning process, reducing costs and simplifying the operation of the system. Experimental studies have confirmed the high efficiency and feasibility of using ion exchange units in modern operating conditions, which makes them universal in application for various industries, including metallurgy and chemistry. The main idea of the …
Approach Formula To Increase Energy Efficiency Of Internal Combustion Engines In The “Green Economy” And Impact On The Natural Ecosystem,
2025
Tashkent State Technical University, Tashkent city, Republic of Uzbekistan, PhD, Associate Professor, https://orcid.org/0009-0006-3435-8774
Approach Formula To Increase Energy Efficiency Of Internal Combustion Engines In The “Green Economy” And Impact On The Natural Ecosystem, Zakirjon Ergashevich Musabekov, Hilola Zokir Qizi Uralova, Sayyodbek Ilxomjon O‘G‘Li Abdullajonov
Technical science and innovation
This article discusses, analyzes, and proposes solutions for the role of internal combustion engines in forming a "green economy", as well as ways to replace or modernize them. The relationship between internal combustion engines and the "green economy," as well as their energy efficiency and impact on natural ecosystems, is a crucial and urgent issue. These engines primarily generate energy through the combustion of petroleum-based fuels such as gasoline and diesel. However, this process releases harmful gases into the atmosphere, contributing to environmental degradation. The green economy is an economic model designed to protect the environment, ensure the efficient management …
Mechanical Cleaning Of Industrial Exhaust Gases By Wet Method.,
2025
Tashkent State Technical University, Tashkent city, Republic of Uzbekistan, https://orcid.org/0000-0003-3674-8881X
Mechanical Cleaning Of Industrial Exhaust Gases By Wet Method., A. A. Turgunov, E. A. Egamberdiev, R. F. Rashidov, A. A. Kholmurodov, D. J. Ergash
Technical science and innovation
Environmental protection is a priority area of human development. This paper presents the materials of scientific research of the creative group of the Tashkent State Technical University named after Islam Karimov, aimed at mineralization of the load on the environment, in particular on the atmospheric air of industrial enterprises. One of the more accessible solutions to this problem is the use of modern, more efficient devices for capturing and neutralizing exhaust gas emissions into the atmosphere from industry. Today, the use of mechanical methods for capturing pollutants is relevant due to the simplicity of design and operation. Wet methods for …
Modern Ir-Spectroscopic Methods For The Analysis Of Hydroxybenzene-Methanal Resin Obtained On The Basis Of 2,5-Furandion,
2025
Tashkent State Technical University, Tashkent city, Republic of Uzbekistan, https://orcid.org/0000-0002-1792-4774
Modern Ir-Spectroscopic Methods For The Analysis Of Hydroxybenzene-Methanal Resin Obtained On The Basis Of 2,5-Furandion, Sherali Anvarovich Umarov, Ravshan Israilovich Ismailov Ismailov
Technical science and innovation
The chemical changes occurring during the synthesis of hydroxybenzene-methanal resins obtained on the basis of 2,5-furandion under various ratios and temperature conditions were investigated using the IR spectroscopic method. Analysis of the compositional changes in the resin during the production of the thermoreactive resin revealed that the content of hydroxyl groups (~3300–3500 cm⁻¹) decreased, while the aldehyde groups (~1700–1750 cm⁻¹) increased; moreover, the presence of ether groups (~1050–1150 cm⁻¹) indicated that the process was successful. The synthesis of resins based on thermoreactive hydroxybenzene-methanal resins was carried out at high temperatures (70°C, 80°C, 95°C). During the identification of the functional groups …
Sorption-Spectroscopic Method For Determining Mn Ions In Wastewater,
2025
National University of Uzbekistan named after Mirzo Ulugbek, Tashkent city, Republic of Uzbekistan,DSc, Professor, https://orcid.org/0000-0003-3116-3518;
Sorption-Spectroscopic Method For Determining Mn Ions In Wastewater, Zulayho Asanalievna Smanova, Zukhra Ziyatovna Yakshieva, Nazira Kuchkarbayevna Madusmanova, Gulyorkhon Otkir Qizi Miradkhamova
Technical science and innovation
In this article, the processes of metal complex synthesis are studied in detail. Zinc OEDF+NTF complexation reactions were carried out in the presence of polyhydric alcohols, ethylene glycol, glycerol, and citric acid. For the first time, the synergistic efficiency of a mixture of zinc OEDF+NTF complexes with methyldiethanolamine, used as an inhibitor of mineral salt accumulation, was studied. It was found that when selecting the components in equivalent amounts, the inhibition efficiency of the composition is at least 90%. The high efficiency of inhibiting mineral salt accumulation in the composition is due to the presence of methyldiethanolamine, alkylimidazoline, and their …
The Influence Of Dispersed Fillers On The Mechanical Properties Of Sulfur Polymer Heterocomposites,
2025
University of Economics and Pedagogy, Karshi city, Republic of Uzbekistan, DSc, Associate Professor, https://orcid.org/0000-0003-3113-1962;
The Influence Of Dispersed Fillers On The Mechanical Properties Of Sulfur Polymer Heterocomposites, Erkin Abdukhafizovich Rakhmatov, Durdiymurad Gurbanovich Gadamov, Umida Alijonovna Ziyamukhamedova, Jasurbek Himmat Ugli Nafasov, Elbek Tukhtanazar Ugli Turgunaliev, Shokhjakhon Uktam Ugli Abdurakhimov
Technical science and innovation
This article discusses improving the physical, mechanical, and operational properties of composite materials modified with sulfur-containing plasticizers used in the modern construction industry. Furthermore, based on an in-depth analysis of the literature, the types and sizes of fillers and the significance of their mixing technology in the formation of a structure with low porosity of a composite material with a sulfur binder have been studied. The article thoroughly describes a method for obtaining a composite material with a stable sulfur-containing binder, the processes of preparing a solid filler, impregnating the filler with an organic modifier, humidifying and heating the filler …
Reweighting Configurations Generated By Transferable, Machine Learned Models For Protein Sidechain Backmapping,
2025
University of Arkansas, Fayetteville
Reweighting Configurations Generated By Transferable, Machine Learned Models For Protein Sidechain Backmapping, Jacob Monroe
Chemical Engineering Faculty Publications and Presentations
Multiscale modeling requires the linking of models at different levels of detail, with the goal of gaining accelerations from lower fidelity models while recovering fine details from higher resolution models. Communication across resolutions is particularly important in modeling soft matter, where tight couplings exist between molecular-level details and mesoscale structures. While multiscale modeling of biomolecules has become a critical component in exploring their structure and self-assembly, backmapping from coarse-grained to fine-grained, or atomistic, representations presents a challenge, despite recent advances through machine learning. A major hurdle, especially for strategies utilizing machine learning, is that backmappings can only approximately recover the …
Evaluating Coal-Jatropha Curcas Composite Briquettes As Sustainable Fuel Alternatives,
2025
Edith Cowan University
Evaluating Coal-Jatropha Curcas Composite Briquettes As Sustainable Fuel Alternatives, Amad Ullah Khan, Muhammad Saleem, Muhammad Abas, Zakir Ullah, Khan Muhammad, Farida Anjum, Aamer Sharif, Melkamu Tadesse Getachew
Research outputs 2022 to 2026
Coal is a major fuel source but raises environmental concerns. This study investigated the feasibility of utilizing a composite briquette sustainable fuel produced from subbituminous coal and Jatropha curcas biomass. Briquettes were prepared with varying weight ratios of coal to J. curcas biomass (90:0–0:90) using corn starch as a binder. The influence of this ratio on the briquettes’ properties was comprehensively evaluated through proximate analysis, ultimate analysis, scanning electron microscopy (SEM), and X-ray fluorescence (XRF) analysis. The results revealed that increasing the J. curcas content in the briquettes gradually decreased the moisture content, ash content, and fixed carbon content while …
Exploring The Impact Of Multiwall Carbon Nanotubes On Enhancing Water-Based Mud Performance,
2025
The British University in Egypt
Exploring The Impact Of Multiwall Carbon Nanotubes On Enhancing Water-Based Mud Performance, Attia Attia, Mohamed Saad Elhossieny Dr., Hesham Abuseda Dr., Ahmed Gouish Prof., Adel Salem Prof.
Petroleum Engineering and Gas
Drilling fluids are critical components in hydrocarbon and geothermal well construction, particularly in extreme downhole environments such as deep reservoirs and high-temperature geothermal systems. Key challenges in designing water-based drilling muds (WBDM) for these applications include effective thermal management, maintenance of rheological stability, and enhancement of thermal conductivity under high-temperature, high-pressure (HTHP) conditions. Recent advances in nanotechnology suggest that nanoscale additives, such as uniformly dispersed carbon nanotubes (CNTs), can significantly improve the thermorheological performance of drilling fluids compared to conventional formulations. However, stabilizing critical fluid properties—including viscosity, filtration efficiency, mud cake integrity, and gel strength—remains a persistent challenge in WBDM …
Scalable Mxene-Based Textile Supercapacitors,
2025
University of Nebraska-Lincoln
Scalable Mxene-Based Textile Supercapacitors, Abaigeal Aydt
Honors Program: Senior Projects (Public)
The demand for flexible and wearable energy storage devices for portable applications has led to the exploration of textile-based supercapacitors (TSCs). TSCs will allow for the creation of a new class of energy harvesting and storing technology directly into our clothing and will require using non-toxic and/or biocompatible materials. This will result in a greener and more sustainable path to address the challenges at the nexus of energy, mobility, and sustainability. To fabricate a TSC, a yarn made of fibers, such as wool or cotton, is coated with MXene flakes; MXenes are composed of transition metal carbides, nitrides, or carbonitrides …
In-Situ Density Measurement For Enhanced Electrorefining Material Accountancy,
2025
Brigham Young University - Provo
In-Situ Density Measurement For Enhanced Electrorefining Material Accountancy, Edward Mercado, Carlos Mejia, Ranon Fuller, Devin Rappleye
Student Works
To further enhance the proliferation resistance of electrorefining (ER) processes, precise and reliable analytical methods are essential for determining the inventory of fissile material. This can be achieved by electrochemically measuring the salt concentration and converting it to mass using its density. However, the density within the refiner is not fixed, and small variations in salt composition can significantly impact its thermophysical properties. While an ideal mixing model provides reasonable density estimates (with errors up to 2-3%), such errors are unacceptable when precise material accountancy of fissile material is crucial. This study developed a methodology to measure density in situ …
Rheological, Interfacial, And Filtration Behavior Of Lignocellulosic Nanomaterials In Suspension And Emulsion Drilling Fluids,
2025
Louisiana State University and Agricultural and Mechanical College
Rheological, Interfacial, And Filtration Behavior Of Lignocellulosic Nanomaterials In Suspension And Emulsion Drilling Fluids, Meen Sung Koo
LSU Doctoral Dissertations
In recent years, the rheological aspects of suspensions/emulsions applied by cellulose nanomaterials (CNMs) have been gained considerable interests due to high gel-forming properties ascribed by hydrophilicity, crystallinity, ease functionalization, and high aspect ratio. Introducing residual lignin in CNMs (LCNMs) seemed to be capable of achieving various advantages in the application of CNMs ascribed by hydrophobicity, binding effects, and abundant aromatic groups derived from complexity of lignin. This dissertation dedicates to the characterizations of (L)CNMs, and rheological properties of (L)CNMs applied fluids (i.e., suspension and emulsion). In the suspension system, the presence of lignin in LCNMs decreased gel strength, viscosity, and …
Improving The Stability And Selectivity Of Methane Dry Reforming Catalysis Through Active Site And Process Tuning,
2025
Louisiana State University and Agricultural and Mechanical College
Improving The Stability And Selectivity Of Methane Dry Reforming Catalysis Through Active Site And Process Tuning, Jonathan Lucas
LSU Doctoral Dissertations
Dry reforming of methane (DRM) is a potential industrial solution to greenhouse emissions whereby CH4 and CO2 are reacted on a transition metal catalyst to produce syngas, a feed stock for higher value chemical products. Ni can be used as the catalyst for DRM replacing the high cost and low abundance noble metals (Pt, Pd, Rh). However, the harsh process conditions of DRM (T > 700°C, P of 1-10 bar) readily deactivate Ni through coking and sintering. Ni supported on reducible oxides, specifically CeO2 and CeO2-ZrO2 (CZO), have been widely studied to combat the rapid …
A Comparison Of Unconventional Microwave And Ultrasound-Assisted Extraction Methods Used For Flavonoids,
2025
Department of Chemical Engineering, University of Jember, Jawa Timur 68121, Indonesia
A Comparison Of Unconventional Microwave And Ultrasound-Assisted Extraction Methods Used For Flavonoids, Istiqomah Rahmawati, Daffa Hafiziaulhaq Azizi, Jihan Nafila Wibowo, Muhammad Reza, Boy Arief Fachri, Bekti Palupi, Meta Fitri Rizkiana, Helda Wika Amini, Ifan Ramadana, Felix Arie Setiawan
Makara Journal of Science
Cocoa pods (Theobroma cacao L.) are a rich source of flavonoids, which are natural antioxidants known for their health benefits. This study investigated the use of microwave-assisted extraction (MAE) and ultrasound-assisted ex-traction (UAE) to extract the maximum flavonoids and antioxidants from cocoa pods. MAE and UAE are efficient and sustainable methods for extracting bioactive compounds like flavonoids and antioxidants from cocoa pods, offer-ing faster extraction, reduced solvent use, and better compound preservation compared to conventional methods. These technologies unlock the untapped potential of cocoa pods for applications in food, cosmetics, and pharmaceuti-cals. The effects of extraction time (2–10 min), microwave …
Analytical Electrochemistry Of Nickel, Platinum, And Platinum-Nickel Electrodepositions,
2025
University of New Mexico
Analytical Electrochemistry Of Nickel, Platinum, And Platinum-Nickel Electrodepositions, Kyle James Troche
Nanoscience and Microsystems ETDs
Nickel and platinum electrodeposits have numerous applications in corrosion and wear-resistant coatings, electronic connectors, heat resistance, metal finishings, and catalysts. The addition of additives can vastly change the morphology of the deposition. Electrokinetic parameters can be calculated by conducting rotating disk electrode (RDE) experiments along with Koutecky-Levich analysis. Significant challenges need to be addressed to deposit uniform films of Pt-Ni alloys from a single co-deposition bath. The main challenge is platinum’s catalytic property to reduce the overpotential for the hydrogen generation reaction. An Investigation into methanol and carbon monoxide’s hydrogen generation reaction suppression was conducted. Electrodeposition of nickel, platinum, and …
Flipping Out: Role Of Arginine In Hydrophobic Interactions And Biological Formulation Design,
2025
University of Minnesota
Flipping Out: Role Of Arginine In Hydrophobic Interactions And Biological Formulation Design, Jonathan W.P. Zajac, Praveen Muralikrishnan, Idris Tohidian, Xianci Zeng, Caryn L. Heldt, Sarah L. Perry, Et. Al.
Michigan Tech Publications
Arginine has been a mainstay in biological formulation development for decades. To date, the way arginine modulates protein stability has been widely studied and debated. Here, we employed a hydrophobic polymer to decouple hydrophobic effects from other interactions relevant to protein folding. While existing hypotheses for the effects of arginine can generally be categorized as either direct or indirect, our results indicate that direct and indirect mechanisms of arginine co-exist and oppose each other. At low concentrations, arginine was observed to stabilize hydrophobic polymer folding via a sidechain-dominated direct mechanism, while at high concentrations, arginine stabilized polymer folding via a …
