Chemical Engineering Commons^™

Microgrid Development Using A Grid Tie Inverter, Hartono Budi Santoso, Budiyanto Budiyanto

Makara Journal of Technology

The use of renewable energy sources (RES), especially photovoltaic (PV), to meet the demand of electrical energy has been getting a great deal of attention as an alternative solution to electrical energy deficit problems. RES are being applied in power systems in a variety of configurations including microgrid systems. One of the characteristics of a microgrid is capability to supplying power to grid when there is an excess power to supply local load. This research examines the chances of saving power consumption from grid using power converters grid tie inverter (GTI) in a microgrid configuration. The test is done by …

Surface Treatment Of Fly Ash For Improving The Tensile Strength Of Fly Ash/Unsaturated Polyester Composites, Sugiman Sugiman, Paryanto Dwi Setyawan

Makara Journal of Technology

The paper presents the surface treatment of fly ashes using acid and alkali solution on the tensile strength of the fly ash/unsaturated polyester (UP) composites. Sulfuric acid (H2SO4), hydrofluoric acid (HF) and sodium hydroxide (NaOH) solution with concentration of 0%, 5%, 10%, 15%, and 20% (by weight) were used for surface treatment of fly ashes. Generally, the tensile strength of the treated fly-ash/UP composites shows a significant increase compared to the untreated fly ash. Of all surface treatments studied, the optimum tensile strength was obtained at a concentration of 10%. At this concentration, at a fly ash content of 30% …

Recycling Roof Tile Waste Material For Wall Cover Tiles, Ambar Mulyono, Silfia Mona Aryani, Joko Lulut

Makara Journal of Technology

Prior research on roof tile waste treatment has attempted to find the appropriate technology to reuse old roof tile waste by create wall cladding materials from it. Through exploration and experimentation, a treatment method has been discovered to transform the tile fragments into artificial stone that resembles the shape of coral. This baked clay artificial stone material is then processed as a decorative element for vertical surfaces that are not load-bearing, such as on the interior and exterior walls of a building. Before applying the fragments as wall tiles, several steps must be taken: 1) Blunting, which changes the look …

Semiconductor Thermal Neutron Detector, Toru Aoki, Aki Miyake, Takayuki Nakano, Akifumi Koike, Hisashi Morii, Hidenori Mimura

Makara Journal of Technology

The CdTe and GaN detector with a Gd converter have been developed and investigated as a neutron detector for neutron imaging. The fabricated Gd/CdTe detector with the 25 mm thick Gd was designed on the basis of simulation results of thermal neutron detection efficiency and spatial resolution. The Gd/CdTe detector shows the detection of neutron capture gamma ray emission in the 155Gd(n, g)156Gd, 157Gd(n, g)158Gd and 113Cd(n, g)114Cd reactions and characteristic X-ray emissions due to conversion-electrons generated inside the Gd film. The observed efficient thermal neutron detection with the Gd/CdTe detector shows its promise in neutron radiography application. Moreover, a …

Minimal Medium For Optimal Growth And Lipid Production Of The Microalgae Scenedesmus Dimorphus, Colin Welter, Jacob Schwenk, Bahar Kanani, John Van Blargan, Joanne M. Belovich

Chemical & Biomedical Engineering Faculty Publications

The culture of Scenedesmus dimorphus at the laboratory scale has often been in standard microalgae media, such as 3N-Basal Bold medium (3N-BB), which contains 15 different chemicals. Given the extremely tight profit margins of large-scale production of biofuel from microalgae, it is important to identify the minimally sufficient quantities of nutrients necessary to maximize lipid productivity. The individual and interactive effects of six groupings of the components of 3N-BB medium on growth rate, lipid content, and total biomass yield of S. dimorphus were determined. Trace metal and vitamin concentrations were reduced to 1/6 the level of 3N-BB medium without adversely …

Sulfonated Perfluorocyclobutyl (Pfcb) Aryl Ether Polymers: Synthesis, Reactivity, And Characterization For Polymer Electrolyte Applications, Jiyoung Park

All Dissertations

Perfluorocyclobutyl (PFCB) aryl ether copolymers are excellent candidates for proton exchange membrane (PEM) component in PEM fuel cells. Sulfonated PFCB copolymer membranes exhibit not only high chemical/thermal/mechanical stability but also high proton conductivity. In this regard, PFCB aryl ether copolymers were synthesized via thermal step-growth [2 + 2] cyclopolymerization from aryl bis-(trifluorovinyl ether) (TFVE) monomers and oligomers. Experimental and computational studies confirmed that copolymerization of relatively electron-rich and electron-poor TFVE monomers gave selective-segmented copolymers in an one-pot polymerization. After sulfonation, the PFCB copolymers comprising hydrophilic and hydrophobic segments gave membranes with high proton conductivity. Cross-linked membranes of the sulfonated PFCB …

Gas Composition Analysis Using Limited Production Data Eagle Ford Case Study, Ryckur K. Shuttler

Honors Capstones

No abstract provided.

Synthesis Of Ferrocene Copolymers And Investigation Of Their Electrochemical Properties., Alzharani Ahmed

Electronic Theses & Dissertations

Ferrocene is an organometallic compound. It is a classical metallocene consisting of two cyclopentadienyl rings bound on opposite sides of a central iron atom. Such organometallic compounds are also called sandwich compounds. Ferrocene copolymers have well known electrochemical capabilities. The main objective of this thesis is to synthesize vinyl ferrocene copolymers and test their electrochemical properties in aqueous solutions with different electrolytes (sodium nitrate, sodium perchlorate, and phosphate buffered saline). Vinylferrocene and 3-phenyl[5]ferrocenophane-1,5- dimethylene were synthesized using a Wittig reaction. Both ferrocene monomers were copolymerized with N-ethylmaleimide and N-phenylmaleimide and the resulting polymers were analyzed by Gel Permeation chromatography, IR …

Structural Characterization Of Super-Acid Oligomerized Fatty Esters., Esam Allehyani

Electronic Theses & Dissertations

Fatty acid methyl esters can be oligomerized with very strong acid catalysts - superacids such as tetrafluoroboric or triflic acid with formation of dimer and trimer fatty acids at much lower temperature, such as 80-90 °C, than what is used presently. Insight into the reaction of polymerization of fatty esters/ acids can be obtained by structural characterization. This would determine the properties of the oligomeric products and their ability to substitute currently used materials. It was presumed that dimer fatty, trimer fatty acid esters, and oligomeric fatty acid esters are produced by polymerization of fatty acid methyl esters by a …

Formulation And Evaluation Of Resistive Inks For Applications In Printed Electronics, Sughosh Satish Bhore

Masters Theses

In the 21^st century, it has been shown that printing methodologies can be used to print electrically functional devices on a variety of substrates. In comparison to conventional electronic manufacturing methods, printing is a more cost effective and less complex process. The requirements for manufacturing Printed Electronics (PE) components are much more demanding than graphic printing applications due to the additional requirement of easy electron flow. This additional requirement increases the need for print uniformity and layer-to-layer registration to a much higher degree. In this work, hybrid UV-curable, water-based, electrical resistive inks were formulated. Inkjet inks were prepared by …

Manufacturing The Next Generation Of Vaccines: Non-Egg Based Platform For Influenza Vaccine, Andrew B. Price

Chemical Engineering Undergraduate Honors Theses

This report explores the design of an influenza vaccine manufacturing facility using a non-egg based expression platform. The current standard procedure in flu vaccine production is to grow the virus in bird eggs. However, recently there is evidence that supports production by other expression platforms. The Sf9 insect cell is considered in this report. Facility design including cell culture media formulation through product storage for shipment and final formulation is considered based on the use of an existing facility. The new design also employs the use of disposable equipment such as bioreactors and purification unit operations. These disposables help reduce …

Fuctional Properties Of Phthalocyanine Dye Based Inks, Yumeizhi Jia

Masters Theses

Currently, inkjet printing techniques are getting more attention. They have the features of non-contact and additive patterning feasibility, compatibility with different substrates (the materials on which the ink is printed), low temperature processing, and low cost (1) (2). They can be used for patterning solution processable polymers or nanoparticle inks on various substrates including conductive materials, paper and glass (3). The need for proper functional inks is increasing every year. The goal of my work was to formulate a phthalocyanine water based ink, which can work as a dielectric ink. In my research, all the materials which were used to …

Investigation Of Recycled Paper Deinking Mechanisms, Veronika Husovska

Dissertations

The use of water-based inks is on the rise. Sub-micron pigment particles are used for flexographic and inkjet water-based inks. Conventional deinking eliminates larger particles than those from these new ink systems. Therefore, water-based inks represent recycling difficulty.

Deinking experiments of water-based inks are carried out. The deinking strategy initially investigated elimination of pressure sensitive adhesive due to similar acrylic polymer chemistry used in water based inks. The impact of pH on stickies and ink agglomeration during deinking is studied. Experiments in acidic regions show growth of acrylic inks and stickies agglomerates, simplifying elimination.

Pre-recycling of water-based inks is explored. …

Characteristics Of Glass Ionomer Cements Composed Of Glass Powders In Cao-Sro-Zno-Sio2 System Prepared By Two Different Synthetic Routes, Ill Yong Kim, Chikara Ohtsuki, Aisling Coughlan, Lana Placek, Anthony W. Wren, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

Glass ionomer cements (GICs) are composed of an acid degradable glass, polyacrylic acid and water. Sol-gel processing to prepare the glass phase has certain advantages, such as the ability to employ lower synthesis temperatures than melt quenching and glasses that are reported to have higher purity. A previous study reported the effects of glass synthesis route on GIC fabrication. However, in that study, the sol-gel derived glass exhibited a reduced concentration of cations. This study investigates increasing the cation content of a sol-gel derived glass, 12CaO·4SrO·36ZnO·48SiO₂ (molar ratio) by heating before aging to reduce dissolution of cations. This glass …

Reassessment Of Biowish Activation Procedure For Denitrification, William Wah Yee

Master's Theses

BiOWiSH^TM – Aqua is a blend of preserved multi-bacteria culture with the capability of denitrification. If an anaerobic nitrate rich activation procedure is used instead of the standard aerobic activation procedure, the denitrification rate is increased by 28 percent under the conditions of 30°C, 1C:1N, 200mg/L of carbon, and 200mg/L nitrogen.

Uv-Assisted Stabilization Of Polyacrylonitrile-Based Carbon Fiber Precursors, Marlon Salvador Morales Sandoval

All Dissertations

Due to their high strength and stiffness coupled with low density, carbon fibers are the preferred reinforcing fibers used in high-performance polymer matrix composites. Consequently, the demand for carbon fibers is expected to grow from 40,000 metric tons to about 150,000 metric tons over the next decade. A large fraction of the increase is anticipated in the industrial sector that is cost-sensitive. Therefore, there is a need for the development of novel processes and precursors to reduce the carbon fiber production cost and expand the use of carbon fibers. This research focuses on the development of an alternative, rapid stabilization …

Structure, Rheology And Optical Properties Of Plasmonic Fluids, Tao Cong

Dissertations - ALL

Fluids with tunable optical and rheological properties are of fundamental and practical interest. They can be easily processed to manufacture thin films and interfaces for applications such as molecular detection and light trapping in photovoltaics. Cationic surfactants such as cetyl-trimethylammonium bromide have the ability to self assemble with metallic nanoparticles to form a corona or a double-layer vesicular structure. These structures upon further interaction with wormlike micelle fragments are hypothesized to form micelle-nanoparticle elastic networks. In this dissertation, solution phase self-assembly is utilized to uniformly distribute various metallic nanoparticles to produce stable multicomponent plasmonic fluids with remarkable color uniformity. The …

Pyrene Oligomers: Their Isolation, Molecular Characterization, And Phase Behavior, David Esguerra Taborda

All Dissertations

Carbonaceous pitches can serve as attractive precursors for advanced carbon materials such as high thermal conductivity fibers or carbon-carbon composites. Yet the effects of composition and molecular structure on the bulk properties (e.g., mesophase content and melting point) of these precursors remain only partly known, mainly because of the difficulties associated with the isolation, identification, and quantification of the large (i.e., molecular weight (mol wt) > 350-400 Da) polycyclic aromatic hydrocarbon (PAH) oligomers comprising these pitches. In this study, oligomeric fractions were isolated via supercritical extraction (SCE) from two representative pitches: a petroleum pitch (M-50) produced by the thermal polymerization of …

Effect Of Graphitic Carbon Nanomodifiers On The Electromagnetic Shielding Effectiveness Of Linear Low Density Polyethylene Nanocomposites, Byron Villacorta Hernandez

All Dissertations

Conductive polymer composites have become alternative materials for providing electromagnetic and electrostatic shielding where metals are not suitable. In this study, the effect of crystallinity, morphology, concentration and orientation of carbon nanomodifiers on shielding provided by their polyethylene-based composites has been investigated relative to their transport properties.

First, the electrical properties and EM SE of composites consisting of heat-treated carbon nanofibers (Pyrograf^® -III PR-19 CNF) in a linear low density polyethylene (LLDPE) matrix were assessed. Heat treatment (HT) of CNF at 2500°C significantly improved their graphitic crystallinity and intrinsic transport properties, thereby increasing the EM SE of the nanocomposites. …

Biodegradation Of Cresols Using Pseudomonas Putida Immobilized In Poly Vinyl Alcohol (Pva) Gel, Riham Mohamed Sorkatti Abu Bakr

Theses

The characteristics and viability of polyvinyl alcohol (PVA) as a support material for biomass immobilization and utilization for the biodegradation of cresols have been evaluated. PVA gel pellets were prepared by repeated freezing-thawing method using different PVA compositions. The porous structures of the PVA pellets were examined using a Compound Microscope and SEM and revealed that the matrix structure and pore size distribution were affected by PVA composition. Mechanical properties of the PVA gel were also characterized to evaluate the PVA integrity as a matrix for immobilizing microbial cells and found to be dependent on the PVA mass composition. The …