Chemical Engineering Commons^™

Energy Systems Analysis For A Solar Economy, Dharik Sanchan Mallapragada

Open Access Dissertations

The use of solar energy for human needs faces challenges owing to its relatively low energy intensity and intermittent availability, coupled with the constrained availability of renewable carbon and land resources. This study uses systems analysis tools to identify carbon and energy efficient transformations of solar energy for different purposes, including transportation fuels and grid-scale energy storage. These efforts have been complemented with a feasibility analysis of existing fossil-energy and other hybrid pathways.

In an era of limited fossil resources, liquid fuels from sustainably available (SA) biomass could meet the energy needs of the transportation sector. We present a method …

Spectroscopic And Kinetic Study Of Copper-Exchanged Zeolites For The Selective Catalytic Reduction Of Nox With Ammonia, Shane Adam Bates

Open Access Dissertations

The recent application of metal-exchanged, small-pore zeolites for use in the selective catalytic reduction (SCR) of NO_x with ammonia NH₃ for automotive deNO_x applications has been a great stride in achieving emission standard goals. Copper-exchanged SSZ-13 (Cu-SSZ-13), the small-pore zeolite in this study, has been shown to be very hydrothermally stable and active under conditions presented in the exhaust of the lean-burn diesel engine. In this work, detailed studies were performed to identify many aspects of the active site(s) in Cu-SSZ-13 in order to learn about the standard SCR mechanism.

A series of seven Cu-SSZ-13 samples were …

Atomic Level Study Of Water-Gas Shift Catalysts Via Transmission Electron Microscopy And X-Ray Spectroscopy, Mehmed Cem Akatay

Open Access Dissertations

Water-gas shift (WGS), CO + H₂ O [Special characters omitted.] CO₂ + H₂ (ΔH° = -41 kJ mol ^-1 ), is an industrially important reaction for the production of high purity hydrogen. Commercial Cu/ZnO/Al₂ O₃ catalystsare employed to accelerate this reaction, yet these catalysts suffer from certain drawbacks, including costly regeneration processes and sulfur poisoning. Extensive research is focused on developing new catalysts to replace the current technology. Supported noble metals stand out as promising candidates, yet comprise intricate nanostructures complicating the understanding of their working mechanism.

In this study, the structure of the supported …

Gas Barrier And Mechanical Properties Of Crosslinked Ethylene Vinyl Acetate Nanocomposites, S. A. Ahmad Ramazani, M. Shafiee, Hossein Abedsoltan, A. Shafiee

Chemical and Biochemical Engineering Faculty Research & Creative Works

In this research, the effects of crosslinking agent and clay content on the morphology, barrier and mechanical properties of ethylene vinyl acetate-organoclay nanocomposites prepared by solution method were studied. Dicumyl peroxide has been used as crosslinking agent. The morphology of the prepared nanocomposites was investigated using wide-angle X-ray diffraction and transmission electron microscopy. Wide-angle X-ray diffraction and transmission electron microscopy indicated that the prepared nanocomposites had predominantly intercalated morphologies. The obtained results of permeability tests showed that the permeability of ethylene vinyl acetate films dramatically decreases with addition of organoclay and dicumyl peroxide. Mechanical tests showed that tensile modulus and …

The Biological Impact Of Concurrent Exposure To Metallic Nanoparticles And A Static Magnetic Field, Kristen K. Comfort, Elizabeth I. Maurer, Saber M. Hussain

Chemical and Materials Engineering Faculty Publications

The rapid advancement of technology has led to an exponential increase of both nanomaterial and magnetic field utilization in applications spanning a variety of sectors. While extensive work has focused on the impact of these two variables on biological systems independently, the existence of any synergistic effects following concurrent exposure has yet to be investigated. This study sought to ascertain the induced alterations to the stress and proliferation responses of the human adult low calcium, high temperature keratinocyte (HaCaT) cell line by the application of a static magnetic field (approximately 0.5 or 30 mT) in conjunction with either gold or …

Molecular Dynamics At Constant Pressure: Allowing The System To Control Volume Fluctuations Via A “Shell” Particle, Mark J. Uline, David S. Corti

School of Chemical Engineering Faculty Publications

Since most experimental observations are performed at constant temperature and pressure, the isothermal-isobaric (NPT) ensemble has been widely used in molecular simulations. Nevertheless, the NPT ensemble has only recently been placed on a rigorous foundation. The proper formulation of the NPT ensemble requires a “shell” particle to uniquely identify the volume of the system, thereby avoiding the redundant counting of configurations. Here, we review our recent work in incorporating a shell particle into molecular dynamics simulation algorithms to generate the correct NPT ensemble averages. Unlike previous methods, a piston of unknown mass is no longer needed to control …

Heats Of Combustion For Four Utah Leaf Species, Megan M. Woodhouse, Dr. Thomas Fletcher

Journal of Undergraduate Research

Empirical models have been developed to predict the spread of forest fire models from data about the burning plant species, terrain, and wind conditions. Over the past three years, a research group at Brigham Young University has collected data for ignition temperatures and time to ignition for eight leaf species involved in wildland fires. Four of these species are found in the Southern California chaparral, while the four other species are found in Utah. To further improve the fire models it is desirable to know the heats of combustion for each of the different leaf species. Heats of combustion can …

Characterization Of Variables In Electrical Killing Of Bacteria: Voltage And Current Geometry, Taylor Turner, Dr. William Pitt

Journal of Undergraduate Research

As part of a constant pursuit of better health researchers continuously investigate the role of bacteria in disease and infection. Much research today investigates methods for effectively killing unwanted bacteria in the body. Modern antibiotic medications are the most effective method of accomplishing this, but they have their limits. One particular limit of today’s antibiotics is the ability to eliminate biofilms. Biofilms consist of many layers of bacterial cells growing on top of each other, typically attached to a solid surface. Antibiotics cannot penetrate the layers of biofilms, leaving the lower bacteria untouched after treatment. This problem led us to …

Evaluation Of Three Chemical Coatings On Biomaterial Induced Thromboembolism, Joseph Flinders, Dr. Kenneth Solen

Journal of Undergraduate Research

When blood contacts man-made biomaterials such as those used in artificial organs (e.g. hemodialyzers, oxygenators, etc.) a chain of events occurs that can lead to medical complications as serious as a stroke. These events include proteins (particularly fibrinogen) adhering to the biomaterial’s surface, the accumulation of blood platelets on the fibrinogen to form “Thrombi”, and then the dislodging of the thrombi to form particles (microemboli) that can block downstream arteries or capillaries causing a “stroke” or other cardiovascular event.

Antibody-Conjugated Polymeric Micelles That Attach To Specific Cancer Cells, Douglas S. Lewis, Dr. William G. Pitt

Journal of Undergraduate Research

In the past decade, many efforts have been made to improve chemotherapeutic treatments for cancer patients. One of the specific efforts seeks to actively deliver anti-cancer drugs to the target tissue rendering the chemotherapy more efficient and less damaging to nearby uninfected cells.

Hypothermia-Induced Platelet Aggregation And Fibrinogen Functionality, Adam Broderick, Dr. Ken Solen

Journal of Undergraduate Research

Hypothermia-Induced Platelet Aggregation (HIPA) may pose a significant risk for patients undergoing some surgical procedures. During heart surgery, a patient’s core temperature is typically lowered to reduce tissue damage. Hall et al. (2002) observed that this caused blood platelet aggregation in ~30% of test subjects1 and increases post-operative neurological impairment after hypothermic coronary bypass surgery, possibly through occlusion of small blood vessels by platelet aggregates.2

Quantifying The Relationship Between Platelet Activity And Blood-Materials Interactions, Kenneth Solen

Journal of Undergraduate Research

In clinical practice, variations among patients in the degree of blood-material interaction are evidenced in the fact that physicians have long sought for ways to provide patient-specific treatment1. No clinical screening yet exists to test the level of interaction expected from a given patient. My research attempted to test the hypothesis that a correlation exists between platelet function and blood-material interaction.

Stabilizing Nanostructured Solid Oxide Fuel Cell Cathode With Atomic Layer Deposition, Yunhui Gong, Diego Palacio, Xueyan Song, Rajankumar L. Patel, Xinhua Liang

Chemical and Biochemical Engineering Faculty Research & Creative Works

We demonstrate that the highly active but unstable nanostructured intermediate-temperature solid oxide fuel cell cathode, La_0.6Sr_0.4CoO_3-δ (LSCo), can retain its high oxygen reduction reaction (ORR) activity with exceptional stability for 4000 h at 700 C by overcoating its surfaces with a conformal layer of nanoscale ZrO₂ films through atomic layer deposition (ALD). The benefits from the presence of the nanoscale ALD-ZrO₂ overcoats are remarkable: a factor of 19 and 18 reduction in polarization area-specific resistance and degradation rate over the pristine sample, respectively. The unique multifunctionality of the ALD-derived nanoscaled ZrO₂ overcoats, …

Synthesis Of A Polymeric Micelle That Can Target And Attach To Specific Tissues, Douglas S. Lewis, Dr. William Pitt

Journal of Undergraduate Research

In the past decade, many efforts have been made to improve chemotherapeutic treatments for cancer patients. One of the specific efforts seeks to actively deliver anti-cancer drugs to the target tissue rendering the chemotherapy more efficient and less damaging to nearby uninfected cells.

Peo-Ppo-Pla: An Anti-Cancer Drug Carrier Subtitle (If Applicable), James Lattin, Dr. William Pitt

Journal of Undergraduate Research

For over a decade ultrasound enhanced drug delivery systems have been under development. These systems often use polymeric molecules that form micelles. In aqueous solutions (such as blood), a spherical micelle is formed as the hydrophilic ends of the molecules interact with the solution and the hydrophobic ends are pushed to the inside of the sphere where they can interact with each other.

Tumor Drug Concentration Due To Ultrasonic Drug Delivery, Bryant Staples, Dr. William Pitt

Journal of Undergraduate Research

The tri-block copolymer, Pluronic P105, has been found to be an ideal ultrasonically activated drug delivery vehicle because it forms micelles with hydrophobic polypropylene oxide cores that sequester hydrophobic drugs (Fig. 1). These micelles release their contents upon the application of low frequency ultrasound [1] such that drugs can be released specifically at the ultrasonicated region (Fig. 2). Such ultrasonically controlled release has been effective against cancer cells in vitro [2] and in vivo [3].

Effect Of Water Concentration During Polymerization Of A Hydrogel On Swelling And Mechanical Properties, Justin J. Baker, Dr. William Pitt

Journal of Undergraduate Research

Hydrogels are polymers that absorb water and thus swell in the presence of water and/or body fluids. Hydrogels have been used in many drug-delivery and medical applications.1 One such application is to apply a thin coating of a hydrogel to the outer surface of a hearing aid to eliminate acoustic feedback. Acoustic feedback is the high-pitched squeal caused by an incomplete seal between the hearing aid and the surface of the ear canal. This incomplete seal allows amplified sound to escape and be re-amplified by the hearing aid. By coating a hearing aid with a hydrogel, the humidity and oils …

Bioremediation Of Contaminated Groundwater Development Of Bio-Wall Technology, Lyn Bobincheck, Dr. W. Vincent Wilding

Journal of Undergraduate Research

Contaminated groundwater results from uncontrolled release of wastes such as fuel and industrial solvents. This contamination is cleaned up through several methods including bioremediation. Current methods of bioremediation include traditional pump and treat, bioventing, and bio-walls. Bio-walls are a new, promising technology described by several researchers.1,2 The purpose of this research was to determine the state of the art bio-wall technology, and to present a bio-wall design which optimizes necessary parameters for bioremediation.

Correlating Thomboembolism To Individual Platelet Aggregation Rate, Luke Werrett, Dr. Kenneth Solen

Journal of Undergraduate Research

The objective of this research project was to identify a correlation between a traditional platelet activity test using an aggregometer, and a new test that measures interactions between blood and man-made materials in a simulated blood flow environment. A correlation between these data would give artificial organ recipients and open-heart surgery candidates a more thorough risk analysis of their situation, and indicate the need for caution or additional medication.

The Mechanism Of Gravity Induced, Counter-Current Flow Of Oil And Water In Porous Beds, Kari Cook, Dr. Hugh Hales

Journal of Undergraduate Research

Computerized simulation of the flow in underground petroleum reservoirs is widely used by oil companies to optimize the production of oil and gas. Such simulations are known in the Industry as “reservoir simulation”. They are based on Darcy’s Law, smoothly varying flow potentials, and the assumption that all phases move uniformly through the pore spaces. It seems possible that at low flow rates, such as those resulting when gravitational forces predominate, a different mechanism applies. The more dense phases may move downward in some pores, while the lighter fluids move upward through others. This would result in much more rapid …