Chemical Engineering Commons^™

Oxidation Process Of H 2 O /Uv For Cod Reduction Of Wastewater From Soybean Tofu Production, Komala Pontas, Abrar Muslim

Makara Journal of Technology

Chemical Oxygen Demand (COD) reduction of wastewater from soybean tofu production was studied by conducting advanced oxidation process (AOP) using hydrogen peroxide with UV radiation catalysts in a closed cylindrical glass reactor. The hydroxyl radical (*OH) concentration from H2O2 decomposition was modeled, and exponential trends were found for the *OH concentration over radiation time and operation temperature. As a result, it was found that the maximal *OH concentration was 0.209 mol L-1 at 240 minutes and 50 °C. The *OH concentration exponentially increased following rise in operation temperature. The H2O2/UV AOP application reduced COD concentration to approximately 42.41% from 10,545 …

Uplift Of Shoreline Regions On Pagai Island Due To The September 12, 2007 Mw 8.4 Earthquake Captured By Sar Image, Ashar Muda Lubis

Makara Journal of Technology

At least 25 people were killed by the September 12, 2007 Mw 8.4 Bengkulu earthquake, and many buildings were destroyed in Bengkulu and West Sumatra provinces. It is very important to estimate the earth surface deformation due to the earthquake to understand the rupture size and its process. The aim of this research is to estimate the shoreline change and vertical displacement on Pagai Island associated with the September 12, 2007 Mw 8.4 Bengkulu earthquake. The intensity of ALOS-PALSAR satellite images is used to access the pattern of displacement. The result shows that Pagai Island demonstrated huge uplift due to …

Effect Of Fly Ash Fortification In The Manufacture Process Of Making Concrete Towards Characteristics Of Concrete In Sulfuric Acid Solution, Asep Handaya Saputra, Muhammad Shohibi, Masatoshi Kubouchi

Makara Journal of Technology

Fly ash is a silica or alumino silica material that can be used as a constituent of cement in the concrete manufacturing process. Utilization of fly ash aims to improve durability and minimize the reduction of concrete’s compressive strength exposed to an acidic environment, which can be achieved through the pozzolanic reaction of fly ash with Ca(OH)2 within concrete. The reduced content of Ca(OH)2 through pozzolanic reaction will minimize the tendency of ettringite formation (compounds that cause deterioration and decrease the compressive strength of concrete). In order to determine the relation between fly ash replenishment into concrete with concrete’s characteristics …

Strategies For The Production Of Cell Wall-Deconstructing Enzymes In Lignocellulosic Biomass And Their Utilization For Biofuel Production, Sang-Hyuck Park, Rebecca Garlock Ong, Mariam Sticklen

Department of Chemical Engineering Publications

Microbial cell wall-deconstructing enzymes are widely used in the food, wine, pulp and paper, textile, and detergent industries and will be heavily utilized by cellulosic biorefineries in the production of fuels and chemicals. Due to their ability to use freely available solar energy, genetically engineered bioenergy crops provide an attractive alternative to microbial bioreactors for the production of cell wall-deconstructing enzymes. This review article summarizes the efforts made within the last decade on the production of cell wall-deconstructing enzymes in planta for use in the deconstruction of lignocellulosic biomass. A number of strategies have been employed to increase enzyme yields …

Heat Transfer Mechanisms In Water-Based Nanofluids., Masoudeh Ahmadi

Electronic Theses and Dissertations

Nanofluids are a class of heat transport fluids created by suspending nano-scaled metallic or nonmetallic particles into a base fluid. Some experimental investigations have revealed that the nanofluids have remarkably higher thermal conductivities than those of conventional pure fluids and are more suited for practical application than the existing techniques of heat transfer enhancement using millimeter and/or micrometer-sized particles in fluids. Use of nanoparticles reduces pressure drop, system wear, and overall mass of the system leading to a reduction in costs over existing enhancement techniques. In this work, the heat transfer coefficient is determined experimentally using copper oxide (CuO) based …

Simulation Of Lateral Migration And Sedimentation Of A Flexible Fiber In A Vertical Weak Shear Flow, Ali Ibrahim Neamah Neamah

Masters Theses

This research is a thorough numerical investigation and critical analysis of lateral migration of a deformable particle settling in a vertical weak shear flow. Under the vertical weak shear fluid, the deformable particle may move either to the coagulation area, or the dispersion area, depending on Reynolds numbers, shear Reynolds number, fiber flexibility, and aspect ratio. In this study, a lattice Boltzmann equation is used to solve Navier-Stokes equation and a flexible particle method is employed to attack the problem of motion of a flexible fiber. A bounce-back rule is used to deal with moving boundaries interacting with fluids. Several …

Targeted Products From Fast-Hydropyrolysis And Hydrodeoxygenation Of Biomass, Ian Tad Smith

Open Access Theses

Previously, the H2Bioil process was proposed as a possible way to convert sustainably available intact biomass into liquid fuels. The optimization of this process and possible synergies with other biomass conversion processes are presented in this thesis.

The selectivity of the PtMo hydrodeoxygenation catalyst was tuned using two different hydrogen partial pressures: 25 bar, and 2.5 bar. This effect was studied on cellulose and intact biomass samples to determine the effect that hydrogen has upon the retention of aromatic compounds found in intact biomass. These experiments show that it is possible for the hydrogenation activity of the PtMo catalyst to …

Sustainability Assessment For Energy Systems And Chemical Process Industries, Michael J. Matzen

Department of Chemical and Biomolecular Engineering: Dissertations, Theses, and Student Research

Sustainability has become an important factor in the chemical process and energy industries with a strong drive for process improvements towards more environmentally conscious solutions. However, there are many ways of defining sustainability and even more ways of trying to determine how sustainable a process is. This work looks into applying a conjunction of tools including; process simulation, multi-criteria decision matrices and life-cycle assessment to more quantitatively determine sustainability metrics. We have applied these tools for the production of electricity, methanol and dimethyl ether. A novel method of electricity production, in chemical looping combustion (CLC), was used that inherently involves …

Field Amplified Sample Stacking On Amyloid Beta (1-42) Oligomers Using Capillary Electrophoresis, Sadia Ali Paracha

Graduate Theses and Dissertations

According to recent literature, it is believed that the oligomeric form of amyloid beta (Aβ) is the leading cause of Alzheimer’s disease (1; 8; 10; 12-18). Additionally, recent studies have eluded to the impact of Alzheimer’s disease (AD) both economically and Socially in today’s society where an increase of about 71% of AD related deaths were recorded between 2000 and 2013 (7). Since the oligomeric forms of Aβ vary in size, shape and some believe conformation, it is vital to utilize a separation technique, such as capilllary electrophoresis (CE) to further understand Aβ aggregation. By understanding Aβ aggregation, treatment of …

Production Of Ethanol From Cereal Food Fines Using Dilute-Acid Hydrolysis, Andrew Edward Arnett

Graduate Theses and Dissertations

Cereal food fines are a leftover by-product from breakfast cereal processing that is typically sold as animal feed or used as a pet food ingredient; however this product could be of greater value as a feedstock for the production of fuel ethanol via fermentation. In order for this material to be fermented it has to be broken down in to simple sugars using hydrolysis. One method of hydrolysis is called dilute-acid hydrolysis, whereby low concentrations of acid are added to the feedstock to facilitate the breaking of chemical bonds. This study investigates the effect of different concentrations of acid to …

Formulation And Evaluation Of Soy Polymer Based, Gravure Printed Resistive Inks For Applications In Printed Electronics, Bhushan Hiralal Patil

Masters Theses

Today, the majority of the commercially available conductive inks are formulated using expensive metallic particles, such as silver and gold. Most of the inks use volatile solvents in the formulation, which are hazardous to the environment as emission of VOCs is the major concern. In the case of water-based inks, usually petroleum-based acrylic polymers are used. Apart from being nonrenewable raw materials, acrylic polymers are carcinogenic in nature. Also, acrylic polymers are used in a variety of applications, such as the automotive, medical device, paint, and adhesive industries. Often times, the ink industry has to compete with other industries for …

Evapoporometry: An Effective Analytical Technique For Membrane Pore Size Characterization Of Hollow Fiber Membranes, Alex J. Moix

Chemical Engineering Undergraduate Honors Theses

A new analytical technique called evapoporometry has shown to be an effective and inexpensive method for membrane pore size characterization. This technique is based on the correlation between vapor pressure and pore size as described by the Kelvin equation. Evapoporometry has many advantages over tradition pore size characterization techniques. This technique allows for large sample sizes, uses minimal equipment, is capable of analyzing membranes within a wide range of pore sizes, and provides a highly descriptive representation of the pore distribution. This research looks at the application of evapoporometry as a technique for characterization of hollow fiber membranes. Using the …

Hybrid Aryl-Ether-Ketone And Hyperbranched Epoxy Networks, John Misasi

Dissertations

In this dissertation, relationships between chemical structures, cure kinetics and network architectures are correlated to bulk mechanical properties for novel, hybrid epoxy-amine networks. The work is split into two primary sections: the first is the synthesis and characterization of multifunctional glassy networks based on aryl-ether-ketone diamine curatives, while the second is based on the synthesis and characterization of hyperbranched epoxy polymers and their resulting networks.

Three aryl-ether-ketone (AEK) diamines of increasing molecular weights were synthesized and used to cure 4,4’-tetraglycidylether of diaminodiphenylmethane (TGDDM); the resulting networks were compared to 4,4’-diaminodiphenyl sulfone cured TGDDM. Architectural differences were created by varying cure …

Stochastic Simulation Of Lagrangian Particle Transport In Turbulent Flows, Guangyuan Sun

Theses and Dissertations

This dissertation presents the development and validation of the One Dimensional Turbulence (ODT) multiphase model in the Lagrangian reference frame. ODT is a stochastic model that captures the full range of length and time scales and provides statistical information on fine-scale turbulent-particle mixing and transport at low computational cost. The flow evolution is governed by a deterministic solution of the viscous processes and a stochastic representation of advection through stochastic domain mapping processes. The three algorithms for Lagrangian particle transport are presented within the context of the ODT approach. The Type-I and -C models consider the particle-eddy interaction as instantaneous …

Production And Harvest Of Microalgae In Wastewater Raceways With Resource Recycling, Alexander Colin Roberts

Master's Theses

Microalgae can be grown on municipal wastewater media to both treat the wastewater and produce feedstock for algae biofuel production. However the reliability of treatment must be demonstrated, as well as high areal algae productivity on recycled wastewater media and efficient sedimentation harvesting. This processes was studied at pilot scale in the present research.

A pilot facility was operated with nine CO₂-supplemented raceway ponds, each with a 33-m² surface area and a 0.3-m depth, continuously from March 6, 2013 through September 24, 2014. The ponds were operated as three sets of triplicates with two sets continuously fed …

Modeling Of Gas Production From Shale Reservoirs Considering Multiple Transport Mechanisms, Chaohua Guo, Mingzhen Wei, Hong Liu

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Gas transport in unconventional shale strata is a multi-mechanism-coupling process that is different from the process observed in conventional reservoirs. In micro fractures which are inborn or induced by hydraulic stimulation, viscous flow dominates. And gas surface diffusion and gas desorption should be further considered in organic nano pores. Also, the Klinkenberg effect should be considered when dealing with the gas transport problem. In addition, following two factors can play significant roles under certain circumstances but have not received enough attention in previous models. During pressure depletion, gas viscosity will change with Knudsen number; and pore radius will increase when …

Design And Synthesis Of Polymer, Carbon And Composite Electrodes For High Energy And High Power Supercapacitors, Margarita Arcila-Velez

All Dissertations

Supercapacitors (SCs) are promising energy storage devices because they deliver energy faster than Li-ion batteries and store larger amounts of charge compared to dielectric capacitors. SCs are classified in electrical double layer capacitors (EDLCs) and pseudocapacitors, based on their charge storage mechanism. EDLCs store charge electrostatically, i.e. by physical charge separation. This mechanism limits the storable amount of energy to the available surface area of the electrode, typically made of carbon materials, but grants good cycling stability of the SC device. Pseudocapacitor electrodes, commonly made of conducting polymers or metal oxides, store charge faradaically, i.e. through redox reactions throughout the …

Separation Of Oil From A Brackish Water Stream, Kayli A. Quinton

Chemical Engineering Undergraduate Honors Theses

In the past 40 years, a variety of enhanced oil recovery (EOR) methods have been developed and applied to mature and mostly depleted oil reservoirs. Chemical and sonic stimulation are two enhanced oil recovery methods in which emulsions are created either as a primary or secondary effect. The resulting emulsion viscosity is considerably lower than that of dry crude thus increasing permeability of and recovery from pay zones. During Chemical enhanced oil recovery, caustic or preformed surfactants are injected into oil reservoirs, which results in flooding and periodic breakthrough of stable oil-water emulsions. The emulsions from chemical enhanced oil recovery …

Galvanic Corrosion Of Magnesium Coupled To Steel At High Cathode-To-Anode Area Ratios, Dila Ram Banjade

Theses and Dissertations

In this study, the impact of galvanic coupling of magnesium to steel on the corrosion rate, surface morphology, and surface film formation was investigated. In particular, the role of self-corrosion was quantified as previous studies showed discrepancies between model predictions and experimental results that were likely due to significant self-corrosion. This experimental study examined the corrosion of Mg coupled to steel in 5 wt% NaCl at cathode-to-anode area ratios that ranged from 5 to 27. Results showed that self-corrosion was significant and accounted for, on average, one-third of total corrosion. Moreover, self-corrosion varied with time and cathode size, and was …

Plasma Catalysis Using Low Melting Point Metals., Maria Carreon

Electronic Theses and Dissertations

Plasma catalysis is emerging as one of the most promising alternatives to carry out several reactions of great environmental importance, from the synthesis of nanomaterials to chemicals of great interest. However, the combined effect of a catalyst and plasma is not clear. For the particular case of 1-D nanomaterials growth, the low temperatures synthesis is still a challenge to overcome for its scalable manufacturing on flexible substrates and thin metal foils. Herein, the use of low-melting-point metal clusters under plasma excitation was investigated to determine the effectiveness in their ability to catalyze the growth of 1-D nanomaterials. Specifically, plasma catalysis …