Chemical Engineering Commons^™

Systematic Hazard Analysis Of Flare System Nodes In Chemical Process Safety, Hayder A. Alhameedi, Athmar A. Alzubaidi, Joseph D. Smith, Doug Allen, Saud Aldawood, Paul Ani

Chemical and Biochemical Engineering Faculty Research & Creative Works

Multidimensional consequences may arise from an accident in the flare system of any chemical or petrochemical plant due to the improperly managed flare system, which can lead to the presence of the toxic and flammable gases. The Hazard and Operability Study (HAZOP) is a systematic method used to assess and identify risks that can occur during operation, ensuring risk reduction and the safety of using equipment or units. This study aims to apply the HAZOP technique to identify the hazards associated with the gas flaring process in an air-assisted flare. The air-assisted flare system was subdivided into four sections (nodes), …

Predicting Groundwater Withdrawals Using Machine Learning With Limited Metering Data: Assessment Of Training Data Requirements, Dawit Asfaw, Ryan G. Smith, Sayantan Majumdar, Katherine Grote, Bin Fang, B. B. Wilson, V. Lakshmi, J. J. Butler

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The future of major aquifer systems supporting irrigated agriculture is threatened due to unsustainable groundwater pumping. Metering of pumping is key for implementing robust groundwater management, but metering is limited in most aquifers. Although machine learning methods have been used to estimate pumping over certain regions, these studies have not fully demonstrated the data quantity and input parameter requirements to accurately estimate regional groundwater pumping. This study determined the data quantity required and identified relevant features to develop Random Forests-based annual groundwater pumping estimates (2008–2020) over the Kansas High Plains aquifer. We predicted pumping at two spatial scales, i.e., point …

Electromagnetic Treatment Enhancing Performance Of Metal Materials: A Review, Lechun Xie, Hongxin Sun, Yan Wen, Lin Hua, Lai Chang Zhang

Research outputs 2022 to 2026

Due to the limitations of traditional metal processing methods, including high energy consumption, slow process dynamics and possible introduction of defects, electromagnetic treatment has been highlighted as a more environment-friendly and energy-efficient alternative, which can efficiently and selectively enhance material properties. This article summarizes the latest advances in electromagnetic treatment of metal materials to enhance material performance and outlooks the directions in electromagnetic treatment technology. It delves into electromagnetic field applications in manipulating the microstructure and properties. First, it explores the potential mechanisms of interaction between electromagnetic fields and metal materials, including thermal and athermal effects. Afterwards, it provides a …

Recent Advances In The Design Principles Of Lithium Selective Membranes, Shayan Abrishami, Huan Xiao, Mohsen Asadnia, Ze Xian Low, Amir Razmjou

Research outputs 2022 to 2026

The growing demand for lithium in energy storage applications has intensified the need for efficient lithium extraction technologies, with membrane processes emerging as a promising approach. Among various membrane technologies, nanostructured membranes with precisely engineered channels have shown exceptional potential for selective lithium extraction due to their ability to control ion transport at the molecular level. This review provides a comprehensive analysis of the fundamental design principles governing lithium-selective membranes, with a specific focus on nanochannel-based systems. We examine the critical parameters that influence lithium selectivity, including surface charge distribution, nanochannel dimensions, morphology, and wettability, while exploring how these factors …

A Comprehensive Review On The Recovery Of Lithium From Lithium-Ion Batteries And Spodumene, Asad Ali, Sadia Afrin, Abdul Hannan Asif, Yasir Arafat, Muhammad Rizwan Azhar

Research outputs 2022 to 2026

The growing demand for Lithium-Ion batteries (LIBs) for use within varied electronics and electric vehicles (EVs) has raised concerns about the sustainability of lithium extraction from natural deposits. This study provides a comprehensive comparison of lithium recovery through mining of spodumene deposits, and the recovery of lithium from used batteries via recycling, in terms of technological, economic and environmental impacts. Lithium recovered through mining and refining operations prompt significant land disruption and soil contamination and possess large ecological, water and carbon footprints. Contrastingly, lithium recovered through battery recycling undergoes successive heat and chemical treatments, leading to waste minimisation and a …

Temperature-Dependent Properties Of Cu-Doped Znte Thin Films Deposited On Slg Substrates Via Rf Magnetron Sputtering And E-Beam Techniques, Sherif Salah, Camellia Doroody, Fazliyana ‘Izzati Za'abar, Zheng Jie Feng, Prajindra Sankar Krishnan, Ahmad Wafi Mahmood Zuhdi, Muhammad Najib Harif, Nur Irwany Ahmad, Yap Boon Kar, Mohammad Nur-E-Alam

Research outputs 2022 to 2026

Copper doping in zinc telluride (ZnTe) thin films has been extensively studied for optoelectronic applications; however, challenges remain in optimizing temperature-dependent diffusion while minimizing defect-related emissions. Although numerous studies have explored Cu-doped ZnTe, comprehensive investigations using electron-beam (E-beam) evaporation remain limited, especially concerning its influence on diffusion dynamics, defect formation, and electrical properties. This study systematically examined Cu-doped ZnTe films fabricated via E-beam evaporation with a fixed 50 nm Cu layer deposited at three substrate temperatures (RT, 150 °C, and 300 °C), followed by rapid thermal annealing (RTA) at 100 °C and 200 °C for 1 h under a nitrogen …

Thermal Fatigue Failure Mechanisms And Enhancement Strategies Of Die Steel, Chuan De Li, Hong Yu Yang, Bai Xin Dong, De Li Chen, Shi Li Shu, Feng Qiu, Qi Chuan Jiang, Lai Chang Zhang

Research outputs 2022 to 2026

Thermal fatigue failure is the core issue that restricts the development of die-casting technology, and it directly impacts the lifespan of the dies and the resulting economic benefits. This article reviews the fundamental mechanisms of thermal fatigue failure of die steels, classifies the potential failure mechanisms and discusses them in detail. This article examines the pivotal factors that affect the thermal fatigue resistance of die steels from four perspectives: alloying elements, processing techniques, microstructure, and inherent properties. On this basis, this article summarizes the advantages and disadvantages of various methods to enhance thermal fatigue resistance, such as alloying element optimization, …

Effect Of Short-Chain Polymer Binders On The Mechanical And Electrochemical Performance Of Silicon Anodes, Fei Sun, L. Zurita-Garcia, Dean R. Wheeler

Faculty Publications

Polymer binders are crucial components in providing both mechanical support and chemical stability to the structure of porous Li-ion electrodes. Particularly in silicon anodes, the active material undergoes substantial volume expansion of up to 275%. Due to the mechanical constraint of the current collector, these silicon materials tend to expand in the normal direction while exhibiting substantial particle rearrangement and plastic deformation. Conventional rigid binders such as polyacrylic acid (PAA) and polyimide (PI), while providing satisfactory initial capacity, do not eliminate diminished long-term performance. Our research attempts to develop binder formulations that can accommodate sufficient flexibility for the substantial volume …

Design And Optimization Of Anode Catalysts For Direct Ethanol Fuel Cells: Advances And Challenges In C-C Bond Activation And Selective Modulation Of The C1 Pathway, Kai-Chi Qin, Meng-Tian Huo, Yu Liang, Si-Yuan Zhu, Zi-Hao Xing, Jin-Fa Chang

Journal of Electrochemistry

Direct ethanol fuel cells (DEFCs) are a promising alternative to conventional energy sources, offering high energy density, environmental sustainability, and operational safety. Compared to methanol fuel cells, DEFCs exhibit lower toxicity and a more mature preparation process. Unlike hydrogen fuel cells, DEFCs provide superior storage and transport feasibility, as well as cost-effectiveness, significantly enhancing their commercial viability. However, the stable C–C bond in ethanol creates a high activation energy barrier, often resulting in incomplete electrooxidation. Current commercial platinum (Pt)- and palladium (Pd)-based catalysts demonstrate low C–C bond cleavage efficiency (

Methane Partial Oxidation With Ni-Mg-Al Hydrotalcites: Impact Of Magnesium On Catalyst Performance, Dalia A. Ali Dr.

Chemical Engineering

The partial oxidation of methane (POM) is a promising route for hydrogen-rich syngas production with lower energy requirements compared to steam reforming. Herein, Ni-incorporated Mg-Al hydrotalcite- derived mixed oxide catalysts (5Ni-HT-x, x = 60, 65, 70, 75 wt.% Mg) were synthesized via co-precipitation and evaluated for CH₄ conversion and H₂ yield. Characterization techniques, including X-ray Diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), BET, H₂-TPR, TEM, FTIR, TGA, and Raman spectroscopy, were employed to investigate catalyst structure, active site stability, and carbon deposition. As a constituent of hydrotalcite-derived mixed oxides (HT), Ni2+ is strongly bound within the hydrotalcite- derived mixed oxides structure, …

Superhydrophilic Porous Coooh Nano-Architecture With Abundant Oxygen Vacancies For Enhanced Urea Electrooxidation At Ampere-Level Current Densities, Wen-Jing Lv, Xiao-Man Tang, Xue-Tong Wang, Wen-Cai Liu, Jian-Wen Zhu, Guo-Jing Wang, Yuan-Zhi Zhu

Journal of Electrochemistry

The conversion of urea-containing wastewater into clean hydrogen energy has gained increasing attention. However, challenges remain, particularly with sluggish catalytic kinetics and limited long-term stability of urea oxidation reaction (UOR). Herein, we report the loosely porous CoOOH nano-architecture (CoOOH LPNAs) with hydrophilic surface and abundant oxygen vacancies (O_v) on carbon fiber paper (CFP) by electrochemical reconstruction of the CoP nanoneedles precursor. The resulting three-dimensional electrode exhibited an impressively low potential of 1.38 V at 1000 mA·cm⁻² and excellent durability for UOR. Furthermore, when tested in an anion exchange membrane (AEM) electrolyzer, it required only 1.53 V at …

Upcycling Waste To Wealth: Cuo-Sio₂/Reduced Graphene Nanocomposite From Pomegranate Peels For One-Pot Low-Temperature Conversion Of Waste Oils Into Valuable Fatty Acid Monomers, Attia Attia, Shahenda Mahran Dr., Maria Centeno Prof., Basudeb Saha

Petroleum Engineering and Gas

and hence reduce the price of the fatty acid monomers. This study reports for the first time a novel, environmentally benign, highly active copper oxide-silica oxide/reduced graphene oxide (CuO-SiO2/RGO), heterogeneous nano-catalyst derived from waste pomegranate peels, for the one-pot, low-temperature synthesis of fatty acid monomers from high-acid-value waste vegetable oil (WVO). The synthesised nano-catalyst was extensively characterised using XRD, FT-IR, TEM, SEM, EDX and TGA-DTA. Further, it was utilised to synthesise fatty acidrich oleic phenoxypropyl acrylate (OPA) monomer from high acid value WVO via a single-step reaction.

Investigation Of Co-Current And Counter-Current Multiphase Flow In Upstream Drilling And Production Applications, Hazem Fleifel

LSU Doctoral Dissertations

In the domain of upstream Petroleum Engineering, the dynamics of co-current and counter-current multiphase flows present huge challenges, significantly impacting the efficiency of associated processes. This study investigates two specific applications concerning these flow behaviors, involving both laboratory experiments and transient computer simulations. This work investigates two distinct well control and production enhancement processes, involving multiphase flow dynamics: the bullheading kill procedure and liquid-assisted gas lift (LAGL).

The first topic (Topic 1) explores the bullheading process, a type of well control methods, by challenging the traditional understanding that gas removal efficiency increases monotonically with injection pump flow rate. Through 1D …

Boosted Electrochemical Oxidation Of Methanol At Feox/Pd/Au Ternary Nanocatalyst, Ghada El-Nowihy

Chemical Engineering

In this paper, a highly effective catalyst for methanol electrochemical oxidation (MEO) was developed by the sequential deposition of spherical gold nanoparticles (nano-Au) on a glassy carbon (GC) rod’s surface followed by palladium nanoparticles (nano-Pd), then, iron oxide nanoparticles (nano-FeOx) to form FeOx/Pd/Au/GC catalyst. The sequence of catalyst’s layers proved crucial in optimizing its performance towards MEO. Notably, FeOx/Pd/Au/GC electrode produced a remarkable enhancements in the catalytic activity (by 7 times) and stability (approximately 16 fold) when compared to those produced at Pd/GC rod. Additionally, the onset potential for MEO was significantly reduced by approximately 40 mV. Through material and …

Novel Nano-Composite Materials (Nncms) With The Designations J1, J2, And J3 For Removal Several Harmful Ions, Mohammed K. Al-Doseri, Safaa. R. Fouda, Mohamed Mossad, Mahmoud H. Mahmoud

Mansoura Engineering Journal

The most toxic material to the environment is heavy metals. remove heavy metals from wastewater is done by adsorption. Many papers have been done using different materials to take off toxic dangerous ions from wastewater. Noval Nano-composites material (NNCM)as designated as J1, J2, and J3 the most used adsorbents in this study. To conduct the experiments, synthetic wastewater was generated in the lab. Batch experiments were conducted to create the best conditions for removing these ions from the wastewater. The optimum conditions obtained were 90 min optimum contact time, and pH equal seven, optimal NNCM dose was 0.5 g/L achieving …

Equilibration And Transport Of Binary Mixtures On Planar And Porous Nanomaterials, Andrew Torres

Electronic Theses and Dissertations

We present results of a Kinetic Monte Carlo investigation of the adsorption dynamics of binary gas mixtures on planar and porous sorbents, with a focus on identifying and characterizing kinetic processes involved in uptake evolution and how they influence equilibrium conditions. We also investigate varying thermodynamic simulation parameters such as interactions, alkane lengths, partial pressures and pore configurations to determine how they impact these kinetic processes as well as equilibrium properties. This study matters both for better understanding how kinetics and equilibrium are connected and for improving practical techniques in separation applications. For planar surfaces, weak species overshoot kinetic processes …

Calcium-Ion Transport In Gel And Solid Polymer Electrolytes: From Solvent-Solute Interactions To Molecular Simulations For Next-Generation Calcium Batteries, Xinlu Wang

Dissertations - ALL

Multivalent metal-ion batteries, especially calcium (Ca²⁺) and magnesium (Mg²⁺) systems, are attractive alternatives to lithium-ion technologies owing to their high theoretical energy density, improved safety profiles, and abundant natural resources. Nevertheless, the successful commercialization of these technologies is impeded by challenges in electrolyte development, particularly related to cation solvation, ion transport efficiency, and interfacial stability. This dissertation addresses these challenges through comprehensive experimental investigations and molecular dynamics simulations of polymer-based electrolytes designed explicitly for multivalent cation conduction. In the first study, polymer gel electrolytes comprising poly(ethylene glycol) diacrylate (PEGDA) and low dielectric solvents—1,3-dioxolane (DOL) and dimethoxyethane (DME)—with calcium bis(trifluoromethanesulfonyl)imide (Ca(TFSI)₂) …

Investigating Resilience Of Cyberattack Detection Using Lyapunov-Based Economic Model Predictive Control To Data Poisoning, Helen Durand, Akkarakaran Francis Leonard

Chemical Engineering and Materials Science Faculty Research Publications

Cyberattacks may be performed on process control systems due to their integration of networking and computing with physical systems. Prior work in our group has developed detection strategies for nonlinear systems under sensor, actuator, and combined sensor and actuator attacks which can ensure, under characterizable conditions, that attacks can be detected before they cause safety issues. However, this work did not take into account the potential that an attacker could attempt to provide data to a process that causes an attack to remain undetected but that also is consistent with different process dynamics than those which the process has. This …

Response Of Dynamic Processes With Control Implemented On A Noisy Quantum Computer, Shilpa Narashimhan, Dominic Messina, Henrique Oyama, Helen Durand

Chemical Engineering and Materials Science Faculty Research Publications

A major challenge to determining the applicability (and potential outperformance over classical computers) of a quantum computer (QC) within chemical manufacturing processes is quantum noise. Computations by a QC are error-prone due to the influence of quantum noise inherent to the hardware. Errors in control inputs may destabilize a chemical process and lead to unsafe conditions for manufacturing personnel and the environment. The response of a process with control implemented on a QC to errors due to noise must be investigated thoroughly. In this work, the impacts of control input errors due to quantum noise on a process are modeled …

Heuristic Strategies For Process Stabilization Using Proportional Control Implemented By A Noisy Quantum Simulator, Keshav Kasturi Rangan, Helen Durand

Chemical Engineering and Materials Science Faculty Research Publications

Processing and storage demands of industrial processes are causing fields such as optimization, scheduling, and control to assess the effectiveness of quantum devices in their applications. A key objective of control systems is to ensure process safety. This paper focuses on the potential of quantum devices to compute control inputs that maintain system safety despite sources of nondeterminism inherent to currently available quantum devices (quantum noise). In our previous work, we employed a quantum simulator to assess whether a quantum implementation of a proportional (P) control law could stabilize a single-input/single-output system under quantum noise approximated from a real quantum …