Chemical Engineering Commons^™

Polymers For Delivering A Substance Into A Cell, Kaushal Rege, Ravindra S. Kane, Steven M. Cramer, Sutapa Barua

Chemical and Biochemical Engineering Faculty Research & Creative Works

Disclosed herein are polymers that can be made cationic and used to deliver a substance into a cell. Also disclosed are pharmaceutical compositions comprising the polymers and methods of using the polymers.

Functionalization Of Gold Nanoparticles (Gnpss) Using The Isolate, Functionalize, And Release (Isofure) Methodology, David Spencer, Hariharasudhan D. Chirra, J. Zach Hilt

Kaleidoscope

No abstract provided.

Biocomaptibility Analysis And Cancer Therapy Applications Of Core-Shell Composite Magnetic Nanoparticles, Anastasia Kruse, Robert J. Wydra, J. Zach Hilt, Kimberly W. Anderson

Kaleidoscope

No abstract provided.

Investigation Of Spillover Effect To Enhance Hydrogen Storage, Sarah C. Corrigan, Lin Simpson, Thomas Gennett

STAR Program Research Presentations

Hydrogen is an attractive energy option because of its low
environmental impact, but a critical problem is its low energy
density, which makes it difficult to store. For example, the US
Department of Energy (DOE) hydrogen plan for fuel cell powered
vehicles requires a gravimetric density of 6.5 wt%. There are several
existing hydrogen storage methods, including compressed gas,
liquefaction, metal hydrides, and physisorption, but at present, none
of these technologies comes close to achieving the targets set by the
DOE. Although chemical storage methods have been claimed to be the
most promising hydrogen storage technology, and activated carbons the …

Fabrication And Characterization Of Thermomechanically Processed Sulfur And Boron Doped Amorphous Carbon Films, Lonnie Carlson

Department of Chemical and Biomolecular Engineering: Dissertations, Theses, and Student Research

Small scale, high power density, reliable, and long-life power supplies would be useful or even critical for space missions or the growing number of microdetectors, microsensors, and miniature vehicles. Alpha or beta particle voltaic devices could satisfy these requirements but have been shown to degrade quickly due to radiation damage. Amorphous carbon (a-C) PN junctions or PIN devices could provide radiation hardness and sufficiently high efficiency. As the range of alpha and beta particles in a-C is ~20-120μm, much thicker films than are typical are needed to maximize collection of the particle energy.

In this work, the fabrication of thermomechanically …

Did Mineral Surface Chemistry And Toxicity Contribute To Evolution Of Microbial Extracellular Polymeric Substances?, Jie Xu, Jay M. Campbell, Nianli Zhang, William J. Hickey, Nita Sahai

College of Polymer Science and Polymer Engineering

Modern ecological niches are teeming with an astonishing diversity of microbial life in biofilms closely associated with mineral surfaces, which highlights the remarkable success of microorganisms in conquering the challenges and capitalizing on the benefits presented by the mineral-water interface. Biofilm formation capability likely evolved on early Earth because biofilms provide crucial cell survival functions. The potential toxicity of mineral surfaces toward cells and the complexities of the mineral-water-cell interface in determining the toxicity mechanisms, however, have not been fully appreciated. Here, we report a previously unrecognized role for extracellular polymeric substances (EPS), which form biofilms in shielding cells against …

Fabrication Of Printed Substrate For Surface Enhanced Raman Spectroscopy, Ali Eshkeiti

Masters Theses

A novel surface enhanced Raman spectroscopy (SERS) substrate was successfully fabricated on a silicon wafer using inkjet printing and on polyethylene terephthalate (PET) using gravure printing. Silver (Ag) nanoparticle (NP) based ink, was used for roughening of the surface of silicon and PET. A thickness of 400 nm was measured for the printed Ag NP printed film on silicon and the thickness of the single and double layered films on PET were measured as 340 nm and 680 nm, respectively by using vertical scanning interferometry. The Ag NP printed SERS substrate was tested for application with heavy metal compounds like …

Characterization And Quantification Of Monomers, Oligomers, And By-Products From Xylan During Biomass Pretreatment, Ching-Shuan Lau

Graduate Theses and Dissertations

Biomass pretreatment generates inhibitory products, which reduce the overall yield of xylose for ethanol production. Understanding of hemicellulose depolymerization into xylose is essential to identify the pretreatment conditions that maximize xylose formation, but minimize the generation of these inhibitory products, such as formic acid and furfural. Thus, the goal of this project is to understand how dilute acid pretreatment parameters affect hemicellulose depolymerization, maximize xylose concentrations, and minimize by-products formation.

To progress towards this goal, rates and mechanisms of hemicellulose release must be determined. Birchwood xylan was used as the starting material to produce xylose oligomers. The hydrolyzed birchwood xylan …

An Experimental Study On Thermal Stability Of Biodiesel Fuel, Yiying Zhu

Biomedical and Chemical Engineering – Theses

Biodiesel fuel, as renewable energy, has been used in conventional diesel engines in pure form or as biodiesel/diesel blends for many years. However, thermal stability of biodiesel and biodiesel/diesel blends has been minimally explored. Aimed to shorten this gap, thermal stability of biodiesel is investigated at high temperatures.

In this study, batch thermal stressing experiments of biodiesel fuel were performed in stainless steel coils at specific temperature and residence time range from 250 to 425 °C and 3 to 63 minutes, respectively.

Evidence of different pathways of biodiesel fuel degradation is demonstrated chromatographically. It was found that biodiesel was stable …

En Route Towards Α-Benzotriazoyl Nitroso Derivatives, Jean-Christophe M. Monbaliu, Lucas K. Beagle, Judit K. Beagle, Matthias Zeller, Christian V. Stevens, Alan R. Katritzky

Chemistry Faculty Publications

A new class of geminally-substituted nitroso compounds, i.e., α-benzotriazoyl nitroso derivatives, is presented. These compounds display a rather different behavior than other related nitroso compounds bearing a geminal electron-withdrawing group. An unexpected and spontaneous oxidation to the nitro analog is observed in solution.

Micro Hydroelectric Power Generation, Roberto Arraya Saenz

Chemical Engineering Undergraduate Honors Theses

MICRO-HYDRO ELECTRIC POWER GENERATION Roberto Arraya Department of Chemical Engineering – Honors Thesis ABSTRACT A major industrial water user in New Mexico discharges approximately 3.8 million gal of wastewater per day. The topology of the site provides an elevation difference of about 150 ft between the plant site and the entrance to the municipal sewage line; this flow and elevation difference is sufficient to produce about 40 kW of electrical power using a water turbine/electrical generator set to extract power from the flowing stream. This report includes designs and economic analyses for two distinct cases. One case is based on …

The Influence Of Coating Structure On Sheet-Fed Offset Ink Setting Rates, Ting Chen

Masters Theses

Much attention has been paid to the study of quickset ink setting as a complex ink-coating interaction. Offset ink setting rates are typically measured as ink splitting forces versus time and the slope of the regression line obtained from a plot of these measured values is reported, but scant attention has been paid to the deviations from that straight line. An initial slow ink setting rate is desired to minimize back-trap mottle, carryover picking and piling and enhance ink gloss; then a faster ink setting rate during sheet delivery to the pile is desired to reduce the likelihood of ink …

Adsorption Kinetics Of Pb(Ii) And Zn(Ii) Ions Unto Carbonized Groundnut Shells And Maize Cobs, Leke Luter, Aboi Julius, Henry T. Dekaa, B. A. Ikyenge, Ande Sesugh, Monday Uchenna Okoronkwo

Chemical and Biochemical Engineering Faculty Research & Creative Works

Maize cobs and groundnut shell adsorbents from agricultural by-products were carbonized and investigated for adsorption of two selected metals, Lead (Pb II) and Zinc (Zn II) from aqueous solutions of these metals. Kinetic studies of the adsorption processes were investigated employing Elovich and the intraparticle diffussion models. The results showed that, the adsorption capacities of these comparatively cheaper adsorbents and their efficiency for the removal of Pb(II) and Zn(II) ions from aqueous solution present them suitable for use in place of the costly commercial activated carbons.

Gallium Containing Glass Polyalkenoate Anti-Cancerous Bone Cements: Glass Characterization And Physical Properties, A. W. Wren, A. Coughlan, L. Placek, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

A gallium (Ga) glass series (0.48SiO₂-0.40ZnO-0.12CaO, with 0.08 mol% substitution for ZnO) was developed to formulate a Ga-containing Glass Polyalkenoate Cement (GPC) series. Network connectivity (NC) and X-ray Photoelectron Spectroscopy (XPS) was employed to investigate the role of Ga³⁺ in the glass, where it is assumed to act as a network modifier. Ga-GPC series was formulated with E9 and E11 polyacrylic acid (PAA) at 50, 55 and 60 wt% additions. E11 working times (T_w) ranged from 68 to 96 s (Lcon.) and 106 s for the Ga-GPCs (LGa-1 and LGa-2). Setting times (T_s) …

Experimental Composite Guidance Conduits For Peripheral Nerve Repair: An Evaluation Of Ion Release, X. F. Zhang, A. Coughlan, H. O'Shea, Mark R. Towler, S. Kehoe, D. Boyd

Chemical and Biochemical Engineering Faculty Research & Creative Works

Poly (lactide-co-glycolide) (PLGA) - Pluronic F127 - glass composites have demonstrated excellent potential, from the perspective of controlled mechanical properties and cytocompatibility, for peripheral nerve regeneration. In addition to controlling the mechanical properties and cytotoxicity for such composite devices, the glass component may mediate specific responses upon implantation via degradation in the physiological environment and release of constituent elements. However, research focused on quantifying the release levels of such therapeutic ions from these experimental medical devices has been limited. To redress the balance, this paper explores the ion release profiles for Si⁴⁺, Ca²⁺, Na⁺, …

Determining The Operation Limits Of Two Distillation Columns, Murat Ozkaya

Masters Theses and Doctoral Dissertations

The two distillation columns of Wacker Institute pilot plant at the Chattanooga State Community College are investigated for stable operating regions, flooding phenomena that occurs in the bubble-cap tray distillation column, weeping phenomena that occurs in the sieve tray distillation column, and comparison of operation between the two distillation columns. With the use of a distributed control system (DCS) and glass equipment in the pilot plant, these phenomena are analyzed visually and with the help of instrumentation readings. The energy usage and production limits of both distillation columns are discussed. The flooding of bubble-cap trays occur before reaching production goals …

The Reduction Of Glycerol Flow In A Porous Medium Through A Barrier Coating Application, Thomas Tran

Masters Theses

Coatings for paper are categorized into two groups: pigmented or functional. Functional coatings provide functionality in addition to the normal coating properties. Functional coatings can be used for friction control, release properties, abrasion resistance, and barrier properties. A coating that is designed to control barrier properties can be categorized into a sub-group of functional coatings called barrier coatings.

Barrier coatings can retard or eliminate the flow of fluids thru a coated substrate. The barrier can be effective in repelling or resisting the transmission rate of numerous fluids including moisture, oil, oxygen, grease, and glycerol. Barrier coatings have many useful applications …

Enzyme Actuated Bioresponsive Hydrogels, Andrew Wilson

All Theses

Bioresponsive hydrogels are emerging with technological significance in targeted drug delivery, biosensors and regenerative medicine. Conferred with the ability to respond to specific biologically derived stimuli, the design challenge is in effectively linking the conferred biospecificity with an engineered response tailored to the needs of a particular application. Moreover, the fundamental phenomena governing the response must support an appropriate dynamic range and limit of detection. The design of these systems is inherently complicated due to the high interdependency of the governing phenomena that guide the sensing, transduction, and the actuation response of hydrogels. To investigate the dynamics of these materials, …

Microstructural And Mechanical Characterization Of Soy-Based Polyethylene Fibers, Ozgun Ozdemir

All Theses

Bio-composite fibers have attracted increasing attention from environmentally-conscious consumers because of their low cost and biodegradability. Soy protein isolates and other purified forms have been proposed as bio-based substitutes for pure synthetic polymers for use in textiles. However, fibers from pure soy proteins do not possess adequate properties for use as textile fibers. Therefore, this research aimed to investigate composite fibers consisting of soy and polyethylene for their microstructure and mechanical properties. Changes in properties with increasing filler content and long-term properties of fibers were systematically examined.
First, the microstructure of the fibers was investigated by optical analysis. Six different …

Inkjet Printability Of Electronic Materials Important To The Manufacture Of Fully Printed Otfts, Sooman Lim

Dissertations

In this study, the inkjet printability of materials important to fabricating OTFTs was researched. In order to understand the jetting evolution of inkjet printed inks, simulations were performed with a nano copper and nano particle silver ink. To predict the inkjettability of the nano copper ink, Z and Oh numbers at different temperatures were determined. The results from the simulation studies were compared to experimental results obtained using a Dimatix inkjet printer. For the semiconductor ink, the inkjet printability of two organic semiconductors, P2TDC17FT4 (poly[(3,7-diheptadecylthieno[3,2-b]thieno[2',3':4,5]thieno[2,3-d]thiophene-2,6-diyl)[2,2'-bithiophene]-5,5'-diyl] dissolved in 1,2-dichlorobenzene and P3HT (poly-3 hexylthiophene) were compared to determine the relationship between drop …